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ISSN ………… - International Network for Bamboo and Rattan

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BAMBOO FOR PULP AND PAPER<br />

A State of the Art Review<br />

With Annotated Bibliography<br />

T.K. Dhamodaran<br />

Scientist (Wood Science)<br />

R. Gnanaharan<br />

Research Co-ordinator<br />

K. Sankara Pillai<br />

Librarian<br />

KERALA FOREST RESEARCH INSTITUTE<br />

Peechi – 680 653, Kerala, India<br />

March 2003<br />

BAMBOO FOR PULP AND PAPER<br />

A State of the Art Review<br />

With Annotated Bibliography


Kerala Forest Research Institute<br />

Peechi – 680 653, Kerala, India<br />

This report <strong>for</strong>ms part of the Consultancy project “Preparation of State of the Art Reviews (STARs) along<br />

with Annotated Bibliographies on selected topics of <strong>Bamboo</strong>s <strong>and</strong> <strong>Rattan</strong>s”.<br />

Project Co-ordinator : K. Sankara Pillai<br />

Project Leader<br />

<strong>Bamboo</strong> In<strong>for</strong>mation Centre – India<br />

OTHER STARs<br />

1. Dendrocalamus strictus<br />

2. Bambusa bambos<br />

3. Management of Natural Sympodial <strong>Bamboo</strong> St<strong>and</strong>s <strong>and</strong> Plantations.<br />

4. Collection, Conservation, Evaluation <strong>and</strong> Utilization of <strong>Rattan</strong> Germplasm.<br />

5. <strong>Bamboo</strong>s in Agro<strong>for</strong>estry Systems.<br />

This work was carried out with the financial support from the <strong>International</strong> <strong>Network</strong> <strong>for</strong> <strong>Bamboo</strong> <strong>and</strong> <strong>Rattan</strong> (INBAR)


PREFACE<br />

<strong>Bamboo</strong> is regarded as a major resource that meets the need of common people <strong>and</strong> also as a poverty<br />

alleviator due to its multi purpose uses. As a result of this, bamboo resources are of great importance in<br />

the rural socio-economy of several tropical countries. As pulp <strong>and</strong> paper being the major commercial<br />

bamboo consuming sector, it is very necessary to have an updated in<strong>for</strong>mation on the state of art related<br />

to its pulping processes <strong>and</strong> technologies <strong>for</strong> the optimal utilization of this valuable resource. It is in this<br />

context, <strong>for</strong> the proper management <strong>and</strong> utilization of bamboo <strong>for</strong> paper <strong>and</strong> pulp, the <strong>International</strong><br />

<strong>Network</strong> <strong>for</strong> <strong>Bamboo</strong> <strong>and</strong> <strong>Rattan</strong> (INBAR) assigned KFRI to prepare a State of the Art Review (STAR)<br />

on <strong>Bamboo</strong>s <strong>for</strong> Pulp <strong>and</strong> Paper.<br />

The report consists of three parts. In Part I, a brief highlights of pulp <strong>and</strong> paper making principles are<br />

dealt with, which is very essential to follow the Part II, <strong>Bamboo</strong> <strong>for</strong> Pulp <strong>and</strong> Paper. An annotated<br />

bibliography, arranged alphabetically by Author’s name is given in Part III.<br />

I sincerely thank INBAR <strong>for</strong> providing financial support <strong>for</strong> preparing the report. Dr. T.K. Dhamodaran,<br />

Scientist (Wood Science), Dr. R. Gnanaharan, Research Coordinator <strong>and</strong> Shri. K. Sankara Pillai,<br />

Librarian, KFRI, authors of this report deserve special mention <strong>for</strong> preparing an excellent report.<br />

I hope this report will equally be useful to researchers, wood, pulp <strong>and</strong> paper technologists <strong>and</strong> pulp<br />

industry <strong>and</strong> all concerned with the promotion of sustainable utilization of bamboo <strong>for</strong> pulp <strong>and</strong> paper.<br />

Peechi J.K.Sharma Ph.D<br />

March 2003 Director


ACKNOWLEDGEMENTS<br />

Our sincere thanks are due to <strong>International</strong> <strong>Network</strong> <strong>for</strong> <strong>Bamboo</strong> <strong>and</strong> <strong>Rattan</strong> (INBAR) <strong>for</strong> providing<br />

financial assistance, without which the work could not have been materialised. Thanks are due to<br />

Dr. J.K. Sharma, Director, Kerala Forest Research Institute, <strong>for</strong> his keen interest <strong>and</strong> encouragements<br />

shown in the study. We also thank Mr. K.H. Hussain, Mrs. N. Sarojam <strong>and</strong> Mr. K.F. George <strong>for</strong> their help<br />

in the bibliographic compilation. Thanks are due to Mr. B. Jithesh, Technical Assistant, Library <strong>and</strong><br />

Mrs. Sheeba Sabu, Technical Assistant, Wood Science Division of KFRI <strong>for</strong> DTP work <strong>and</strong> Mr. P.K.<br />

Thulasidas, Wood Science Division of KFRI <strong>for</strong> Technical assistance. Thanks are due to Dr. K.M.Bhat<br />

<strong>and</strong> Dr. C. Mohanan, Scientists of KFRI <strong>for</strong> editorial scrutiny.<br />

Authors


PREFACE<br />

ACKNOWLEDGEMENTS<br />

CONTENTS<br />

PART I. PULPING AND PAPER MAKING PRINCIPLES<br />

1. Introduction 1<br />

2. Early History of Pulp <strong>and</strong> Paper Production 2<br />

3. Chemical Constituents <strong>and</strong> Fibre Morphology 4<br />

3.1. Chemical constituents 4<br />

3.2 Fibre morphology 6<br />

3.3. Characterization of pulp 6<br />

4. Processes <strong>and</strong> Principles 8<br />

4.1. Mechanical pulping 8<br />

4.2. Chemical pulping 9<br />

4.3. Bleaching 21<br />

4.4. Recovery of pulping chemicals 26<br />

4.5. Paper manufacture 26<br />

PART II. BAMBOO FOR PULP AND PAPER<br />

5. <strong>Bamboo</strong>s : Distribution, Utilization , Storage <strong>and</strong> Economics 31<br />

5.1. About bamboos 31<br />

5.2. Distribution of bamboos 31<br />

5.3. History of pulp production from bamboo 32<br />

5.4. Decay while storage <strong>and</strong> control measures 34<br />

5.5. Economics of bamboo plantation 37<br />

6. Chemical composition 39<br />

7. Fibre morphology 43<br />

8. Types of pulp 47<br />

9. Pulping 49<br />

9.1. Mechanical pulping 49<br />

9.2. Chemical pulping 50<br />

9.3. Non-conventional <strong>and</strong> other pulping methods 55<br />

9.4. Effect of variables – Factors affecting pulp yield 56<br />

9.5. Effect of active alkali content 58<br />

9.6. Pulping of mixture of bamboo <strong>and</strong> hardwoods 59<br />

9.7. Effect of age, position of culm <strong>and</strong> nodes 62<br />

9.8. Optimum utilization 63<br />

i<br />

Page


10. Bleaching 65<br />

11. Beating 70<br />

12. Pulp <strong>and</strong> sheet characteristics 72<br />

13. Black liquor 77<br />

14. Types of paper 78<br />

15. Industrial experience 79<br />

16. Species suitability 83<br />

17. Appendices 99<br />

1 A. Some st<strong>and</strong>ard terms used in pulping processes 99<br />

1 B. Explanation of some general terms used in describing pulp strength properties 99<br />

2 A. Proximate chemical analysis, fibre dimensions <strong>and</strong> pulp strength of some cellulose<br />

raw materials used in paper making 99<br />

2 B. Composition of raw materials used in paper making 100<br />

3 A. Proximate chemical analysis of two important Indian bamboo species 101<br />

3 B. Variation of fibre characteristics of some Indian bamboos 101<br />

4 A. Survey of pulping processes 102<br />

4 B. Non-conventional pulping procedures<br />

5 A. Alkali consumption, kappa number, unbleached pulp yield <strong>and</strong> chemical<br />

composition of some Indian bamboos <strong>and</strong> their pulps 105<br />

5 B. Characteristics of unbleached cold-soda pulp 105<br />

5 C. Characteristics of rayon grade pulp produced from bamboos by 106<br />

M/s. Gwalior Rayons, Kerala, India<br />

6 A. Bleaching chemicals 107<br />

6 B. General conditions/ Parameters governing bleaching processes 107<br />

6 C. Symbols used to describe sequences used in multi-stage bleaching of pulps 108<br />

6 D. Common industrial bleaching sequences 109<br />

6 E. Non-established bleaching sequences 109<br />

7 Mean values of strength properties of unbeaten <strong>and</strong> beaten pulps of some<br />

Indian bamboo species 110<br />

8 The suitability of some Indian bamboos <strong>for</strong> pulp <strong>and</strong> paper 111<br />

9 A. Paper grades 112<br />

9 B. Types of commercial papers/ boards produced in India from bamboo pulp 117<br />

PART III. ANNOTATED BIBLIOGRAPHY 119<br />

Paper Mills <strong>and</strong> History of Pulp <strong>and</strong> Paper 1<br />

General Pulping <strong>and</strong> Paper Making 3<br />

<strong>Bamboo</strong> Resources <strong>and</strong> Distribution 10<br />

<strong>Bamboo</strong> <strong>for</strong> Pulp, Paper <strong>and</strong> Rayon 17<br />

Species Suitability <strong>for</strong> Pulp <strong>and</strong> Paper 27<br />

ii


Anatomy <strong>and</strong> Chemical Constituents 31<br />

Cellulose, Hemicellulose <strong>and</strong> Lignin 34<br />

Fibre Morphology <strong>and</strong> Characteristics 42<br />

Mechanical Pulping 47<br />

Chemical Pulping 48<br />

Kraft Pulping 58<br />

Rayon Grade Pulping 62<br />

Mixed Pulping 63<br />

Bleaching <strong>and</strong> Beating 65<br />

Storage of <strong>Bamboo</strong> <strong>and</strong> Pulp 69<br />

AUTHOR INDEX 75<br />

iii


PART I. PULPING AND PAPER MAKING PRINCIPLES<br />

1. INTRODUCTION<br />

Pulp is the most important product of chemical conversion of ligno-cellulosic materials. In bamboo<br />

growing countries, like India, bamboo is a main raw material <strong>for</strong> producing pulp <strong>for</strong> paper <strong>and</strong> rayon. The<br />

gap between production <strong>and</strong> requirement <strong>for</strong> paper <strong>and</strong> paper products keeps increasing with the st<strong>and</strong>ard<br />

of living is going up. The term ‘pulp’ is used generically <strong>for</strong> mechanical pulps, semi-chemical <strong>and</strong><br />

chemical pulps. Be<strong>for</strong>e dealing with the topic ‘bamboo <strong>for</strong> pulp <strong>and</strong> paper’, it is important to have a<br />

minimum underst<strong>and</strong>ing of different pulping processes. Part I deals primarily with an overview of early<br />

history, chemical constituents <strong>and</strong> fibre morphology of ligno-cellulosic material <strong>and</strong> the different<br />

processes available <strong>for</strong> producing pulp <strong>and</strong> paper. Part II deals specifically on the role of bamboo in the<br />

production of pulp <strong>and</strong> paper. Some of the st<strong>and</strong>ard terms used in pulping processes are given in<br />

Appendix 1. Part III contains the annotated bibliography.


2. EARLY HISTORY OF PULP AND PAPER PRODUCTION<br />

The invention of paper making in about AD105 belongs to the Chinese. The first papers were made to<br />

some extent from the inner bark of paper mulberry tree <strong>and</strong> to a larger extent from bamboo<br />

(Libby 1962) 7a . The principles behind the Chinese process of making paper during those days were<br />

almost the same as that employed today in the manufacture of h<strong>and</strong>-made papers, in so far as the<br />

mechanical operations of <strong>for</strong>ming the sheets are concerned. The culms of bamboo were cut near the<br />

ground <strong>and</strong> sorted into bundles according to age. The younger the bamboo, the better the quality of the<br />

paper that was made from it. The bundles were buried under of mud <strong>and</strong> water <strong>for</strong> a period of two weeks<br />

in order to soften them. Later, they were taken out, cut into small pieces, ground in mortars with a little<br />

water <strong>and</strong> pounded to a pulp with large wooden pestles. This semi-fluid mass, after being cleansed of the<br />

coarsest parts, was transferred to a tub of water, so that the whole became of sufficient consistency to<br />

<strong>for</strong>m the paper. Then, a sheet was taken up with a mould or frame, which was constructed of bamboo in<br />

small strips made smooth <strong>and</strong> round like wires, which allowed the water to drain away, leaving a sheet of<br />

felted fibres. On each side of the tub was placed a stove with an inclined top of clay. A sheet was then put<br />

on one stove by removing the edge of the mould <strong>and</strong> laying the paper flat on the stove to which it<br />

adhered. The sheet previously put on the stove was then removed <strong>and</strong> the process was repeated. A<br />

smoother paper was obtained by brushing a solution of fish glue or alum onto the sheets <strong>and</strong> polishing by<br />

rubbing them with smooth stones.<br />

The Chinese established a paper mill at Samark<strong>and</strong> sometime during the 6 th century. In AD795 the Arabs<br />

introduced the process <strong>and</strong> developed it further in their own country. The process was introduced into<br />

Europe through the crusaders, who visited Palestine <strong>and</strong> Syria during the 12 th century, <strong>and</strong> later many<br />

improvements were incorporated. France had a paper mill in Essonnes in 1189. By this time, wire had<br />

replaced the reeds <strong>for</strong> the moulds. The first paper mill in Germany was erected in 1336, <strong>and</strong> in Engl<strong>and</strong> in<br />

1498. The first paper mill in the United States was established in Philadelphia during 1696. In 1798,<br />

Louis Robert, a printer’s helper, invented a machine that would make paper in lengths of 12- 15 meters.<br />

The invention of the ‘fourdrinier’ machine during the 19 th century <strong>and</strong> the ‘cylinder’ machine during 1809<br />

marked revolutionary changes in the art of paper making.<br />

The first mill <strong>for</strong> producing full chemical pulp by the sulphite (soda) process was erected at Philadelphia<br />

during 1855. The invention of sulphate (kraft) pulping made a revolution in the manufacture of wood pulp<br />

<strong>and</strong> numerous kraft pulp mills were established. Pulping by the neutral sulphite semichemical process was<br />

employed <strong>for</strong> the production of corrugated board in the United States in 1925.<br />

2


Up to 1890, the purpose of pulp production was exclusively to furnish the paper industry. In 1892,<br />

however, Cross <strong>and</strong> Bevan discovered the xanthation of cellulose <strong>and</strong> realized the possibility of producing<br />

a regenerated cellulose fibre, rayon. The viscose process was developed <strong>and</strong> in 1903, a Norwegian<br />

sulphite mill began to deliver bleached sulphite pulp <strong>for</strong> textile purposes to Engl<strong>and</strong>. The expansion of<br />

viscose industry was marked with the possibility of utilizing kraft pulp produced by the prehydrolysis<br />

kraft process <strong>for</strong> dissolving grade pulp <strong>and</strong> the first mill <strong>for</strong> producing prehydrolysis kraft pulp was<br />

started in Germany in 1929.<br />

3


3. CHEMICAL CONSTITUENTS AND FIBRE MORPHOLOGY<br />

Even though any ligno-cellulosic material including bamboo can be pulped with suitable methods,<br />

in<strong>for</strong>mation on the chemical constitution <strong>and</strong> fibre morphology is important in deciding their technocommercial<br />

suitability as well as the method of pulping. Generally, long-fibred materials with high<br />

cellulose content, low lignin, extractives <strong>and</strong> ash contents are preferred. Fibre length influences the<br />

tearing, burst <strong>and</strong> tensile strength properties of sheets. Properties like lumen <strong>and</strong> fibre diameter as well as<br />

their ratio (flexibility coefficient) <strong>and</strong> the wall thickness are known to affect the pulp strength.<br />

3.1. Chemical constituents<br />

3.1.1. Cellulose<br />

Cellulose is the most abundant <strong>for</strong>m of the naturally occurring compounds of carbon. This <strong>for</strong>ms the<br />

principal component of the cell wall of all woods, straws <strong>and</strong> grasses (bamboo). As it is most frequently<br />

found in fibrous <strong>for</strong>m, it has got good tensile strength, <strong>and</strong> as it is insoluble in cold <strong>and</strong> hot water, it <strong>for</strong>ms<br />

an important component of pulp <strong>and</strong> paper. Cellulose is a polymeric carbohydrate, a polysaccharide with<br />

repeating units of glucose. The neighbouring glucose units are joined through carbon atoms 1 <strong>and</strong> 4.<br />

Cellulose being relatively resistant to oxidation, lignin <strong>and</strong> other colouring matters can be removed with<br />

bleaching agents without appreciable damage to the strength of pulp. The alpha or true cellulose content<br />

of a fibrous material does not affect directly its pulpability, but the higher the alpha-cellulose content of a<br />

material, the higher the yield of fully delignified, bleached chemical <strong>and</strong> semichemical pulps.<br />

3.1.2. Hemicelluloses<br />

When wood is freed from extractives (compounds which are soluble in cold water or in neutral organic<br />

solvents) <strong>and</strong> is then carefully freed from lignin, it yields a fibrous product termed holocellulose, which<br />

represents the sum total of cellulose <strong>and</strong> other polysaccharides; the latter are usually termed<br />

hemicelluloses (or polyoses). Pulping processes remove not only lignin (imperfectly) but also some of<br />

the less resistant hemicelluloses; so, holocellulose cannot be obtained by ordinary pulping operation.<br />

The hemicelluloses contain mainly sugar units other than glucose (such as xylose, mannose, arabinose,<br />

rhamnose, galactose, etc.). Usually the dominant unit in the hemicelluloses is xylose, but frequently<br />

mannose units are present in appreciable amounts, especially in the case of the hemicelluloses of<br />

coniferous woods. The hemicellulose fractions which contain xylose (<strong>and</strong> uronic acid) units are often<br />

4


termed ‘xylans’ or more loosely ‘pentosans’. Those contain mannose units linked to each other <strong>and</strong> to<br />

glucose units have been referred as ‘mannans’.<br />

The hemicelluloses (when freed from lignin) swell more than does cellulose <strong>and</strong> are in part dispersible in<br />

water. They have adhesive properties not shared by cellulose. Whereas cellulose is fibrous,<br />

hemicelluloses are non-fibrous. Whereas cellulose is quite insoluble in cold alkali, hemicelluloses are<br />

quite soluble in dilute caustic soda. In any chemical pulping operations, some of the initial hemicelluloses<br />

are retained in the pulp. A portion of the less resistant hemicelluloses is removed during digestion, <strong>and</strong><br />

their degradation products are then found in the spent liquors.<br />

In the case of pulps freed from lignin by adequate <strong>and</strong> controlled bleaching, the hemicelluloses have been<br />

shown repeatedly to contribute greatly to tensile <strong>and</strong> bursting strength <strong>and</strong> to folding endurance of the<br />

pulp sheet. Both the quantity <strong>and</strong> the type of hemicelluloses in a pulp influence the pulp properties <strong>and</strong><br />

the type of paper that can be made from such a pulp. There are certain disadvantages also about their<br />

presence. These are undesirable <strong>for</strong> dissolving grade pulp. In the case of certain bleached pulps, these are<br />

responsible <strong>for</strong> a loss in brightness of the bleached pulp on storage or aging.<br />

3.1.3. Lignin<br />

Lignin is the cementing substance between fibres <strong>and</strong> tissues <strong>and</strong> is concentrated mainly in the region of<br />

the middle lamella <strong>and</strong> imparts rigidity to wood tissue. Lignin exists in wood or bamboo as branchedchain<br />

polymer molecules. The lignin may be separated from an associated wood component either by<br />

preferentially dissolving lignin or by preferentially dissolving non-lignin components. Isolated lignins, in<br />

general, are amorphous <strong>and</strong> non-crystalline, <strong>and</strong> show definite softening points at elevated temperatures.<br />

The average molecular weight is in the range of 11,000. An important property of lignin is its capacity to<br />

absorb ultra violet light. The chemical skeleton of lignin is a phenylpropane or a “C6 – C3” or a “C9” type.<br />

Pulping is basically <strong>and</strong> mainly a delignification process employing inorganic acids or alkalies <strong>and</strong> other<br />

compounds or organic solvents <strong>and</strong> compounds or by employing biological agents such as certain fungi<br />

which will selectively attack on lignin, causing its degradation <strong>and</strong> consequent dissolution. The amount<br />

<strong>and</strong> reactivity of lignin have a marked effect on the pulpability of the material. These differ depending<br />

upon the raw material (softwoods, hardwoods, bamboos, etc.). During most pulping reactions,<br />

components other than lignin are simultaneously removed. The character of pulp depends upon the <strong>for</strong>m<br />

<strong>and</strong> amount of energy supplied <strong>for</strong> accomplishing the separation. Chemical, mechanical or a combination<br />

of the two <strong>for</strong>ms of energy are utilized. In general, when chemical energy alone is supplied, completely<br />

separated fibres are obtained; whereas in mechanical <strong>and</strong> semichemical pulping (combination of<br />

5


mechanical <strong>and</strong> chemical processing) whole fibres, fibre bundles, damaged fibres, <strong>and</strong> fibre fragments are<br />

produced. With the various methods now available <strong>for</strong> partitioning the two <strong>for</strong>ms of energy, pulps of<br />

widely diverse properties can be processed. Bleaching of pulp is also a process mainly employed <strong>for</strong><br />

further purification of the pulp by removing the remaining portions of lignin <strong>and</strong> other colour bodies in<br />

the pulp.<br />

3.2. Fibre morphology<br />

Fibre dimensions indicate the suitability of a fibrous raw material <strong>for</strong> producing pulp. Generally, the<br />

average fibre length of soft woods, hardwoods <strong>and</strong> bamboos is 3.5, 1.3 <strong>and</strong> 2.7 mm respectively. It varies<br />

within <strong>and</strong> between species as well as within trees <strong>and</strong> due to different locations. The fibre length is<br />

roughly 100 times longer than its diameter.<br />

The fibre length influences mainly pulp strength, the tearing resistance in particular <strong>and</strong> to a lesser extent,<br />

the burst, tensile <strong>and</strong> the fold. Properties like fibre diameter <strong>and</strong> lumen diameter, if considered<br />

individually, have no appreciable influence on pulp strength, but the cell wall thickness is known to<br />

improve the paper strength. Flexibility coefficient influences tensile strength <strong>and</strong>, to some extent, the<br />

burst strength also, while the relative fibre length influences tearing resistance (Siddique <strong>and</strong> Chowdhury<br />

1982) 352 . The Runkel ratio (cell wall thickness to lumen diameter) gives an indication of suitability of<br />

fibres <strong>for</strong> paper making (Runkel 1949). The values of Runkel ratio are classified into three groups.<br />

Runkel Runkel ratio values Relative thickness Remarks <strong>for</strong> paper<br />

Group<br />

of cell wall<br />

making<br />

1 Less than unity Thin Very good<br />

2 About equal to unity Medium Good<br />

3 More than unity Thick Poor<br />

Wood, bamboo <strong>and</strong> other grasses falling under Runkel group 1 <strong>and</strong> 2 are suitable <strong>for</strong> pulp <strong>and</strong> paper<br />

making, while those falling under group 3 are of poor quality <strong>for</strong> pulping.<br />

Appendix 2. A & B gives the details of chemical analysis <strong>and</strong> fibre dimensions of some commonly used<br />

cellulose raw materials including bamboo <strong>for</strong> pulp <strong>and</strong> paper.<br />

3.3. Characterization of pulp<br />

An underst<strong>and</strong>ing of pulp properties is vital <strong>for</strong> both internal control purposes <strong>and</strong> as a means of<br />

describing the pulp grade <strong>for</strong> sale. Methods of wood analysis are thoroughly discussed in the monograph<br />

6


on wood chemistry (Browning 1952) 381 . Descriptions of wood <strong>and</strong> pulp analyses are found in different<br />

publications (Sieber 1951 19a ; Merck 1957 53 ; Rydholm 1965) 70 <strong>and</strong> also in the charts brought out by the<br />

professional associations of the Pulp Industry in various countries such as the USA (TAPPI St<strong>and</strong>ards),<br />

Sweden (CCA St<strong>and</strong>ards), Germany (Merkblatt des Vereins der Zellstoff- und Papier-Chemiker und-<br />

Ingenieure), Sc<strong>and</strong>inavia (Scan- C St<strong>and</strong>ards), <strong>and</strong> by the <strong>International</strong> Committee <strong>for</strong> Cellulose Analysis<br />

(ICCA St<strong>and</strong>ards).<br />

3.3.1. Determination of residual lignin<br />

3.3.1.1. Chlorine number <strong>and</strong> permanganate / kappa number<br />

Determination of residual lignin in the pulp is the most important of all pulp analyses. It indicates the<br />

degree of delignification obtained by the cook <strong>and</strong> <strong>for</strong>ms the basis of comparison <strong>for</strong> many of the cooking<br />

results, such as yield, screenings, pulp brightness, etc. It is based on measurement of a chemical reaction,<br />

such as chlorination or permanganate oxidation. These methods are more rapid <strong>and</strong> suitable <strong>for</strong> adoption<br />

in the mills, even though they have the drawback of giving only a relative figure <strong>for</strong> the lignin content <strong>and</strong><br />

not an absolute value.<br />

Chlorine numbers are obtained by measuring the chlorine which reacts with lignin in substitution <strong>and</strong><br />

oxidation reactions. The Roe chlorine number indicates the grams of chlorine absorbed in 15 minutes at<br />

20 0 C by 100 gram pulp containing 55 gram water. Its correlation with the lignin content of the pulp is<br />

fairly straight-lined, with a factor of about 0.9 <strong>for</strong> sulphite <strong>and</strong> 0.8 <strong>for</strong> sulphate (kraft) pulps.<br />

Permanganate numbers are based on the fact that lignin is rapidly oxidised by potassium permanganate.<br />

At st<strong>and</strong>ardized conditions the excess permanganate can be determined after a certain reaction period. A<br />

figure <strong>for</strong> the permanganate consumption can thus be obtained, which is a rapid <strong>and</strong> accurate measure of<br />

the lignin content of the pulp. ICCA St<strong>and</strong>ards redefined the permanganate number as Kappa number <strong>and</strong><br />

is related to the Klason lignin content by a factor of 0.13, <strong>and</strong> to the Roe chlorine number by a factor of<br />

0.20 <strong>for</strong> sulphite <strong>and</strong> 0.16 <strong>for</strong> kraft pulp.<br />

7


4. PROCESSES AND PRINCIPLES<br />

4.1. Mechanical pulping<br />

Mechanical or groundwood process is the oldest process <strong>for</strong> converting ligno-cellulosic into pulp <strong>and</strong><br />

its invention by Keller in 1843 in Germany marked a milestone in the history of paper making.<br />

Mechanical or groundwood pulp is made either by pressing the wood against a revolving grinding<br />

stone or by passing chips through a mill, in the presence of water. The wood fibres are separated <strong>and</strong><br />

to a considerable degree fragmented. Pulp yield is very high, amounting to nearly 90 per cent of the<br />

dry–basis weight of the wood processed. Fresh mechanical pulp is light yellow in colour; it is often<br />

bleached white <strong>for</strong> the production of papers in which the yellow colour is undesirable. It finds its<br />

greatest use <strong>for</strong> newsprint, magazine papers, certain packaging papers <strong>and</strong> absorbent papers.<br />

Within the group of mechanical pulping processes (see Appendix 4A), modifications of the traditional<br />

grinding process include groundwood production with a preceding steaming step, application of<br />

chemicals, <strong>and</strong> grinding process under pressure. All processes aim at reducing power consumption<br />

<strong>and</strong> improving groundwood properties. The process which applies chemicals be<strong>for</strong>e or during<br />

grinding yields chemigroundwood (CGW). Sulphite, bisulphite solutions, kraft-like liquors, sodium<br />

hydroxide, sodium bicarbonate, etc. are used <strong>for</strong> the pretreatment which results in energy savings <strong>and</strong><br />

increased brightness of the groundwood. The use of a pressure-resistant grinding chamber at much<br />

higher temperatures yields pressure groundwood (PGW). Chemi-pressurized groundwood<br />

(CPGW) is produced by the use of 5 per cent caustic soda <strong>and</strong> 2.5 per cent hydrogen peroxide within<br />

the pressure grinder.<br />

Another modified mechanical pulping covers the refiner mechanical pulping processes. The<br />

principal characteristics of refiner mechanical pulping are the use of chips (also wafers or even<br />

sawdust) <strong>and</strong> the application of disk refiners of various types <strong>for</strong> defibration <strong>and</strong> fibrillation of the raw<br />

material. Depending on the process conditions, refiner mechanical pulping processes yield different<br />

types of pulps such as refiner mechanical pulp (RMP), chemi-refiner mechanical pulp (CRMP),<br />

pressurized refiner mechanical pulp (PRMP), <strong>and</strong> chemi-thermomechanical pulp (CTMP).<br />

The Masonite process <strong>and</strong> the Asplund process come under the refiner mechanical pulping processes<br />

but they are principally more closely related to the production of fibreboard material. In the Masonite<br />

process wood is defibred by steam explosion, per<strong>for</strong>med by a quick release of pressure (up to 70 bar)<br />

after a steam treatment of chips in a digester (‘Mason gun’) at temperatures up to 285 0 C <strong>for</strong> a few<br />

seconds. The crude fibre product is further refined <strong>and</strong> screened. The Asplund process is the first<br />

thermomechanical process, applying steam at high temperature <strong>and</strong> disk refining under pressure; thus<br />

it <strong>for</strong>ms the basic procedure of the thermomechanical pulping.<br />

8


The most important industrial refiner mechanical pulping process today is the thermomechanical<br />

pulping (TMP). The process involves an impregnation <strong>and</strong> preheating step of washed wood chips<br />

with saturated steam under pressure. The preheated chips are fed to the disk refiner <strong>for</strong> defibration at<br />

approximately the same temperature <strong>and</strong> pressure as in the preheating stage. The secondary refining<br />

stage is generally carried out at atmospheric pressure. There<strong>for</strong>e, the defibred material is exp<strong>and</strong>ed<br />

into a cyclone where the steam is removed, <strong>and</strong> refined in one or two stages to the desired freeness.<br />

The rejects from screening <strong>and</strong> cleaning are thickened <strong>and</strong> recycled to the refining step or separately<br />

refined. The TMP process yields 91-98 per cent pulp which has a lower brightness than groundwood<br />

pulp.<br />

In the chemimechanical process (CMP), mechanically destructed chips are impregnated with<br />

alkaline peroxide liquor (NaOH/H2O2) at 40-60 0 C at atmospheric pressure <strong>for</strong> 1.5–2 hrs be<strong>for</strong>e lowconsistency<br />

(5%) refining.<br />

Air pollution problems in mechanical pulping are less significant than in chemical pulping. However,<br />

RMP, TMP <strong>and</strong> particularly CRMP <strong>and</strong> CTMP processes cause mill effluents with considerable<br />

amounts of extractives.<br />

The world-wide increase in the application of mechanical, thermomechanical <strong>and</strong> chemimechanical<br />

pulping processes to produce pulps from non-wood fibre sources including bamboo is described<br />

extensively by Misra (1980) 521 .<br />

4.2. Chemical pulping<br />

Chemical pulping employs chemical reagents to effect a separation of the cellulose fibres from other<br />

wood components. Wood chips are cooked with suitable chemicals in aqueous solution, usually at<br />

elevated temperatures <strong>and</strong> pressures. The objective is to dissolve the lignin <strong>and</strong> other extraneous<br />

compounds, leaving the cellulose intact <strong>and</strong> in fibrous <strong>for</strong>m. This objective can be realised to a<br />

commercially satisfactory degree through the use of chemical reagents, although there is an<br />

appreciable dissolution of carbohydrate material <strong>and</strong> degradation of cellulose. Pulp yields are usually<br />

about 50 per cent of the wood weight. Because the chemical processes consume relatively large<br />

quantities of inorganic chemicals such as alkalies, paper makers devised methods <strong>for</strong> reagent chemical<br />

recovery from the spent cooking liquor; recovery has remained an integral part of chemical pulping.<br />

Environmental <strong>and</strong> economical concerns necessitated chemical recovery as a very important part of<br />

chemical pulping.<br />

9


4.2.1. Alkaline pulping processes<br />

The soda process <strong>and</strong> the sulphate(or kraft) process are the two principal alkaline pulping techniques<br />

<strong>and</strong> the basis <strong>for</strong> several modified alkaline processes, including kraft pulping after a prehydrolysis<br />

step <strong>for</strong> the production of dissolving pulp. Sodium hydroxide is the principal cooking chemical in<br />

both processes, while in sulphate pulping sodium sulphide is an additional pulping component. Both<br />

processes received their names from the regeneration chemicals used to compensate <strong>for</strong> the loss of<br />

sodium hydroxide, namely sodium carbonate (soda) <strong>and</strong> sodium sulphate, respectively.<br />

4.2.1.1. Soda process<br />

Soda process, the first process to manufacture chemical pulp, was invented by Hugh Burgess in 1851,<br />

employed caustic soda (sodium hydroxide) solution <strong>for</strong> cooking. The soda pulp is of relatively low<br />

strength <strong>and</strong> use of the process is limited to manufacture of filler pulps from hardwoods, which are<br />

then mixed with a stronger fibre <strong>for</strong> printing papers.<br />

4.2.1.2. Kraft (sulphate) process<br />

In 1884, a German chemist, Karl F. Dahl employed sodium sulphate in place of Sodium carbonate<br />

(soda ash) the chemical recovery system. This substitution produced cooking liquor that contained<br />

sodium sulphide along with caustic soda. Pulp so produced was stronger than soda pulp <strong>and</strong> was<br />

called kraft pulp, so named from the German <strong>and</strong> Swedish word <strong>for</strong> ‘strong’ <strong>and</strong> the process is<br />

termed as kraft process. The process is also termed as sulphate process because of the use of sodium<br />

sulphate (salt cake) in the chemical makeup. Sulphate, however, is not an active ingredient of the<br />

cooking liquor. The term ‘sulphate process’ is perhaps a misnomer, or at least misleading, as it might<br />

cause one to suspect that sulphate rather sulphide is used in the actual cooking. Almost any species of<br />

wood can be pulped by the sulphate process, which may be considered practically a universal pulping<br />

process. Resins or pitch, if present, are all readily saponified in the alkali employed <strong>and</strong> are<br />

chemically altered <strong>and</strong> dissolved in the kraft process. This material is removed from the pulp <strong>and</strong><br />

becomes a valuable by-product. Bark <strong>and</strong> knots yield to kraft cooking, lignin is easily removed, <strong>and</strong><br />

cellulose remains relatively stable. Kraft pulp, however, was dark in colour <strong>and</strong> was difficult to<br />

bleach. For many years, the growth of the process was slow because of its limitation to papers in<br />

which colour <strong>and</strong> brightness were unimportant. In the 1930s, with the discovery of new bleaching<br />

techniques, bleached kraft pulp became commercially important. The availability of pulp of high<br />

whiteness <strong>and</strong> the exp<strong>and</strong>ing dem<strong>and</strong> <strong>for</strong> unbleached kraft in packaging resulted in rapid growth of<br />

the process, making kraft process the predominant wood-pulping method. Many soda mills were<br />

converted to adopt kraft process because of the greater strength of the pulp. A liquor- recovery system<br />

is always an essential part of kraft pulping. The dissolved organic constituents in the spent pulping<br />

10


liquors are burned <strong>for</strong> steam generation or some, like the turpentine <strong>and</strong> tall oil are recovered, <strong>and</strong> the<br />

inorganic pulping chemicals are recovered <strong>and</strong> reused.<br />

In the kraft cooking operation, wood chips are prepared <strong>and</strong> fed to digesters. These huge cylindrical<br />

towers have a number of zones or compartments. Wood chips <strong>and</strong> cooking liquor are fed into the top<br />

<strong>and</strong> injected into successive zones of high pressure <strong>and</strong> temperature, where impregnation <strong>and</strong> cooking<br />

takes place as the chips progress downward. Additional zones wash the spent liquor from the chips. In<br />

batch cooking, after the digester is charged with chips, a mixture of “black liquor”, the spent liquor<br />

from a previous cook, <strong>and</strong> “white liquor”, a solution of NaOH <strong>and</strong> sodium sulphide from the chemical<br />

recovery plant, is pumped in. The digester is heated either by direct injection of steam or by the<br />

circulation of cooking liquor through a heat exchanger. After completion of the cook, the contents of<br />

the digester are blown to a blowpit by rapid opening of valve. The violence of the blow defibres the<br />

cooked chips. The spent cooking liquor is washed from the pulp; the later is then screened <strong>and</strong> sent to<br />

the bleach plant or directly to the paper mill if it is to be used unbleached. Some of the spent liquor<br />

(black liquor) is used <strong>for</strong> an admixture with white liquor to charge new cooks; the remainder is sent to<br />

the recovery plant to reconstitute cooking chemicals. The quantity of sodium present in the black<br />

liquor is such that its re-use is economically necessary.<br />

4.2.1.3. Prehydrolysis kraft pulping<br />

For dissolving grade pulp, the purity of kraft pulps is insufficient. Purification of kraft pulps is<br />

difficult since the impurities are rendered alkali-stable during the kraft cook. There<strong>for</strong>e, an entirely<br />

different method has been applied to make kraft pulps of sufficient reactivity <strong>for</strong> dissolving purposes,<br />

namely prehydrolysis prior to kraft cooking. This consists of treatment at fairly low temperature with<br />

concentrated acids, at intermediate cooking temperature with dilute acids or high cooking temperature<br />

with water only. A considerable part of the hemicelluloses <strong>and</strong> fairly little cellulose are hydrolysed to<br />

shorter chains, part of which dissolve in the cooking liquor together with a limited fraction of acidsoluble<br />

lignin. In the subsequent kraft cook the main delignification reaction takes place. The net<br />

result of the two-stage prehydrolysis- kraft cook is there<strong>for</strong>e a high-alpha pulp of reduced yield. The<br />

yield, as well as the alphacellulose content, is very much dependent on the extent of prehydrolysis.<br />

About 87- 97 per cent alphacellulose content can be achieved by this process.<br />

4.2.1.4. Anthraquinone as an additive in alkaline pulping<br />

The use of anthraquinone (AQ) as an additive in the alkaline pulping processes is found to have the<br />

benefits of increased delignification rates as well as reduced alkali charges <strong>and</strong> improved pulp<br />

properties <strong>and</strong> yields. AQ acts as a redox catalyst in the liquor system.<br />

11


By addition of 0.05 per cent AQ, the cooking time is reduced by 25-35 per cent <strong>and</strong> the alkali charge<br />

by 5 per cent while yields increase by 1.5-3 per cent at the same residual lignin level <strong>and</strong> comparable<br />

strength properties are obtained as in conventional kraft pulping (Goel et al. 1980).<br />

4.2.1.5. Sulphite process<br />

The ‘sulphite process’ was invented during 1857 by an American chemist, B.C. Tilghman who<br />

observed the effect of sulphurous acid in softening wood. He obtained cellulose fibres by treating<br />

wood with bisulphite–sulphurous acid solutions under high temperature <strong>and</strong> pressure. The base used<br />

was calcium <strong>and</strong> later magnesium. Sodium <strong>and</strong> ammonium are also used as base, which are having<br />

advantages in liquor-recovery operations. Sulphite pulps are relatively light in colour, are easily<br />

bleached to a high-white colour, have moderately good strength properties. Sulphite pulp is almost<br />

pure cellulose <strong>and</strong> is used in fine papers.<br />

4.2.2. Semichemical pulping<br />

Semichemical pulping processes are characterised in principle by a chemical treatment preceded by a<br />

mechanical refining step <strong>for</strong> defibring or fibrizing. This general definition also applies to the<br />

chemimechanical processes <strong>and</strong> the high-yield chemical pulping processes such as the sulphite <strong>and</strong><br />

kraft. It is more suitable to hardwoods.<br />

The chemical treatment in semichemical <strong>and</strong> chemimechanical pulping can be effected with reagents<br />

like sodium sulphite, caustic soda, <strong>and</strong> kraft liquor. The sodium sulphite is usually buffered to near<br />

neutrality with sodium carbonate or bicarbonate or kraft green liquor.<br />

The most important semichemical process is undoubtedly the neutral sulphite semichemical (NSSC)<br />

process. The general advantages of the NSSC process are low requirements with regard to wood<br />

quality <strong>and</strong> species, high yields, relatively low consumption of chemicals at a given residual lignin<br />

content, low capital investment <strong>and</strong> profitable small production units as compared to full chemical<br />

pulping. Besides single hardwoods <strong>and</strong> hardwood mixtures, mixtures of hardwoods <strong>and</strong> softwoods<br />

can also be pulped successfully with the NSSC process. NSSC pulping is also used <strong>for</strong> non-wood<br />

plants <strong>and</strong> residues because of the generally low lignin contents of these materials <strong>and</strong> the widely<br />

variable conditions offered by the NSSC pulping.<br />

The principal process involves impregnation with a neutral sodium sulphite pulping liquor at about<br />

125 0 C <strong>for</strong> an hour under pressure after a short steaming of the chips at atmospheric pressure,<br />

followed by cooking at temperatures between 160 <strong>and</strong> 190 0 C, depending on the cooking time, which<br />

may vary between 15 minutes <strong>and</strong> 8 hours, which again depending on the type of digester used <strong>and</strong><br />

12


the desired pulp type <strong>and</strong> quality. Defibration is carried out by means of single or multi-stage<br />

refinement process using disk refiners.<br />

The lignin content of the NSSC pulps is high as compared to those from chemical pulps, <strong>and</strong> ranges<br />

between 10 <strong>and</strong> 15 per cent. Due to the high lignin <strong>and</strong> polyoses content the NSSC pulp has low<br />

conventional strength properties. The typical NSSC pulp is normally much more rigid <strong>and</strong> stiff than<br />

kraft pulp. There<strong>for</strong>e, it is the most typical <strong>and</strong> suitable fibre material <strong>for</strong> the production of<br />

corrugating medium.<br />

The caustic soda in the soda semichemical process reacts with the lignin-carbohydrate complex to<br />

<strong>for</strong>m soluble sodium lignate, <strong>and</strong> the carbohydrates are solubilized by hydrolysis. However, this lignin<br />

reaction occurs only after a major portion of the caustic soda has been consumed in neutralizing the<br />

readily available acetyl <strong>and</strong> methoxyl groups <strong>and</strong> in hemicellulose dissolution. There<strong>for</strong>e, lignin<br />

removal is the least in alkaline semichemical pulping.<br />

The cold-soda or cold caustic process, which is less important than the NSSC process, involves in<br />

principle, the treatment of chips with a sodium hydroxide solution at temperatures generally between<br />

20 <strong>and</strong> 30 0 C <strong>and</strong> a final refiner defibration. In the cold-soda chemimechanical pulping, the caustic<br />

soda attacks the fibre bond mainly by reaction with the acetyl <strong>and</strong> other acid groups, which are<br />

reactive even at room temperature. The most important step in the cold-soda pulping is the<br />

impregnation with alkaline liquor to reach a very fast but total penetration of the chips, causing the<br />

necessary swelling of fibres <strong>and</strong> avoiding considerable losses of polyoses. Impregnation times are<br />

between 15 <strong>and</strong> 120 minutes with generally short reaction times of 15-30 minutes in pressurized <strong>and</strong><br />

continuous systems. The concentrations of NaOH are generally low (0.25–2.5%), but up to 10 per<br />

cent in the case of some roller mill impregnation systems. Cold-soda pulping requires little installation<br />

capital, <strong>and</strong> despite the cost of the chemicals, the processing costs are actually lower than in stone<br />

grinding, because of reduced energy consumption. In some process modifications the liquor is reused<br />

up to 20 times.<br />

The cold-soda pulp yield ranges between 85 <strong>and</strong> 92 per cent, whereby the selectivity of lignin <strong>and</strong><br />

polyoses dissolution is much lower than NSSC pulping. The main disadvantage of cold-soda pulps is<br />

a generally a low brightness level (40-50%), which can be effectively increased by a two-stage<br />

peroxide-hypochlorite bleaching.<br />

As the cold-soda pulps have properties comparable to NSSC pulps, these are used as unbleached<br />

coarse grades <strong>for</strong> corrugating medium production, <strong>and</strong> as bleached grades <strong>for</strong> printing papers <strong>and</strong><br />

newsprint in combination with groundwood pulp <strong>and</strong> chemical pulp.<br />

13


In the kraft semichemical process, the reactions of kraft liquor are similar except thiolignin is<br />

<strong>for</strong>med <strong>and</strong> dissolved. Because of the buffering nature of the sodium sulphhydrate in the kraft liquor,<br />

attack on the hemicelluloses <strong>and</strong> cellulose is less in the kraft than in the soda process.<br />

In the acid sulphite <strong>and</strong> bisulphite semichemical pulping, the delignification reaction predominates<br />

under acid conditions. As with the NSSC process, the mechanism of delignification probably involves<br />

sulphonation of the lignin of the middle lamella in the solid state, followed by hydrolysis to soluble<br />

lignosulphonic acid <strong>and</strong> carbohydrates. The hemicelluloses are less dissolved in these acid procedures<br />

than in the others.<br />

In the sulphite chemimechanical pulping, the neutral or acid sodium sulphite solutions dissolve<br />

mainly carbohydrates. The relatively high temperatures employed have an important weakening effect<br />

on the fibre bond. The material from the chemical stage may be partially disintegrated <strong>and</strong> defibred<br />

through the mechanical action of digester discharging, conveying, or deliquoring. The first action in<br />

the defibring–refining machine is probably heating the fibre bond <strong>and</strong> further weakening it to the<br />

point that it will split. Temperature is an important factor in fibrizing semichemically softened fibrous<br />

material. The second action in the mechanical state is the actual disintegration of the fibre aggregates<br />

<strong>and</strong> separation into individual fibres. The third action in the fibrizing zone of the machine, which is<br />

generally superimposed on the defibring action, is the refining or processing of the individual fibres to<br />

prepare them <strong>for</strong> papermaking. This action, which largely involves fibrillation, softening, <strong>and</strong><br />

<strong>for</strong>mation of colloidal, mucilage-like surfaces, is <strong>for</strong> the purpose of stock preparation as with any<br />

other type of pulp. The actions occurring during the mechanical part of semichemical pulping may<br />

take place in one or more stages or passes. This is determined by a number of factors including the<br />

kind of fibrous material <strong>and</strong> its particle size, the degree <strong>and</strong> kind of chemical treatment, <strong>and</strong> the<br />

requirements <strong>for</strong> papermaking.<br />

The semichemical pulps have chemical <strong>and</strong> strength properties intermediate between groundwood <strong>and</strong><br />

full chemical pulps. The brightness of these pulps varies from 35 to 55 per cent which can be<br />

improved to 80 to 85 per cent by multi-stage bleaching. The semichemical pulps are characterized by<br />

their high lignin <strong>and</strong> hemicellulose (pentosans) contents.<br />

4.2.2.1. High-yield chemical pulping<br />

There is no clear border line between semichemical pulping <strong>and</strong> the so-cold high-yield chemical<br />

pulping, or between the resulting pulps. From a practical aspect, many high-yield chemical pulps are<br />

more or less semichemical pulps with regard to their yields (55-70% <strong>and</strong> even higher) <strong>and</strong> typical<br />

process design (disk refining after the chemical treatment).<br />

14


High-yield chemical pulps are obtained in principle by modified sulphite <strong>and</strong> sulphate processes; by<br />

applying reduced charges of chemicals <strong>and</strong> / or reduced cooking time <strong>and</strong> temperature, <strong>and</strong> a refining<br />

step after cooking. High-yield sulphite pulps are produced by an acidic sulphite, bisulphite or<br />

alkaline sulphite process. In high-yield acid sulphite pulping (with calcium, magnesium or sodium<br />

bases) the reaction rate is usually decreased by cooking at lower temperatures (120-130 0 C) <strong>and</strong> with<br />

lower acidity of the liquor, i.e, less sulphur dioxide, than in full chemical sulphite pulping. Common<br />

yields of unbleached pulps are between 60 <strong>and</strong> 70 per cent. High-yield acidic sulphite pulps are often<br />

produced in newsprint sulphite mills, saving up to 30 per cent of wood compared with full chemical<br />

pulps. The pulps are mainly used as newsprint furnish in mixtures with groundwood <strong>and</strong> chemical<br />

pulp. Generally the strength values (except burst strength) <strong>and</strong> the freeness are lower than those of<br />

comparable full chemical pulps.<br />

In high-yield bisulphite pulping, the cooking liquor has no excess of sulphur dioxide <strong>and</strong> the<br />

maximum cooking temperature is somewhat higher than that in acidic sulphite pulping. The preferred<br />

bases are sodium <strong>and</strong> magnesium. High-yield bisulphite pulps are generally used in the same fields as<br />

acidic sulphite pulps (eg., in newsprint).<br />

High-yield alkaline sulphite pulping, a modification of alkaline sulphite pulping, is becoming an<br />

increasingly interesting alternative to the kraft process. The cooking liquor is buffered between pH 9<br />

<strong>and</strong> 12, containing sodium sulphite, sodium carbonate, sodium hydroxide <strong>and</strong> sodium sulphide. The<br />

yields lie around 60 per cent <strong>and</strong> the pulp is brighter than normal kraft pulp. Due to its good strength<br />

properties, the pulp is useful as linerboard.<br />

In high-yield kraft or sulphate pulping, the typical karft process is modified either by reducing the<br />

charge of chemicals by about one-half or by decreasing the cooking time <strong>and</strong> temperature. The yields<br />

are generally between 55 <strong>and</strong> 65 per cent, but even up to 80 per cent are also possible. Usually highyield<br />

kraft pulps have lower strength values <strong>and</strong> are darker than normal kraft pulps <strong>and</strong> NSSC pulps.<br />

The process is used <strong>for</strong> both hardwoods <strong>and</strong> softwoods.<br />

A survey of different pulping procedures is given in Appendix 4.A.<br />

4.2.3. Dissolving or Rayon grade pulping<br />

The chain-like high molecular weight cellulose polymer can be trans<strong>for</strong>med into fibres or films of<br />

desired properties by spinning, casting, rolling, or extruding, from a melt or from solution. The<br />

natural, renewable polymer cellulose frequently occurs as fibres that are too short <strong>for</strong> textile uses. It<br />

cannot however be converted directly into longer fibres or into film because it can neither be melted<br />

nor simply dissolved in a solvent owing to strong hydrogen bonding in the material. A suitable<br />

15


cellulose derivative must first be prepared be<strong>for</strong>e it is possible to <strong>for</strong>m a spinning solution from which<br />

cellulose can be regenerated. The commercially used systems <strong>for</strong> this purpose are the viscose process<br />

<strong>and</strong>, to a lesser extent the cuprammonium (Bemberg) process, <strong>and</strong> the acetate process.<br />

The starting material <strong>for</strong> the preparation of cellulose solutions via complex <strong>for</strong>mation or derivatization<br />

must be a cellulose of high purity <strong>and</strong> good processability. Refined wood pulp or the so-called<br />

dissolving pulp (also termed as chemical conversion pulp, alpha pulp, rayon grade pulp, etc.) is used<br />

<strong>for</strong> the manufacture of rayon, cellophane, plastics, films, explosives <strong>and</strong> other cellulose derivatives,<br />

etc. The main requirements of a dissolving pulp are good processability (especially good<br />

filterability), high-yield, <strong>and</strong> a good overall economy.<br />

The production of dissolving pulp from materials having high silica <strong>and</strong> pentosan content is<br />

complicated. The removal of pentosans can be accomplished by conventional methods, i.e., by acid<br />

hydrolysis during sulphite cooking or by acid prehydrolysis followed by kraft cooking. The<br />

difficulties with silica can be partly overcome with repeated hot <strong>and</strong> cold alkali purifications (Jame<br />

<strong>and</strong> Scheuring 1953). The general minimum requirements <strong>for</strong> a viscose dissolving pulp <strong>for</strong> producing<br />

bulk products are listed below :<br />

Alpha-cellulose : >89%<br />

Solubility in 5% NaOH :


4.2.4. Non-conventional pulping processes<br />

The non-conventional pulping processes include well-known pulping principles, which are, however,<br />

only rarely applied commercially. Their industrial application is often limited by high costs of<br />

chemicals <strong>and</strong> special equipment requirements. However, they posses the advantage of more<br />

environmental friendliness techniques. Appendix 4B gives a survey of different non-conventional<br />

pulping procedures. Pulping via sodium-xylene sulphonate, aqueous ethanol, ketone-ammonia<br />

mixture, ethanol amine, peracetic acid, oxygen-alkali, etc., are some of the ef<strong>for</strong>ts to develop pollution<br />

free pulping processes. Among the various processes, some commonly referred methods are described<br />

below :<br />

4.2.4.1. Ethanol-water pulping<br />

Aqueous ethanol is a powerful delignifying agent. Retention of lignin is strongly dependent on pH of<br />

the cooking liquor. After distilling off the alcohol from ethanol-water black liquor, a major fraction of<br />

the solubilized lignin separates as a quasi-molten phase.<br />

4.2.4.2. Hydrotropic pulping<br />

Certain substances which are only slightly soluble in water become more soluble in the presence of<br />

certain salts known as hydrotropic salts. These are salts of organic acids which have a large organic<br />

group <strong>and</strong> are themselves soluble in water. It has been shown that a near-saturated aqueous solution of<br />

sodium xylen sulphonate at approximately 70 0 C, will dissolve large quantities of lignin. These salts<br />

appear to act as catalysts. As they are not consumed, they can be recovered unchanged <strong>for</strong> reuse. Also<br />

they hydrolyse wood or straw at a much faster rate than the chemicals used in other processes of pulp<br />

making. In pulping with sodium xylene sulphonate, cooking could be accomplished in shorter time<br />

<strong>and</strong> at lower temperature than with other st<strong>and</strong>ard processes. For most woods the composition of the<br />

hydrotropic cooking solution is approximately one third salt <strong>and</strong> two thirds water; the solution is<br />

adjusted to a slightly acid pH (3.5). A typical cook, <strong>for</strong> paper bags takes 2-3 hrs. at 145 0 C <strong>and</strong> 4 bar<br />

pressure. At the end of the cook, the solution is filtered from the pulp <strong>and</strong> reused half a dozen times<br />

<strong>for</strong> other cooks. The solution is then diluted with warm water (40- 60 0 C) to a salt concentration of 8-<br />

10 per cent <strong>for</strong> precipitating the lignin. The lignin is removed by filtration <strong>and</strong> the solution is<br />

evaporated until the concentration of sodium xylenesulphonate is nearly 30 per cent; at this stage the<br />

solution can once again be used <strong>for</strong> cooking. The solution is nonscaling <strong>and</strong> noncorrosive <strong>and</strong> free<br />

from objectionable odour. The pulp is pressed to a consistency of about 40 per cent, washed free of<br />

the remaining hydrotropic salt. The properties of the pulp fall between those of an acid sulphite <strong>and</strong> an<br />

alkaline kraft pulp. The yield is 10 per cent higher <strong>and</strong> gives a high white colour in the usual<br />

bleaching processes.<br />

17


4.2.4.3. Nitric acid pulping<br />

The nitric acid pulping process consists of a two- stage pulping operation. In the first stage nitric acid<br />

is used to remove the lignin <strong>and</strong>, to a lesser degree, the pentosan <strong>and</strong> other non-cellulosic materials<br />

without damaging the cellulose fibre. The chemical reactions involved are nitration, oxidation <strong>and</strong><br />

hydrolysis. The second stage consists of an alkaline extraction of the nitrolignin residues encrusting<br />

the cellulose fibre. I to 4 per cent sodium or ammonium hydroxide is normally used to dissolve <strong>and</strong><br />

disperse these residues.<br />

Although high-yield pulps (45- 52%) displaying good physical strength properties intermediate<br />

between kraft <strong>and</strong> sulphite pulps have been obtained under a wide range of pulping conditions, the<br />

high cost of the acid, which must be used in relatively large concentrations (52%) <strong>and</strong> lack of an<br />

efficient recovery system caused a bottle-neck <strong>for</strong> commercial adoption of this process on a wide<br />

scale.<br />

4.2.4.4. Peracetic acid pulping<br />

Lignin degradative oxidation is used in the pulping process with peracetic acid. This reagent<br />

selectively delignifies <strong>and</strong> gives pulp in high yield but requires large amounts of expensive chemicals<br />

<strong>and</strong> there<strong>for</strong>e not economical.<br />

4.2.5. Sulphur free chemical pulping processes<br />

Environment protection concerns led to the development of sulphur free chemical processes as<br />

alternatives to sulphite <strong>and</strong> kraft pulping. Non-sulphur alkaline pulping covers delignification<br />

procedures such as, two-stage soda-oxygen process, single-stage oxygen process, <strong>and</strong> the alkaline –<br />

AQ-peroxide process.<br />

The two-stage soda-oxygen pulping process involves a high-yield soda cook, followed by a<br />

mechanical defibration <strong>and</strong> a concluding oxygen bleaching in alkaline medium. The cooking stage has<br />

the greatest influence on final pulp yields <strong>and</strong> properties. The yield after the cooking stage should be<br />

in the range of 60-65 per cent to reach high final yields after the bleaching procedure, <strong>and</strong> to achieve<br />

optimal refining conditions with regard to energy input <strong>and</strong> fibre protection. The yields of bleached<br />

pulps are comparable to kraft pulp yields, while the strength properties are somewhat lower. A<br />

practical aspect of this process is the fact that it can run in established kraft pulp digestion <strong>and</strong><br />

recovery equipment with an added refining section <strong>and</strong> an oxygen bleaching plant.<br />

In the single-stage oxygen pulping process, the delignification is carried out in slightly alkaline<br />

solutions (pH 7-9) of sodium hydroxide, sodium carbonate or hydrogen carbonate (also in the<br />

18


presence of hydrogen peroxide) at 140-150 0 C <strong>and</strong> high oxygen pressures in the range of 20-40 bar.<br />

The pressure cooking is carried out at low consistency to maintain the temperature level. To avoid<br />

insufficient oxygen penetration into the wood very thin chips (< 1.5 mm) must be used. The pulps are<br />

generally obtained in high yields <strong>and</strong> good brightness, but the strength properties are usually not<br />

comparable to those of kraft pulps. Strength improvements can be obtained by sodium hydrogen<br />

carbonate pre-cooking, increasing the carbon dioxide content in the gas phase, <strong>and</strong> by addition of<br />

potassium iodide or other metal compounds as cellulose protectors (Fujii <strong>and</strong> Hannah 1978).<br />

In the alkaline–AQ-peroxide process, delignification is carried out in two stages with a refining step<br />

in between. The first stage is a high-yield soda-AQ cook down to kappa numbers of 50-60. The<br />

second delignification step is per<strong>for</strong>med as a medium to high consistency (>10%) hydrogen peroxide<br />

bleaching (


commune (Ramaswami <strong>and</strong> Ramanathan 1989) 66 . Currently the time required after treatment is in<br />

the order of days <strong>and</strong> can be reduced with the identification of right strains <strong>and</strong> other treatment<br />

conditions. The treatment can be done either during transport or storage in the yard.<br />

4.2.7. Effect of process variables <strong>and</strong> conditions on pulping<br />

The end results of pulping, as measured by pulp yield <strong>and</strong> quality, are affected by the variables<br />

controlling the chemical as well as mechanical stages of the process. The physical <strong>and</strong> chemical<br />

characteristics of the fibrous material, its state of sub division, the composition of the pulping liquor,<br />

the amount of chemical applied, <strong>and</strong> the time <strong>and</strong> temperature of pulping are some of the variables<br />

affecting the chemical processing stage. An increase in temperature results in an increase in the rate of<br />

pulping <strong>and</strong> a decrease in pulping time <strong>for</strong> a given degree of delignification. Vroom (1957) 434<br />

developed the concept of ‘H factor’ – a means of expressing cooking time <strong>and</strong> temperature as a single<br />

variable. The penetration of the cooking liquor into the fibrous material is an important dependent<br />

variable. The mechanical stage is affected by the properties of the materials from the chemical stage<br />

<strong>and</strong> its subdivision, the slurry consistency, the temperature, the number of passes, <strong>and</strong> the design of<br />

the machine <strong>and</strong> its elements.<br />

Since small chips are more easily penetrated with the pulping chemical than large ones, the <strong>for</strong>mer are<br />

particularly favoured. It is recommended to use chips having a dimension of 20-30mm in the grain<br />

direction in full chemical pulping as against 10-13mm <strong>for</strong> semichemical pulping. Chips reduced<br />

laterally to matchstick dimensions by hammer or disk mills are used to some extent.<br />

4.2.8. Yields of various pulping processes<br />

A classification of pulping processes based on present- day terminology <strong>and</strong> showing the relations <strong>and</strong><br />

overlappings with respect to yields is given below (McGovern 1962) 414 :<br />

Sl<br />

No.<br />

Process Yield (%)<br />

1 Mechanical (groundwood) : 90-95<br />

2 Chemigroundwood : 85-90<br />

3 Chemimechanical<br />

- Cold-soda, sodium sulphite, bisulphite : 85-95<br />

4 Semichemical<br />

- Neutral sulphite, bisulphite, kraft, soda : 65-85<br />

5 Coarse- fibre<br />

- steam, mild chemical : 70-90<br />

6 High yield chemical<br />

- kraft, sulphite : 50-65<br />

7 Chemical<br />

- sulphate, soda, sulphite, bisulphite<br />

: 40-50<br />

- pre-hydrolysis sulphate<br />

: 35-40<br />

20


4.3. Bleaching<br />

The object of bleaching is to render the pulp whiter without excessive degradation of the cellulose.<br />

Industrial bleaching of pulps first with hypochlorite <strong>and</strong> later with chlorine, partly in combination, <strong>and</strong><br />

with an intermediate extraction step with alkali began at the end of the 19 th century. The development<br />

of pulp bleaching techniques in the 20 th century has led to a large number of bleaching chemicals<br />

(Appendix 6A) applied in numerous <strong>and</strong> highly specific processes (Appendix 6B, C, D & E) today.<br />

The principal aim of pulp bleaching is to increase brightness. The whiteness of pulps is generally<br />

determined by measuring the reflectance of nearly monochromatic light (457 microns) by a st<strong>and</strong>ard<br />

General Electric (GE) reflectance meter. A magnesium oxide plate of known reflectance is used as a<br />

st<strong>and</strong>ard. The brightness values are expressed as percentage of light reflected by the sample as<br />

compared with that reflected by a completely white surface. Unbleached pulps generally exhibit<br />

brightness values ranging from 25-65 GE units. The sulphite process usually gives the brightest<br />

unbleached pulps, whereas those produced by kraft, soda or semichemical processes can be quite<br />

dark. Groundwood pulps have brightness values in between 40 <strong>and</strong> 60 units.<br />

To produce white fibres from the brown or pale yellow pulps, treatment with a bleaching agent is<br />

required. The nature of the bleaching operation depends on several factors: the type of raw material<br />

used to make the pulp, the pulping process, the degree of whiteness desired, <strong>and</strong> the purpose <strong>for</strong><br />

which the pulp is to be used. Bleaching carries further the fibre purification accomplished in the<br />

pulping process. As the light-absorbing chromophoric component in unbleached pulps are<br />

predominantly functional groups of degraded <strong>and</strong> altered residual lignin, bleaching can be per<strong>for</strong>med<br />

either by converting <strong>and</strong> stabilizing chromophoric groups without loss of substance (ligninpreserving<br />

bleaching) or by removing the lignin (lignin- removing bleaching). The traces of lignin <strong>and</strong><br />

other coloured substances (quinone like substances <strong>for</strong>med from the phenolic groups of lignin by<br />

various oxidative processes are known to absorb visible light) are removed or converted to colourless<br />

<strong>for</strong>ms by bleaching. The extraneous constituents of wood also contribute to the colour of certain<br />

pulps, especially the groundwood pulps. Along with the removal of the residual lignin <strong>and</strong> other<br />

compounds, insufficiently delignified particles (shives, bark specks) are also partly removed.<br />

There<strong>for</strong>e, bleaching can additionally be regarded as a purification process, which is used especially<br />

in the case of dissolving pulp production to obtain a pure pulp with high alpha-cellulose content.<br />

Bleaching without delignification to brightness values above 70 is difficult to achieve. High<br />

brightness is not, of course, the only important characteristic of bleached pulps. A good paper pulp<br />

must also have good strength <strong>and</strong> good papermaking properties, <strong>and</strong> it is important that these<br />

properties are not lost in the bleaching process.<br />

21


Pulp bleaching chemicals can be classified into oxidising agents (chlorine, sodium or calcium<br />

hypochlorite, chlorine dioxide, hydrogen or sodium peroxide, oxygen, etc.) <strong>and</strong> reducing agents<br />

(sodium or zinc hydrosulphite, sodium or zinc dithionite, sodium bisulphite, etc.) (Appendix 6A).<br />

Present bleaching systems permit consistencies up to 15-25 per cent.<br />

Industrial lignin-removing processes have improved multi-stage bleaching sequences adapted to the<br />

special pulp type <strong>and</strong> combining the different oxidising <strong>and</strong> reducing abilities of the bleaching<br />

chemicals. Degraded lignin <strong>and</strong> other reaction products are extracted during intermediate alkaline<br />

washing stages. Bleaching with peroxide, oxygen or dithionite requires additional chemicals <strong>for</strong><br />

buffering (e.g. sodium silicate), sequestering (e.g. ethylenediamine tetraacetic acid – EDTA) or<br />

stabilizing (e.g. magnesium salts).<br />

4.3.1. Bleaching of chemical pulps<br />

The aim of bleaching chemical pulps is to remove the residual lignin after the cooking process to<br />

obtain so-called full- bleached pulps with brightness levels above 90 per cent or semi-bleached<br />

qualities with brightness values in the range of 60-70 per cent.<br />

4.3.1.1. Multi-stage bleaching systems<br />

In the early days of sulphite pulp manufacture, a single-stage treatment of pulp at low consistency,<br />

using calcium hypochlorite (chlorinated lime) satisfied most requirements. Multi-stage bleaching<br />

systems have evolved <strong>for</strong> difficult to bleach pulps like the kraft in which various sequences of<br />

chemical treatment are employed depending upon the type of unbleached pulp <strong>and</strong> special<br />

requirements. Lignin-removing bleaching is predominantly carried out today in multi-stage<br />

procedures with oxidative stages combining with normally at least one alkaline extraction step. The<br />

multi stage bleaching systems are designed in order to control the process <strong>and</strong> particularly in order to<br />

limit the damage to the cellulosic fibre, since paper made from over bleached pulp does not have full<br />

strength. Apart from the high degree of whiteness or brightness attained, the consumption of bleach<br />

was much less in multi-stage bleaching.<br />

During the normal first stage in a modern bleach plant, the unbleached pulp is chlorinated with 3–4<br />

per cent of gaseous chlorine by rapidly mixing it with the pulp at temperature of 21- 27 0 C. In the<br />

following stage, an alkaline extraction with dilute caustic soda dissolves the chlorinated compounds<br />

which are then washed out. The final stage consists of a treatment with a very alkaline hypochlorite to<br />

neutralise the solution, followed by a final wash. This sequence of bleaching is generally termed as C/<br />

E/H (Chlorination–Extraction–Hypochlorite treatment). By the use of small amounts of chlorine<br />

22


dioxide in later bleaching stages, it is possible to achieve high degrees of purification <strong>and</strong> brightness<br />

without the degradation of cellulose.<br />

The main disadvantage of the process is the extensive degradation of cellulose fibres as well as<br />

introducing high pollutants in the effluent. Further, higher brightness beyond 80 per cent is practically<br />

impossible while using hypochlorite. Alternatively, the use of chlorine dioxide can considerably<br />

reduce the use of free chlorine <strong>and</strong> the chlorination stage which has the advantages of lowering the<br />

consumption of oxidising chemicals as also sodium hydroxide at the extraction stages, improved pulp<br />

properties such as more stable brightness, improved effluent properties such as lower colour, toxicity,<br />

acidity, salinity, organic chlorides, COD <strong>and</strong> mutagenicity. The <strong>for</strong>emost advantage of using chlorine<br />

dioxide bleaching is the benefit of attaining brightness levels in excess of 85 per cent with the<br />

associated less degradation of cellulosic fibres. Practically all over the world chlorine dioxide<br />

bleaching has been in use <strong>for</strong> the last four decades.<br />

Multi-stage bleaching involves a series of stages, each complete within itself <strong>and</strong> operating under<br />

conditions previously described. The procedure may vary from two stages to as many as ten,<br />

involving chlorination, alkali extraction, hypochlorite, chlorine dioxide, <strong>and</strong> peroxide stages. The<br />

symbols used to describe the sequences <strong>and</strong> the various sequences, in practice <strong>for</strong> the bleaching of<br />

pulps are given in Appendix 6C, D &E. Pulps of different brightness may be obtained by varying the<br />

amount of chemical added, sequence of stages, <strong>and</strong> number of stages. The sequence of operation of<br />

the various stages will depend on the type of unbleached pulp, the quality of the bleached pulp, the<br />

brightness desired, <strong>and</strong> the economics of the process.<br />

In most commercial processes chlorination is still the first bleaching step, <strong>and</strong> is also called the prebleaching<br />

stage. Chlorine converts the residual lignin in water- <strong>and</strong> alkali-soluble degradation<br />

products, <strong>and</strong> is there<strong>for</strong>e generally followed by an alkaline extraction step to remove those<br />

components.<br />

4.3.1.2. Substitution <strong>for</strong> chlorine<br />

As chlorination causes the largest number of environmental problems with the bleach plant effluents,<br />

many attempts have been made to replace chlorine or to reduce the amounts of chlorine used or the<br />

chlorinated products in the effluents. This can be accomplished by cooking the pulps down to low<br />

kappa numbers, thus reducing the chlorinated organic load in the effluents, or by replacing part of<br />

chlorinated lignin fragments. Replacing chlorine altogether by peroxide or oxygen bleaching enables<br />

processing of effluents with few problems with regard to environmental protection.<br />

23


Hypochlorite can be used in a single-stage bleaching or in the first stage of multi- stage bleaching,<br />

but is mostly applied after chlorination <strong>and</strong> extraction (C-E-H). As hypochlorite has a severe<br />

degrading effect on cellulose in the neutral pH range at very low kappa numbers it must always be<br />

applied under alkaline conditions.<br />

Pulp <strong>and</strong> paper industry is rated to be one of the highly polluting (in top 20s) industries. Use of<br />

chlorine can release organochlorines, including the carcinogenic dioxin that can enter the food chain.<br />

Most developing countries aim to achieve a total organochlorine (TOCL) level of 0.1 kg per tonne of<br />

paper produced. Hence, there is an increasing trend worldwide to reduce the use of both elemental<br />

chlorine <strong>and</strong> chemicals containing chlorine. Two bleaching processes, which are increasingly being<br />

adopted by the western countries are elemental chlorine free (ECF) bleaching <strong>and</strong> total chlorine<br />

free (TCF) bleaching. As a first step towards adopting more environmentally friendly methods, the<br />

ECF bleaching comprising the replacement of the more dangerous elemental chlorine with chlorine<br />

dioxide is considered <strong>and</strong> is gradually displacing chlorine in the first stage of multi-stage bleaching,<br />

whereas <strong>for</strong>merly it was used in the final stages. This development is the result of several advantages<br />

of chlorine dioxide such as higher brightness, improved strength properties, lower chemical<br />

consumption <strong>and</strong> substantial decrease in the BOD of the effluents. Chlorine dioxide bleaching is<br />

generally per<strong>for</strong>med at low to medium consistency at pH values of 3-5, <strong>and</strong> at low temperatures in the<br />

first stage or at about 70 0 C in intermediate or final stages <strong>for</strong> 3-5 hrs. The use of hydrogen <strong>and</strong><br />

sodium peroxide as the bleaching agents (especially <strong>for</strong> mechanical pulps) is a solution to introduce<br />

the TCF bleaching.<br />

Peroxides, apart from their application in bleaching mechanical pulps, are also established today in<br />

several industrial bleaching sequences <strong>for</strong> chemical pulps. They are mainly used in the latter stages in<br />

combination with chlorine dioxide yielding increased brightness values <strong>and</strong> stability. More recently<br />

the traditional sodium hydroxide extraction (E) is sometimes replaced by an alkaline peroxide stage (P<br />

or P/E) combining bleaching <strong>and</strong> extraction in one stage, <strong>and</strong> resulting in a brightness gain without an<br />

additional stage. By increasing the application of hydrogen peroxide, the amounts of chlorine<br />

bleaching chemicals are reduced resulting in decreased chlorine load of the effluents. Limitations are<br />

still the high price of peroxides <strong>and</strong> the necessary additives <strong>for</strong> stabilization. Peroxide bleaching is<br />

usually per<strong>for</strong>med at medium-to-high consistency at 60-80 0 C <strong>for</strong> 2-4 hrs.<br />

4.3.1.2.1. Oxygen bleaching<br />

Oxygen bleaching (or oxygen delignification) is another eco-friendly bleaching process. As oxidation<br />

is the essential reaction in lignin-removing bleaching, it is quite reasonable to aim at using oxygen as<br />

the cheapest oxidising agent <strong>for</strong> bleaching. In principle, oxygen bleaching is a gas-phase process at<br />

24


pressures usually between 4 <strong>and</strong> 8 bar in alkaline medium, per<strong>for</strong>med at high consistencies of 20-30<br />

per cent <strong>and</strong> temperatures of 90-140 0 C, depending on the alkali used. But as it is not a selective<br />

lignin- degrading chemical, pulps cannot be bleached to high brightness exclusively with oxygen<br />

without considerable attack on the polysaccharides, resulting in rather poor strength properties. Thus<br />

the common practice in mill-scale bleaching today is to remove about one–half of the residual lignin<br />

in unbleached pulps by oxygen, <strong>and</strong> to finish with conventional multi stage bleaching sequences such<br />

as C-(EO)-H-D, D-C-(EO)-D, O-C-D-E, O-C-E-D-E-D or O-D-E-D, etc. The conventional bleach<br />

plants employing sequences such as C-E-H-H will have to do only marginal changes in their industry<br />

to incorporate the D-C-(EO)-D process so that pulps of high brightness can be produced at<br />

considerably <strong>and</strong> relatively low cost. The Kamyr, Sund, Beloit Rauma, etc. have equipments <strong>for</strong> the<br />

needful modifications (Goel et al. 1989) 5 . More than 16 plants throughout the world are employing<br />

this process, the first having been founded in South Africa in 1970. The main practical advantage of<br />

oxygen bleaching is the fact that the effluents from the oxygen step can be processed within the<br />

normal kraft recovery system. In the context of increasing air <strong>and</strong> water pollution from the traditional<br />

bleaching systems, oxygen bleaching has proven its potential as the more environmentally friendly<br />

system.<br />

4.3.2. Colour reduction in the effluent<br />

Some of the technological changes as suggested by Mall et al. (1989) 52 , <strong>for</strong> reducing toxicity <strong>and</strong><br />

colour of the effluents are: elimination or minimum use of sulphur containing pulping processes <strong>and</strong><br />

chlorine containing bleaching processes; extended delignification; modification of bleaching<br />

sequences which includes elimination of caustic extraction stage which is the major contributor of<br />

colour; use of oxygen bleaching, chlorine dioxide bleaching; use of anthraquinone <strong>and</strong> lower sulphur<br />

high-yield pulping processes; total recycle concept, <strong>and</strong> reduction in bleached pulp brightness level.<br />

4.3.3. Bio-bleaching<br />

Microorganisms or enzymes can cause modification of the lignin in the pulp rendering it more<br />

accessible to the bleaching agents, thus the application of biotechnology in bleaching can reduce the<br />

consumption of bleaching chemicals which can further help to reduce the effluent pollution <strong>and</strong><br />

associated toxicity problems. After the alkaline extraction stage, unbleached kraft hardwood pulps<br />

have been treated with xylanases of Escherichia coli clone to yield pulps which are bright <strong>and</strong> have a<br />

kappa number 54 per cent lower than the corresponding control samples (Jurasck et al. 1987) 493a . In<br />

addition, the viscosity of pulps was also higher compared to the control. Begasse CTMP <strong>and</strong> CMP<br />

pulps on treatment with a crude enzyme extract resulted in 2-6 unit improvement in brightness<br />

(Ramaswami <strong>and</strong> Ramanathan 1989) 66 . There is still scope to improve its per<strong>for</strong>mance by<br />

purification of the enzyme <strong>and</strong> identification of the optimal treatment conditions like temperature <strong>and</strong><br />

25


pH. The use of bio-catalysts can accelerate the rate of reaction as well as can have control over the<br />

products <strong>for</strong>med <strong>and</strong> thus the <strong>for</strong>mation of undesirable side products can be controlled. In fermenters<br />

where the enzyme cellulase has been used, it has been found that 50-90 per cent of the enzymes are<br />

free in the solution <strong>and</strong> can be directly reused again (Eriksson <strong>and</strong> Kirk 1985) 503 .<br />

4.4. Recovery of pulping chemicals<br />

The regeneration of black liquor to fresh white liquor is an integrated <strong>and</strong> economically necessary part<br />

of the pulping process, especially in the sulphate <strong>and</strong> the soda process. The importance of the<br />

recovery line within the process may be seen from the fact that more than 25 per cent of the<br />

investment capital <strong>for</strong> a new kraft mill is used <strong>for</strong> the chemical recovery (Harris 1974) 43 . The<br />

chemical recovery cycle covers four main aspects: recovery of pulping chemicals, reduction of waterpollution<br />

by burning the organic matter in the spent liquor, generation of process heat, <strong>and</strong> recovery of<br />

valuable by-products. The principal steps of the recovery line are: evaporation of the black liquor,<br />

incineration of the concentrated liquor, causticizing the furnace smelt, <strong>and</strong> regeneration of the lime.<br />

4.5. Paper Manufacture<br />

4.5.1. Stock preparation – Beating / Refining<br />

.The tendency of cellulose fibres to bond together when dried from a water suspension provides the<br />

essence of paper making technology. Paper manufacture is largely a mechanical operation, although<br />

the chemical <strong>and</strong> physicochemical aspects are all important in determining the final sheet properties.<br />

Unmodified cellulose fibres, as obtained from pulping <strong>and</strong> bleaching operations, are generally<br />

unsuited <strong>for</strong> paper making. These must first be refined; refining or beating operation is conducted<br />

mechanically in beaters or refiners. The entire operation is called stock preparation. Fibres are<br />

abraded <strong>and</strong> fibrillated by the knife-edges or bars in the beater or refiner. Mechanical squeezing <strong>and</strong><br />

pounding of cellulose fibre permits water to penetrate its structure, causing swelling of the fibre <strong>and</strong><br />

making it flexible. During refining or beating, the pulp fibres are separated, crushed, frayed,<br />

fibrillated, <strong>and</strong> cut. They imbibe water <strong>and</strong> swell, become more flexible <strong>and</strong> more pliable. Their<br />

capacity to bond with one another on drying is greatly enhanced, partly through modification of the<br />

fibre surfaces <strong>and</strong> partly because of the creation of new surface area. Papers made from lightly beaten<br />

stocks are typically of low density, soft <strong>and</strong> porous; whereas papers from highly beaten stocks are<br />

dense, hard <strong>and</strong> much stronger. With given pulps, final paper properties are largely controlled through<br />

the type <strong>and</strong> extent of refining action employed.<br />

26


4.5.2. Sizing<br />

Sizing has been described as the treatment given to paper to prevent aqueous solutions, such as ink,<br />

from soaking into it. A typical sizing solution consists of a rosin soap dispersion mixed with the stock<br />

in an amount of 1-5 per cent of fibre. Since there is no affinity between rosin soap <strong>and</strong> fibre, it is<br />

necessary to use a coupling agent, normally alum (aluminium sulphate). The acidity of alum<br />

precipitates the rosin dispersion, <strong>and</strong> the positively charged aluminium ions <strong>and</strong> aluminium hydroxide<br />

flocs (masses of finally suspended particles) attach the size firmly to the negatively charged fibre<br />

surface.<br />

Paper intended <strong>for</strong> writing or printing usually contains white pigments or fillers to increase<br />

brightness, opacity <strong>and</strong> surface smoothness, <strong>and</strong> to improve ink receptivity. Clay (aluminium silicate),<br />

often referred as kaolin or china clay, is commonly used. Another pigment used as filler is titanium<br />

dioxide, which being expensive, is often used in admixture with others. Calcium carbonate is also<br />

used as paper filler <strong>for</strong> printing <strong>and</strong> magazine stocks <strong>and</strong> <strong>for</strong> the filling of cigarette paper, to which it<br />

contributes good burning properties. Because of its reactivity with acid, calcium carbonate cannot be<br />

used in systems containing alum. Other fillers such as zinc oxide, zinc sulphide, hydrated silica,<br />

calcium sulphate, hydrated alumina, talc, barium sulphate <strong>and</strong> asbestos are also in use as fillers in<br />

paper coatings. The amount of filler used may vary from 1- 10 per cent of the fibre.<br />

The most common way to impart colour to paper is to add soluble dyes or coloured pigments to the<br />

paper stock. Other additives such as wet-strength agents (organic resins), deflocculating agents <strong>and</strong><br />

de<strong>for</strong>mers are also incorporated as needed in the stock. To increase the dry strength of paper, the<br />

materials most commonly used are starch, polyacrylamide resins, <strong>and</strong> natural gums such as locust<br />

bean gum <strong>and</strong> guar gum.<br />

4.5.3. Paper sheet <strong>for</strong>mation by machines<br />

The term paper is traditionally applied to a matted or felted sheet of cellulose fibres, <strong>for</strong>med on a fine<br />

wire screen from a dilute water suspension, <strong>and</strong> bonded together as the wire removed <strong>and</strong> the sheet is<br />

dried. The word, paper, is derived from the name of the reedy plant papyrus, which grows abundantly<br />

along the Nile River in Egypt.<br />

The continuous paper machine converts a very dilute aqueous suspension of fibres <strong>and</strong> other<br />

ingredients into a dry sheet of paper at varying speeds. The fourdrinier machine is one of the two<br />

major sheet <strong>for</strong>ming devices in widespread use. It consists in essence of a continuously moving wire<br />

belt or screen, to which the dilute pulp slurry is fed <strong>and</strong> from which the wet, <strong>for</strong>med sheet is removed<br />

27


continuously. The second major type of paper machine, the cylinder machine, differs from the<br />

fourdrinier only in the <strong>for</strong>ming part. Here, in place of the moving wire, one or a series of rotary<br />

cylindrical filters are used.<br />

Many grades of paper receive some type of treatment after <strong>for</strong>mation <strong>and</strong> drying in order to enhance<br />

certain desirable characteristics. Such operations carried out on the paper machine are called machine<br />

converting operations. Machine calendaring is one of the most common converting operations<br />

where the sheet is passed through the nips <strong>for</strong>med by a series of steel rolls, one held on top of the<br />

other. Surface or tub sizing is another common converting operation, particularly in the manufacture<br />

of writing papers. Machine coating is practised <strong>for</strong> book <strong>and</strong> magazine papers to improve their<br />

surface <strong>for</strong> better reproduction of printed images. A coating mix is applied to one or both surfaces of<br />

the dry sheets by any of several means. The coating is often clay, contained in a high- solids aqueous<br />

suspension, which includes suitable adhesives <strong>and</strong> other ingredients. The sheet must be redried after<br />

the coating applications. The finished paper is wound on a large roll at the paper machine.<br />

4.5.4. Paper properties<br />

Used in a wide variety of <strong>for</strong>ms, paper <strong>and</strong> paperboard are characterised by a wide range of properties.<br />

Weight or substance per unit area, called basis weight, is a fundamental property of paper <strong>and</strong><br />

paperboard products. The term ream weight commonly signifies the weight of a lot or batch of paper.<br />

The calliper (thickness) of paper or paperboard is measured by placing a single sheet under a study<br />

pressure of 0.5 to 0.6 bar between two circular <strong>and</strong> parallel plane surfaces, the smaller of which has an<br />

area of 1.6 cm 2 . The density or specific gravity of paper is calculated from the basis weight <strong>and</strong><br />

calliper <strong>and</strong> may vary over wide limits. Most common papers are in the density range of 0.5- 0.7g/cc.<br />

The strength of paper is determined by the following factors in combination: the strength of individual<br />

fibres of the stock; the average length of the fibre; the inter-fibre bonding ability (which is enhanced<br />

by beating/refining action); <strong>and</strong> the structure <strong>and</strong> <strong>for</strong>mation of the sheet. Resistance to rupture when<br />

subjected to various stresses is an important property in practically all grades of paper. Tensile<br />

strength is the greatest longitudinal stress a piece of paper can bear without tearing apart. According<br />

to end-use situations, the wet <strong>and</strong> dry tensile strengths need to be specified separately. The stress is<br />

expressed as <strong>for</strong>ce per unit width of a test specimen. Since, the weight of the paper <strong>and</strong> the width of<br />

the test specimen affect the <strong>for</strong>ce of rupture, a conventional method of comparing inherent paper<br />

strength is the breaking length, the length of a paper strip in meters that would be just selfsupporting.<br />

This value varies from 500 m <strong>for</strong> extremely soft <strong>and</strong> weak tissue to about 8,000 m <strong>for</strong><br />

strong kraft bag paper, <strong>and</strong> to about 14,000 m <strong>for</strong> sheets of paper made under ideal conditions. One of<br />

the oldest <strong>and</strong> most widely used strength tests <strong>for</strong> paper <strong>and</strong> paperboard is the bursting test, or Mullen<br />

test. Bursting strength is defined as the hydrostatic pressure necessary to cause rupture in a circular<br />

28


area of a given diameter. Other strength tests <strong>for</strong> which st<strong>and</strong>ard methods exist are the tearing<br />

strength <strong>and</strong> folding endurance. Explanation of some general terms used in describing pulp strength<br />

properties is given in Appendix 1B.<br />

The most important optical properties of paper are brightness, colour, opacity <strong>and</strong> gloss. The term<br />

brightness has come to mean the degree to which white or near-white paper <strong>and</strong> paperboard reflect the<br />

light of the blue end of the spectrum. This reflectance is measured by an instrument that illuminates<br />

paper at an angle of incidence of 45 0 <strong>and</strong> a wavelength of 457 microns. Opacity is one of the most<br />

desired properties of printing <strong>and</strong> writing papers. Satisfactory per<strong>for</strong>mance of such paper requires that<br />

there be little or no ‘show-through’ of images from one side of the sheet to the other. Satisfactory<br />

opacity in printing papers requires that white mineral pigments be incorporated with the paper stock<br />

or applied as a coating. The terms gloss, glare, finish <strong>and</strong> smoothness are used in describing surface<br />

characteristics of paper. Gloss refers to surface lustre <strong>and</strong> connotes a generally pleasing aspect.<br />

Calendaring <strong>and</strong> coating are important paper-treating methods that affect gloss. Gloss of paper is<br />

determined by measuring per cent reflectance at a low angle of incidence, 15 0 (75 0 from the<br />

perpendicular). Glare refers <strong>for</strong> a more intense reflection <strong>and</strong> a more unpleasant effect. The broad<br />

term finish, refers to the general surface characteristics of the sheet. Smoothness refers to the absence<br />

of surface irregularities under either visual or use conditions.<br />

4.5.5. Paper products<br />

The products of the paper industry are extremely varied. New applications <strong>for</strong> paper involved<br />

converted products. For this, more complex converting operations take place subsequent to the paper<br />

machine operations <strong>and</strong> are called off-machine converting. Supercalendaring, embossing, coating,<br />

waxing, laminating, impregnating, saturating, corrugating <strong>and</strong> printing are but a few of the<br />

common operations. Papers, often coated, waxed, resin-impregnated, or combined with other foils <strong>and</strong><br />

films, are used <strong>for</strong> food packaging. Speciality papers incorporate the use of glass <strong>and</strong> other mineral<br />

fibres. Polyethylene–coated paper is crease-resistant <strong>and</strong> is flexible at temperatures ranging from 20 to<br />

85 0 C, which is used <strong>for</strong> bags, carton, box <strong>and</strong> bag liners as well as <strong>for</strong> disposable diapers, bibs <strong>and</strong><br />

bed sheets. A great variety of technical <strong>and</strong> industrial papers have been developed <strong>for</strong> use in the<br />

manufacture of disposable vacuum bags, engine gaskets, cap liners, wet-cell batteries, <strong>and</strong> many other<br />

special-purpose products. The applications of paper are limited only by man’s ingenuity.<br />

4.5.6. Paper grades<br />

There are several hundred grades of paper <strong>and</strong> paperboard, distinguished from one another by<br />

differences in their properties, in the raw materials from which they are made, or in the process by<br />

29


which they are manufactured. An extensive list of grades of paper is given by American Paper <strong>and</strong><br />

Pulp Association (1951) 23 <strong>and</strong> Labarre (1952) 50 .<br />

The specific properties of the various grades of paper produced by varying many factors including<br />

type of pulp, degree of bleaching <strong>and</strong> purification, thickness of the wet web, degree of pressing in<br />

water removal, degree of pressing in drying <strong>and</strong> calendaring operations, <strong>and</strong> kind <strong>and</strong> quantity of<br />

chemical additives. A brief description of the various grades of paper is given in Appendix 9A.<br />

30


PART II. BAMBOO FOR PULP AND PAPER<br />

5. BAMBOOS : DISTRIBUTION, UTILIZATION, STORAGE AND<br />

ECONOMICS<br />

5.1. About bamboos<br />

<strong>Bamboo</strong> grows in India, Burma, Thail<strong>and</strong>, Indonesia, China, Japan, the Philippines, Australia, South<br />

Africa, South America <strong>and</strong> southern North America. It is a grass of several genera <strong>and</strong> species.<br />

<strong>Bamboo</strong> provides the highest biomass per unit area. There are two types of bamboos: sympodial or<br />

clump <strong>for</strong>ming, as in Bambusa; monopodial or single clump distributed laterally, as in Melocanna.<br />

<strong>Bamboo</strong> grows as high as 40 m with diameter up to 30 cm. The growth rate is tremendous; in 1-2<br />

months of the first year full length is achieved (growth rate is about 15 to 120 cm per day in some<br />

species!) (Martin 1996) 107a <strong>and</strong> culm maturation through lignification takes place during the next two<br />

to three years.<br />

<strong>Bamboo</strong> clumps die off after flowering, which occurs from cycles varying between 50 <strong>and</strong> 60 years<br />

depending on the species. Estimates of total global revenue generated from bamboo <strong>and</strong> its products –<br />

including the value of bamboo used by traditional communities <strong>and</strong> employment generated by them –<br />

range between US $ 4.5 <strong>and</strong> 7.0 billion.<br />

5.2. Distribution of bamboos<br />

Sharma (1982) 121 describes the distribution of bamboos in countries like China, Japan, Korea,<br />

besides that of South <strong>and</strong> Southeast Asia. A total of 1250 species of bamboos from 75 genera are<br />

reported from these countries. Occurrence of more than 50 species of bamboos is reported from<br />

Vietnam (Anonymous 1971). Recently, Ohrnberger (1999) 114 has brought out in<strong>for</strong>mation on<br />

bamboos of the world <strong>and</strong> their distribution.<br />

Gamble (1896)<br />

94 is one of the oldest records available on bamboos of India.<br />

Singh <strong>and</strong> Guha (1981) 429 reviewed the various bamboos occurring in India, including their pulping,<br />

bleaching, beating properties <strong>and</strong> the properties of paper made from these. The upgraded list of<br />

distribution of bamboos in India is provided by ICFRE (1991) 100 <strong>and</strong> Moulik (1997) 111 . A<br />

compendium of 128 species of bamboos from 18 genera occurring in India have been brought out by<br />

Seethalakshmi <strong>and</strong> Kumar (1998) 118 . The two most widely distributed genera in India are Bambusa<br />

<strong>and</strong> Dendrocalamus.<br />

31


5.3. History of pulp production from bamboos<br />

<strong>Bamboo</strong>, “the green gold of the <strong>for</strong>est”, around 10 million tonnes of which are produced annually in<br />

the world, is not expensive, long-fibered, easy to transport <strong>and</strong> there<strong>for</strong>e is an important raw material<br />

<strong>for</strong> the pulp <strong>and</strong> paper industry. Sumg (1967) 20 described the pulp characteristics <strong>and</strong> technology <strong>for</strong><br />

the manufacture of bamboo paper in the 17th century China. Bourdillon (1899) 138 , <strong>and</strong> later Sindall<br />

(1909) 192 <strong>and</strong> Vincent (1911) 205 described the use of bamboo <strong>for</strong> pulp <strong>and</strong> paper. It was India that<br />

took the lead in using bamboo in mechanized paper production. In 1912, the Titaghur Paper Mill in<br />

India started utilizing bamboo as a raw material in a limited scale. In 1918, the India Paper <strong>and</strong> Pulp<br />

Company Limited., Naihat produced paper made completely from bamboo. The pulp industry<br />

accounts <strong>for</strong> about half of India’s bamboo consumption (mostly Dendrocalamus strictus <strong>and</strong> Bambusa<br />

bambos). India uses about 3 million tonnes of bamboo per year in pulp manufacture <strong>and</strong> China about<br />

1 million tonnes. China is set to increase the use of bamboo <strong>for</strong> paper pulp manufacture to a target of<br />

5 million tonnes per year. The use of bamboo <strong>for</strong> pulp is reported to have decreased in India due to<br />

lack of raw material (INBAR 1977) 158 .<br />

Pearson (1912) 186 <strong>and</strong> Raitt (1912) 231 provided the history of work carried out at the Forest Research<br />

Institute, Dehra Dun, India which pioneered <strong>and</strong> laid a strong foundation <strong>for</strong> utilizing bamboo <strong>for</strong> pulp<br />

<strong>and</strong> paper. The general conditions necessary <strong>for</strong> establishment of a paper mill, manufacturing cost,<br />

etc. were provided by them. Bhargava <strong>and</strong> Singh (1941 137 <strong>and</strong> 1942) 26 established the suitability of<br />

bamboo as a raw material in the kraft process which was a major milestone in the pulp industry in<br />

India. Since then, many periodic reviews of the work carried out at the Forest Research Institute,<br />

Dehra Dun, India have appeared (Bhargava 1946 136 ; Singh <strong>and</strong> Mukherjea 1965 79 ; Tewari 1993) 124 .<br />

Tissot (1970) 198 reviewed the status of bamboo as a raw material in the Indian paper industry <strong>and</strong> the<br />

problems encountered in producing pulp <strong>and</strong> paper from bamboo (mainly Dendrocalamus strictus). In<br />

comparison to wood, bamboo can be pulped by the kraft <strong>and</strong> 2-stage alkali processes with less<br />

chemical <strong>and</strong> power (Stevens 1958 80 ; INBAR 1977) 158 . Only minor differences are found between<br />

pulps of 21 Indian bamboo species. The bamboo fibres are shorter than that of conifers but longer<br />

than that of hardwoods <strong>and</strong> narrower than that of wood fibres used in paper making.<br />

An yield of 8 tonnes per ha per year of dry matter (4.0 tonnes of cellulose) was reported (Anonymous,<br />

1955) from the Congo grown small bamboo, Oxytenanthera abyssinica. Hodge (1957) 99 described<br />

the economic future of bamboos in America. The reported annual yield per ha of bamboo cellulosic<br />

material was six times greater than that of southern pine. Belvin (1957) 25 reported the potential of<br />

32


amboo plantations in the USA. Istas (1958) 44 reported that the short, fine <strong>and</strong> stiff fibred dwarf<br />

bamboos of Belgian Congo (Sasa paniculata, S. variabilis, Arundinaria nitida <strong>and</strong> A. simonii) were<br />

unsuitable <strong>for</strong> pulping whereas the larger species, Bambusa vulgaris (with average fibre length around<br />

2.7 mm) from Congo gave promising results. Istas <strong>and</strong> Raekelboom (1962) 160 reported an yield of 50<br />

tonnes per ha of Bambusa vulgaris from Congo which also provided best paper making pulps. They<br />

suggested a cutting cycle of 2 years. Mooney (1959) 110 reported an yield of 5 tonnes air-dry culms<br />

per acre (12.5 tonnes/ ha) with a 4-year cutting cycle <strong>for</strong> Oxytenanthera abyssinica. Breitenbach<br />

(1961) described the status of bamboo as a source of cellulose in Ethiopia. An area of about 1 million<br />

ha was reported to be under the bamboo species, Oxytenanthera abyssinica. An area of 10,000 ha of<br />

bamboo plantation, managed on a 5-year coppice rotation, would keep a pulp mill supplied<br />

permanently with raw material. FPRDI (1962) 148 discussed the merits of bamboo as a raw material<br />

<strong>for</strong> pulp <strong>and</strong> paper making <strong>and</strong> outlined the commercial possibilities of certain economically <strong>and</strong><br />

technically suitable Philippine species such as Gigantochloa levis, G. aspera, Schizostachyum<br />

lumampao, Bambusa blumeana, Bambusa vulgaris <strong>and</strong> B. vulgaris var. striata. Ono (1962) 12<br />

reported the results of a survey of bamboo <strong>for</strong>ests in Indonesia <strong>and</strong> Burma (Myanmer) <strong>and</strong> discussed<br />

the scientific techniques of bamboo pulping industry.<br />

It was reported by Matsui (1963) 178 that about 70 per cent of the <strong>for</strong>est undergrowth in Japan was<br />

composed of Sasa bamboos. The larger species, Sasa kurilensis, was reported to provide an yield of<br />

50-60 tonnes per ha when clear cut. Nelson (1966) 61 reported that Sinarundinaria murielae, three<br />

Phyllostachys spp., two Arundinaria spp. <strong>and</strong> Oxytenanthera abyssinica were promising species <strong>for</strong><br />

planting in the southeast <strong>and</strong> the Pacific coast of the USA. The prospects of bamboo <strong>for</strong> pulp <strong>and</strong><br />

paper <strong>and</strong> board making in India were reported by Guha (1961a 96 & b) 395 . Factors which limit the<br />

actual selection of raw material <strong>for</strong> large scale paper manufacture were enumerated by him.<br />

Ch<strong>and</strong>rasekharan (1968) 476 reported that bamboo only was used commercially in India <strong>for</strong> dissolving<br />

grade pulp.<br />

McGrovern (1967) 180 compared bamboo with southern hardwoods <strong>and</strong> southern pines in the USA<br />

with regard to yield (in India <strong>and</strong> Japan), density, chemical composition, fibre dimensions, conditions<br />

<strong>for</strong> kraft pulping <strong>and</strong> bleaching <strong>and</strong> pulp properties. Razzaque et al. (1981) 233 suggested a 12 month<br />

cutting cycle <strong>for</strong> bamboos <strong>for</strong> pulping. Adkoli (1992) 131 made an assessment of the availability of<br />

bamboo <strong>for</strong> the production of pulp <strong>and</strong> paper in India. Availability of wastel<strong>and</strong>s <strong>for</strong> bamboo<br />

plantations, investments <strong>and</strong> ef<strong>for</strong>ts needed to raise such plantations were also discussed by him.. The<br />

three main species of bamboos, Dendrocalamus strictus, Bambusa arundinacea (B. bambos) <strong>and</strong><br />

Melocanna baccifera are reported to constitute 83 per cent of the total growing stock. Nomura<br />

(1999) 183 described the role of bamboo in pulping in Myanmar.<br />

33


El Bassam <strong>and</strong> Jakob (1996) 146 reported that generally bamboos produced about 7 tonnes dry<br />

matter/ha per year. Cellulose content of more than 40 per cent emphasizes the suitability of bamboo as<br />

a raw material <strong>for</strong> pulp <strong>and</strong> paper production. The pulp yield from bamboos varies from 40-50 per<br />

cent.<br />

Even though China is number one in bamboo production in the world, in<strong>for</strong>mation on the utilization<br />

of bamboo <strong>for</strong> pulping in China is scanty. There was a mass movement in China during 1958 <strong>for</strong><br />

setting up small paper mills in order to solve the problem of shortage of paper <strong>and</strong> board in the<br />

country. As many as 4200 small plants exist in China, out of which 4000 mills produce less than<br />

10,000 tonnes per annum (Rao 1989) 17 . The total bamboo <strong>and</strong> reed pulp production in China recorded<br />

in 1986 was 820,000 tonnes, which <strong>for</strong>ms 9.2 per cent of the total pulp production in the country.<br />

Tang (1999) 21 describes the current situation <strong>and</strong> future developments on the utilization of bamboos<br />

<strong>for</strong> pulp <strong>and</strong> paper in China.<br />

5.4. Decay while storage <strong>and</strong> control measures<br />

<strong>Bamboo</strong> <strong>for</strong> pulp <strong>and</strong> paper manufacture is usually stored outdoors <strong>for</strong> up to a year. Because of lack of<br />

any toxic constituents, bamboo <strong>for</strong>ms a ready food source <strong>for</strong> a variety of organisms. The presence of<br />

large amounts of starch makes bamboo highly susceptible to attack by staining fungi <strong>and</strong> powder–post<br />

beetles (Beeson 1941 541 ; Gardner 1945 546 ; Mathew <strong>and</strong> Nair 1990) 158 . It was found that the lignin<br />

content of bamboo chips subjected to fungal attack did not vary appreciably from that of healthy<br />

bamboo. The bleached pulp from decayed bamboo was more yellower.<br />

Strength properties of pulp from decayed chips were appreciably reduced <strong>and</strong> this was due to the<br />

per<strong>for</strong>ations or bore holes <strong>and</strong> erosion marks in the cell-walls, as observed by anatomical studies of<br />

the fibres from healthy <strong>and</strong> fungal attacked bamboos (Guha et al. 1958) 547 . Decay, mainly attributable<br />

to white-rotters, results in loss of wood substance <strong>and</strong> pulp yield, reduced pulp strength <strong>and</strong> increased<br />

consumption of bleaching chemicals because of the high content of residual lignin in the pulp.<br />

<strong>Bamboo</strong> attacked by brown-rot fungi was unsuitable <strong>for</strong> pulping, as the pulp yield was very low<br />

compared to healthy bamboo <strong>and</strong> the permanganate number was so high that the pulp was<br />

unbleachable. Fungal attack increases pulping costs, owing to increased alkali dem<strong>and</strong>s (because of<br />

acidic nature of fungi) <strong>and</strong> higher bleach consumption (Singh 1977) 566 .<br />

Sheets made from decayed <strong>and</strong> stained bamboo pulp from Bambusa tulda were found to have low<br />

strength. There was no appreciable difference in the yield of unbleached pulp from healthy bamboo<br />

<strong>and</strong> bamboo attacked by stain fungi, but the yield of unbleached pulp from bamboo attacked by decay<br />

fungi was low. The strength properties of pulp from bamboo attacked by decay fungi were lower than<br />

34


those made from bamboo attacked by stain fungi; which in turn were slightly lower than those made<br />

from healthy bamboo (Guha et al. 1958 547 ; Guha 1960 152 ; Bakshi et al. 1960) 539 . It is not advisable<br />

to store bamboos <strong>for</strong> long periods in warm <strong>and</strong> humid areas or under conditions favourable <strong>for</strong> decay.<br />

However, if bamboos have to be stored <strong>for</strong> long periods, storage should be under water or with<br />

suitable prophylactic treatment (which should not interfere with pulping) to prevent decay.<br />

Different studies have been reported on flowered bamboo (Bhargava 1945 136 ; Bakshi et al. 1968 540 ;<br />

Kala 1973 221 ; Dhoundiyal et al. 1973) 144 . Flowered bamboo culms are more resistant to beetle<br />

attack, may be due to starch depletion. Flowered bamboo, if in sound condition, is equally good <strong>for</strong><br />

pulping <strong>and</strong> bleaching.<br />

When Bambusa polymorpha <strong>and</strong> Cephalostachyum pergracile were stored <strong>for</strong> 12 months in piles in<br />

the open or submerged in a natural pond, deterioration through stain <strong>and</strong> rot fungi was severe in the<br />

piles kept in the open but negligible in the bamboo kept under water. Neither duration nor method of<br />

storage had a great effect on chemical composition <strong>and</strong> sulphate pulp yields, but some strength<br />

properties of the pulp decreased about equally in both methods during storage. Brightness <strong>and</strong><br />

response to bleaching were better in pulp from water-stored bamboo; this was also confirmed in a<br />

limited bleaching trial on mechanical pulp from B. polymorpha (Mai-Aung et al. 1969) 557 .<br />

Purushotham (1970) 561 suggested measures <strong>for</strong> protection of bamboo against fungal <strong>and</strong> insect attack<br />

at felling <strong>and</strong> stacking sites. Prophylactic treatment of the raw material while storing outdoors reduced<br />

the wood substance loss by 28-30 per cent <strong>and</strong> pulp yield loss by about 30 per cent (Guha <strong>and</strong><br />

Ch<strong>and</strong>ra 1979) 542 . Kumar et al. (1980) 555 reviewed the work done on storage losses <strong>and</strong> the adverse<br />

effect of inadequate protection on strength of paper sheets, bleach consumption <strong>and</strong> brightness <strong>and</strong><br />

loss in digester capacity utilization. Possible ways of using effective chemicals <strong>for</strong> overcoming these<br />

problems were also described.<br />

For long-term storage of bamboos in the open, it is recommended that the stacks are put-up on<br />

specially prepared ground (above a 10 cm layer of boiler ash <strong>and</strong> powdered lime sludge containing<br />

about 2% BHC) to prevent termite attack. The stacks should be profusely treated during different<br />

stages of stack <strong>for</strong>ming <strong>and</strong> may be covered with treated bamboo mats or thatched grass (Kumar et al.<br />

1994) 554 . Treatments must be done in such a way that chemical pollution of the environment is<br />

avoided. Stacking methods <strong>and</strong> treatments depend on the incidences of both fungal <strong>and</strong> insect attack.<br />

For reed bamboos, vertical stacking results in a small gain in pulp yield over horizontal stacking<br />

because the <strong>for</strong>mer suffers less fungal damage. Monthly treatment with borax – boric acid results in a<br />

substantial gain (Gnanaharan et al. 1982) 560 . A pest management strategy using minimal application<br />

of pesticide is recommended by Nair et al. (1983) 560 .<br />

35


Prophylactic treatment with a mixture of sodium pentachlorophenate (NaPCP), boric acid <strong>and</strong> borax<br />

effected a saving of nearly 60 per cent in terms of pulp yield, in green material over a storage period<br />

of one year. Treatments should be repeated after 4-6 months, immediately after the monsoons (Kumar<br />

et al. 1985) 553 . Storing of bamboo (Bambusa vulgaris) <strong>for</strong> relatively long periods (4 months) should<br />

be avoided. Air-drying facilitates processing without reducing pulp quality quality (Vivone <strong>and</strong><br />

Gomide 1985) 474 .<br />

Maheshwari et al. (1988) 175 described the efficient management of bamboo storage <strong>for</strong> reducing the<br />

cost of paper production. They also described the aspects of optimum inventory of bamboo at<br />

different places of storage, proper selection of site <strong>for</strong> storage, layout of stacks in the yard in<br />

compliance with the insurance rules <strong>and</strong> easy approach <strong>for</strong> transport system, design of stacks,<br />

prevention of fire hazards, preservation of raw materials, etc.<br />

Singh et al. (1988) 237 described the problem of decay on storage <strong>and</strong> its effect on pulp properties.<br />

Fungal <strong>and</strong> borer attacks influence the pulp yield <strong>and</strong> cause appreciable decrease in strength properties<br />

of paper. Prophylactic treatment of bamboos with 2.5 per cent solution of boric acid, borax <strong>and</strong><br />

sodium pentachlorophenate (1:1:0.5) can effect considerable savings in wood raw materials.<br />

Laboratory screening tests on fungicides/insecticides revealed several <strong>for</strong>mulations suitable <strong>for</strong> field<br />

applications (Kumar <strong>and</strong> Dobriyal 1990) 552 . While advanced fungal attack produces unbleachable<br />

pulps, borer attack in epidemic stages reduces the entire stack to powder causing 20-40 per cent<br />

volumetric loss. Termites also attack bamboo stacks, which in the absence of adequate protection can<br />

suffer losses up to a level of one metre from the ground during one year of storage. Protected<br />

bamboos remain sound during storage (Kumar et al. 1990) 551 .<br />

Apart from the chemical methods of protecting bamboos, some traditional (non-chemical) methods of<br />

preservation are also in practice, which include felling bamboos during low sugar content season<br />

(August <strong>and</strong> December - as the sugar content will be higher in spring than in winter); felling bamboos<br />

at maturity when sugar content is low (as the sugar content varies with age); post–harvest<br />

transpiration of bamboo culms (by keeping culms upright against trees <strong>for</strong> few days; parenchyma cells<br />

in plants continue to live <strong>for</strong> some time even after felling <strong>and</strong> during this period the stored food<br />

materials are utilized <strong>and</strong> thus the sugar/starch content in bamboos is lowered), <strong>and</strong> storing under<br />

water <strong>for</strong> a period of 4-12 weeks (which helps to reduce the starch/sugar content by leaching) (Kumar<br />

et al. 1994) 554 . It is reported that bamboos harvested during summer are more rapidly deteriorated<br />

than those harvested in the rainy season (Liese 1980) 168a . Kirkpatrick <strong>and</strong> Simmonds (1958) 549 made<br />

an attempt to correlate the natural durability of bamboo with the time of harvesting based on the<br />

36


phases of the moon. But this aspect was never proved beyond doubt <strong>and</strong> hence remains as a<br />

controversial subject.<br />

5.5. Economics of bamboo plantation<br />

Because of the high quality of pulp that can be obtained from bamboo <strong>and</strong> because of its availability<br />

in large quantity at a reasonable price, bamboo was used extensively as raw material in paper<br />

industry. In 1950, about 225,000 tonnes of bamboo was used in this industry in India (FRI 1951). The<br />

increasingly important role played by bamboo in the development of Indian pulp <strong>and</strong> paper industry is<br />

illustrated by Podder (1959) 14 . From a consumption of 5,830 tonnes in 1924 in India, it rose to<br />

4,50,000 tonnes in 1959. According to the report of Government of India (GOI 1961), bamboo to the<br />

level of 70 per cent was used as raw material in pulp industry in 1958–‘59. In India, bamboo <strong>for</strong>ests<br />

occupy about 10 million ha, roughly about 31 per cent of the total <strong>for</strong>est area of the country. Average<br />

yield of bamboo is 10-15 tonnes per ha per year. With a production of 3.23 million tonnes of bamboo<br />

a year, India is second only to China.<br />

The economics of industrial plantations of Bambusa bambos (Syn. B. bambos), one of the<br />

prime/dominant bamboo species in India was described by Bhat (1970) 86 . He determined the st<strong>and</strong>ing<br />

cost of production of raw material <strong>for</strong> pulping by raising B. bambos as an under-storey crop in the<br />

deciduous <strong>for</strong>ests of India, taking into account the establishment <strong>and</strong> cultural costs. The average<br />

physiological life cycle of this bamboo is reported to be 42 years, of which 2 years are spent in<br />

nursery. The remaining 40 years can be fixed as the rotation <strong>for</strong> this species, <strong>and</strong> the regular cutting<br />

cycle begins at around 10 years from planting. Shanmughavel (1995) 190 discussed the <strong>and</strong> economic<br />

aspects (costs <strong>and</strong> returns from a 6-year-old plantation) of Bambusa bambos <strong>and</strong> suggested that this is<br />

an ideal species <strong>for</strong> commercial plantations.<br />

K<strong>and</strong>elaki (1976) 103 described the investigations in Soviet Georgia on the technical <strong>and</strong> economic<br />

feasibility of utilizing home-grown bamboos as raw material in the pulp <strong>and</strong> paper industry. Selective<br />

harvesting of a high yielding plantation of Phyllostachys edulis of 3-year- old culms yielded 52.73<br />

tonnes per ha per year (as against 4.5 tonnes per ha per year <strong>for</strong> a fir plantation <strong>and</strong> 5.5 tonnes per ha<br />

per year <strong>for</strong> alder). The cost of 1 tonne of bamboo was calculated at 11.77 rubles against 44 rubles <strong>for</strong><br />

conifer pulpwood grown in Georgia. The pay-back period <strong>for</strong> a P. edulis plantation was 7 years from<br />

establishment.<br />

Specific techniques of economic analyses, ie, benefit–cost analysis, marginal analysis, budgeting <strong>and</strong><br />

market research, were suggested by McCormac (1985) 108 viz-a-viz specific bamboo resources <strong>and</strong><br />

development objectives. Wu <strong>and</strong> Xu (1987) 240 described the world level economic benefit of paper<br />

37


making with bamboo(Singh 1989) 77 projected the estimated dem<strong>and</strong> <strong>for</strong> paper <strong>and</strong> paperboard in<br />

India <strong>for</strong> 2000 <strong>and</strong> the requirement of bamboo. Xie et al. (1999) 242 developed a st<strong>and</strong> model of pure<br />

<strong>and</strong> mixed plantation of Moso bamboo (Phyllostachys pubescens) <strong>for</strong> pulp. A model <strong>for</strong> calculating<br />

new culm yield of pure Moso bamboo st<strong>and</strong>s was established based on the non-linear relationship<br />

between culm yield, <strong>and</strong> bamboo st<strong>and</strong> density <strong>and</strong> culm age components. The best high yield<br />

structure <strong>for</strong> pure Moso st<strong>and</strong>s will have a st<strong>and</strong> density of 3000 culms per ha <strong>and</strong> will produce a culm<br />

yield of 31.1 tonnes per ha every two years. In mixed Moso <strong>and</strong> broad leaved tree st<strong>and</strong>s, the most<br />

important structural factor influencing productivity was the bamboo <strong>and</strong> tree density ratio, <strong>and</strong> the<br />

second most important factor was the bamboo st<strong>and</strong>ing density. A bamboo st<strong>and</strong>ing density of 2100<br />

culms per ha mixed st<strong>and</strong> will produce 22.8 tonnes per ha of culms every two years. Yang et al.<br />

(1999) 129 determined the productivity of Moso bamboo st<strong>and</strong>s by habitat <strong>and</strong> management, with<br />

significant differences found between different management regimes, site qualities or status of the<br />

original bamboo st<strong>and</strong>. Yuan et al. (1999) 130 suggested a 3-use management system (bamboo shoots,<br />

young bamboo <strong>for</strong> pulping <strong>and</strong> mature bamboo <strong>for</strong> wood purpose) <strong>for</strong> Moso bamboos in China. The<br />

new management system was more successful than the usual management <strong>for</strong> 2-uses (shoot <strong>and</strong><br />

wood). Detailed data on comparative yield <strong>and</strong> their economics were provided by them.<br />

38


6. CHEMICAL COMPOSITION<br />

In<strong>for</strong>mation on the chemical composition of bamboo is important as far as its utilization <strong>for</strong> pulping<br />

is concerned. Holocellulose (also called hemicelluloses) is the main component contributing to the<br />

strength of paper made from bamboo. The high cellulose content <strong>and</strong> a yield of 40-50 per cent pulp<br />

make bamboo an ideal raw material <strong>for</strong> manufacture of paper. From the angle of paper production, the<br />

average chemical composition of bamboo (on OD weight basis) is :<br />

Holocellulose 61 - 71%<br />

Lignin 20 - 30%<br />

Pentosans 16 - 21%<br />

Silica 0.5-4.0%<br />

Ash 1.0-9.0%<br />

The solubility in different solvents are :<br />

Cold water 1.6- 4.6%<br />

Hot water 3.1- 7.0%<br />

Alcohol-benzene 0.3- 7.8%<br />

1% NaOH 15 - 39%<br />

Apart from the high cellulose content, the other factors like high lignin, pentosans <strong>and</strong> silica contents<br />

as well as higher solubilities are not in favour of ideal pulping conditions. But, since it contains higher<br />

cellulose content, bamboo is a preferred raw material <strong>for</strong> pulping.<br />

Bhargava (1945) 136 provided data on the proximate chemical analysis of 10 bamboo species. In<br />

Dendrocalamus strictus, it was found that the proximate chemical composition varied with locality<br />

<strong>and</strong> also due to flowering.<br />

<strong>Bamboo</strong> pulps from Ochl<strong>and</strong>ra abyssinica <strong>and</strong> Oxytenanthera abyssinica have high alpha-cellulose<br />

content (Monteiro 1949 306 ; Seabra 1954) 189 . Numerous reports are available on the chemical<br />

composition of different species of bamboos grown in different countries [<strong>for</strong> example, Istas <strong>and</strong><br />

Hontoy (1952) 219 <strong>and</strong> Istas et al. (1956) 159 on the Belgian Congo species Sasa japonica, S. kurilensis,<br />

Bambusa hoffii, B. vulgaris, Gigantochloa aspera <strong>and</strong> Ochl<strong>and</strong>ra travancorica; Monsalud <strong>and</strong><br />

Tamolang (1962) 8 on some Philippine species; Tono (1963) 261 on some Japanese bamboos; Nair<br />

(1970) 9 , Maheshwari et al. (1976) 171, 227 , Azzini (1976) 366 , Bhola (1976) 218 , K<strong>and</strong>elaki (1977) 103 ,<br />

Guha et al. (1980) 452 , Karim et al. (1994) 407 on the Indian species Dendrocalamus strictus,<br />

Bambusa bambos, Oxytenanthera monostigma, Bambusa vulgaris, Bambusa tulda, Phyllostachys spp.<br />

<strong>and</strong> Melocanna baccifera; Ku (1971) 165 on Taiwan bamboos including Bambusa beecheyana Munro.<br />

39


var. pubescens; Razzaque et al. (1981) 233 on the Bangladesh bamboo species Melocanna baccifera,<br />

Oxytenanthera nigrociliata, Dendrocalamus longispathus, Bambusa tulda <strong>and</strong> Neohouzeaua dullooa;<br />

Xia (1989) 241 on eight Chinese species]. Proximate chemical composition of the two most important<br />

Indian bamboos, viz., Dendrocalamus strictus <strong>and</strong> Bambusa bambos is given in Appendix 3A. No<br />

appreciable change in the chemical composition of 3- to 36-month-old Bangladesh bamboos was<br />

observed indicating that the bamboo probably attains maturity within its first year of growth<br />

(Razzaque et al. 1981) 233 . Sekyere (1994) 234 reported that Bambusa vulgaris from Ghana had a<br />

cellulose content of 61.2 per cent <strong>and</strong> lignin content of 26.8 per cent indicating its suitability <strong>for</strong><br />

making good quality pulps. Appendix 3A gives the chemical composition of the two most important<br />

Indian bamboo species, Dendrocalamus strictus <strong>and</strong> Bambusa bambos.<br />

The within culm variation of the chemical constituents is also reported to be significant. In<br />

Bambusa vulgaris, the basal portion is reported to have the lowest holocellulose content (70.8 %) <strong>and</strong><br />

highest 1% NaOH solubility (26.5%) as compared to the middle <strong>and</strong> top portions. Significant<br />

interactions were reported between the chemical composition <strong>and</strong> fibre morphology (Jamaludin <strong>and</strong><br />

Abdul Jalil 1994 330 ; Jamaludin et al. 1994) 331 . Regardless of age <strong>and</strong> culm height, the high cellulose<br />

<strong>and</strong> low ash content together with fibre characteristics of Gigantochloa scortechinii from Malaysia<br />

were found beneficial to pulping process (Jamaludin et al. 1993 161 ; Abdul Latif Mohamod et al.<br />

1994) 324 . Variations in chemical constituents due to age (1- to 6-year-old culms of Bambusa bambos)<br />

were reported by Shanmughavel (1995) 190 .<br />

The silica in bamboo causes problems in pulping. Tsuji <strong>and</strong> Ono (1966) 433 reported the ash <strong>and</strong> silica<br />

contents of 14 tropical bamboo species used <strong>for</strong> pulping. The Philippine species Gigantochloa levis,<br />

G. aspera, Schizostachyum lumampao, Bambusa blumeana, B. vulgaris <strong>and</strong> B. vulgaris var. striata<br />

are reported to have a higher range of ash <strong>and</strong> silica content. A positive correlation between the silica<br />

content <strong>and</strong> the specific gravity <strong>and</strong> cell wall thickness in Bambusa blumeana was reported by Espiloy<br />

(1982) 280 . Sadwarte <strong>and</strong> Prasad (1978) 562 described the process of removing silica from bamboo<br />

prior to pulping. A wax of Bambusa bambos culms causing problems in chipping <strong>and</strong> pulping can be<br />

reduced by treatment with steam <strong>for</strong> two hours. The wax was chemically analysed <strong>and</strong> found to be of<br />

industrially low quality (Beri et al. 1967) 135 .<br />

The chemical analysis of 3-year-old culms of Dendrocalamus strictus revealed that the material<br />

contains 64.8 per cent holocellulose. The main structural component of the bamboo hemicelluloses<br />

was reported to be 4-O-methyl glucuronoarabino xylan (Karnik 1960 296 ; Karnik et al. 1963) 297 . The<br />

hemicellulose of Dendrocalamus strictus is reported to be composed of glucuronoxylan having a<br />

molecular weight of 6600 containing D-xylose <strong>and</strong> D-glucuronic acid units in the molar proportion of<br />

approximately 9:1 (Ingle <strong>and</strong> Bose 1969) 293 . The hemicellulose contains 78.0per cent xylose, 9.4 per<br />

40


cent arabinose <strong>and</strong> 12.8 per cent uronic acid; the acetyl <strong>and</strong> methoxyl value being nil (Negi 1969 309 ;<br />

1970) 310 . The hemicellulose of Bambusa bambos contains 78.8 per cent xylose, 11.6 per cent<br />

arabinose <strong>and</strong> 1.8 per cent galactose (Guha <strong>and</strong> Pant 1967) 394 . Xylose (82-92% yield) was the main<br />

constituent of the hemicelluloses isolated from Dendrocalamus strictus, D. hamiltonii <strong>and</strong> Melocanna<br />

baccifera (Dhawan <strong>and</strong> Singh 1982) 278 . Glucose, arabinose, rhamnose <strong>and</strong> glucuronic acid were also<br />

found to be present in small amounts in all the hemicellulose isolates. The yield of sugars was highest<br />

in the case of D. strictus whereas pentosans <strong>and</strong> methoxyl content were the highest in the case of D.<br />

hamiltoni, Melocanna baccifera had the lowest yield of sugars, pentosans <strong>and</strong> methoxyl content.<br />

As pentosans constitute more than 85 per cent of the hemicelluloses, their effect on pulping<br />

characteristics is important. The pentosans are reported to be retained in the cellulose pulps even after<br />

a final stage of cold-alkali purification with 17.5per cent NaOH. This suggests that there are ‘alkali<br />

resistant’ pentosans in close association with the cellulose proper (Negi 1970) 310 . A probable inter-<br />

relation between cellulose, lignin <strong>and</strong> hemicellulose in Dendrocalamus strictus is described by<br />

Mukherjea <strong>and</strong> Guha (1971) 307 in their studies on the methods <strong>for</strong> isolating cellulose from lignin <strong>and</strong><br />

pentosan components. Once the pentosans are rendered non-resistant, treatment with alkali be<strong>for</strong>e<br />

chlorite treatment produces pulps with a high content of resistant pentosans whereas chlorite treatment<br />

alone makes the pentosans non-resistant to alkali extraction (Guha <strong>and</strong> Negi 1972) 394 . Maximum<br />

amount of alkali resistant pentosans are retained in chlorite pulp <strong>and</strong> minimum in the sulphate pulp of<br />

Dendrocalamus strictus (Singh et al. 1974) 317 . Biyani et al. (1967) 378 obtained a pulp with low<br />

pentosan content from Bambusa bambos by nitric acid pulping. Prehydrolysis /sulphate process may<br />

be the only effective means of removing the pentosans from bamboo chips (at a cost of considerable<br />

loss of alpha-cellulose) <strong>and</strong> thus enabling a dissolving-grade pulp to be obtained (Bawagan 1968) 268 .<br />

The pentosans present <strong>and</strong> ash content of the various bamboos used in India <strong>for</strong> making rayon pulp<br />

were reported by Saboo (1992) 482 .<br />

<strong>Bamboo</strong> lignin is a typical grass lignin composed of mixed dehydrogenation polymers of coniferyl,<br />

sinapyl <strong>and</strong> p-coumaryl alcohols. The unique feature of bamboo lignin is that it contains 5-10 per cent<br />

ester of p-coumaric acid (Higuchi 1958 288 , Higuchi <strong>and</strong> Kaivamura 1966) 289 . Lignin of D. strictus is<br />

found to be composed of two fractions, one carrying high methoxyl value (19%) <strong>and</strong> the other having<br />

low value (2%) (Pant et al. 1975) 311 . The <strong>for</strong>mer is easily extractable under mild conditions whereas<br />

the latter requires drastic conditions. Aldol type side chain (R-CH-(OH)-CH2-CHO) <strong>and</strong> presence of<br />

bivanillyl structure with alpha-alpha linkage <strong>and</strong> 1-(4-hydroxy-3-methoxy)-3 hydroxy propane-1-one<br />

have been suggested <strong>for</strong> the bamboo lignin. Vanillic acid, vanillin <strong>and</strong> syringaldehyde are present as<br />

terminal moieties <strong>and</strong> are linked through beta-position of side chain of the main precursors via<br />

carboxylic acid group (Bist et al. 1974 275 ; 1975 276 ; Sabharwal et al. 1962) 313 .<br />

41


The difference in the lignin content of different species of Indian bamboos is reported to be negligible<br />

(24 ± 3%). The structure of bamboo lignin is more similar to hardwood lignin than that to conifer<br />

lignin. There is a correlation between the number of C 9 units of different bamboos <strong>and</strong> breaking<br />

length of the beaten pulps. Prehydrolysis of Dendrocalamus strictus will lead to decreased pulp yield<br />

at higher pH <strong>and</strong> at more cooking time. The lignin yield from prehydrolysate decreases as the pH goes<br />

towards acidic side. The methoxyl content in isolated lignin decreases with increase of lignin yield,<br />

while total hydroxyl increases. The acidic <strong>and</strong> aqueous lignins are less condensed than soda lignin.<br />

The chemical characteristics of milled lignin from Ochl<strong>and</strong>ra travancorica <strong>and</strong> the C, H, O <strong>and</strong> S<br />

content of Dendrocalamus giganteus lignin <strong>and</strong> their functional groups (methoxyl, hydroxyl <strong>and</strong><br />

carboxylic) <strong>and</strong> correlations between these <strong>and</strong> on the oxidation products of the lignins are also<br />

reported (Kapoor <strong>and</strong> Guha 1984 295 ; Vijan <strong>and</strong> Madan 1996) 263 . Clear differences in the structure<br />

exist between lignin isolates from sound <strong>and</strong> flowered bamboos.<br />

The extractive contents of Dendrocalamus strictus <strong>and</strong> their effect on sizing were described by Rao<br />

et al. (1983) 469 . The removal of extractive components will improve sizing substantially. The<br />

presence of oleic acid <strong>and</strong> its derivatives in the extractives are attributed to be responsible <strong>for</strong> this<br />

effect. Glucose <strong>and</strong> starch contents were higher in samples from middle <strong>and</strong> upper portions of the<br />

culms of 1-, 3- <strong>and</strong> 5-year-old Bambusa vulgaris vulgaris (Azzini et al. 1987) 266 . Fengal <strong>and</strong> Shao<br />

(1984) 244 reported 2.6 per cent extractives, 25.5 per cent lignin, 15.3 per cent alpha-cellulose <strong>and</strong><br />

24.3 per cent polyoses in Phyllostachys makinioi. The main polyoses are arabinoxylan with xylose :<br />

arabinose ratio of about 17 : 1. Ultra structure revealed through electron micrographic studies<br />

shows a lamellar deposition of lignin <strong>and</strong> polyoses within the secondary walls. Lignin is soluble by<br />

parts in alkaline as well as in acidic reagents. Sodium hydroxide solution removes cell wall substance<br />

mainly from secondary walls, whereas trifluoro acetic acid removes substance from compound middle<br />

lamellae. Wang <strong>and</strong> Lirn (1984) 438 , in their study on the high yield pulping of bamboo waste<br />

(shavings <strong>and</strong> nodes of Dendrocalamus latiflorus, Phyllostachys edulis <strong>and</strong> Phyllostachys makinoi)<br />

using neutral sulphite- anthraquinone process reported that the ash <strong>and</strong> extractive contents of bamboo<br />

wastes were higher than those of wood. Lignin content was lower than that of softwood, but similar to<br />

that of hardwood. The lignin content of Phyllostachys edulis was the highest.<br />

The nodal <strong>and</strong> internodal portions of bamboo culm differ in their chemical constituents. Internodal<br />

portion of Dendrocalamus strictus has higher holocellulose <strong>and</strong> lower lignin, pentosans, extractives<br />

<strong>and</strong> ash compared to its nodal portion (Maheshwari <strong>and</strong> Satpathy 1988) 175 . The contents of chemical<br />

components in Gigantochloa scortechinii increase with age <strong>and</strong> height level of the culms, but the<br />

correlation is insignificant (Abdul Latif et al. 1994) 324 . Regardless of age <strong>and</strong> culm height, the high<br />

cellulose content of this species makes it suitable <strong>for</strong> pulping.<br />

42


7. FIBRE MORPHOLOGY<br />

Fibre length of bamboo is generally greater than that of hardwoods. The fibre morphology of 12<br />

bamboo species from India showed a mean fibre length ranging from 1.01 to 4.03 mm (Bhargava<br />

1945) 136 . Various studies have been reported on the fibre dimensions of different bamboo species<br />

from different countries <strong>and</strong> their suitability <strong>for</strong> commercial pulping [Seabra (1954) 189 on some<br />

African bamboos; Istas et al. (1956) 159 ten species from Belgian Congo; Du (1957) 386 on seven<br />

Taiwan species including Sinocalamus latiflorus having the longest fibre; Ku (1971) 165 on the<br />

Thail<strong>and</strong> species Bambusa beecheyana Munro var. pubescens; <strong>and</strong> on the Indian species Bambusa<br />

vulgaris, Dendrocalamus strictus, Oxytenanthera monostigma <strong>and</strong> Melocanna baccifera by<br />

Maheshwari et al. (1976a) 227 , Azzini (1976) 366 <strong>and</strong> Guha et al. (1980) 457 ]. Varshney (1965) 262<br />

reported the effect of anatomical characteristics of bamboos on pulping. The quality of the cook,<br />

especially the mechanical properties of the pulp are determined by the degree of impregnation of<br />

cooking chemicals in the chips, the diffusion rate during cooking <strong>and</strong> the amount of screen rejects <strong>and</strong><br />

by the residual parenchyma <strong>and</strong> ray cells. Pulps made from different species of bamboo show less<br />

variation than expected (Grant 1962) 37 . The fibre content was found to increase with culm height <strong>and</strong><br />

decrease from outer to inner part of the culms in Phyllostachys reticulata of age 1-6 years (Kitamura<br />

1962) 332 . But, the variation in parenchyma proportion in this species due to age was not significant.<br />

The parenchyma proportion in Phyllostachys reticulata was very close to that of Dendrocalamus<br />

strictus Singh et al. (1971) 354 . In general, it is there<strong>for</strong>e probable that parenchyma proportion in<br />

different species varies within narrow limits only; fibre dimensions, however, vary widely in different<br />

species (Monsalud 1965) 338 .<br />

Chu <strong>and</strong> Yao (1964) 326 provided details on the fibre length, cell wall thickness <strong>and</strong> percentage of<br />

fibres <strong>and</strong> other elements of 33 Chinese bamboo species <strong>and</strong> classified these bamboos on the basis of<br />

fibre characteristics <strong>for</strong> pulp <strong>and</strong> paper. Out of these, 21 species were found promising <strong>for</strong> yielding<br />

high quality pulp. Later, Xia (1989) 241 reported the fibre length of eight Chinese bamboo species.<br />

The fibre dimensions, flexibility coefficients, Runkel <strong>and</strong> slenderness ratios of four Thai bamboo<br />

species were described by Premrasmi <strong>and</strong> Aranyaputi (1965) 63 . Monsalud (1965) 338 described the<br />

fibre characteristics of 13 Philippine bamboo species. Unlike woods, fibre dimensions or their derived<br />

values are not useful in classifying bamboos. The fibre dimensions of some Philippine bamboos <strong>for</strong><br />

long fibred paper pulps were described by Tamolang (1962) 355 , Monsalud <strong>and</strong> Tamolang (1962) 8<br />

<strong>and</strong> Zamuco (1972) 359 . The morphological as well as chemical composition <strong>and</strong> suitability <strong>for</strong><br />

pulping of various bamboo species as well as pulping processes were reviewed by Ukil (1961) 203 <strong>and</strong><br />

Witkoski (1964) 210 .<br />

43


Within a culm, the proportion of different cell types shows a regular pattern from interior towards<br />

periphery within the wall as well as from base to top (Liese <strong>and</strong> Mende 1969). But, between species<br />

Dendrocalamus strictus <strong>and</strong> Bambusa tulda, the variation in parenchyma proportion is found not<br />

significant. With increasing height, the amount of parenchyma cells decreases with corresponding<br />

increase in proportion of fibres.<br />

In brief, a number of domestic bamboos tested <strong>for</strong> paper pulp have shown a wide variation in the<br />

mean fibre <strong>and</strong> tissue characteristics as given below:<br />

Fibre length 152 0– 4030 µ m<br />

Fibre diameter 13.14–19.94 µ m<br />

Lumen diameter 2.18 – 9.94 µ m<br />

Cell wall thickness 3.71 – 6.16 µ m<br />

Parenchyma proportion 17.1 – 26.9%<br />

Singh et al. (1976 353 ; 1988) 237 described the fibre morphology of 12 Indian bamboo species<br />

(Appendix 3. B). No relationship could be found between fibre characteristics <strong>and</strong> strength properties<br />

of paper, since wide variations existed within species. Because of the variation within species, pulp<br />

sheet properties of bamboos could not be predicted from fibre dimensions or chemical composition.<br />

Fibre characteristics cannot be used as a criteria <strong>for</strong> classifying the bamboos <strong>for</strong> paper <strong>and</strong> pulp<br />

production. Fibre length is generally considered to be an important factor <strong>for</strong> tearing strength while<br />

the l/d ratio is associated with breaking length <strong>and</strong> burst factor of the wood pulp (Dinwoodie 1965).<br />

The average l/d ratio <strong>for</strong> bamboo is around 180 (Podder 1979) 15 .<br />

Studies on fractionated pulp of Dendrocalamus strictus have shown a highly negative correlation<br />

between parenchyma proportion <strong>and</strong> pulp sheet properties. However, along with fibre length,<br />

parenchyma proportion accounted <strong>for</strong> 94 per cent of the variation in the strength properties of the<br />

sheets (Singh et al. 1976) 534 . Within clump, variation of fibre length was reported <strong>for</strong> 12 Indian<br />

bamboo species (Pattanath 1972) 346 . While the fibre length in the lower portion of the culm is more<br />

than that at higher levels, the pattern of variation differs from species to species. Fibre length also<br />

does not show any consistent relationship with internode length. Variations have also been reported<br />

from outside to inside in bamboo walls (Liese <strong>and</strong> Grosser 1972) 336 . Thus, bamboo should be<br />

regarded as a physically heterogeneous mixture of fibres. A positive correlation between cell wall<br />

thickness, silica content, <strong>and</strong> specific gravity is reported in Philippine bamboos (Espiloy 1982) 280 .<br />

44


Based on the values of Runkel ratio obtained, Wai <strong>and</strong> Murakami (1984) 356 categorized different<br />

species from Myanmmar into groups A, B <strong>and</strong> C. Group A contains species having a substantial<br />

number of thin walled fibres (eg, Melocanna baccifera), group B contains a small number of thin<br />

walled fibres (eg. Bambusa polymorpha <strong>and</strong> Dendrocalamus membranaceus) <strong>and</strong> group C consists<br />

almost entirely of thick walled fibres with very small lumen (eg. Cephalostachyum pergracile,<br />

Bambusa tulda <strong>and</strong> Dendrocalamus longispathus). This grouping was very useful in evaluating <strong>and</strong><br />

explaining the sheet properties. The influence of fibre morphology on sheet properties was much<br />

greater in the fines-free pulp sheets than in the whole pulp sheets. The sheets of group A pulp were<br />

denser <strong>and</strong> had significantly better strength properties, except <strong>for</strong> tear index, than the sheets of other<br />

pulp groups of the same beating levels. The small amount of thin-walled fibres contributed to the<br />

burst index <strong>and</strong> the folding endurance of the group B fines-free pulp sheets.<br />

Data on the variation in fibre length, diameter, cell wall thickness <strong>and</strong> Runkel ratio of five bamboo<br />

species from Bangaladesh (Melocanna baccifera, Oxytenanthera nigrociliata, Dendrocalamus<br />

longispathus, Bambusa tulda <strong>and</strong> Neohouzeaua dulooa) with age revealed no appreciable changes in<br />

fibre dimensions with increasing age (from 3 - 36 months), indicating that the species probably attain<br />

maturity within their first year of growth (Razzaque <strong>and</strong> Siddique 1970) 68 . The fibre dimensions<br />

(average fibre length, diameter <strong>and</strong> cell wall thickness) <strong>and</strong> values derived from these (Runkel ratio,<br />

flexibility coefficient <strong>and</strong> relative fibre length) of 13 Bangladesh bamboo species were reported by<br />

Siddique <strong>and</strong> Chowdhury (1982) 352 , out of which three species were found very much suitable <strong>for</strong><br />

paper making. Studies on the effect of parenchyma cell content on the characteristics <strong>and</strong> properties of<br />

kraft pulp from Bambusa vulgaris with an optimum degree of delignification revealed that the<br />

presence of parenchyma cells will greatly reduce the pulp strength (Gomide et al. 1985) 248 .<br />

Significant within culm variations in fibre properties such as cell wall thickness, fibre length <strong>and</strong><br />

slenderness ratio have been reported <strong>for</strong> Bambusa vulgaris (Jamaludin <strong>and</strong> Abdul Jalil 1991) 330 . The<br />

basal portion is reported to have the longest fibres (3.51 mm) <strong>and</strong> highest slenderness ratio (245.0)<br />

compared to the middle <strong>and</strong> top portions. Studies on the fibre morphology of 1to 3-year-old<br />

Gigantochloa scortechinii from Malaysia showed that the fibres were long to about 3.0-5.0 mm with<br />

thick cell wall of 7 microns. The high Runkel ratio <strong>and</strong> low flexibility coefficient of this species<br />

indicated its undesirability <strong>for</strong> paper making; however, its long fibres with high slenderness ratio <strong>and</strong><br />

high holocellulose content make the species suitable <strong>for</strong> paper pulp production (Jamaludin et al.<br />

1993 161 ; Abdul Latif et al.1994 324 ; Abdul Latif <strong>and</strong> Mohamod Tamizi 1992). Within culm variation<br />

as well as variations due to age in the anatomical properties of Bambusa vulgaris, Bambusa blumeana<br />

<strong>and</strong> Gigantochloa scortechinii from Malaysia were reported by Abdul Latif <strong>and</strong> Mohamod Tamizi<br />

(1992). The fibre dimensions (except fibre wall thickness <strong>and</strong> Runkel <strong>and</strong> l /d ratios) increased with<br />

age. A fibre length of 2.65 mm with Runkel ratio of 1.03 reported <strong>for</strong> Bambusa vulgaris from China<br />

45


indicates its suitability <strong>for</strong> pulp <strong>and</strong> paper making (Sekyere 1994) 234 . The variations in fibre<br />

dimensions of Bambusa vulgaris from Malaysia based on a detailed study on 50 mature culms are<br />

also available (Jamaludin et al. 1994) 331 .<br />

The fibre properties of 22 Chinese bamboo species were described by Zhang (1995) 214 . Xia <strong>and</strong><br />

Zeng (1996) 358 described the fibre length, fibre width, cell wall thickness <strong>and</strong> cavity diameter of<br />

Bambusa distegus. The fibre length <strong>and</strong> cell wall thickness increased with age, while cavity diameter<br />

decreased.<br />

The fibre length <strong>and</strong> percentage content of +50, +65, +100 <strong>and</strong> –100 mesh fibres in both bleached<br />

<strong>and</strong> unbleached fibres from Bambusa bambos increased with age (Shanmughavel <strong>and</strong> Francis<br />

1996) 350 .. This result indicates that the species attains maturity during the first year of growth, so that<br />

<strong>for</strong> pulping purpose a 1-year cutting cycle can be followed. The finding of Mazzei <strong>and</strong> Rediko<br />

(1967) 179 that 1-year- old culms of Bambusa vulgaris gave the best pulp, is also in support of the<br />

suggested 1-year cutting cycle. These confirm the conclusion of Siddique <strong>and</strong> Chowdhury (1982) 352 .<br />

A comparison between 10 Indian bamboo species from a natural st<strong>and</strong> <strong>and</strong> two species from<br />

plantations on fibre dimensions did not reveal any significant correlations between fibre length,<br />

diameter <strong>and</strong> wall thickness. There was only a minimal increase in fibre length with increasing age of<br />

plantation grown Bambusa bambos (Shanmughavel <strong>and</strong> Francis 1998) 351 . However, there was a<br />

significant difference in fibre length across the culms.<br />

46


8. TYPES OF PULP<br />

Investigations <strong>for</strong> utilizing bamboo <strong>for</strong> different types of pulps started in the early 1890s (Sindall<br />

1909 192 ; Vincent 1911 205 ; Pearson 1912 186 ; Raitt 1912 231 ; Bhargava <strong>and</strong> Singh 1942) 26,137 .<br />

Bambusa bambos <strong>and</strong> Dendrocalamus strictus were reported to be suitable <strong>for</strong> the production of<br />

rayon pulp (Karnik <strong>and</strong> Sen 1948) 480 . The preparation of dissolving pulp from bamboo was described<br />

by Jogleker <strong>and</strong> Donofrio (1951) 162 . The use of Phyllostachys bambusoides of not more than 15 years<br />

of age from Savannah as a raw material <strong>for</strong> the preparation of dissolving grade pulp by prehydrolysis<br />

<strong>and</strong> sulphate pulping was described by Nafziger et al. (1960) 417 . This species was also suggested <strong>for</strong><br />

producing newsprint from chemical, semi-chemical <strong>and</strong> mechanical pulps. Dissolving pulp from<br />

Melocanna bambusoides was prepared by prehydrolysis sulphate process (Oye <strong>and</strong> Mizuno<br />

1970) 421 . From Ochl<strong>and</strong>ra travancorica, viscose rayon grade pulp was prepared by prehydrolysis<br />

sulphate process (Bhat <strong>and</strong> Viramani 1961) 475 . Prehydrolysis cooking of bamboos at 160 – 165 0 C<br />

<strong>for</strong> 4 hours followed by sulphate cooking at 160 0 C <strong>for</strong> 2 hours with a total sodium hydroxide 20 per<br />

cent <strong>and</strong> sulphidity 20 per cent, were suggested <strong>for</strong> the preparation of dissolving grade pulp (Tsuji et<br />

al. 1965) 432 . With these prehydrolysis conditions, pentosans were less than 5 per cent. The average<br />

degree of polymerisation compared favourably with that of similar pulps from wood. In comparison<br />

with wood, bamboo pulp has a higher rate of depolymerisation during aging, low cold-alkali solubility<br />

but comparatively high hot-alkali solubility, <strong>and</strong> a similar degree of crystallinity, but a higher rate of<br />

acid hydrolysis <strong>and</strong> lower levelling of degree of polymerisation (Oye <strong>and</strong> Mizuno 1970) 421 . The<br />

chemical properties <strong>and</strong> filterabilities of viscose showed no great difference from those of wood.<br />

Bambusa bambos was found superior to Phyllostachys reticulata in polymerisation <strong>and</strong> yield.<br />

<strong>Bamboo</strong> dust (wastes) can also be used <strong>for</strong> rayon <strong>and</strong> paper grade pulps <strong>and</strong> the process is described<br />

by Gupta <strong>and</strong> Jain (1966) 477 . Improved sulphate pulping procedures <strong>for</strong> preparing dissolving grade<br />

pulp from Dendrocalamus strictus (in which nearly 25% of the total lignin is held in the lumen <strong>and</strong><br />

between the primary <strong>and</strong> secondary walls of the fibres) are described by P<strong>and</strong>e (1966 523, 524 ;<br />

1967 525 ). The manufacture of dissolving pulp from the Chinese bamboos Sinocalamus latiflorus <strong>and</strong><br />

Bambusa stenostachya was described by Chang <strong>and</strong> Kuo (1976) 382 . The role of bamboos in the<br />

industrial manufacture of rayon grade pulp as well as a general picture of the process of industrial<br />

manufacturing of dissolving grade pulp from bamboo was described by Saboo (1992) 482 .<br />

Nitric acid pulping of bamboo <strong>for</strong> making paper-grade pulp from Bambusa bambos yielded highest<br />

screened pulp (40.9%) as obtained by cooking with 10 per cent nitric acid at 80 0 C <strong>for</strong> 6 hours <strong>and</strong><br />

extracting with 1 per cent sodium hydroxide at 120 0 C <strong>for</strong> 1 hour (Biyani et al. 1967) 378 . In view of<br />

the low pentosan content of the pulp, the process is promising.<br />

47


High-yield <strong>and</strong> good quality pulp, especially with regard to tearing strength suitable <strong>for</strong> paper making,<br />

can be produced from Bambusa vulgaris, B. vulgaris var. vittata <strong>and</strong> B. tuldoides, the most common<br />

bamboos found in Southern Brazil (Mazzei et al. 1967) 179 . One-year-old culms gave the best result.<br />

Indian bamboos were reported to be suitable <strong>for</strong> high-yield refiner mechanical pulping (Eberhardt<br />

1968) 362 . Escolano <strong>and</strong> Semana (1970) 147 reported the suitability of Bambusa vulgaris sulphate pulp<br />

<strong>for</strong> paper. On the basis of the quality of pulp, optimum conditions <strong>for</strong> producing kraft pulp from<br />

Oxytenanthera ritcheyi were described by Bh<strong>and</strong>ari (1981) 445 . Similarly, the cooking conditions <strong>for</strong><br />

producing bamboo + mixed hardwood pulps were also reported (Bhargava et al. 1985) 217 .<br />

48


9. PULPING<br />

Tissot (1970) 198 , on the basis of a study of four Indian mills, discussed the problem of making pulp<br />

<strong>and</strong> paper from bamboo. The cooking processes used (kraft, sulphite <strong>and</strong> neutral sulphite) <strong>and</strong> the<br />

bleaching <strong>and</strong> refining procedures followed were reviewed. He suggested solutions to overcome<br />

problems of blade wear due to the presence of silica.<br />

An account of investigations carried out on the pulping of bamboos at FRI, Dehra Dun, India, from<br />

1860 to 1944 was described by Bhargava (1945) 136 . Data on the semi-commercial pulping tests of<br />

Dendrocalamus strictus, D. hamiltonii, D. longispathus, Melocanna bambusoides, Bambusa bambos,<br />

B. polymorpha, B. tulda, Ochl<strong>and</strong>ra travancorica, Oxytenanthera nigrociliata <strong>and</strong> Teinostachyum<br />

dulooa were provided in this report. Later, Singh <strong>and</strong> Mukherjea (1965) 79 summarised the results of<br />

50 years of work at the FRI, Dehra Dun, India, on the pulping of various indigenous materials,<br />

including bamboos. Guha <strong>and</strong> Pant (1972) 6 reviewed the work carried out at FRI, Dehra Dun since<br />

1964 on various indigenous materials <strong>for</strong> pulp, paper <strong>and</strong> board industry including bamboos, reeds,<br />

grasses <strong>and</strong> agricultural residues. Singh <strong>and</strong> Guha (1981) 194 reviewed the research carried out on<br />

pulping, bleaching <strong>and</strong> paper making from different bamboo species occurring in India.<br />

9.1. Mechanical pulping<br />

The mechanical pulping of bamboo was reported by Bhat <strong>and</strong> Viramani (1957) 273 <strong>and</strong> they showed<br />

that the newsprint prepared from the furnish of groundwood pulp <strong>and</strong> chemical pulp in the ratio 70:30<br />

was as strong as the then imported newsprint.<br />

9.1.1. Thermo-mechanical pulping<br />

Soda thermo-mechanical (STM) <strong>and</strong> soda sulphite thermo-mechanical (SSTM) pulp from bamboo<br />

(Dendrocalamus strictus) was prepared from pre-impregnated chips, using a 10 per cent solution of<br />

NaOH <strong>and</strong> a mixture of NaOH <strong>and</strong> sodium sulphite in the ratio of 4:1 separately, respectively.<br />

Impregnated chips were heated at 120 0 C steam temperature <strong>for</strong> 3 minutes (Singh et al. 1987) 318 .<br />

9.1.2. Chemi-mechanical pulping<br />

Mukherjea <strong>and</strong> Guha (1965) 416 described a newly developed chemi-mechanical high-yield process<br />

used at FRI, Dehra Dun, India <strong>for</strong> pulping non-wood <strong>for</strong>est products including bamboos. The resultant<br />

pulps are reported to be suitable <strong>for</strong> preparing newsprint, writing, printing <strong>and</strong> grease-proof papers.<br />

49


9.2. Chemical pulping<br />

<strong>Bamboo</strong> pulp has been used in India from the beginning of the last century <strong>for</strong> making a variety of<br />

papers (Anonymous 1915). It was the Raitt process that was employed in those days <strong>for</strong> the pulping<br />

of bamboo in India (Raitt 1912 231 , 1925 & 1931) 424 . Digesting methods defers according to the<br />

different pulp characteristics desired (Tutiya <strong>and</strong> Imai 1940 202 ; Kato 1955) 408, 409 . Dendrocalamus<br />

strictus, Bambusa bambos <strong>and</strong> reed bamboo are the preferred species that were subjected to pulping<br />

by various chemical processes (Ahamed <strong>and</strong> Karnik 1944) 265 . Addition of sodium aluminate as an<br />

auxiliary was found to increase the alpha-cellulose content of the pulp, but the ash content was<br />

increased. An important factor in bamboo pulping is to achieve good penetration of the cooking<br />

chemicals into the bamboo tissue. This difficulty is caused by the presence of an impenetrable<br />

epidermis <strong>and</strong> strong bundle sheaths as well as the limited area of conducting channels <strong>and</strong> complete<br />

absence of rays (Desp<strong>and</strong>e 1953) 143a . Severe mechanical crushing of the bamboo <strong>and</strong> chipping to<br />

short particles were suggested as the means of resolving this problem. Pressure impregnation cooking<br />

developed later improved the quality of pulps (Istas et al. 1956) 159 .<br />

Belvin (1957) 25 described the research ef<strong>for</strong>ts in bamboo pulping in South America. The process of<br />

making the “Joss” paper (ceremonial paper) from Bambusa stenostachya, B. oldhamii,<br />

Dendrocalamus latiflorus <strong>and</strong> Phyllostachys pubescens in China was described by Perdue et al.<br />

(1961) 363 .<br />

9.2.1. Alkaline pulping processes<br />

9.2.1.1. Soda pulping<br />

Gremler <strong>and</strong> McGovern (1960) 391 reviewed the history of cold-soda pulping, emphasizing the<br />

various continuous methods used. Pulping Bambusa polymorpha showed that short impregnation<br />

periods would result in completely defibrated pulp <strong>and</strong> high freeness. Good quality h<strong>and</strong>-made paper<br />

was produced from the cold- soda bamboo pulp (Rao et al. 1962) 364 . Later, Nicholas <strong>and</strong> Navarro<br />

(1964) 419 evaluated the cold-soda pulps from some Philippine bamboos. The characteristics of<br />

unbleached bamboo cold-soda pulp was described by Islam et al. (1989) 511 (Appendix 5.B).<br />

Sulphite process being the best <strong>and</strong> soda process the poorest <strong>for</strong> pulping bamboo, Devgan (1964) 425<br />

suggested the incorporation of 2 per cent elemental sulphur in the soda-cooking of Dendrocalamus<br />

strictus.. The kinetics of alkaline pulping of Dendrocalamus strictus was described by Singh <strong>and</strong><br />

Guha (1975) 429 . Up to a yield level of 70 per cent there was a linear correlation between the lignin<br />

content <strong>and</strong> kappa number as well as between lignin- carbohydrate ratio <strong>and</strong> yield. Regression<br />

equations were also developed <strong>for</strong> these parameters.<br />

50


9.2.1.2. Kraft (sulphate) pulping<br />

A kraft cooking conditions of 20-22 per cent alkali, 25 per cent sulphidity, 162-177 0 C temperature<br />

<strong>and</strong> 5-6 hours cooking time <strong>for</strong> the pulping of culms of all ages in a mixture including nodes, were<br />

used initially (Raitt 1912) 231 . A fractional method of digestion was developed later which involved<br />

10 per cent total alkali on air-dry bamboos at a concentration of 2 per cent alkali <strong>for</strong> 2 hours at<br />

115-121 0 C <strong>for</strong> the first stage followed by a second stage consisting of a total alkali of 18 per cent on<br />

air-dry bamboo at a concentration of 6 per cent cooking liquor <strong>for</strong> 3 hours treatment at 150 0 C. The<br />

spent liquor from the second stage of digestion was used <strong>for</strong> the first stage. The pre-cook could be<br />

considered as buffered soaking at high temperature, to achieve penetration without damage to the<br />

carbohydrates prior to the actual cooking reactions. Yield of 45-50 per cent unbleached pulps was<br />

obtained. The sulphate pulping of reed bamboo was reported to produce 92.7 per cent alpha-cellulose<br />

(Anonymous 1947). The requirements of alkali charges <strong>for</strong> the unbleached <strong>and</strong> bleached grades of<br />

bamboo pulp at temperatures of 160-170 0 C <strong>for</strong> several hours were described by Anonymous (1949)<br />

<strong>and</strong> Sproull (1955) 472a . Bambusa vulgaris from Mexico was reported to be suitable <strong>for</strong> kraft<br />

pulping (Carrasco <strong>and</strong> Salvador 1961) 30 . The giant Philippine bamboo Gigantochloa aspera was<br />

reported to produce sulphate pulps of excellent tearing strength (Monsalud 1964) 58 . By maintaining<br />

optimum conditions <strong>for</strong> sulphate cooking, it was possible to obtain good quality kraft pulp with a<br />

yield of 45 per cent from Neohouzeaua dulooa (Nepenin <strong>and</strong> Bang 1969) 467 . The kraft/sulphate pulps<br />

were darker <strong>and</strong> hard to bleach, but were strong enough <strong>for</strong> packaging products. Later, Kadarisman<br />

<strong>and</strong> Silitonga (1974) 405 described the sulphate pulping of some South-East Asian bamboos. Sulphate<br />

pulping of Dendrocalamus giganteus was tried <strong>and</strong> results were compared with those of D. strictus,<br />

the main species of bamboo used <strong>for</strong> pulp <strong>and</strong> paper in India. D. giganteus is a better raw material <strong>for</strong><br />

both unbleached <strong>and</strong> bleached pulps (Guha et al. 1975) 41 . Unbleached pulp from Bambusa tulda by<br />

kraft process can be produced with a yield of up to 44.1 per cent the species is suitable <strong>for</strong> the<br />

manufacture of wrapping, writing <strong>and</strong> printing papers (Bhola 1976) 218 .<br />

9.2.1.3. Kraft-anthraquinone (AQ) pulping<br />

Anthraquinone (AQ) can act as a pulping catalyst <strong>and</strong> increase the rate of delignification <strong>and</strong> the alkali<br />

dem<strong>and</strong>. Low sulphidity (15%) kraft pulping of muli bamboo (Melocanna baccifera) with<br />

anthraquinone (0.05%) increased the pulp yield by 2 per cent of oven-dried bamboo compared with<br />

that from low sulphidity kraft pulping alone, <strong>and</strong> by 0.8 per cent over that of normal (25% sulphidity)<br />

kraft pulping (Maheshwari 1979 464 ; Nazak 2et al. 1979) 465 . The viscosity of AQ-catalysed low<br />

sulphidity kraft pulps was almost equal to that of the normal kraft control <strong>and</strong> better than that of the<br />

pulp from low sulphidity (15%) kraft pulping alone. Burst, tear <strong>and</strong> tensile strength properties were<br />

almost the same as or better than that of pulp obtained in normal kraft pulping. The use of AQ is<br />

51


there<strong>for</strong>e, not only beneficial at low sulphidity in improving the yield <strong>and</strong> quality of the pulp but it<br />

will also lead to reduction of air pollution because of the lower sulphidity input (Bhowmick et al.<br />

1991 376, 447 ; 1992) 449 . A tentative economic analysis of kraft <strong>and</strong> soda-anthraquinone pulping of<br />

muli bamboo showed that better benefits could be achieved in soda + AQ pulping compared with soda<br />

pulping (Goyal <strong>and</strong> Misra 1982 456 ; Bhowmick et al. 1992) 449 . Bh<strong>and</strong>ari (1981) 445 prepared kraft<br />

pulps from Oxytenanthera ritcheyi by three different cooking schedules. On the basis of pulp<br />

evaluation <strong>for</strong> various strength properties, kappa number <strong>and</strong> unbleached pulp yield, optimum pulping<br />

conditions, O. ritcheyi was a suitable raw material <strong>for</strong> the production of wrapping <strong>and</strong> writing<br />

/printing papers. Vapour phase kraft pulping of Dendrocalamus strictus was described by Goyal <strong>and</strong><br />

Misra (1982) 492 .<br />

9.2.1.4. High-yield kraft pulping<br />

To improve the pulp yield to about 60-64 per cent, a process <strong>for</strong> the separation of fibres <strong>and</strong><br />

parenchyma <strong>and</strong> separate digestion of both, followed by blending was developed by Vyas et al.<br />

(n.d.) 435, 436 . In the conventional sulphate pulping process, Dendrocalamus strictus containing 35.7<br />

per cent parenchyma <strong>and</strong> 64.5 per cent fibres gave a yield of 40.5 per cent only. About 91 per cent of<br />

original parenchyma contained in the bamboo was lost during the sulphate pulping. The improved<br />

process developed <strong>for</strong> high-yield pulping consisted of mechanically disintegrating bamboo chips <strong>for</strong><br />

splints to cause cleavage between fibres <strong>and</strong> parenchyma tissues <strong>and</strong> separately processing each tissue<br />

to pulp. From the mechanically separated fibre fraction chemical pulp was obtained by conventional<br />

digestion <strong>and</strong> beating process. The amount of bleached fibre pulp <strong>and</strong> parenchyma pulp obtained was<br />

the same. On mixing the two pulps, the final yield went up to 60-70 per cent of original bamboo. The<br />

pulp was found to be suitable <strong>for</strong> the production of cheap grade printing paper.<br />

9.2.1.5. Alkaline sulphite pulping<br />

The use of magnesium sulphite <strong>for</strong> the digestion of bamboo was reported (Tutiya et al. 1941) 201 <strong>and</strong><br />

later ‘magnifite’ process was reported <strong>for</strong> Dendrocalamus latiflorus (Chao <strong>and</strong> Pan 1963) 360 .<br />

Increased pulp yield, stronger pulp, shorter cooking time <strong>and</strong> reduced consumption of cooking<br />

chemicals, etc. were the advantages of this process. Rydholm (1966) 71 reported the sulphite pulp<br />

yield of Dowga bamboo Bambusa bambos.<br />

<strong>Bamboo</strong> chips, after impregnation with 40 per cent Na2SO3 <strong>for</strong> 24 hours <strong>and</strong> steam cooking <strong>for</strong> two<br />

minutes at 187 0 C (saturated steam pressure 1.26 MPa) was found not capable of producing good<br />

quality pulp at ultra-high yield. A combination of Na2SO3 with a lower percentage of NaOH was<br />

suggested to be a compromise between pulp yield loss <strong>and</strong> a gain in strength properties (Ray et al.<br />

1994) 67 .<br />

52


9.2.1.6. Alkaline sulphite - anthraquinone (AS – AQ) pulping<br />

Pulping bamboo using the alkaline sulphite process, with added anthraquinone facilitated easier<br />

pulping at comparatively low cooking temperatures <strong>and</strong> gave a higher yield, higher pulp brightness<br />

<strong>and</strong> easier bleaching than did kraft pulping (Jauhari <strong>and</strong> Ghosh 1984) 404 . Addition of 0.1% AQ<br />

offered the advantage of producing pulp of low kappa number (originally 25 <strong>and</strong> 32) with high pulp<br />

yield (originally 61<strong>and</strong> 60 respectively <strong>for</strong> kappa numbers 25 <strong>and</strong> 32) <strong>and</strong> also enabled the cooking<br />

temperature to be reduced. Alkaline sulphite-AQ pulping <strong>for</strong> Bambusa arundinaceae was reported by<br />

Wang (1982) 439 <strong>and</strong> Phyllostachys pubescens by Yao <strong>and</strong> Zou (1986) 442 .<br />

9.2.1.7. Neutral sulphite semichemical (NSSC) pulping<br />

Unbleached pulps of yield 56-68 per cent <strong>and</strong> with satisfactory strength properties were prepared from<br />

Dendrocalamus strictus by the NSSC process (Guha <strong>and</strong> Pant 1961) 395 . Bleaching of the NSSC pulp<br />

achieved 37-44 per cent yield with satisfactory brightness <strong>and</strong> strength properties <strong>for</strong> the production<br />

of white papers. The suitability of Bambusa vulgaris from Mexico <strong>for</strong> the NSSC pulping was reported<br />

by Carrasco <strong>and</strong> Salvador (1961) 30 . Acid soluble lignin to the extent of 1.5 per cent was reported<br />

from the bamboo NSSC pulp (Schowing <strong>and</strong> Johanson 1965).<br />

Out of the three pulping processes (cold-soda, neutral sulphite-NSSC <strong>and</strong> sulphate) compared by<br />

Chen et al. (1973) 383 , the NSSC pulps, although the lowest in yield, showed good strength (near that<br />

of imported Canadian kraft pulp) <strong>and</strong> to 72-88 per cent GE brightness by the C-E-H (chlorination<br />

/alkali extraction / hypo-chlorite bleaching sequence) schedule. The net yield of 48.3-53.2 per cent <strong>for</strong><br />

the bleached pulp was well above that obtained from fully cooked pulps. <strong>Bamboo</strong> NSSC pulps were<br />

suitable <strong>for</strong> high-grade papers.<br />

9.2.1.8. Neutral sulphite – anthraquinone (NS-AQ) pulping<br />

Bose et al. (1998) 395 conducted neutral sulphite anthraquinone pulping of muli bamboo in the<br />

laboratory. The total yield gain in the NS-AQ process was 6 to 7.9 per cent more than that of the kraft<br />

control at kappa number 20. The use of 0.1 per cent AQ was sufficient to give the desired effect. The<br />

strength properties of unbleached NS-AQ pulps were lower than those of kraft pulps.<br />

9.2.1.9. Kraft – semichemical pulping<br />

Semichemical pulp with encouraging yield <strong>and</strong> characteristics from muli bamboo (Melocanna<br />

baccifera) was obtained by cooking with white liquor from the recovery cycle, ie., by adopting the<br />

kraft semi-chemical process. The strength properties of the semi-chemical pulp were relatively lower<br />

than those of conventional kraft pulp, but it was possible to produce an acceptable grade of pulp under<br />

53


carefully chosen cooking conditions. The yield was higher (72-74%) than that of conventional kraft<br />

pulp (45-48 per cent). The optimum limit of sulphidity in kraft (sulphate) pulping of muli bamboo was<br />

about 17 per cent, yielding best quality pulp (Alam et al. 1997) 365, 443 .<br />

9.2.1.10. Rayon grade pulping<br />

Prehydrolysis kraft pulping of bamboo <strong>for</strong> preparing rayon grade pulp was studied by various authors<br />

(Gohel <strong>and</strong> Thoria 1936; Jogleker <strong>and</strong> Donofrio 1951 162 ; Horio <strong>and</strong> Takhama 1958 477a ; Karnik 1958<br />

477b 479a 480a 481<br />

& 1963 ; Karnik <strong>and</strong> Sen 1958 <strong>and</strong> Ramsarma 1962) <strong>and</strong> carried to the mill scale in<br />

the Gwalior, India (Rydholm 1965) 78 . Prehydrolysis kraft pulping of reed has also been investigated<br />

(Simionescu et al. 1956 482a ; 1957 482b & 1958 482c ; Ivanov 1957) <strong>and</strong> carried to the mill scale in<br />

Rumania.<br />

Dissolving grade pulp from Phyllostachys bambusoides was prepared by prehydrolysis sulphate<br />

pulping techniques. Influence of the condition of raw material <strong>and</strong> different variables in the hydrolytic<br />

treatment upon the yield <strong>and</strong> characteristics of the pulps under constant pulping <strong>and</strong> bleaching<br />

condition was described by Nafziger et al. (1960) 417 . Dendrocalamus strictus was reported to be<br />

suitable <strong>for</strong> rayon grade pulp by the sulphate prehydrolysis process (Karnik 1961) 478, 479 . Viscose<br />

rayon pulp from Ochl<strong>and</strong>ra travancorica was prepared by water prehydrolysis sulphate process (Bhat<br />

<strong>and</strong> Viramani 1961) 475 . Dissolving pulp can be prepared by prehydrolysis cooking at 160 or 165 0 C<br />

<strong>for</strong> 4 hours, followed by sulphate cooking at 160 0 C <strong>for</strong> 2 hours, with total NaOH 20 per cent, <strong>and</strong><br />

sulphidity 20 per cent. With these prehydrolysis conditions, pentosans were less than 5 per cent.<br />

Rayon grade pulp was prepared from Bambusa bambos, Dendrocalamus strictus, Melocanna<br />

baccifera <strong>and</strong> Ochl<strong>and</strong>ra travancorica by using prehydrolysis sulphate pulping (followed by multistage<br />

bleaching sequence consisting of chlorination/ caustic extraction/ hypochlorite/ chlorine<br />

dioxide/ SO2 treatment. Suzuki (1964) 484 reported about a Japanese technique, the ‘Kakusapu<br />

process’, <strong>for</strong> the preparation of viscose from bamboo. Pulps produced from B. bambos, B. vulgaris<br />

<strong>and</strong> B. aurea (Syn. B. atrovirens) using commercial digestion conditions were found not suitable <strong>for</strong><br />

rayon manufacture (Lele 1964) 480b . It was found that Bambusa bambos was superior to Phyllostachys<br />

reticulata in polymerisation <strong>and</strong> yield (Tsuji et al. 1965) 432 . Rydholm (1966) 71 reported the data on<br />

chemical composition (percentage of extractives, lignin, cellulose <strong>and</strong> hemicelluloses), sulphite pulp<br />

yield, alpha cellulose content <strong>and</strong> prehydrolysis kraft pulp yield <strong>for</strong> Dowga bamboo (Bambusa<br />

bambos). He also described the role of bamboo in India <strong>for</strong> dissolving pulp industry.<br />

Prehydrolysis may be the only effective means of removing the pentosans from the bamboo chips<br />

(though at a cost of considerable loss of alpha-cellulose) <strong>and</strong> thus enabling a dissolving grade pulp to<br />

be obtained (Bawagan 1968) 268 . Among many species evaluated Bambusa bambos, Dendrocalamus<br />

54


strictus, Melocanna bambusoides <strong>and</strong> Ochl<strong>and</strong>ra travancorica are commonly utilized <strong>for</strong> the<br />

production of rayon grade pulp (Singh <strong>and</strong> Bhola 1968) 483 . The relationship between pulping<br />

conditions <strong>and</strong> reactivity of dissolving pulp prepared from bamboo (Melocanna bambusoides) by the<br />

prehydrolysis sulphate process was examined by Oye et al. (1970) 421 <strong>and</strong> Oye <strong>and</strong> Mizuno<br />

(1972) 423 . <strong>Bamboo</strong> pulp has lower resistance to mercerisation than hardwood pulp made by similar<br />

process <strong>and</strong> has low resistance to sulphidation. Its filterability is similar to that of wood pulps. P<strong>and</strong>e<br />

(1970) 62 described a promising technique in sulphate pulping that permits the removal of sufficient<br />

pentosans to bring the pulp within the limits specified <strong>for</strong> dissolving grade pulp. The characteristics of<br />

rayon grade pulp produced from Indian bamboos were reported by Nair (1970) 9 (Appendix 5.C)<br />

Chang <strong>and</strong> Kuo (1976) 382 described the manufacturing of dissolving grade pulp from the Chinese<br />

bamboos, Sinocalamus latiflorus <strong>and</strong> Bambusa stenostachya. Kuang et al. (1985) 461 made a<br />

comparison of the mercerisation of kraft pulps from bamboo <strong>and</strong> spruce.<br />

9.3. Non-conventional <strong>and</strong> other pulping methods<br />

Hydrotropic pulping, as an ef<strong>for</strong>t to develop pollution-free pulping processes using sodium xylene<br />

sulphonate as solvent, was reported <strong>for</strong> making bamboo rayon grade pulp. In this method, the bamboo<br />

is cut, crushed, dried <strong>and</strong> then digested by means of a 30-50 per cent solution of aqueous sodium<br />

xylene sulphonate at about 160 0 C <strong>for</strong> 6 hours <strong>and</strong> at 180 0 C <strong>for</strong> 7-8 hours. After digestion the pulp is<br />

washed in a solution of about 20 per cent sodium xylene sulphonate <strong>and</strong> bleached. The lignin can be<br />

separated from the digestion liquor by adding water <strong>and</strong> the liquor can be used again. A yield of 46<br />

per cent unbleached pulp was obtained by this process from Bambusa tulda <strong>and</strong> 42 per cent from<br />

Phyllostachys bambusoides. The pulp had a high cellulose content <strong>and</strong> was suitable <strong>for</strong> rayon<br />

manufacture (Anonymous 1947).<br />

During hydrotropic pulping of bamboo, a fraction of pentosans is converted to furfural <strong>and</strong> dissolved<br />

in the hydrotropic liquor along with lignin. However, the sum of dissolved furfural <strong>and</strong> of pentosans<br />

remaining in the pulp is less than the pentosan content of bamboo. Approximately 50 per cent of alpha<br />

xylose is converted into furfural if the latter does not decompose in the hydrotropic solution. The<br />

proportion of converted xylose increases upon addition of acetic acid to the solution <strong>and</strong> decreases<br />

upon addition of lignin (Hasegava <strong>and</strong> Ito 1959) 287 . Schwenzon (1963 74 ; 1965) 75 reported the<br />

possibility of hydrotropic pulping of bamboo, especially using salicylic acid/ glycol at temperature<br />

160-170 0 C <strong>for</strong> 3-6 hours cooking period.<br />

Organosolv pulping of Dendrocalamus strictus using ethanol-water as the delignifying agent results<br />

in chemical pulps with yield 43-44 per cent. Use of sodium xylene sulphonate (1.0%) as a pulping<br />

additive can improve the strength properties: tensile index by about 5 per cent, tear index 30 per cent<br />

55


<strong>and</strong> burst index by about 15 per cent, but the tensile index <strong>and</strong> burst index was lower than that of<br />

bamboo kraft pulp of equivalent yield by about 20 per cent <strong>and</strong> 37 per cent respectively whereas tear<br />

index was slightly higher (4.0%). However, use of dodecyl benzene sulphonate sodium salt as<br />

pulping additive does not exhibit any significant influence on either type of pulp. Ethanol-water -<br />

sodium xylene sulphonate – bamboo pulp gives the best results in respect of strength properties.<br />

Sodium xylene sulphonate helps in stabilization of carbohydrates during the process of<br />

delignification, as a result of which an improvement in strength properties is observed (Singh et al.<br />

1989) 193 .<br />

The chlorination process is reported to be suitable <strong>for</strong> the production of bleachable pulp from<br />

Cephalostachyum pergracile (Mai-Aung 1961) 520 . Mahanta et al. (1979) 412 described the non-<br />

sulphur pulping of bamboo. Maheshwari (1982) 51 described some basic aspects of high-yield<br />

pulping. A laboratory study conducted by Zafar <strong>and</strong> Abdullah (1987) 122 indicated that bio-<br />

mechanical pulping (biological delignification) of bamboo by Coriolus versicolor might be possible.<br />

Under some economic considerations, nitric acid pulping of bamboo is worth commercial<br />

consideration (Bolker <strong>and</strong> Singh 1965 379 ; Mahanta <strong>and</strong> Chaliha 1970) 411 . A highest screened pulp<br />

yield of 40.9 per cent was obtained in the cooking of Bambusa bambos with 10 per cent HNO3 <strong>for</strong> 6<br />

hours <strong>and</strong> extracting with 1 per cent NaOH at 120 0 C <strong>for</strong> 1 hour. In view of the low pentosan content<br />

of the pulp, nitric acid pulping is promising <strong>for</strong> paper grade pulp (Biyani 1966 377 ; Biyani et al.<br />

1967) 378 .. Air-dry chips of Dendrocalamus strictus were cooked with nitric acid <strong>and</strong> sodium nitrite<br />

<strong>and</strong> the residual wood was extracted with dilute solution of caustic soda. Addition of sodium nitrite up<br />

to a certain extent enhanced the delignification while pulping by nitric acid process. The Klason lignin<br />

content, pentosan content <strong>and</strong> permanganate number of the pulp were found to decrease with increase<br />

in concentration of nitric acid <strong>and</strong> cooking time <strong>and</strong> temperature (Dhawan 1980) 385 ).<br />

Yamagishi et al. (1970) 440 delignified the Japanese Sasa bamboos (Sasa senanensis) by peracetic<br />

acid pulping at 70 0 C. The pulp yield was 57.3 per cent, with low lignin content. The brightness of<br />

the pulp was high, but the pentosan content was greater than 20 per cent. The pulp was markedly<br />

superior in breaking length <strong>and</strong> burst factor, <strong>and</strong> slightly superior in tear factor, to a semi-kraft pulp of<br />

similar yield <strong>and</strong> lignin content, while its folding endurance was satisfactory. Microscopic observation<br />

revealed fibres with an intact structure accompanied by many small parenchyma cells.<br />

9.4. Effect of variables - Factors affecting pulp yield<br />

Phyllostachys makinoi <strong>and</strong> six other species were pulped in the Raitt process <strong>and</strong> the effect of<br />

variables such as time, sulphidity, etc. were investigated <strong>and</strong> yields of 41-47 per cent were obtained<br />

56


(Du 1957) 386 . Yields of 82 <strong>and</strong> 62 per cent <strong>for</strong> cold soda semi-chemical <strong>and</strong> neutral sulphite pulps<br />

respectively were attained from Phyllostachys bambusoides, but stone grinding with <strong>and</strong> without<br />

chemical pre-treatment failed to produce satisfactory pulps from the mature culms (Nafziger et al.<br />

1961) 417 . The effect of temperature, pressure, alkali strength, <strong>and</strong> cooking time while pulping B.<br />

bambos, B. vulgaris <strong>and</strong> B. aurea (Syn. B. atrovirens) on their alpha cellulose content <strong>and</strong> optimum<br />

conditions <strong>for</strong> each species was reported by Lele (1964) 480b .<br />

Splitting of the digestion into two stages with an intermediate refining stage will increase the pulp<br />

yield of bamboos (Singh et al. 1970) 427 . The increase in yield of kraft bamboo pulp from 47.1 to 53.3<br />

per cent is without any significant effect on the strength properties. In the binary pulping process<br />

suggested <strong>for</strong> Dendrocalamus strictus, the chips are disintegrated by a kollergang or a refiner <strong>and</strong><br />

separated by screening into prosenchymatous <strong>and</strong> parenchymatous tissues. These are pulped<br />

separately by the sulphate process or by mechanical process. The pulps of yield 75 per cent (based on<br />

OD weight) are then mixed to obtain maximum yield of pulp of acceptable strength. Pulping<br />

procedures that give yields of approximately 40-45 per cent bleached chemical pulp from<br />

prosenchymatous tissues <strong>and</strong> approximately 29-35 per cent mechanical pulp from parenchymatous<br />

tissues, will help in using pulp mixtures with more than 50 per cent chemical pulp (Mukherjea 1967)<br />

182<br />

.. Refiner is more suitable than a kollergang, both <strong>for</strong> disintegrating chips <strong>and</strong> <strong>for</strong> grinding the<br />

steamed chips.<br />

Factors affecting the relative yield of sulphate pulp obtainable from bamboo (Dendrocalamus strictus)<br />

by two different cooking systems were evaluated. An alkaline treatment <strong>for</strong> the brown stock was also<br />

suggested <strong>for</strong> its high yield pulping (Banthia et al. 1972b&c). Mild alkali treatments on hard,<br />

moderately hard <strong>and</strong> normally cooked chemical <strong>and</strong> semi-chemical pulps of bamboo can produce soft<br />

pulps with minimum loss of yield <strong>and</strong> properties (Banthia et al. 1972) 371, 372 . Alkali treatment <strong>for</strong><br />

Arundinaria jaunsarensis (Ringal) at 30 0 C is beneficial as far as the pulp characteristics are<br />

concerened. The ash, pentosan <strong>and</strong> lignin content of the soaked material decreases with increase in<br />

cellulose content <strong>and</strong> in the concentration of alkali in the soaking liquor (Kh<strong>and</strong>uri <strong>and</strong> Biswas<br />

1960) 410 . Treatment with alkali be<strong>for</strong>e chlorite treatment will produce pulp with high content of alkali<br />

resistant pentosans whereas chlorite treatment alone will make the pentosans non-resistant to alkali<br />

extractions, <strong>and</strong> once pentosans are rendered non-resistant, it will be difficult to revert them back to<br />

resistant pentosans (Guha <strong>and</strong> Negi 1972) 394 .<br />

Kraft sulphate pulp yield from the Taiwan bamboos, Bambusa beecheyana var. pubescens, B.<br />

dolichoclada, B. stenostachya, Dendrocalamus latiflorus <strong>and</strong> Phyllostachys makinoi varied with<br />

cooking conditions, from 41 to 47 per cent (Chao <strong>and</strong> Pan 1972) 452 . Chen et al (1974) 361 prepared<br />

pulps <strong>for</strong> printing papers from five species of bamboo by three pulping processes: (a) two-stage<br />

57


digestion with hot water (150 0 C) followed by NaOH; (b) two-stage digestion with dilute NaOH (at<br />

100 0 C) followed by more concentrated NaOH; <strong>and</strong> (c) single-stage digestion with NaOH. In each<br />

trial the pulp was bleached in three stages be<strong>for</strong>e testing. Process (a) (2- stage digestion with hot water<br />

followed by NaOH) gave the highest yield <strong>and</strong> best physical properties of pulp <strong>and</strong> the lowest<br />

bleaching ratio, resulting in economical pulping. The pulp with the best physical properties was from<br />

Bambusa beecheyana var. pubescens <strong>and</strong> B. dolichoclada followed by B. stenostachya <strong>and</strong><br />

Dendrocalamus latiflorus. Phyllostachys makinoi was judged the least suitable. This result about the<br />

suitability of these species was in agreement with the earlier findings of Chao <strong>and</strong> Pan (1972) 452 .<br />

The effect of pH on the pre-hydrolysis of Dendrocalamus strictus was described by Devi et al.<br />

(1982) 384 . Chips were cooked in 1per cent H2SO4, 10 per cent NaOH or water <strong>for</strong> 90 or 150 minutes.<br />

Pulp yield decreased at higher initial <strong>and</strong> final pH values <strong>and</strong> with longer pre-hydrolysis. Kar et al.<br />

(1987) 406 described the effect of moisture content in the bamboo chips on pulping characteristics.<br />

Strength properties <strong>and</strong> bleachability of high yield pulp can be improved through chemical<br />

modifications of their lignin Singh et al. (1987) 318 Soda thermo mechanical (STM) <strong>and</strong> soda–sulphite<br />

thermo mechanical (SSTM) pulps of bamboo can be modified using chlorine, sodium sulphite <strong>and</strong><br />

hypochlorite.<br />

Alkali consumption, kappa number, unbleached pulp yield <strong>and</strong> chemical composition of 12 Indian<br />

bamboo species <strong>and</strong> their pulps are described by Singh (1989) 77 (Appendix 5.A)<br />

9.5. Effect of active alkali content<br />

Semana (1965) 426 , in his studies on the variables in sulphate pulping of the Philippine bamboo,<br />

Gigantochloa aspera has shown the interactions of active alkali concentration, kappa number <strong>and</strong><br />

sulphidity as well as cooking temperatures, pulp yield <strong>and</strong> pulp strength. A total of 12-24 per cent<br />

alkali (based on OD fibre) is sufficient to produce pulp ranging from high kappa numbers (up to 70)<br />

suitable <strong>for</strong> wrapping papers to easily bleachable grades with kappa numbers as low as 12.6. Yields<br />

<strong>and</strong> strength properties of pulps often are practically unaffected within a sulphidity range of 17.0-33.9<br />

per cent. If alkali content drops below 20 per cent, the kappa number will rise when sulphidity<br />

exceeded 25.5 per cent. Pulp from bamboo cooked at a maximum temperature of 180 0 C may show<br />

similar yields but will have low strength than those digested at 170 0 C. At lower alkali concentrations,<br />

180 0 C cooking will yield pulps with lower kappa number. For making wrapping paper <strong>and</strong> linear<br />

board stock, less than 20 per cent alkali <strong>and</strong> a maximum temperature of 170 0 C are preferable.<br />

Kraft semichemical pulps with the best physical properties were produced with the use of 15 per cent<br />

active alkali, which also enabled the yield to be increased by approximately 5 per cent compared with<br />

58


the conventional sulphate pulp. The kraft semi-chemical pulp was having excellent chemical<br />

properties, superior to larch <strong>and</strong> birch pulps (Ujiie <strong>and</strong> Matsmoto 1967) 473 . The low yield of bamboo<br />

pulp compared with that of hardwoods can be improved at the expense of strength by pulping with<br />

only 10 or even 5 per cent active alkali. Sulphate pulp at a screened yield of 41.4 per cent <strong>and</strong><br />

permanganate number of 15 from Bambusa vulgaris was produced using an active alkali of 15.6.<br />

Evaluation of the pulp characteristics showed that addition of beater adhesives will yield pulp with<br />

improved quality desired <strong>for</strong> bag <strong>and</strong> wrapping papers (Escolano <strong>and</strong> Semana 1970) 147 .<br />

To find out to what extent the cooking should be continued in kraft pulping of muli bamboo<br />

(Melocanna baccifera), the effect of active alkali charge was studied by Shah et al. (1991) 472 . The<br />

rate of delignification increased with an increase in active alkali charge. The transition points<br />

between the initial <strong>and</strong> bulk, <strong>and</strong> between the bulk <strong>and</strong> residual phases shifted to a lower lignin<br />

content with an increase in alkali charge. The use of an active alkali charge of 18 per cent as NaOH<br />

was sufficient to continue the cook in the delignification phase. Cooking of Bambusa vulgaris grown<br />

in Ghana with 18 per cent active alkali <strong>for</strong> 90 minutes yielded 54.2 per cent pulp with kappa number<br />

of 48.2 (Sekyere 1994) 234 . From the physical <strong>and</strong> strength properties of the pulp, it was found that B.<br />

vulgaris could produce good paper.<br />

9.6. Pulping of mixture of bamboo <strong>and</strong> hardwoods<br />

The cooking of different species (M. smithii <strong>and</strong> B. vulgaris) separately <strong>and</strong> as mixture <strong>and</strong> the papers<br />

made from both the pulps were described by Istas <strong>and</strong> Raekelboom (1960) 220 . For the production of<br />

unbleached pulps from a mixture of bamboo <strong>and</strong> mixed hardwoods, the minimum proportion of<br />

bamboo required is 50 per cent <strong>for</strong> good strength properties (Guha et al. 1966) 397 . Pilot scale trial<br />

production of bleached pulps from a mixture of 50:50 proportion of bamboo <strong>and</strong> mixed hardwoods at<br />

the Bengal Paper Mill, Raniganj, India was carried out under different conditions of sulphate pulping<br />

<strong>and</strong> bleaching. The ideal condition <strong>for</strong> the sulphate cooking is to use a sulphidity of 25 per cent with<br />

total chemicals of 15.5 per cent Na2O at 170 0 C <strong>for</strong> 2 hours. A pulp yield of 52 per cent can be<br />

achieved with permanganate number 18.8. Good breaking length (5310 m), burst factor (39.4), tear<br />

factor (120) <strong>and</strong> folding endurance (double folds of 240) can be expected.<br />

Studies on sulphate pulping of bamboo <strong>and</strong> mixed hardwoods showed that satisfactory high- <strong>and</strong> lowbrightness<br />

pulps <strong>and</strong> semi-bleached pulps could be obtained from a 50:50 mixture of bamboo <strong>and</strong><br />

mixed hardwoods (Singh et al 1968) 532 . Bhargava et al. (1969) 487 studied the effect of impregnation<br />

temperature <strong>and</strong> alkali concentration on the cooking of mixture of bamboo <strong>and</strong> mixed hardwoods. For<br />

a mixture of 60 per cent Dendrocalamus strictus <strong>and</strong> the remaining portion with hardwood, Boswellia<br />

serrata, the optimum unbleached pulp yield from chips cooked with 18.5-20 per cent active alkali was<br />

59


obtained at an impregnation temperature of 125 0 C. With higher alkali concentration, a lower<br />

impregnation temperature can be used, but the total yield of unbleached pulp will be reduced.<br />

Generally, bamboos <strong>and</strong> hardwoods have different cooking characteristics. Thus, ideally, it is better<br />

to cook separately <strong>and</strong> then blend the pulps together. <strong>Bamboo</strong> <strong>and</strong> a hardwood, Boswellia serrata,<br />

although grown under the same climatic <strong>and</strong> soil conditions, had different cooking characteristics;<br />

while a better grade pulp with less chemical consumption was produced from bamboo by the 2-stage<br />

temperature treatment method, it took a 4- stage impregnation method <strong>for</strong> B. serrata. <strong>Bamboo</strong> <strong>and</strong> B.<br />

serrata should there<strong>for</strong>e be cooked separately. However, as the total bleach dem<strong>and</strong> of the two pulps<br />

produced by the same method of cooking to the same kappa number level is very similar, pulps can be<br />

mixed together <strong>and</strong> bleached (Mishra <strong>and</strong> Rao 1969) 57 .<br />

Guha <strong>and</strong> Sharma (1970) 38 compared the chemical pulping of the hardwood, Casuarina equisetifolia<br />

with the bamboo Dendrocalamus strictus. They produced wrapping paper from unbleached pulps of<br />

C. equisetifolia, bamboo <strong>and</strong> a 75:25 mixture of the two. Yield <strong>and</strong> strength properties were higher <strong>for</strong><br />

the hardwood pulp, but it was not suitable <strong>for</strong> mechanical pulps. Pasaribu <strong>and</strong> Silitonga (1974) 497<br />

reported on trials of sulphate process of a 3-component mixture of hardwoods <strong>and</strong> four bamboo<br />

species (Bambusa bambos, B. vulgaris, Dendrocalamus asper <strong>and</strong> Gigantochloa ater). Cooking<br />

conditions were recommended <strong>for</strong> mixed pulping of bamboos with hardwoods. The strength<br />

properties of pulps containing different component ratios are also discussed.<br />

Barrichello <strong>and</strong> Foelkel (1975) 374 briefly described the Kleinert’s rapid alkaline pulping process <strong>and</strong><br />

gave the results of an experiment on the use of this method in the production of chemical pulp from<br />

Bambusa vulgaris var. vittata in Sao Paulo, Brazil. Pulp yields <strong>and</strong> strengths comparable with those<br />

obtained by the normal sulphate process were achieved, <strong>and</strong> there were savings in time <strong>and</strong> energy.<br />

They further found that in the case of blends containing 5 <strong>and</strong> 10 per cent bamboo (on total chip<br />

weight basis) with the hardwood Eucalyptus saligna, pulps were superior in yield <strong>and</strong> tear strength<br />

than the pulp from E. saligna, alone. There was no difference between the pulps in beating time, h<strong>and</strong><br />

sheet density, tensile <strong>and</strong> burst strengths (Barrichello <strong>and</strong> Foelkel 1975) 373 .<br />

Satisfactory kraft pulps have been obtained with (a) 70 per cent bamboo (Dendrocalamus strictus), 15<br />

per cent Mysore gum (Eucalyptus tereticornis) <strong>and</strong> 15 per cent dadup (Erythrina suberosa) <strong>and</strong> (b) 50<br />

per cent bamboo, 20 per cent Acacia arabica, 15 per cent Mysore gum <strong>and</strong> 15 per cent dadup<br />

(Krishnamachari et al. 1975) 48 . Alternatively, from a furnish containing 30 per cent chemical pulp<br />

from Ochl<strong>and</strong>ra travancorica <strong>and</strong> 70 per cent stone groundwood/ refiner mechanical/ cold-soda/<br />

sulphate pulp from stored <strong>and</strong> fresh Eucalyptus hybrid (Mysore gum), yielded newsprint of<br />

satisfactory strength properties (Guha et al. 1975) 41 . The preparation of mixed pulps from bamboos<br />

60


<strong>and</strong> hardwoods was described by Rai <strong>and</strong> Jaspal (1976) 498 also. Guha et al. (1980) 42 studied the yield<br />

<strong>and</strong> properties of pulps from bamboo (Dendrocalamus strictus) combined with different proportions<br />

of mixed hardwoods. They found that increase in the percentage of hardwood slightly increased the<br />

yield <strong>and</strong> but decreased the strength properties. Mixed pulps had satisfactory properties <strong>for</strong> the<br />

manufacture of writing, printing <strong>and</strong> wrapping paper <strong>and</strong> 3- layer board. Singh et al. (1981) 78 took<br />

Dendrocalamus strictus’s pulpability suitability index as 100 <strong>and</strong> compared its pulping characteristics<br />

with hardwoods, whose suitability indices was 100 + /- 15, <strong>for</strong> wrapping <strong>and</strong> writing /printing papers.<br />

Cold-soda pulps mixed with bamboo sulphate pulp in the ratio of 4:1 appeared suitable <strong>for</strong> newsprint.<br />

A mixture containing 30 or 40 per cent bamboo residue along with mixed hardwoods was also<br />

reported to give satisfactory sulphate pulp yield with good strength properties (Chiou <strong>and</strong> Tsai<br />

1982) 489 . Dwivedi et al. (1983) 490 described the high yield semi-chemical pulping of a mixture of<br />

bamboo <strong>and</strong> hardwoods.<br />

Small dosage addition of anthraquinone (AQ) in the kraft pulping of bamboos with mixed tropical<br />

hardwoods was reported to be beneficial (Nazak et al. 1979 ) 466 . Comparison of kraft pulping at 17<br />

per cent sulphidity on bamboo + mixed hardwoods (70:30) with bamboo (100 per cent) <strong>and</strong> mixed<br />

hardwoods (100 per cent) using anthraquinone revealed that anthraquinone addition in kraft pulping<br />

liquor is beneficial <strong>for</strong> the economy of pulping bamboo <strong>and</strong> tropical mixed hardwoods (Goyal <strong>and</strong><br />

Misra 1982 492 ; Rawath et al. 1985) 470 . A test case showed that the cost of pulp production could be<br />

reduced by Rs. 80/- tonne <strong>for</strong> bamboo <strong>and</strong> tropical mixed hardwoods in a medium sized pulp mill.<br />

Addition of different AQ dosages (0.05 to 0.25%) led to the reduction of the kappa number of<br />

bamboo+mixed hardwood pulp. Anthraquinone addition further helped to reduce the bleach<br />

consumption <strong>and</strong> improved the strength properties. AQ in small dosage (0.05%) is more effective in<br />

improving the yield of bamboo + mixed hardwood (70:30) digested at lower kappa number.<br />

Increasing the sulphidity from 0 to 20 per cent increased the pulp yield, reduced the rejects percentage<br />

<strong>and</strong> generally improved the strength properties. The effects were greatest in the 60:40 mixture of<br />

bamboo <strong>and</strong> mixed hardwoods <strong>and</strong> least in bamboo alone. Optimum sulphidity was 16 per cent <strong>for</strong><br />

bamboo <strong>and</strong> 18 per cent <strong>for</strong> bamboo/mixed hardwoods (Mishra et al. 1984) 415 . It was reported that<br />

bamboos needed only lesser alkali than hardwoods <strong>for</strong> producing bleachable pulps. It was also found<br />

that pulps in higher yield can be produced by separate digestion of bamboos <strong>and</strong> mixed hardwoods<br />

(Bhargava et al. 1985) 217 . Mixed hardwoods, to 20 per cent in the mixed furnish, had no detrimental<br />

effect on pulping quality <strong>and</strong> the physical <strong>and</strong> strength properties.<br />

As it will be expensive to have separate streams <strong>for</strong> the cooking of bamboo <strong>and</strong> hardwoods, the<br />

feasibility of pulping them together was investigated in a 50:50 mixture. Encouraging results were<br />

obtained in the laboratory as well as pilot-plant trails. The investigation revealed that as the<br />

61


percentage of hardwoods in the mixture increased, the breaking length improved, burst factor<br />

improved slightly; tear factor <strong>and</strong> double folds decreased with the increase in the amount of<br />

hardwoods (Singh 1989) 193 .<br />

9.7. Effect of age, position of culm <strong>and</strong> nodes<br />

Kitamura (1962) 332 described the variation in fibre content of 1- to 6-year-old Phyllostachys<br />

reticulata after pulping by soda process. Age played no significant part, but fibre content was found to<br />

increase with culm height <strong>and</strong> to decrease from outer to the inner parts of the culms. Culms (from 15year-old<br />

clumps at Campinas, Brazil) ranging from 1 to 4 years in age were pulped by soda process.<br />

The effect of culm age on pulp yield was significant at the 5 per cent level <strong>for</strong> 2-year-old culms only.<br />

No effects on tearing, tensile or folding strength could be attributed to culm age. Paper from 2-yearold<br />

culms, however, had a significantly higher bursting strength. Pulps were in general highly porous.<br />

Bambusa vulgaris can produce paper of good quality, resembling that from unbleached kraft soft<br />

wood pulp in tearing strength. From the industrial viewpoint, no advantage is gained by selecting<br />

culms of a particular age (Medina <strong>and</strong> Ciaramello 1965) 181 . Processing variables in pulping, age <strong>and</strong><br />

decay at the time of processing cause variation in the quality of sulphate pulp (Gopal 1968) 505 .<br />

Maheshwari <strong>and</strong> Satpathy (1984) 174 reported the pulp <strong>and</strong> paper making characteristics of bamboos<br />

of different ages. The pulp from young culms of sasa bamboo (Sasa kurilensis) was comparable with<br />

that of sulphite pulps of full-grown culms (Ujiie et al. 1986) 239 . In a study using 1-, 3-, or 5-year-old<br />

Bambusa vulgaris culms, shredded <strong>and</strong> treated with dilute H2SO4, fibre yield <strong>for</strong> paper making was<br />

higher in younger culms (Azzini et al. 1987) 266 . No appreciable changes in pulp yields <strong>and</strong> strength<br />

properties could be found with increasing the age of bamboos (Melocanna baccifera, Oxytenathera<br />

nigrociliata, Dendrocalamus longispathus, Bambusa tulda <strong>and</strong> Neohouzeaua dulooa) from<br />

Bangladesh, taken at three months intervals from 3 to 36 months (Razzaque et al. 1981) 233 .<br />

Subjecting Bambusa bambos of 1- to 6- years of age separately <strong>for</strong> pulping <strong>and</strong> evaluation of their<br />

characteristics indicated that this species attains maturity during the first year of growth, so that <strong>for</strong><br />

pulping purposes, it is suitable <strong>for</strong> a 1-year cutting cycle (Shanmughavel <strong>and</strong> Francis 1996) 350 .<br />

As bamboos probably attain maturity within their first year of growth, a 12- month cutting cycle can<br />

be recommended <strong>for</strong> pulping material.<br />

Muli bamboo belonging to four age groups (9, 21, 33 <strong>and</strong> 45 months) from Bangladesh was kraft<br />

pulped. A bleachable grade pulp was obtained at lower cooking times with 9-month-old bamboo than<br />

with older ones. The pulp yield at a given point of delignification was highest with 21-month-old<br />

bamboo. The strength properties of the pulp were independent of age Bose et al. 1988) 451 . The<br />

62


pulping properties of bamboos of different ages were investigated by Xia (1989) 241 also. It was found<br />

that 1- to 2-year-old bamboos were suitable <strong>for</strong> pulping. The pulping characteristics of bamboos of<br />

different ages <strong>and</strong> different portions of the culms of a few common varieties are described by<br />

Maheshwari <strong>and</strong> Satpathy (1983 172 & 1990) 228 . Jamaludin et al. (1992) 161 reported the effect of age,<br />

active alkali <strong>and</strong> beating revolutions on the pulping characteristics of 1- to 3-year-old Gigantochloa<br />

scortechinii. The pulp properties of 1- to 3-year-old bamboos show satisfactory strength properties.<br />

Variations of fibre morphology <strong>and</strong> chemical constituents of Gigantochloa scortechinii due to<br />

position in the culm (within culm), between culms, <strong>and</strong> age (1-, 2-, 3-year-old) revealed that the fibre<br />

dimensions increased with age <strong>and</strong> decreased with height. Chemical composition data correlated<br />

insignificantly with age <strong>and</strong> height. Contents of chemical components increased with age <strong>and</strong> height.<br />

Regardless of age <strong>and</strong> culm height, the high cellulose content of this species together with its fibre<br />

characteristics indicates its good potential as a raw material <strong>for</strong> pulp <strong>and</strong> paper (Abdul Latif Mohamod<br />

et al. 1994) 324 .<br />

Although nodal portions produce poor kraft pulp, it is not feasible to separate nodes <strong>and</strong> internodes<br />

be<strong>for</strong>e digestion <strong>and</strong> the reduction in yield <strong>and</strong> quality of whole bamboo pulp due to the nodal portion<br />

is not significant (Maheshwari et al. 1976) 171 . Nodal <strong>and</strong> internodal portions of the bamboo culms<br />

differ in their chemical constitution. Internodal portion of bamboo has higher holocellulose <strong>and</strong> lower<br />

pentosans, extractives, ash <strong>and</strong> lignin compared to nodal portion. Pulp yield is lower with more rejects<br />

in the case of nodal portion (Maheshwari <strong>and</strong> Satpathy 1988) 175 . Fibre length <strong>and</strong> strength properties<br />

of pulp from nodal region is also comparatively lower. As such bamboo culms show the intermediate<br />

trend in all properties. Evaluation of the pulp properties of Bambusa vulgaris from Ghana also<br />

showed that it is not necessary to separate the node from internode during pulping (Sekyere 1994) 234 .<br />

9.8. Optimum utilization<br />

About 50,000 tonnes of bamboo dust are being reported to be wasted in India every year, <strong>and</strong> with the<br />

increase in utilization of bamboo from one million tonnes to two million tonnes, this wastage will<br />

naturally be on the increase. Many reports suggest the possible avenue of utilization of bamboo<br />

wastes <strong>for</strong> pulping. This includes the production of pressed pulp boards by Asplund<br />

thermomechanical defibration process (Singh 1960) 76 ; <strong>for</strong> paper <strong>and</strong> rayon grade pulps (Gupta <strong>and</strong><br />

Jain 1966) 477 ; <strong>for</strong> the production of wrapping paper from the sulphate pulps <strong>and</strong> writing <strong>and</strong> printing<br />

papers from the bleached sulphate pulps (Guha et al. 1966) 457a . From bamboo shoot – sheath (BSS)<br />

of Sinocalamus latiflorus, after steam treatment, soda pulp was produced in the laboratory, <strong>and</strong> by<br />

neutral sodium sulphite in a paper mill; it was were found to have an average fibre length of 1.6 mm<br />

(equal to or longer than hardwoods), <strong>and</strong> suitable <strong>for</strong> making good quality printing paper <strong>and</strong><br />

corrugating medium, or <strong>for</strong> blending with other pulps. The yield was low (20% on oven-dried basis)<br />

63


(Ku <strong>and</strong> Pan 1975) 224 . Chang <strong>and</strong> Duh (1978) 139 also described the utilization of bamboo residue <strong>for</strong><br />

pulp <strong>and</strong> paper. Pulping of bamboo tops/twigs <strong>and</strong> branches was described by Ku (1978) 166 <strong>and</strong><br />

Maheshwari (1982) 170 . The beneficial effect of anthraquinone (AQ) on the alkaline pulping of<br />

bamboo wastes was also established (Wang 1981) 437 . The shavings <strong>and</strong> nodes of Dendrocalamus<br />

latiflorus, Phyllostachys edulis <strong>and</strong> P. makinoi were pulped using the neutral sulphite–anthraquinone<br />

process. Yields <strong>and</strong> pulp strength (breaking length, burst <strong>and</strong> tear factors) were reported <strong>for</strong> varying<br />

total alkali, alkali ratio <strong>and</strong> anthraquinone in the pulping process (Wang <strong>and</strong> Lirn 1985) 537 .<br />

64


10. BLEACHING<br />

Use of bleaching powder <strong>for</strong> the bleaching of bamboo chemical pulps has the problem of a reversion<br />

of colour to a brownish shade while storage. A two-stage bleaching using the application of 70-80 per<br />

cent of the total bleach dem<strong>and</strong> on the first stage <strong>and</strong> the remainder, 20-30 per cent, in the second<br />

stage overcomes the above issue of colour reversion (Bhargava 1945) 136 . An intermediate hot alkali<br />

wash with 0.1 per cent NaOH solution, containing about 2 per cent NaOH on the weight of air-dry<br />

pulp was given to partially bleached pulp at the end of first stage. After the second stage of bleaching,<br />

the pulp is thoroughly washed with water <strong>and</strong> then poured with chlorine or bleaching powder solution<br />

in the order of 0.1-0.2 per cent or 0.3-0.6 per cent respectively, on the weight of the pulp. Pulps<br />

bleached by this way is found to retain the whiteness <strong>and</strong> brilliancy of shade <strong>for</strong> reasonable long<br />

periods while storage.<br />

Many bleaching agents of both reducing as well as oxidising nature such as sodium bisulphite, zinc<br />

hydrosulphite, zinc dust <strong>and</strong> sulphur dioxide, sodium peroxide <strong>and</strong> sodium chlorite are accepted <strong>for</strong><br />

the bleaching of bamboo mechanical pulps (Bhat <strong>and</strong> Viramani 1961) 475 . Of the reagents used, only<br />

sodium peroxide <strong>and</strong> chlorine to give satisfactory results with reasonable consumption of chemicals.<br />

Kato (1955) 408, 409 described the digestion of bamboo pulps. When bleached, NSSC pulps from<br />

Dendrocalamus strictus (yield 37-44%) were found to have satisfactory brightness <strong>and</strong> strength<br />

properties <strong>for</strong> the production of white paper (Guha <strong>and</strong> Pant 1961) 395 . Bleachable pulp could be made<br />

by the chlorination process from shredded Cephalostachyum pergracile (Mai-Aung 1961) 520 . The<br />

colour reversion of bamboo pulp bleached with CEH sequence was also reported (Bapna et al.<br />

1961 500 , Maheshwari et al. 1980 519 ; Maheshwari 1981) 517 . The sulphate pulp from Bambusa<br />

blumeana responded well to the st<strong>and</strong>ard three stage bleaching process. Good quality bond, air-mail<br />

bond, onion skin, kraft wrapping <strong>and</strong> bag papers could be produced from this species of bamboo<br />

(Escolano et al. 1964) 387 . Bleached sulphate pulp yields of 39-58 per cent are reported <strong>for</strong> bamboos<br />

(Gajdos et al. 1971) 389 . An optimum viscosity dissolving grade pulp from Dendrocalamus strictus<br />

was achieved by replacing the chlorination stage by CIO treatment; after further bleaching a most<br />

satisfactory bleached pulp was obtained (P<strong>and</strong>e 1966 523 ; 1967) 525 . The bleaching qualities of the<br />

sulphate pulp (yield 46%) produced from the Philippine bamboo, Schizostachyum luampao, equalled<br />

or exceeded those of Indian bamboos <strong>and</strong> the best North American bamboos.<br />

Satisfactory bag <strong>and</strong> wrapping papers were made with 100 per cent bamboo pulp <strong>and</strong> good writing<br />

paper from 70 per cent bleached bamboo <strong>and</strong> 30 per cent unbleached Philippine hardwood pulp<br />

(Anonymous 1966). The production of bleached sulphate pulp from mixture of bamboo <strong>and</strong> mixed<br />

65


hardwoods (50:50 mixture) was described by Guha et al. (1966) 398 . The unbleached pulp of bamboo<br />

<strong>and</strong> mixed hardwoods obtained by cold-caustic soda process possessed low initial brightness <strong>and</strong><br />

consequently was hard to bleach. Bhat et al. (1972) 501 tried various bleaching methods <strong>and</strong> assessed<br />

the yield <strong>and</strong> efficiency of the methods to improve brightness of the pulps. Bleached pulps in<br />

satisfactory yields could be produced from ringal (Arundinaria spp.) (Guha et al. 1966) 397 . The<br />

bleach consumption <strong>and</strong> strength properties of sulphate pulp obtained from Phyllostachys<br />

bambusoides are comparable to those obtained from Dendrocalamus strictus except in the case of tear<br />

factor <strong>and</strong> folding endurance which are found lower in the case of P. bambusoides. But strength<br />

obtained is found sufficient <strong>for</strong> the production of writing <strong>and</strong> printing papers (Guha <strong>and</strong> Pant 1966) 396 .<br />

The Philippine bamboos, Gigantochloa levis, G. aspera, Schizostachyum lumampao, Bambusa<br />

vulgaris, B. vulgaris var. striata <strong>and</strong> B. blumeana are reported to be easily digested <strong>and</strong> bleachable<br />

pulps with permanganate numbers from 13.0 to 18.2 <strong>and</strong> screened pulp yield from 41.3 to 48.0 per<br />

cent can be obtained (Semana et al. 1967) 471 .<br />

Decayed bamboos consume more bleaching chemicals because of the high content of residual lignin<br />

in the pulp; cost of production is there<strong>for</strong>e higher than that from healthy bamboos (Bakshi et al.<br />

1968) 540 . The bleachability of bamboos from Gabon <strong>and</strong> reeds from India is described by Doat<br />

(1970) 502 . The CEH sequence of bleaching is detailed here. A comparison with typical pulps made<br />

from Central European conifers <strong>and</strong> hardwoods shows that bamboo pulps are more difficult to bleach<br />

<strong>and</strong> are generally inferior in mechanical properties. A procedure consisting of controlled hypochlorite<br />

bleaching followed by a mild H2O2 / SO2 treatment was developed <strong>for</strong> improved economical bleaching<br />

of bamboo sulphate pulp without loss of pulp yield or quality (Banthia et al. 1972) 372 . Maheshwari<br />

(1975) 495 detailed the chlorination of sulphate pulps of bamboo. The peroxide bleaching of CEHH<br />

bleached pulps <strong>and</strong> sulphate pulps was described by Ledouse et al. (1981) 516 . The effect of peroxide<br />

addition in extraction stage on optical properties of bamboo pulp was described by Maheshwari<br />

(1990). The effect of hydrogen peroxide addition in the alkaline stage of CEH as well as CED<br />

bleaching of bamboo pulp on the final bleached pulp properties was described by Rao et al.<br />

(1988) 529 . Inclusion of hydrogen peroxide in the bleaching extraction stage is advantageous.<br />

The results of bleaching tests on the sulphate pulps from the Taiwan bamboos, Bambusa beecheyana<br />

var. pubescens, B. dolichoclada, B. stenostachya, Dendrocalamus latiflorus <strong>and</strong> Phyllostachys<br />

makinoi were reported by Chao <strong>and</strong> Pan (1972) 452 . The pulping <strong>and</strong> bleaching trials on five Taiwan<br />

bamboo species by the cold-soda neutral sulphite (NSSC) <strong>and</strong> sulphate process were reported by Chen<br />

et al. (1973) 383 . The NSSC pulps, although lowest in yield, showed good strength <strong>and</strong> were bleached<br />

to 72-88 per cent GE brightness by the chlorination /alkali extraction / hypochlorite (CEH) bleaching<br />

sequence. The net yield of 48.3 – 53.2 per cent <strong>for</strong> the bleached pulp was well above that obtained<br />

66


from fully cooked pulps. The sulphate pulps were darker <strong>and</strong> hard to bleach, but were strong enough<br />

<strong>for</strong> packaging products. The best properties were shown by pulps from Bambusa beecheyana var.<br />

pubescens, followed by Bambusa dolichoclada, Bambusa stenostachya, Sinocalamus latiflorus <strong>and</strong><br />

Phyllostachys makinoi; the last two being unsuitable <strong>for</strong> pulping. Bleached pulp from muli bamboo<br />

(Melocanna baccifera / M. bambusoides / Bambusa baccifera) was prepared by Guha et al.<br />

(1980) 42 in India <strong>and</strong> Karim et al. (1994) 407 in Bangladesh.<br />

The kinetics of chlorination stages of bleaching bamboo kraft pulps was described by Kumar et al.<br />

(1974) 515 <strong>and</strong> Maheshwari (1975) 495 . The bleaching properties of Bambusa tulda from Shillong were<br />

described by Bhola (1976) 218 . Bleaching of kraft pulp changes the properties of pulp throughout the<br />

CEH bleaching sequence (Jain et al. 1976) 512 . Bh<strong>and</strong>ari (1981) 445 produced kraft pulp from<br />

Oxytenanthera ritcheyi at the optimum conditions of cooking <strong>and</strong> the pulp was bleached. The<br />

optimum bleaching conditions, bleached pulp yield, brightness <strong>and</strong> various strength properties of<br />

bleached sheets were also reported. This species was found as a suitable raw material <strong>for</strong> the<br />

production of wrapping, writing <strong>and</strong> printing paper. Hypochloite pre-treatment prior to chlorination<br />

has a beneficial effect on tear strength <strong>and</strong> folding endurance of bleached bamboo pulps (Fellegi <strong>and</strong><br />

Rao 1980 4 ; Rao et al. 1980) 528 . The effect of chlorination <strong>and</strong> pH on final bleached pulp<br />

characteristics was explained detailed by Faul (1982) 504 . The effect of bleached pulp viscosity on<br />

strength properties was described by Maheshwari (1982) 518 .<br />

Pulps from the high-yield alkaline sulphite process with <strong>and</strong> without anthraquinone (AQ) can be<br />

easily bleached with calcium hypochlorite to a brightness of 78 <strong>and</strong> 76 per cent with bleached pulp<br />

yield of 59.4 <strong>and</strong> 57.4 per cent respectively. The physical <strong>and</strong> strength properties <strong>and</strong> opacity were<br />

matching with those of sulphite pulp (Jauhari <strong>and</strong> Ghosh 1984) 404 . The kraft – AQ pulping of<br />

bamboo <strong>and</strong> mixed hardwoods showed that bleach consumption of all the AQ-based pulps was lower<br />

<strong>and</strong> physical strength properties of the bleached pulps superior to pulps without AQ additive (Rawat<br />

et al. 1985) 470 . Pulps in higher yield can be produced by separate digesters <strong>and</strong> separate bleaching of<br />

bamboos <strong>and</strong> mixed hardwoods, instead of mixed digestion of these two raw materials of<br />

heterogeneous nature (Bhargava et al. 1985) 217 . High-yield pulps from bamboo wastes can also be<br />

bleached satisfactorily (Wang <strong>and</strong> Lirn 1985) 537 . The bleachability of pulp from both nodes <strong>and</strong><br />

internodes is same under identical conditions. The bleached pulp viscosity is lower in case of pulp<br />

from nodal portion (Maheshwari <strong>and</strong> Satpathy 1988) 175 .<br />

The bleaching of bamboo pulps can be done to desired level of brightness with CHH sequence. Total<br />

chlorine requirement <strong>and</strong> post colour number are higher while the strength properties are lower in<br />

CHH bleached pulp compared to CEHH bleached pulp. For CHH bleached pulp of low kappa number<br />

67


adverse effects are not much (Suman <strong>and</strong> Subhash 1987) 535 . As the alkali extraction stage is<br />

eliminated, the alkali consumption is lower <strong>and</strong> colour of combined effluent of CHH sequence is very<br />

light compared to CEHH sequence. It is suggested that on maintaining the pulp kappa number low<br />

(below 25), CHH sequence can be followed. The bleachability of high yield pulps can be improved by<br />

chemical modification of lignin. Soda thermomechanical (STM) <strong>and</strong> soda sulphite thermomechanical<br />

(SSTM) pulps of bamboos are modified using chlorine, sodium sulphite <strong>and</strong> hypochlorite (Singh et al.<br />

1987) 318 . The C/ S/ H combination (chlorine-sodium bisulphite-hypochlorite) <strong>for</strong> bleaching of STM<br />

<strong>and</strong> SSTM pulps gave optimum strength properties at a brightness level of 45 per cent ISO (Tewari<br />

1992) 124 .<br />

Singh et al. (1988) 237 , in their review on aspects of pulping <strong>and</strong> paper making from bamboos, gave a<br />

brief account on the research ef<strong>for</strong>ts carried out on pulp bleaching. Cold-soda high-yield bamboo<br />

pulp has low initial brightness (20-27% ISO) <strong>and</strong> high yellowness (51-63%). Even with 25 per cent<br />

calcium hypochlorite, brightness achieved under normal conditions is only 45 per cent ISO (Rao et al.<br />

n.d 527 ; Roy et al. n.d) 530 . In general, conventional methods of bleaching lignin rich high-yield pulps<br />

are ineffective in brightening bamboo cold-soda pulp. Infra-red spectra of thin sheets of bamboo coldsoda<br />

pulp will indicate the presence of chromophoric groups such as acetyl, carboxylic structures,<br />

unsaturated carbonyl, ring quinone <strong>and</strong> conjugated structures which are either present in the raw<br />

material or produced during pulping <strong>and</strong>/ or bleaching are responsible <strong>for</strong> poor bleachability <strong>and</strong> high<br />

yellowness of bamboo cold-soda pulps (Islam et al. 1989) 511 . Also, it may be that some fine quality<br />

wax portions are present in the fibre may be creating a barrier to bleaching agent. Hypochlorite may<br />

be exerting an oxidising action on the wax causing the production of ester groups which are difficult<br />

to remove/ bleach. It is also possible that some colour bodies present undergo photochemical<br />

polymerisation <strong>and</strong> are strongly absorbed on the fibre surface (Tewari 1992) 124 . Bleachability of the<br />

pulp with oxidative <strong>and</strong> reductive bleaching agents like calcium hypochlorite, hydrogen peroxide,<br />

dithionite <strong>and</strong> borohydride are ineffective in improving the brightness of cold-soda bamboo pulp. Pretreatment<br />

with SO2/ H2SO4 <strong>and</strong> extraction of cold-soda pulp with alkali prior to hypochlorite<br />

bleaching has beneficial effect on brightness improvement (Rao et al. 1980) 528 . Presence of small<br />

amount of hydrogen peroxide in the pre-alkali extraction stage further improves the brightness even<br />

up to a level of 48 per cent ISO. To achieve a brightness gain of 6-7 points, about 5-6 per cent yield<br />

has to be sacrificed. Peroxides are used <strong>for</strong> the delignification of bamboo sulphate pulps (Maheshwari<br />

1985) 304 . Calcium hypochlorite bleachability of this pulp is enhanced when sodium carbonate is used<br />

as additive. The enhanced bleachability is due to the elimination of carbonyl groups following<br />

oxidation with nascent oxygen which is believed to be the active bleaching agent in sodium carbonate<br />

buffered calcium hypochlorite bleaching systems.<br />

68


The effectiveness of 12 commercial enzymes <strong>for</strong> pre-bleaching bamboo (Bambusa bambos <strong>and</strong><br />

Dendrocalamus strictus) kraft pulps was investigated by Bajpai <strong>and</strong> Bajpai (1996) 444 . Different<br />

xylanases varied in their maximum obtainable effect. The enzymes, ‘Bleachzyme F’ <strong>and</strong> ‘Irgazyme 40<br />

S’ were able to decrease the active chlorine requirement in the first stage of bleaching by 20<br />

percentage or decrease ClO2 in the last stage of brightening by 4 kg per metric tonne of pulp in the<br />

CDEHD sequence. Alternatively, at the same chemical charge, it was possible to increase the final<br />

brightness approaching 89 per cent ISO. The use of enzymes had no adverse effect on the pulp<br />

viscosity <strong>and</strong> strength properties.<br />

The fines in bamboo unbleached pulp amount to around 30 per cent. The fines contain more of lignin,<br />

extractives <strong>and</strong> ash than the fibrous fraction. In the ‘whole’ pulp, the fines consume bleaching<br />

chemicals more than the fibrous part. Though the fines have comparatively poor optical property,<br />

according to Sahu <strong>and</strong> Patel (1996) 349 , these do not deteriorate correspondingly the optical properties<br />

of the whole pulp <strong>and</strong> there may not be any need there<strong>for</strong>e to eliminate the fines during paper<br />

manufacturing.<br />

69


11. BEATING<br />

As bamboo fibres are heterogeneous in respect of lumen width, fibre length, <strong>and</strong> diameter <strong>and</strong><br />

proportions of parenchyma, which all in turn will result in differences in the physical properties of the<br />

pulp, beating will reduce the difference in these physical properties. Grant (1964) 506 described the<br />

beating characteristics of bamboo pulps. Singh et al. (1988) 237 gave a brief review of the research<br />

ef<strong>for</strong>ts carried on beating properties of bamboos.<br />

Control of temperature <strong>and</strong> consistency during the beating process is required to develop proper fibre<br />

to fibre bonding during the course of sheet <strong>for</strong>mation. For bamboo pulp, the optimum temperature <strong>for</strong><br />

beating is found to be 35 0 C <strong>and</strong> the optimum consistency is 1.5 0 . From a study made on the beating<br />

characteristics of bamboo pulp in a Valley beater, power consumption was more at higher temperature<br />

<strong>and</strong> less at higher consistencies (Guha et al. 1976) 508 . Beating of commercial bleached sulphate pulp<br />

from Dendrocalamus strictus in a Valley beater revealed that from the point of strength, the optimum<br />

temperature <strong>for</strong> beating is around 35 0 C. However, there is a linear relationship between breaking<br />

length/ bulk <strong>and</strong> freeness, which is independent of temperature <strong>and</strong> consistency (Guha et al 1976) 508 .<br />

As pentosan content in the bamboo pulp is increased, the beating time progressively reduces (Negi<br />

1970) 310 . Pulping <strong>and</strong> beating of mixed hardwoods <strong>and</strong> bamboo separately <strong>and</strong> then blending are<br />

preferred than cooking <strong>and</strong> beating of hardwoods <strong>and</strong> bamboo together (Biswas 1971; Singh et al.<br />

1971) 533 . Krishnagopalan et al. (1975) 514 described the effect of refining on the morphology <strong>and</strong><br />

properties of bamboo paper. The effect of beating revolutions on the pulp characteristics of 1- to 3-<br />

year-old Gigantochloa scortechinii was described by Jamaludin et al. (1992) 161 .<br />

The effect of beating variables like consistency <strong>and</strong> temperature on strength development in bamboo<br />

pulp was reported by Singh et al. (1976) 533 . Investigations on the variations in fibre morphology as<br />

well as orientation of the fibres in the h<strong>and</strong> sheets revealed no significant difference in the strength<br />

properties, but when the temperature was varied, significant differences in fibre dimensions were<br />

observed. On beating, various cell wall layers of bamboo fibre open up leaving a gap between. This<br />

gap not only increases the percentage of void area in the sheet, but also does not allow the fibres to<br />

bind to a compact mass. This appears to be the main h<strong>and</strong>icap of the bamboo fibres. Breaking length<br />

<strong>and</strong> burst factor are found higher when the pulp is beaten with a phosphor bronze tackle <strong>and</strong> the<br />

difference is more pronounced at lower consistency, whereas a stone roll beater gives a higher tear<br />

factor <strong>and</strong> the difference is more pronounced at higher consistency (Singh et al. 1976) 534 . In respect<br />

of strength properties there was a marked difference between the beaten <strong>and</strong> unbeaten pulps (Singh et<br />

al. 1976) 353 .<br />

70


Effects of beating on the fibre dimensions <strong>and</strong> the strength <strong>and</strong> optical properties of the sulphate pulp<br />

from Dendrocalamus strictus were described by Rao et al. (1978) 526 . Morphological changes in the<br />

fibres were illustrated by them through photomicrographs. The changes in relation to the observed<br />

critical beating value above which tensile strength <strong>and</strong> bursting strength declined were discussed.<br />

<strong>Bamboo</strong> pulp fibres respond to beating more rapidly than do wood fibres; this is probably due to the<br />

difference in secondary wall structure between the fibres. The secondary wall consists of alternately<br />

arranged broad <strong>and</strong> narrow layers. During the beating process, a number of transverse <strong>and</strong> concentric<br />

cracks are generated in the broad layers, which cause an internal fibrillation. The outer broad layers<br />

with their numerous cracks separate from the inner layers <strong>and</strong> swell greatly toward the outside. The<br />

outer secondary wall layer of bamboo fibres has a micro fibril angle of about 20 0 with respect to the<br />

fibre axis which is much smaller than that of the S1 layer of wood fibres. As a result, this layer appears<br />

to offer little resistance to prevent the external swelling of the broad layers (Wai et al. 1985) 357 . The<br />

mean values of strength properties of unbeaten <strong>and</strong> beaten pulps of 12 Indian bamboo species were<br />

reported by Singh (1989) 77 (Appendix 7).<br />

The optical properties of the bamboo pulp in terms of brightness remain almost constant as the<br />

beating proceeds while the brightness <strong>and</strong> opacity of wood pulps decrease. The increase in opacity<br />

<strong>and</strong> light scattering coefficient of bamboo pulp with increasing beating time has been attributed to the<br />

presence of fines. The bamboo pulp has a low scattering coefficient due to its rather high fibre<br />

coarseness (Hunter 2002) 157 .<br />

Addition of beater adhesives such as starch, guar gum <strong>and</strong> locust–bean gum improves the burst, fold<br />

<strong>and</strong> tensile strength considerably <strong>and</strong> produces high quality bag <strong>and</strong> wrapping papers from sulphate<br />

pulps of Bambusa vulgaris. The resulting papers have strength properties superior to those of the<br />

commercial papers <strong>and</strong> exceed the US Federal specifications (Escolano <strong>and</strong> Semana 1970) 147 . Guha<br />

et al. (1970) 393 reported the effect of 16 natural gums available commercially, two varieties of<br />

commercial carboxymethyl cellulose (Cellpro-LSH <strong>and</strong> Cellpro-LVE) <strong>and</strong> six samples of seed gums<br />

on bleached bamboo pulp as wet additives.<br />

71


12. PULP AND SHEET CHARACTERISTICS<br />

Bhargava (1945) 136 in his review of the investigations on bamboo <strong>for</strong> pulp <strong>and</strong> paper manufacture at<br />

the Forest Research Institute, Dehra Dun from 1860 to 1944, described the strength properties of kraft<br />

pulps of some selected Indian bamboo species. The compositions <strong>and</strong> strength of pulps obtained by<br />

soda, kraft <strong>and</strong> NSSC processes under varying conditions of cooking were compared <strong>and</strong> described by<br />

Fukuyama et al. (1955) 388 . The kraft process gave the strongest pulps. The NSSC pulp (yield 54-<br />

57%) showed excellent tearing strength, with an alpha-cellulose content of 59.8 per cent. Both kraft<br />

<strong>and</strong> NSSC processes were recommended <strong>for</strong> the pulping of sasa bamboos. The properties of pulps <strong>and</strong><br />

papers prepared from 10 bamboo species of Belgian Congo, using three different methods of cooking,<br />

were described by Istas et al. (1956) 159 . Good sulphate pulps are obtainable, but except in tearing<br />

strength, the resulting papers are inferior to those of a medium quality kraft. The application of<br />

pressure while cooking will improve the quality of pulps. Unbleached pulps (yield 56-68%) of<br />

satisfactory strength properties can be prepared from Dendrocalamus strictus by the neutral sulphite<br />

semi-chemical (NSSC) process. When bleached, these pulps (yield 37-44%) will have satisfactory<br />

brightness <strong>and</strong> strength properties <strong>for</strong> the production of white papers (Guha <strong>and</strong> Pant 1961) 395 . Kato<br />

(1961) 47 prepared drawing paper from Japanese bamboo pulp <strong>and</strong> found it excellent.<br />

Kraft pulps made from the Philippine species, Schizostachyum lumampao, Gigantochloa aspera,<br />

Bambusa vulgaris, Bambusa blumeana were found deficient in burst strength, but had sufficient tear<br />

strength <strong>for</strong> Grade A <strong>and</strong> Grade B wrapping papers (Monsalud et al. 1965) 59 . Investigations on the<br />

soda pulp characteristics of 1- to 4-year-old culms of Bambusa vulgaris (Medina <strong>and</strong> Ciaramellao<br />

1965) 181 revealed no effects on tearing, tensile or folding strength due to culm age. Paper from 2-<br />

year-old culms, however, had a significantly higher bursting strength. Bambusa vulgaris produces<br />

paper of good quality, resembling that from unbleached kraft softwood pulp in tearing strength. From<br />

the industrial st<strong>and</strong> point, no advantage is gained by selecting culms of a particular age. No<br />

appreciable changes in the strength properties of pulp are found with increasing the age of five species<br />

of bamboos of Bangladesh origin (Melocanna baccifera, Oxytenanthera nigrociliata, Dendrocalamus<br />

longispathus, Bambusa tulda <strong>and</strong> Neohouzeaua dullooa) (Razzaque et al 1981) 233 . The pulp strength<br />

properties of 1- to 3-year-old Gigantochloa scortechinii were described by Jamaludin et al.<br />

(1992) 161 <strong>and</strong> found satisfactory.<br />

The yield, bleach consumption <strong>and</strong> strength properties of the pulps obtained from Phyllostachys<br />

bambusoides are comparable to those obtained from Dendrocalamus strictus except in the case of tear<br />

factor <strong>and</strong> folding endurance which are found lower in case of P. bambusoides. But the strength<br />

obtained is found sufficient <strong>for</strong> production of writing <strong>and</strong> printing papers (Guha <strong>and</strong> Pant 1966) 396 .<br />

72


Bleached kraft pulp of bamboo <strong>and</strong> mixed hardwoods (in the ratio1:1) is found to possess satisfactory<br />

strength properties. A bleached pulp yield of around 45 per cent is obtained with a tensile index of<br />

63.8-73.8 Nm/g, burst index 4.81-5.22 kPa.m 2 /g, <strong>and</strong> tear index 17.8-19.8 mNm 2 /g.<br />

Studies on the variations of sheet properties of the various sulphate pulp fractions from Gigantochloa<br />

aspera have shown that bursting <strong>and</strong> tensile strength increased, the tear strength decreased, <strong>and</strong> the<br />

folding endurance remained constant on going from long to short fibre fractions (Gonzalez <strong>and</strong><br />

Escolano 1965) 390 . The Philippine bamboos, Gigantochloa levis, G. aspera, Schizostachyum<br />

lumampao, Bambusa vulgaris, B. vulgaris var. striata <strong>and</strong> B. blumeana gave kraft pulps with higher<br />

tearing resistance but lower folding endurance, bursting <strong>and</strong> tensile strength than softwood <strong>and</strong><br />

hardwood pulps (Semana et al. 1967) 471 . The sulphate pulp obtained from Bambusa vulgaris<br />

(screened yield of 41.4 <strong>and</strong> permanganate number of 15.0) by using an active alkali charge of 15.6<br />

was characterised by very high tearing resistance but low bursting strength. The folding <strong>and</strong> tensile<br />

strength was within the range of other commercial kraft pulps, which are tested <strong>and</strong> used as st<strong>and</strong>ards.<br />

The experimental bag <strong>and</strong> wrapping papers produced from this pulp were higher in tearing resistance<br />

but lower in burst, fold <strong>and</strong> tensile strength. Addition of beater adhesives such as starch, guar gum <strong>and</strong><br />

locust-bean gum in the pulp overcomes the above deficiencies <strong>and</strong> produces good quality bag <strong>and</strong><br />

writing papers.<br />

As the pentosan content of the bamboo pulp is increased, the strength properties are also found to<br />

increase up to a critical limit of 14, 9 <strong>and</strong> 14 per cent respectively <strong>for</strong> breaking length, burst factor <strong>and</strong><br />

tear factor (Negi 1970) 310 .<br />

Investigations on the influence of variation in fibre dimensions <strong>and</strong> parenchyma proportion on the<br />

sulphate pulp sheet properties of Dendrocalamus strictus revealed that inclusion of parenchyma<br />

lowered the tensile strength <strong>and</strong> tearing resistance up to 30 per cent (Singh et al. 1971) 354 . Jain <strong>and</strong><br />

Reddi (1964), claimed that removal of parenchyma increased the bulk <strong>and</strong> reduced the strength<br />

properties. Fibre length, determined from unbeaten pulp, accounts <strong>for</strong> 77-90 per cent variations in<br />

strength properties. A high negative correlation with parenchyma proportion <strong>and</strong> the pulp sheet<br />

properties was reported. Fibre length <strong>and</strong> parenchyma proportion together accounted <strong>for</strong> 90 per cent<br />

of the variations in strength properties.<br />

Comparative data on the sulphate pulp properties <strong>and</strong> the properties of h<strong>and</strong> sheets from the sulphate<br />

pulps of Bambusa beecheyana Munro var. pubescens <strong>and</strong> some other Taiwan bamboos were reported<br />

by Ku (1971) 165 . Sulphate pulps of good strength properties, especially with high tearing strength are<br />

obtained from the Taiwan bamboos, Bambusa beecheyana var. pubescens, B. dilichoclada, B.<br />

stenostachya, Dendrocalamus latiflora <strong>and</strong> Phyllostachys makinoi. Pulp yields varied with cooking<br />

73


conditions, from 41-47 per cent (Chao <strong>and</strong> Pan 1972) 452 . Krishnagopalan (1973) 333 described the<br />

paper <strong>for</strong>ming properties of bamboo in relation to its fibre characteristics. The tensile, burst <strong>and</strong> tear<br />

indices at lowest pulp yield (45%) was 45.4 Nm/g, 3.13 kPam 2 /g <strong>and</strong> 18 mNm 2 /g respectively (Singh<br />

<strong>and</strong> Guha 1975) 429 . The yield <strong>and</strong> strength of pulp obtained by the Kleinert’s rapid alkaline pulping<br />

process of Bambusa vulgaris var. vittata from Sao Paulo were comparable with those obtained by the<br />

normal sulphate process (Barrichello <strong>and</strong> Foelkel 1975) 374 . Because of the variation of properties<br />

within species, no relationship could be established between fibre characteristics <strong>and</strong> strength<br />

properties of paper; the variation in pulp sheet properties cannot be predicted from fibre dimensions or<br />

chemical composition (Singh et al. 1971 354 , 1976 353 ). Grading 12 Indian bamboos (including 5<br />

species of Bambusa <strong>and</strong> 3 species of Dendrocalamus) <strong>for</strong> their pulping suitability based on pulp yield,<br />

alkali consumption <strong>and</strong> sheet properties showed that Dendrocalamus hamiltonii was the best. High<br />

quality unbleachable pulps could be prepared from Ochl<strong>and</strong>ra travancorica <strong>and</strong> O. rheedi (yield 48-<br />

49%, kappa number 22-25) using 15 per cent active alkali at 25 per cent sulphidity <strong>and</strong> 943 H-factor<br />

at 170 0 C. The tensile index, burst index <strong>and</strong> tear index ranged 63.9-70.6 Nm/g, 4.40-5.66 kPam 2 /g<br />

<strong>and</strong> 20-3-22.5 mNm 2 /g respectively (Singh et al. 1977) 236 . Dendrocalamus hamiltonii when<br />

compared with D. strictus <strong>and</strong> Bambusa tulda from Pakistan gave the highest soda pulp yield <strong>and</strong> best<br />

tearing strength properties comparable to those of karft pulp from Pinus roxburghii <strong>and</strong> Southern pine<br />

kraft pulp (Suleiman 1994) 196 . However, the bonding properties of bamboo pulp were inferior to<br />

those of softwood kraft pulp. The pulp sheet properties of some Indian bamboos were described by<br />

Singh <strong>and</strong> Bhola (1978) 316 .<br />

The characteristics of chemical, semi-chemical, chemi-mechanical <strong>and</strong> mechanical pulps obtained<br />

from the Brazilian bamboos (Guadua angustifolia, G. glomerata, G. morim, G. superba <strong>and</strong> Nastus<br />

(Cenchrus) amazonicus) were described by Correa et al. (1977) 143 .<br />

The strength properties of mixtures of bamboos <strong>and</strong> mixed hardwoods in different component ratios<br />

were described by Pasaribu <strong>and</strong> Silitonga (1974) 497 . The yield <strong>and</strong> properties of pulps from bamboo<br />

(Dendrocalamus strictus) combined with different proportions of mixed hardwood pulps (a mixture of<br />

30-40% each of Terminalia tomentosa <strong>and</strong> T. bellirica <strong>and</strong> 2.5-5% each of 8 other species) were<br />

reported by Guha et al. (1980) 42 . Increase in the percentage of hardwoods slightly increased the yield,<br />

but decreased strength properties. Even then, mixed pulps still had satisfactory properties <strong>for</strong> the<br />

manufacture of writing, printing <strong>and</strong> wrapping paper as well as <strong>for</strong> 3-layer board.<br />

Evaluation of strength characteristics of bleached <strong>and</strong> unbleached kraft pulps obtained from<br />

Oxytenanthera ritcheyi at optimum cooking conditions revealed that the species was a suitable raw<br />

material <strong>for</strong> the production of wrapping, writing <strong>and</strong> printing paper (Bh<strong>and</strong>ari 1981) 445 . Sulphate,<br />

neutral sulphite, lime <strong>and</strong> thermo-mechanical pulps were prepared from Bambusa vulgaris, B. viridi,<br />

74


Gigantochloa apus <strong>and</strong> G. aspera. The chemical properties of the pulps were analysed in relation to<br />

their effect on paper properties. Neutral sulphite pulp gave the best results in terms of high yield <strong>and</strong><br />

satisfactory paper mechanical properties (Tshiamala et al. 1984) 431 . The soda thermo-mechanical<br />

(STM) <strong>and</strong> soda-sulphite thermo-mechanical (SSTM) pulp from Dendrocalamus strictus was<br />

bleached with chlorine (2.5%) at 30 0 C <strong>and</strong> pulp consistency 2.5 per cent <strong>for</strong> 60 minutes followed by<br />

sodium sulphite (5%) treatment at 80 0 C <strong>and</strong> 5 per cent consistency <strong>for</strong> 60 minutes (C/ S<br />

combination). In a second set of experiment, the above treated STM <strong>and</strong> SSTM pulps were further<br />

treated with calcium hypochlorite (5% available chlorine) at 45 0 C <strong>and</strong> 8 per cent consistency (C/ S/ H<br />

combination). It was found that the C/ S/ H combination with the application of 5 per cent of each<br />

chemical gave optimum improvement in strength properties in all the pulps at brightness level 45 per<br />

cent ISO. For STM pulp, the tensile index increased from 22.07 to 30.18 Nm/g <strong>and</strong> burst index from<br />

0.72 to 1.56 kPam 2 /g. For SSTM pulps the tensile index rose from 32.28 to 42.96 Nm/g <strong>and</strong> burst<br />

index increased from 1.62 to 2.55 kPam 2 /g.<br />

The strength properties of unbleached normal sulphite (NS) – anthraquinone pulps from muli bamboo<br />

(Melocanna baccifera) were lower than those of kraft pulps (Bose et al. 1988) 451 . The physical <strong>and</strong><br />

strength properties of the pulp were found to be independent of age of the bamboos. Anthraquinone<br />

(AQ) catalysed low sulphidity kraft pulp obtained from muli bamboo (Melocanna baccifera) had<br />

almost the same viscosity as that of the kraft control <strong>and</strong> better than the pulp of 15 per cent sulphidity<br />

(Bhowmick et al. 1991) 447, 448 . The burst, tear <strong>and</strong> tensile strength properties of the pulp increased on<br />

addition of anthraquinone. The strength properties of the anthraquinone catalysed pulps were almost<br />

the same or better than the pulp obtained in normal kraft pulping.<br />

The unbleached pulp (yield 49.8% with kappa number 28.3) properties of eight Chinese bamboos<br />

were described by Xia (1989) 241 . The pulp strength was found satisfactory. Based on the unbleached<br />

pulp yield <strong>and</strong> strength properties, he ranked Schizostachyum funghomii as the best <strong>and</strong> Bambusa<br />

textillis <strong>and</strong> B. pervariabilis as second <strong>and</strong> third <strong>and</strong> Phyllostachys pubescens (moso bamboo) as last.<br />

The pulp characteristics <strong>and</strong> physical properties of the paper h<strong>and</strong>sheets made from bamboo <strong>and</strong> water<br />

hyacinth pulp blends were described by Goswami <strong>and</strong> Saikia (1994) 36 . Blending of bamboo pulp<br />

with water hyacinth increased the strength. Paper h<strong>and</strong>sheets made with a blend of water hyacinth<br />

pulp (75 0 SR) at 75:25 proportion gave a tear index of 4.9 Nm 2 /g, tensile index of 51.1 Nm 2 /g <strong>and</strong><br />

burst index of 7.3 kPam 2 g. These were higher than the values obtained from sheets made with pulp<br />

blends of 80:20 or 90:10. Blends of 75:25 were also found to give satisfactory greaseproof properties.<br />

The difference in secondary layer structure of bamboo fibres leads to different swelling behaviours<br />

compared to that of wood fibres. <strong>Bamboo</strong> paper showed a low drainage resistance (0.55) compared to<br />

75


Sc<strong>and</strong>inavian birch (0.66) <strong>and</strong> eucalypts (0.77) <strong>and</strong> drainage time at a tensile index of 70 Nm/g. The<br />

presence of fines <strong>and</strong> their characteristic swelling behaviour may be the reason <strong>for</strong> this. The<br />

morphological characteristics of the bamboo fibres give paper with a high tear strength <strong>and</strong> burst<br />

index, which is rather similar to that of hardwood. The tensile stiffness is low compared to that of<br />

Sc<strong>and</strong>inavian softwood. The strain strength lies between that of hardwood <strong>and</strong> softwood (Hunter<br />

2002) 157 . The ratio of fibre strength to bond strength is higher in the case of bamboo pulp compared<br />

to that of commercial softwoods. The tensile strength of bamboo can be improved by removing<br />

primary fines prior to refining. The bamboo fibres give sheets with high bulk <strong>and</strong> high porosity. The<br />

coarseness <strong>and</strong> the characteristic shape of the fibres cause an uneven surface, which necessitates<br />

coating with a pigment layer in order to achieve good printing results in pure bamboo papers.<br />

76


13. BLACK LIQUOR<br />

The bamboo kraft black liquor usually contains silica in the range of 5-8 g/l as SiO2. The high silica content<br />

leads to the <strong>for</strong>mation of soluble silicates during pulping which causes troubles at the chemical recovery<br />

stage. The addition of calcium oxide to the black liquor is effective in reducing the silica content from 5.0-<br />

7.2 g/l to 1.3-1.8 g/l, <strong>and</strong> the precipitated calcium silicate is easily removed by filtration without reducing the<br />

amount of organic matter <strong>and</strong> sodium (Tsuji <strong>and</strong> Ono 1966) 433 . Desilicification of high silica containing<br />

kraft black liquor is achieved by using various reagents such as aluminium sulphate <strong>and</strong> magnesium<br />

sulphate, carbon dioxide (Isono <strong>and</strong> Ono 1967 399 ; 1968) 401, 402 <strong>and</strong> kraft green liquor by aluminium<br />

sulphate (Isono <strong>and</strong> Ono 1968) 400 . Kulkarni et al. (1984) 462 made an attempt <strong>for</strong> desilication by the method<br />

of lowering the pH of black liquor by carbonation. It was found that temperature <strong>and</strong> pH were the two<br />

important parameters that needed to be optimised <strong>for</strong> the selective precipitation of silica. The pH range <strong>for</strong><br />

silica precipitation was largely influenced by the temperature during carbonation. Also it was found that at<br />

all temperatures <strong>and</strong> pH levels there was a co-precipitation of lignin. Treatment of sludge with calcium oxide<br />

or aluminium hydroxide at 80 0 C helps in re-dissolution of co-precipitated lignin without dissolving silica<br />

portion. The carbonised black liquor can be filtered easily on 600 mesh nylon cloth under reduced pressure<br />

of around 0.3 kg/cm 2 . Sathyanarayana et al. (1992) 73 made adaptations to black liquor evaporators so that a<br />

mixture of bamboo <strong>and</strong> hardwood pulp (at a ratio of 70:30) could be processed as effectively as bamboo<br />

alone. The viscosity of black liquors from bamboo alone <strong>and</strong> bamboo with mixed hardwoods in different<br />

proportions can be reduced with increase in initial residual alkali of the black liquor (Khare et al. 1984) 494 .<br />

This will help in reducing the clogging of the evaporated tubes <strong>and</strong> better per<strong>for</strong>mance of the recovery.<br />

Vanillin can be produced from bamboo black liquor by alkaline nitrobenzene oxidation, but yields are too<br />

low to make the process technically feasible (Bharatia <strong>and</strong> Veeramani 1974) 375 . The engineering properties<br />

(thermal conductivity <strong>and</strong> specific gravity) of bamboo kraft black liquors were reported by Koorse <strong>and</strong><br />

Veeramani (1976) 459, 4 6 0 .<br />

Khanna <strong>and</strong> Swaleh (1981) 513 made the first report on the analysis of bamboo (Dendrocalamus strictus)<br />

black liquor. Madan <strong>and</strong> Vijan (1995) 252 described the physico-chemical properties of Dendrocalamus<br />

giganteus kraft spent liquor. With a view to the possible utilization of kraft lignin as a by-product, lignin<br />

from spent liquor left from the pulping of sound <strong>and</strong> flowered Dendrocalamus giganteus by the kraft process<br />

was isolated (Vijan <strong>and</strong> Madan 1996) 263 . Data were tabulated on the C, H, O <strong>and</strong> S content of the lignins<br />

<strong>and</strong> the content of Klason lignin <strong>and</strong> functional groups (methoxyl, hydroxyl <strong>and</strong> carboxylic) <strong>and</strong> correlations<br />

between them, <strong>and</strong> on the relative retention time <strong>and</strong> percentage of alkaline nitrobenzene oxidation products<br />

of the lignins. The results indicate clear differences in structure between lignin isolates from sound <strong>and</strong><br />

flowered bamboos.<br />

77


14. TYPES OF PAPER<br />

Experiments conducted at the Forest Research Institute, Dehra Dun have established the suitability of<br />

bamboo as a material <strong>for</strong> the manufacture of kraft paper <strong>and</strong> have led to the pioneering of the industry<br />

in India (Bhargava <strong>and</strong> Singh 1942) 26 . The bamboo pulp from Dendrocalamus strictus combined<br />

with different proportions of mixed hardwood pulps has satisfactory properties <strong>for</strong> the manufacture of<br />

writing <strong>and</strong> printing paper, wrapping paper <strong>and</strong> 3- layer board (Guha et al. 1980) 42 .<br />

Newsprint was produced from the bamboo Phyllostachys bambusoides (Nafziger et al. 1961) 417 .<br />

Dendrocalamus strictus was reported to be suitable <strong>for</strong> the production of white papers (Guha <strong>and</strong> Pant<br />

1961) 395 . Phyllostachys bambusoides is suitable <strong>for</strong> the production of writing <strong>and</strong> printing papers<br />

(Guha <strong>and</strong> Pant 1966) 396 . Ringal (Arundinaria spp.) is reported to be suitable <strong>for</strong> the production of<br />

chemical pulps by the sulphite process <strong>for</strong> writing <strong>and</strong> printing papers (Guha et al. 1966) 397 . Good<br />

quality bond, air-mail bond, onion skin, offset book, kraft wrapping <strong>and</strong> bag papers can be produced<br />

from the sulphate pulp of Bambusa blumeana (Escolano et al. 1964). Bambusa vulgaris was reported<br />

to be suitable <strong>for</strong> bag <strong>and</strong> wrapping papers with excellent tearing but poor bursting strength properties<br />

(Escolano <strong>and</strong> Semana 1970) 147 . The folding <strong>and</strong> tensile strength of both the pulp <strong>and</strong> paper are<br />

within the range of imported pulps/papers. Guha et al. (1970) 40 reported that Braille printing paper<br />

can be successfully produced from Indian bamboos. Jati bamboo (Bambusa tulda) was reported to be<br />

unsuitable <strong>for</strong> manufacture of wrapping, writing <strong>and</strong> printing papers (Bhola 1976) 218 . Oxytenanthera<br />

ritcheyi was reported to be a suitable raw material <strong>for</strong> the production of wrapping, writing <strong>and</strong><br />

printing paper (Bh<strong>and</strong>ari 1981) 445 .<br />

78


15. INDUSTRIAL EXPERIENCE<br />

<strong>Bamboo</strong> can be chipped in the same way as wood giving basically the similar chip <strong>for</strong>m <strong>and</strong><br />

appearance. The large sized bamboo has to be crushed be<strong>for</strong>e chipping. The chipping should be such<br />

that it should not produce fines. Bhargava <strong>and</strong> Singh (1942) 137 tested chips of Dendrocalamus<br />

strictus <strong>for</strong> uni<strong>for</strong>mity, bleachability <strong>and</strong> pulp yield under identical conditions of digestion. The most<br />

satisfactory was that from the crushed one, but crushing has the disadvantage of high power<br />

consumption <strong>and</strong> also size of crushed chips was more irregular <strong>and</strong> uneven than that of chips obtained<br />

by oblique chipping. An ideal method would be to cut the bamboo into more or less uni<strong>for</strong>m chips,<br />

<strong>and</strong> crush the chips, so that the bundle sheets of the bamboo vascular bundles would be loosened <strong>and</strong><br />

separated out from the ground tissues <strong>and</strong> their rigidity reduced, thus giving an easier <strong>and</strong> quicker<br />

penetration of the cooking liquors. Initially mills used the two-stage pulping process developed by<br />

Raitt (1912 231 ; 1925; 1931) 424 at FRI, Dehra Dun, India. But with the advancement in research, at<br />

present mostly pulping is carried out in a single-stage cooking by kraft process. The general pulping<br />

conditions employed in paper mills in India are: active pulping chemicals 14-18 per cent as Na2O;<br />

sulphidity varying between 13 <strong>and</strong> 25 per cent at 160-170 0 C. The kappa number ranges between 16<br />

<strong>and</strong> 25 <strong>and</strong> the pulp yield between 40 <strong>and</strong> 45 per cent.<br />

Generally, in short fibred pulps, it is necessary to incorporate 25-30 per cent long fibred pulps, such as<br />

from bamboo (Bhat <strong>and</strong> Guha 1952 269 , 1953 270 ; Bhat et al. 1952 271 , 1956, 1960 27 ; Bhat <strong>and</strong> Jaspal<br />

1957) 272 . Chen (1958) 140 described the layout, equipments <strong>and</strong> methods of the mill of the Longlived<br />

Pulp <strong>and</strong> Paper Corporation Ltd. at Formosa. Lund (1942) 362a developed a mechanical disintegrator<br />

<strong>for</strong> the production of fibres. A defibrating machine, the ‘Chemifiner’, was introduced <strong>and</strong> its<br />

contribution to the process of low-power cold-soda pulping was described by Gremler <strong>and</strong> McGovern<br />

(1960) 391 . <strong>Bamboo</strong> shredded by a machine developed by the Armour Research Foundation in co-<br />

operation with the Union of Burma Allied Research Institute showed distinct advantages of easy to<br />

wash pulp, requiring less water <strong>and</strong> satisfactory chemical recovery <strong>and</strong> over chipped bamboos (Mai-<br />

Aung <strong>and</strong> Fleury 1960) 177 . <strong>Bamboo</strong> nodes were practically eliminated in the shredding action <strong>and</strong><br />

there<strong>for</strong>e there was almost no silica in the resulting pulp. The absence of hard nodes results in less<br />

screening <strong>and</strong> uncooked particles.<br />

In order to reduce the surface wax content of Bambusa bambos while pulping, a steam treatment <strong>for</strong> 2<br />

hours is necessary (Beri et al. 1967) 135 . The penetration of alkaline liquor is much quicker <strong>and</strong> deeper<br />

in the cross-sectional than the longitudinal direction of the culm or chips. Alkali penetrates rapidly<br />

<strong>and</strong> uni<strong>for</strong>mly once the outer waxy skin has been dissolved. Consequently, the deciding factor <strong>for</strong><br />

79


effective cooking is not the length of the chip, but thickness of the culm which if shredded or crushed,<br />

is uni<strong>for</strong>mly cooked whatever its length (Banthia et al. 1970) 369a .<br />

<strong>Bamboo</strong> fibres have become an established raw material <strong>for</strong> paper making in tropical countries using<br />

different types of paper machines. The study of Mishra <strong>and</strong> Kothari (1969) 56 will be of interest to<br />

paper technologists as well as those who are engaged in paper designing to suit the requirements of<br />

running bamboo pulp stock on a fourdrinier machine.<br />

To increase the yield of pulp <strong>for</strong> the production of kraft paper from bamboo <strong>and</strong> Eucalyptus gr<strong>and</strong>is,<br />

experiments were conducted by splitting the digestion into two stages with an intermediate refining<br />

stage. The yield of bamboo pulp was found to increase from 47.1 to 53.3 per cent without any<br />

significant effect on the strength properties of pulp (Singh et al. 1970) 427 . The experiences on the<br />

pulping of bamboos <strong>and</strong> mixed hardwoods, from the Sirpur Paper Mills, India, showed that higher<br />

alkali concentration in the range of 16-20 per cent Na2O was required to produce a bleachable pulp<br />

with permanganate number 20, in comparison to the very low alkali (11-13% Na2O of 16-18%<br />

sulphidity) to produce pulp of the above quality from bamboos only (Mishra 1971) 54 . Sulphate pulps<br />

from both eucalypts <strong>and</strong> rubber wood can be mixed with bamboo chemical pulp <strong>for</strong> making the<br />

ordinary quality writing <strong>and</strong> printing papers (Nair 1971) 60 . The Bengal Paper Mill in India was the<br />

first pulp mill in the world to use the mixture of different species of hardwoods <strong>and</strong> bamboo in a<br />

continuous digester <strong>for</strong> pulping (a mixture of 60% of bamboo <strong>and</strong> 40% mixed hardwoods) with high<br />

heat diffusion washing (Bhargava 1968 486 ; Aggarwal 1971) 22 . The rejects on Johanson knotter are<br />

2.5 per cent of raw material. The pulps are bleached with 12 per cent chlorine in four stages. Various<br />

qualities of paper are made from the pulp. Evaluation of the strength properties of the pulps of<br />

composition 30 per cent mixed hardwoods <strong>and</strong> 70 per cent bamboo, beaten in Valley <strong>and</strong> Lampen<br />

mills at consistencies varying from 1.37 to 1.97 per cent, <strong>for</strong> different time intervals, obtained from<br />

the Bengal Paper Mills revealed that pulps beaten in the Valley beater at higher consistencies gave<br />

better strength properties (Singh et al. 1971) 531 .<br />

Hydraulic <strong>and</strong> steam phase type Kamyr digesters were employed earlier <strong>for</strong> the cooking of bamboo.<br />

Later on, modified pressurised feeder, the ‘ASTHMA’ digester has been employed <strong>for</strong> the pulping of<br />

bamboo. The raw material is heated up to 115 0 C by steaming in the steaming vessel. A plug feed<br />

discharges into the digester by means of high pressure steam of about 10-12 bar. The steam flow is<br />

used <strong>for</strong> heating the raw material to a cooking temperature of about 165 0 C. The raw material is<br />

retained at the cooking temperature in the liquor phase. Then it reaches the discharge zone located in<br />

the bottom of the digester. The pulp is discharged by means of a slowly rotating scraper <strong>and</strong> cooked<br />

by injecting wash water in the digester bottom. Then the pulp is discharged at 10 per cent consistency<br />

through the blow valve. This digester type is used in the Phoenix Mill in Thail<strong>and</strong> <strong>and</strong> operates on<br />

80


amboo <strong>and</strong> kenaf alternatively. The next development was to combine ASTHMA feeding system<br />

with conventional ‘Hi-heat’ washing system which can be applied to the chip characteristics of<br />

bamboo. The steam <strong>and</strong> power consumption in the ASTHMA digester is considerably lower<br />

compared with that of the batch digester system or other digester types <strong>for</strong> bamboo. The considerable<br />

amount of hot water with a temperature of 75 0 C produced could be used <strong>for</strong> pulp washing <strong>and</strong> in the<br />

bleaching plant. Two mills of the Hindustan Paper Corporation (HPC) in India, the Novgong <strong>and</strong><br />

Cachar Mills are equipped with ASTHMA digester with Hi-heat washing system. The experience<br />

from Thail<strong>and</strong> <strong>and</strong> India clearly confirmed that the simplified ASTHMA feed system is a satisfactory<br />

system which gives proper impregnation <strong>and</strong> a small amount of rejects <strong>and</strong> the Hi-heat washing<br />

technique is as efficient on bamboo as it is on hardwood <strong>and</strong> softwood pulps (Singh et al. 1988 237 ;<br />

Tewari 1992) 124 .<br />

The sulphate pulping of bamboo (Dendrocalamus strictus) was studied from the beginning to the end<br />

of cook, applying the concept of representing the times <strong>and</strong> temperatures of the cooking cycle by<br />

Vroom’s H-factor. The experimental results showed that H-factor can be employed as a means of<br />

predicting compensating adjustments of cooking times <strong>and</strong> temperatures to give the same yield of<br />

pulp, kappa number <strong>and</strong> lignin content with varying cooking cycles. This indicated that the concept of<br />

H-factor can suitably be applied as a guide <strong>for</strong> controlling sulphate pulping process of bamboo in<br />

mills by predicting times <strong>for</strong> a variety of temperatures or vice-versa to make necessary adjustments in<br />

the cooking cycle so as to get equivalent pulp yield. For an experimental st<strong>and</strong>ard cooking cycle of 90<br />

minutes from 80-170 0 C <strong>and</strong> 90 minutes at 170 0 C employed, the H-factor was found to be 91982<br />

(Singh <strong>and</strong> Guha 1976) 430 .<br />

The design of special drum-type chippers <strong>for</strong> processing bamboo without splintering was described in<br />

Anonymous (1978b). The per<strong>for</strong>mance of a PN bamboo disc chipper (investment, maintenance costs<br />

<strong>and</strong> chip quality) was reported to be superior to that of others used in the Indian pulp <strong>and</strong> paper<br />

industry (P<strong>and</strong>it et al. 1978) 13 . Suitability of some Indian bamboos <strong>for</strong> pulp <strong>and</strong> paper was reported<br />

by Nair (1970) 9 (Appendix 8).<br />

In many mills, the bleaching of kraft pulps is carried out by using chlorine <strong>and</strong> calcium hypochlorite<br />

as bleaching agent with intervening caustic soda extraction. Total bleach dem<strong>and</strong> varies from 12 to 15<br />

per cent to attain a brightness of 70-75 per cent. The Phoenix Mill in Thail<strong>and</strong> follows the C-D-E-H-D<br />

bleaching obtaining 87 per cent ISO brightness. The Novgong <strong>and</strong> Cachar mills in India use 5-stage<br />

bleaching with C-E-H-E-D sequence.<br />

With the increase of the cost of bamboo, ef<strong>for</strong>ts are made to utilize bamboo at the maximum <strong>for</strong><br />

pulping. Banthia <strong>and</strong> Misra (1968) 369 described an economical method of recovery of bamboo dust<br />

81


<strong>and</strong> knotter (nodes) rejects in a bamboo kraft pulp mill (wastes amount to 2-5% of the weight of<br />

bamboo chipped <strong>and</strong> 0.5-2.0% of the weight of pulp produced respectively), with minimum use of<br />

alkali <strong>and</strong> maximum yield recovery. Patnaik et al. (1984) 256 reported about the cooking of bamboo<br />

pin chips, which are removed as bamboo dust during the screening of chips. Studies showed that the<br />

small quantity of pulp obtained from separate cooking of pin chips can be mixed with normal kraft<br />

pulp <strong>for</strong> the manufacture of kraft paper without any significant effect on the physical <strong>and</strong> strength<br />

properties of paper. Mixing of up to 5 per cent of pin chips with the usual chips, the quality of pulp<br />

does not deteriorate much. An improved process control strategy was reported <strong>for</strong> the kraft pulping of<br />

Dendrocalamus strictus so as to produce pulp of uni<strong>for</strong>m quality (Pravin 1987) 468 . Adaptations were<br />

made to black liquor evaporators so that a mixture of bamboo <strong>and</strong> hardwood pulp (at a ratio of 70:30)<br />

could be processed as efficiently as bamboo only (Sathyanarayana et al. 1992) 73 .<br />

The available in<strong>for</strong>mation on the suitability of different species is consolidated <strong>and</strong> given in the next<br />

chapter. Almost all varieties of paper are made from bamboo; eg. Machine glazed (MG) kraft, kraft<br />

linear, wrapping <strong>and</strong> printing paper, typing paper, map litho, duplicating paper, duplex board,<br />

newsprint, etc(Tewari 1992) 124 (Appendix 9.B). In India, bamboo pulp meets the requirements of<br />

long fibred pulp <strong>for</strong> producing various kinds of paper. However, bamboo mechanical pulps/<br />

emichemical high-yield pulps have limited use due to poor strength <strong>and</strong> bleachability. Concerted<br />

researches are under way using microbial modification of lignins in high-yield pulps.<br />

82


16. SPECIES SUITABILITY<br />

The following Tables consolidate the available in<strong>for</strong>mation on investigations on pulping qualities of<br />

various species from different countries.<br />

1. Arundinaria alpina<br />

Subject of investigation Country Reference<br />

Storage; fibre morphology; chemical<br />

composition; cooking schedules; pulp <strong>and</strong> paper<br />

properties<br />

Belgian Congo<br />

(Africa)<br />

83<br />

Istas <strong>and</strong> Raekelboom 1962<br />

Pulping potential Ethiopia Cunningham <strong>and</strong> Clark<br />

1970<br />

2. Arundinaria jaunsarensis<br />

Cold caustic soda treatment India Kh<strong>and</strong>uri <strong>and</strong> Biswas 1960<br />

Alkali treatment India Kh<strong>and</strong>uri <strong>and</strong> Biswas 1961<br />

Sulphate pulp; pulping of mixture of bamboo <strong>and</strong><br />

mixed hard woods; bleaching<br />

India Guha et al. 1966 (b,d)<br />

3. Arundinaria nitida<br />

Suitability <strong>for</strong> pulping Belgian Congo<br />

(Africa)<br />

4. Arundinaria simonii<br />

Suitability <strong>for</strong> pulping Belgian Congo<br />

(Africa)<br />

5. Bambusa atrovirens (Syn. B. aurea)<br />

Istas 1958<br />

Istas 1958<br />

Suitability <strong>for</strong> rayon pulp, pulping conditions India Lele 1964<br />

6. Bambusa balcooa<br />

Pulp bleaching, yield India Guha 1961b<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique<br />

1970<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury<br />

1982


7. Bambusa bambos (Syn. Bambusa arundinaceae)<br />

Pulping trials India Ahamed <strong>and</strong> Karnik 1944<br />

Semi-commercial pulping tests India Bhargava 1945<br />

Rayon grade pulping India Karnik <strong>and</strong> Sen 1948<br />

Fibre morphology India Ghosh <strong>and</strong> Negi1958<br />

Suitability <strong>for</strong> rayon pulp, pulping conditions India Lele 1964<br />

Rayon grade pulping Japan Tsuji et al. 1965<br />

Fibre morphology; chemical composition; India Singh <strong>and</strong> Mukherjea 1965<br />

method of pulping; yield of pulp; product <strong>for</strong><br />

which the pulp is suitable (Review)<br />

Nitric acid pulping India Biyani 1966<br />

Species introduction, suitability <strong>for</strong> pulping Ghana Kadambi <strong>and</strong> Ashong 1966<br />

Prehydrolysis kraft pulp yield, sulphate pulp<br />

yield<br />

- Rydholm 1966<br />

Pre-steaming <strong>for</strong> wax removal India Beri et al. 1967<br />

Chemical composition; nitric acid pulping India Biyani et al. 1967<br />

Pulping of flowered bamboos India Bakshi et al. 1968<br />

Pulping with mixed hardwoods India Bhargava et al. 1969<br />

Variation in fibre length India Pattanath 1972<br />

Suitability <strong>for</strong> pulping Indonesia Pasaribu <strong>and</strong> Silitonga 1974<br />

Fibre morphology; chemical composition; India Singh et al. 1976 (a, b, c)<br />

pulping; alkali consumption; pulp yield; beating;<br />

pulp strength; pulp sheet properties<br />

Fibre morphology; pulping characteristics India Maheshwari et al. 1976<br />

Chemical composition India Maheshwari et al. 1976<br />

Alkaline sulphite <strong>and</strong> – AQ pulping Taiwan Wang 1982<br />

Storage; pulping; fibre morphology; bleaching;<br />

beating; pulp sheet properties<br />

India Singh et al. 1988<br />

Effect of age on fibre length <strong>and</strong> pulp India Shanmughavel 1995;<br />

characteristics<br />

Shanmughavel <strong>and</strong> Francis<br />

1996 & 1998<br />

Biological pre-bleaching / biological<br />

delignification<br />

India Bajpai <strong>and</strong> Bajpai 1996<br />

8. Bambusa beecheyana<br />

Fibre morphology; chemical composition;<br />

cooking conditions; sulphate pulp properties<br />

9. Bambusa beecheyana var. pubescens<br />

84<br />

Taiwan Ku 1971<br />

Fibre morphology; pulp sheet properties Taiwan Ku 1971<br />

Kraft pulping; pulp sheet properties Taiwan Chao <strong>and</strong> Pan 1972<br />

Pulping process; pulp <strong>for</strong> printing paper;<br />

bleaching; yield; pulp properties<br />

Taiwan Chen et al. 1974<br />

Pulping suitability Taiwan Ku <strong>and</strong> Wang 1990


10. Bambusa blumeana<br />

Pulping qualities; bleaching Philippines FPRDI 1962<br />

Single– stage sulphate pulping process; threestage<br />

bleaching process; types of paper<br />

Philippines Escolano et al. 1964<br />

Bleaching; sulphate pulp <strong>and</strong> paper Philippines Escolano et al. 1964<br />

Kraft pulping qualities Philippines Semana et al. 1967<br />

Chemical composition (silica content); Sulphate<br />

pulping; beater adhesives<br />

Philippines Escolano <strong>and</strong> Semana 1970<br />

Chemical composition (silica content) Philippines Espiloy 1988<br />

Fibre morphology Malaysia Abdul Latif Mohamed <strong>and</strong><br />

Mohamed Tamizi 1992<br />

11. Bambusa distegus<br />

Effect of age on fibre morphology China Xia <strong>and</strong> Zeng 1996<br />

12. Bambusa dolichoclada (Syn. Leleba dolichoclada)<br />

Kraft pulping Taiwan Chao <strong>and</strong> Pan 1972<br />

Methods of cooking; cold soda; NSSC <strong>and</strong><br />

sulphate process; bleaching; pulp characteristics;<br />

yield; types of paper<br />

Taiwan Chen et al. 1973<br />

Methods of cooking; pulp <strong>for</strong> printing paper;<br />

bleaching; yield; pulp properties<br />

Taiwan Chen et al. 1974<br />

Pulping suitability Taiwan Ku <strong>and</strong> Wang 1990<br />

13. Bambusa hoffii<br />

Chemical composition; paper making qualities Belgian Congo<br />

(Africa)<br />

14. Bambusa nutans<br />

85<br />

Istas <strong>and</strong> Hontoy 1952<br />

Fibre morphology; chemical composition; India Singh <strong>and</strong> Mukherjea 1965<br />

method of pulping; yield; types of paper<br />

(Review)<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique<br />

1970<br />

Variation in fibre length India Pattanath 1972<br />

Fibre morphology; chemical composition; India Singh et al. 1976 (a, b, c)<br />

pulping; alkali consumption; pulp yield; beating;<br />

pulp strength; pulp sheet properties<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury<br />

1982


15. Bambusa oldhamii<br />

Mechanical pulp <strong>for</strong> Chinese “Joss”<br />

(ceremonial) paper<br />

Taiwan Perdue et al. 1961<br />

Cooking process; kraft pulping; fibre<br />

Brazil Ciaramellao 1970;<br />

morphology; yield; properties of pulp<br />

Ciaramellao <strong>and</strong> Azzini<br />

1971<br />

Pulping suitability Taiwan Ku <strong>and</strong> Wang 1990<br />

16. Bambusa pervariabilis<br />

Effect of age on chemical composition; pulping<br />

properties<br />

17. Bambusa polymorpha<br />

86<br />

China Xia 1989<br />

Semi-commercial pulping tests India Bhargava 1945<br />

Cold soda pulping USA Gremler<br />

1960<br />

<strong>and</strong> McGovern<br />

Fibre morphology; chemical composition; India Singh <strong>and</strong> Mukherjea 1965<br />

method of pulping; yield; types of paper<br />

(Review)<br />

Bleached kraft pulp Myanmar Mai- Aung et al. 1968<br />

Storage of pulpwood Myanmar Mai- Aung et al. 1969<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique<br />

1970<br />

Variation in fibre length India Pattanath 1972<br />

Fibre morphology; chemical composition; India Singh et al. 1976 (a, b, c)<br />

pulping; alkali consumption; pulp yield; beating;<br />

pulp strength; pulp sheet properties<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury<br />

1982<br />

Fibre morphology; paper making properties Myanmar Wai <strong>and</strong> Murakami 1983 &<br />

1984<br />

Fibre ultra-structure; beating characteristics Myanmar Wai et al. 1985<br />

Storage; pulping; fibre morphology; bleaching;<br />

beating; pulp sheet properties<br />

India Singh et al. 1988<br />

18. Bambusa stenostachya<br />

Industrial kraft pulping Formosa Chen 1958<br />

Mechanical pulp <strong>for</strong> Chinese “Joss”<br />

(ceremonial) paper<br />

Taiwan Perdue et al. 1961<br />

Kraft pulping Taiwan Chao <strong>and</strong> Pan 1972<br />

Methods of cooking; pulp <strong>for</strong> printing paper;<br />

bleaching; yield; pulp properties<br />

Taiwan Chen et al. 1974<br />

Rayon grade pulping China Chang <strong>and</strong> Kuo 1976<br />

Pulping suitability Taiwan Ku <strong>and</strong> Wang 1990<br />

19. Bambusa textiles<br />

Effect of age on chemical composition; pulping<br />

properties; pulp strength<br />

China Xia 1989


20. Bambusa tulda<br />

Semi-commercial pulping tests India Bhargava 1945<br />

Rayon grade pulping India Anonymous 1947<br />

Fibre morphology; chemical composition; India Singh <strong>and</strong> Mukherjea 1965<br />

method of pulping; yield of pulp; product <strong>for</strong><br />

which the pulp is suitable (Review)<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique<br />

1970<br />

Variation in fibre length India Pattanath 1972<br />

Fibre morphology; chemical composition; kraft<br />

pulping; types of pulp bleaching; types of paper<br />

India Bhola 1976<br />

Fibre morphology; chemical composition; India Singh et al. 1976 (a, b, c)<br />

pulping; alkali consumption; pulp yield; beating;<br />

pulp strength; pulp sheet properties<br />

Effect of age on chemical composition, fibre<br />

dimensions, pulp yield <strong>and</strong> strength<br />

Bangladesh Razzaque et al. 1981<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury<br />

1982<br />

Fibre morphology; paper making properties Myanmar Wai <strong>and</strong> Murakami 1984<br />

Storage; pulping; fibre morphology; bleaching;<br />

beating; pulp sheet properties<br />

India Singh et al. 1988<br />

Soda process; yield; pulp strength Pakistan Suleiman 1994<br />

21. Bambusa tuldoides<br />

Sulphate pulping; effect of age Brazil Mazzei et al. 1967<br />

Effect of age on sulphate pulping; pulp strength Brazil Mazzei <strong>and</strong> Rediko 1967<br />

Fibre morphology; cooking process; yield; pulp<br />

properties<br />

Brazil Ciaramellao 1970<br />

Pulp strength Brazil Barrichello <strong>and</strong> Foelkel<br />

1975<br />

22. Bambusa vulgaris<br />

Suitability <strong>for</strong> pulp Belgian Congo<br />

(Africa)<br />

Frison 1951<br />

Chemical composition; paper making qualities Belgian Congo<br />

(Africa)<br />

Istas <strong>and</strong> Hontoy 1952<br />

Fibre morphology; chemical composition Belgian Congo<br />

(Africa)<br />

Istas et al. 1956<br />

Fibre morphology; chemical composition; pulping Belgian Congo Istas 1958<br />

suitability<br />

(Africa)<br />

Pulping of mixture of species Belgian Congo<br />

(Africa)<br />

Istas <strong>and</strong> Raekelboom 1960<br />

NSSC pulping suitability Mexico Carrasco <strong>and</strong> Salvador 1961<br />

Storage; fibre morphology; chemical composition; Belgian Congo Istas <strong>and</strong> Raekelboom 1962<br />

cooking schedules; pulp <strong>and</strong> paper properties (Africa)<br />

Pulping; bleaching Philippines FPRDI 1962<br />

Suitability <strong>for</strong> rayon pulp, pulping conditions India Lele 1964<br />

Kraft pulping; effect of culm age on the paper making<br />

qualities<br />

Brazil Medina <strong>and</strong> Ciaramellao 1965<br />

Species distribution, suitability <strong>for</strong> pulping Ghana Kadambi <strong>and</strong> Ashong 1966<br />

Pulp strength; pulp blending Africa Doat 1967<br />

87<br />

(Continue next page)


Fibre morphology; effect of age on sulphate pulping;<br />

pulp strength<br />

Brazil Mazzei <strong>and</strong> Rediko 1967<br />

Fibre morphology; high- yield pulping Brazil Mazzei et al. 1967<br />

Kraft pulping qualities Philippines Semana et al. 1967<br />

Pulp characteristics Philippines Semana et al. 1967<br />

Pulping with mixed hardwoods India Bhargava et al. 1969<br />

Cooking process; kraft pulping; fibre morphology;<br />

yield; pulp properties<br />

Brazil Ciaramellao 1970<br />

Pulping potential; pulp strength Brazil Cunningham <strong>and</strong> Clark 1970<br />

Sulphate pulping; beater adhesives; types of paper Philippines Escolano <strong>and</strong> Semana 1970<br />

Pulping with mixed hardwoods India Guha <strong>and</strong> Sharma 1970<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique 1970<br />

Cooking process; kraft pulping; fibre morphology;<br />

yield; pulp properties<br />

Brazil Ciaramellao <strong>and</strong> Azzini 1971<br />

NSSC pulping Brazil Janci et al 1971<br />

Suitability <strong>for</strong> pulping Indonesia Pasaribu <strong>and</strong> Silitonga 1974<br />

Pulping with mixed hardwoods Brazil Barichello <strong>and</strong> Foelkel 1975<br />

(a,b)<br />

Fibre morphology; chemical composition Brazil Azzini 1976<br />

Fibre morphology; chemical composition; pulping;<br />

alkali consumption; pulp yield; beating; pulp<br />

strength; pulp sheet properties<br />

India Singh et al. 1976 (a, b,c)<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury 1982<br />

Pulp strength Brazil Gomide et al. 1985<br />

Effect of age on pulping Brazil Azzini et al. 1987<br />

Fibre morphology; chemical composition Malaysia Jamaludin <strong>and</strong> Abdul Jalil<br />

1991<br />

Fibre morphology Malaysia Abdul Latif Mohamod <strong>and</strong><br />

Mohamod Tamizi 1992<br />

Kraft process Malaysia Jamaludin <strong>and</strong> Abdul Jalil<br />

1993<br />

Kraft pulping; yield Malaysia Jamaludin et al. 1993<br />

Fibre morphology; alkaline pulping; effect of active<br />

alkali content; effect of age on pulping<br />

Ghana Sekyere 1994<br />

Fibre morphology; chemical composition Malaysia Jamaludin et al. 1994<br />

23. Bambusa vulgaris var. striata<br />

Fibre morphology; chemical composition; Belgian Congo Istas et al. 1956; Istas 1958<br />

methods of cooking<br />

(Africa)<br />

Fibre morphology; chemical composition; Belgian Congo Istas <strong>and</strong> Raekelboom 1962<br />

methods of cooking<br />

(Africa)<br />

Kraft pulping qualities; bleaching Philippines FPRDI 1962<br />

Chemical composition; kraft pulping qualities;<br />

pulp characteristics<br />

Philippines Semana et al. 1967<br />

24. Bambusa vulgaris var. vittata<br />

Chlorination process; bleached kraft pulp Myanmar Mai-Aung 1961<br />

High –yield pulping Brazil Mazzei et al. 1967<br />

Effect of age on sulphate pulping; pulp strength Brazil Mazzei <strong>and</strong> Rediko 1967<br />

Cooking process; kraft pulping; fibre<br />

morphology; yield; pulp properties<br />

88<br />

Brazil Ciaramellao 1970;<br />

Ciaramellao <strong>and</strong> Azzini<br />

1971<br />

(Continue next page)


Rapid alkaline pulping process; yield <strong>and</strong> Brazil Barrichello <strong>and</strong> Foelkel<br />

strength<br />

1975(a, b)<br />

Fibre dimensions; pulp sheet properties India Singh et al. 1976<br />

Fibre morphology; paper-making properties;<br />

pulping suitability<br />

Myanmar Wai <strong>and</strong> Murakami 1984<br />

Alkaline sodium sulphite- AQ pulping China Yao <strong>and</strong> Zou 1986<br />

25. Cephalostachyum pergracile (Syn Schizostachyum pergracile)<br />

Bleachable grade pulp by chlorination process Myanmar Mai- Aung 1961<br />

Mixed pulping; bleached kraft pulp; pulp<br />

strength<br />

Myanmar Mai- Aung et al. 1968<br />

Variation in fibre length India Pattanath 1972<br />

Fibre morphology; chemical composition; India Singh et al. 1976 (a, b, c)<br />

pulping; alkali consumption; pulp yield; beating;<br />

pulp strength; pulp sheet properties<br />

Fibre morphology; paper-making properties Myanmar Wai <strong>and</strong> Murakami 1984<br />

26. Dendrocalamus asper<br />

Suitability <strong>for</strong> pulping; pulping with mixed<br />

hardwoods<br />

27. Dendrocalamus br<strong>and</strong>isii<br />

89<br />

Indonesia Pasaribu <strong>and</strong> Silitonga 1974<br />

Pulp bleaching Myanmar Mai-Aung et al. 1968<br />

28. Dendrocalamus giganteus<br />

Pulp strength Africa Doat 1967<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique<br />

1970<br />

Sulphate pulp; chemical composition India Guha et al. 1975<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury<br />

1982<br />

Physio-chemical properties of spent liquor India Vijan <strong>and</strong> Madan 1995<br />

Chemical composition India Vijan <strong>and</strong> Madan 1996<br />

29. Dendrocalamus hamiltonii<br />

Semi-chemical pulping India Bhargava 1945<br />

Fibre morphology; chemical composition; pulping;<br />

yield (Review)<br />

India Singh <strong>and</strong> Mukherjea 1965<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique 1970<br />

Fibre morphology; chemical composition; pulping;<br />

alkali consumption; pulp yield; beating; pulp<br />

strength; pulp sheet properties<br />

India Singh et al. 1971, 1976 (a,b,c )<br />

Variation in fibre length India Pattanath 1972<br />

Chemical composition India Dhawan <strong>and</strong> Singh 1982<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury 1982<br />

Storage; pulping; fibre morphology; bleaching;<br />

beating; pulp sheet properties<br />

India Singh et al. 1988<br />

Pulp strength; soda pulping Pakistan Suleiman 1994


30. Dendrocalamus latiflorus<br />

Industrial kraft pulping Formosa Chen 1958<br />

Mechanical pulp <strong>for</strong> Chinese “Joss”<br />

(ceremonial) paper<br />

Taiwan Perdue et al. 1961<br />

Magnifite process Taiwan Chao 1963<br />

Alkaline sulphite pulping Taiwan Chao <strong>and</strong> Pan 1963<br />

Kraft pulping; bleaching Taiwan Chao <strong>and</strong> Pan 1972<br />

Methods of cooking; pulp <strong>for</strong> printing paper;<br />

bleaching; yield; pulp properties<br />

Taiwan Chen et al. 1974<br />

High–yield pulping; chemical composition;<br />

utilization of residue <strong>for</strong> pulping<br />

Malaysia Wang <strong>and</strong> Lirn 1984<br />

Pulping suitability Taiwan Ku <strong>and</strong> Wang 1990<br />

31. Dendrocalamus longispathus<br />

Semi-commercial pulping tests India Bhargava 1945<br />

Fibre morphology; chemical composition; Belgian Congo Istas et al. 1956<br />

methods of cooking; effect of age on pulp<br />

properties<br />

(Africa)<br />

Fibre morphology; chemical composition;<br />

method of pulping; yield; types of paper<br />

(Review)<br />

India Singh <strong>and</strong> Mukherjea 1965<br />

Storage of pulp wood Myanmar Mai-Aung et al. 1969<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique<br />

1970<br />

Variation in fibre length India Pattanath 1972<br />

Fibre morphology; chemical composition; India Singh et al. 1976 (a, b,c)<br />

pulping; alkali consumption; pulp yield; beating;<br />

pulp strength; pulp sheet properties<br />

Effect of age on fibre morphology; chemical<br />

composition; pulping; pulp sheet properties<br />

Bangladesh Razzaque et al. 1981<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury<br />

1982<br />

Fibre morphology; paper making properties Myanmar Wai <strong>and</strong> Murakami 1984<br />

Storage; pulping; fibre morphology; bleaching;<br />

beating; pulp sheet properties<br />

India Singh et al. 1988<br />

32. Dendrocalamus membranaceus<br />

Fibre morphology; paper making properties Myanmar Wai <strong>and</strong> Murakami 1984<br />

33. Dendrocalamus strictus<br />

Pulping trials India Ahmed <strong>and</strong> Karnik 1944<br />

Semi-commercial pulping trial India Bhargava 1945<br />

Rayon grade pulping (prehydrolysis sulphate India Karnik <strong>and</strong> Sen 1948;<br />

process)<br />

Karnik 1961(a ,b)<br />

Fibre morphology; chemical composition; Belgian Congo Istas et al. 1956<br />

methods of cooking; effect of age on pulping<br />

properties<br />

(Africa)<br />

(Continue next page)<br />

90


Fibre morphology; chemical composition; Belgian Congo Istas 1958<br />

methods of cooking<br />

(Africa)<br />

Fibre morphology India Ghosh <strong>and</strong> Negi 1958<br />

Bleaching; pulp sheet characteristics India Guha <strong>and</strong> Pant 1961<br />

NSSC pulping India Guha <strong>and</strong> Pant 1961<br />

Fibre morphology; chemical composition; Belgian Congo Istas <strong>and</strong> Raekelboom 1962<br />

methods of cooking<br />

(Africa)<br />

Dissolving grade pulp India P<strong>and</strong>e 1966<br />

Sulphate pulp characteristics; pulp strength;<br />

types of paper<br />

India Guha <strong>and</strong> Pant 1966<br />

Pulping process India Mukherjea 1967<br />

Chemical composition India Ingle <strong>and</strong> Bose 1969<br />

Pulping with mixed hardwoods India Bharagava et al. 1969<br />

Sulphate pulping India Banthia et al. 1969(b)<br />

Dissolving grade pulp; steam- vapour phase prehydrolysis<br />

India P<strong>and</strong>e 1970<br />

Pulping <strong>and</strong> sulphate pulp sheet properties India Tissot 1970<br />

Pulping with mixed hardwoods India Guha <strong>and</strong> Sharma 1970<br />

Fibre morphology; chemical composition;<br />

methods of cooking<br />

India Mukherjea <strong>and</strong> Guha 1971<br />

Pulping <strong>and</strong> sulphate pulp sheet properties India Singh et al. 1971<br />

Variation in fibre length India Pattanath 1972<br />

Sulphate pulping India Guha et al. 1975<br />

Pulping with mixed hardwoods India Krishnamachari et al. 1975<br />

Alkaline pulping India Singh <strong>and</strong> Guha 1975<br />

Fibre morphology; chemical composition India Maheshwari et al. 1976<br />

Fibre morphology; chemical composition;<br />

pulping<br />

India Maheshwari et al. 1976<br />

Fibre morphology; chemical composition; India Singh et al. 1976 (a, b, c)<br />

pulping; alkali consumption; pulp yield; beating;<br />

pulp strength; pulp sheet properties<br />

Beating India Rao et al. 1978<br />

Kraft – AQ pulping India Maheshwari 1979<br />

Fibre morphology; kraft paper India Guha et al. 1980 (a)<br />

Pulping with mixed hardwoods; types of paper India Guha et al. 1980 (b)<br />

Black liquor analysis India Khanna <strong>and</strong> Swaleh 1981<br />

Pulp <strong>and</strong> paper-making characteristics India Maheshwari 1981 (a)<br />

Pulping with mixed hardwoods India Singh et al. 1981<br />

Chemical composition India Dhawan <strong>and</strong> Singh 1982<br />

Vapour phase kraft pulping India Goyal <strong>and</strong> Misra 1982(b)<br />

Pre-hydrolysis – effect of pH India Devi et al. 1982<br />

Chemical composition; bleaching India Rao et al. 1983<br />

Chemical composition India Kapoor <strong>and</strong> Guha 1984<br />

Improved process control India Pravin 1987<br />

Chemical composition India Maheshwari <strong>and</strong> Satpathy<br />

1988<br />

Storage; pulping; fibre morphology; bleaching;<br />

beating; pulp sheet properties<br />

India Singh et al. 1988<br />

Soda process; pulp strength Pakistan Suleiman 1994<br />

91


34. Gigantochloa aspera<br />

Chemical composition <strong>and</strong> paper- making Belgian Congo Istas <strong>and</strong> Hontoy 1952<br />

properties<br />

(Africa)<br />

Storage; fibre characteristics; chemical Belgian Congo Istas <strong>and</strong> Raekelboom 1962<br />

composition; cooking schedules; pulp <strong>and</strong> paper<br />

properties<br />

(Africa)<br />

Pulping qualities; bleaching Philippines FPRDI 1962<br />

Sulphate (kraft) pulping, pulp strength Philippines Monsalud 1964; Gonzalez<br />

<strong>and</strong> Escolano 1965<br />

Effect of variables in sulphate pulping Philippines Semana 1965<br />

Chemical composition (silica content); kraft<br />

pulping qualities; pulp strength<br />

Philippines Semana et al. 1967<br />

35. *Gigantochloa ater, 36. Gigantochloa apus & 37. Gigantochloa verticillata<br />

Fibre morphology; chemical composition; 3<br />

methods of cooking<br />

* Suitability <strong>for</strong> pulping<br />

Fibre morphology; chemical composition; 3methods<br />

of cooking; effect of age on pulping<br />

properties<br />

Fibre morphology; chemical composition; 3<br />

methods of cooking<br />

38. Gigantochloa levis<br />

Belgian Congo<br />

(Africa)<br />

92<br />

* Indonesia<br />

Belgian Congo<br />

(Africa)<br />

Belgian Congo<br />

(Africa)<br />

Istas et al. 1956<br />

* Pasaribu <strong>and</strong> Silitonga<br />

1974<br />

Istas 1958<br />

Istas <strong>and</strong> Raekelboom 1962<br />

Pulping qualities; bleaching Philippines FPRDI 1962<br />

Chemical composition (silica content) Japan Tsuji <strong>and</strong> Ono 1966<br />

Kraft pulping qualities Philippines Semana et al. 1967<br />

39. Gigantochloa scortechinii<br />

Pulp beating Malaysia Jamaludin et al. 1992<br />

Effect of age on fibre morphology; chemical<br />

composition; pulp sheet properties<br />

40. Guadua amplexifolia<br />

Malaysia Abdul Latif Mohamod et<br />

al. 1994<br />

Pulping potential Mexico Cunningham <strong>and</strong> Clark<br />

1970<br />

41 Guadauaa angustifolia; 42. Guadua glomerata; 43. Guada morim ; 44. Guada<br />

superba<br />

46. Nastus amazonicus<br />

Chemical, semi-chemical, chemi- mechanical<br />

<strong>and</strong> mechanical pulps; pulp characteristics; types<br />

of paper<br />

Brazil Correa et al. 1977


45. Melocalamus compactiflorus<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique<br />

1970<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury<br />

1982<br />

46. Nastus amazonicus<br />

Chemical, semi-chemical, chemi- mechanical<br />

<strong>and</strong> mechanical pulps; pulp characteristics; types<br />

of paper<br />

47. Melocanna baccifera (Syn. Melocanna bambusoides)<br />

93<br />

Brazil Correa et al. 1977<br />

Semi-commercial pulping tests India Bhargava 1945<br />

Fibre morphology; chemical composition; India Singh <strong>and</strong> Mukherjea 1965<br />

method of pulping; yield; product <strong>for</strong> which the<br />

pulp is suitable (Review)<br />

Rayon grade pulping Japan Oye et al. 1970<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique<br />

1970<br />

Variation in fibre length India Pattanath 1972<br />

Fibre morphology; chemical composition; India Singh et al. 1976 (a, b, c)<br />

pulping; alkali consumption; pulp yield; beating;<br />

pulp strength; pulp sheet properties<br />

Kraft – AQ pulping India Maheshwari 1979<br />

Fibre morphology; chemical composition; India Guha et al. 1980<br />

pulping; bleaching; pulp yield; pulp properties;<br />

kraft paper<br />

Effect of age on chemical composition, fibre<br />

dimensions, pulp yield <strong>and</strong> strength<br />

Bangladesh Razzaque et al. 1981<br />

Chemical composition India Dhawan <strong>and</strong> Singh 1982<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury<br />

1982<br />

Fibre morphology; paper-making properties Myanmar Wai <strong>and</strong> Murakami 1984<br />

Storage; pulping; fibre morphology; bleaching;<br />

beating; pulp sheet properties<br />

India Singh et al. 1988<br />

Neutral sulphite –AQ pulping; influence of age<br />

on kraft pulping; pulp strength<br />

Bangladesh Bose et al. 1998 (a,b)<br />

Kraft pulping Bangladesh Shah et al. 1991<br />

Kraft <strong>and</strong> soda – AQ pulping Bangladesh Bhowmick et al. 1991 (a, b)<br />

& 1992 (b)<br />

Chemical composition; soda process; bleaching;<br />

types of paper<br />

Bangladesh Karim et al. 1994<br />

High- yield alkaline/ kraft semi-chemical<br />

pulping<br />

Bangladesh Alam et al. 1997(a, b)


48. Ochl<strong>and</strong>ra scriptoria (Syn. Ochl<strong>and</strong>ra rheedii)<br />

Industrial experience India Singh <strong>and</strong> Mukherjea 1965<br />

Bleaching India Singh et al. 1977<br />

Kraft pulping conditions India Singh et al. 1988<br />

49. Ochl<strong>and</strong>ra travancorica<br />

Pulping trials India Ahamed <strong>and</strong> Karnik 1944<br />

Semi-commercial pulping tests India Bhargava 1945<br />

Rayon grade pulping India Anonymous 1947<br />

Chemical composition <strong>and</strong> paper making Belgian Congo Istas <strong>and</strong> Hontoy 1952<br />

properties<br />

Fibre dimensions; chemical composition; 3methods<br />

of cooking; effect of age on pulp<br />

properties<br />

94<br />

(Africa)<br />

Belgian Congo<br />

(Africa)<br />

Istas et al. 1956<br />

Rayon grade pulping India Bhat <strong>and</strong> Viramani 1961<br />

Storage; pulping; fibre morphology; bleaching;<br />

beating; pulp sheet properties<br />

India Singh et al. 1988<br />

50. Oxytenanthera abyssinica<br />

Pulping suitability Africa Monteiro 1949<br />

Suitability <strong>for</strong> pulping Belgian Congo<br />

(Africa)<br />

Frison 1951<br />

Chemical composition; suitability <strong>for</strong> pulping Mozambique &<br />

Guinea<br />

Seabra 1954<br />

Pulping suitability Abyssinia (Africa) Mooney 1959<br />

Storage; fibre characteristics; chemical<br />

composition; cooking schedules; pulp <strong>and</strong> paper<br />

properties<br />

Belgian Congo<br />

(Africa)<br />

Istas <strong>and</strong> Raekelboom 1962<br />

Species distribution, pulping suitability Ghana Kadambi <strong>and</strong> Ashong 1966<br />

Pulp strength Africa Doat 1967<br />

Variation in fibre length India Pattanath 1972<br />

51. Oxytenanthera monostigma<br />

Fibre morphology; pulping characteristics India Maheshwari et al. 1976


52. Oxytenanthera nigrociliata (Syn. Gigantochloa rostrata)<br />

Semi-commercial pulping tests India Bhargava 1945<br />

Fibre morphology; chemical composition;<br />

method of pulping; yield; types of paper<br />

(Review)<br />

95<br />

India Singh <strong>and</strong> Mukherjea<br />

1965<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique 1970<br />

Variation in fibre length India Pattanath 1972<br />

Fibre morphology; chemical composition; India Singh et al. 1976 (a, b, c)<br />

pulping; alkali consumption; pulp yield; beating;<br />

pulp strength; pulp sheet properties<br />

Effect of age on chemical composition; fibre<br />

dimensions; pulp yield <strong>and</strong> strength<br />

Bangladesh Razzaque et al. 1981<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury 1982<br />

Storage; pulping; fibre morphology; bleaching;<br />

beating; pulp sheet properties<br />

India Singh et al. 1988<br />

53. Oxytenanthera ritchei<br />

Kraft pulping; 3 cooking schedule; bleaching<br />

types of paper<br />

54. Phyllostachys bambusoides<br />

India Bh<strong>and</strong>ari 1981<br />

Rayon grade pulping India Anonymous 1947<br />

Dissolving grade pulp by pre-hydrolysis <strong>and</strong><br />

sulphate pulping<br />

Savannah, Ga Nafzier 1960<br />

Chemical, semi-chemical (cold soda semichemical<br />

<strong>and</strong> neutral sulphite) <strong>and</strong> mechanical<br />

pulp <strong>for</strong> newsprint<br />

Savannah, Ga Nafziger et al. 1961<br />

Newsprint India Guha <strong>and</strong> Pant 1961<br />

Sulphate pulp characteristics; pulp strength;<br />

bleaching; types of paper<br />

India Guha <strong>and</strong> Pant 1966<br />

Sulphate pulp India Guha <strong>and</strong> Pant 1972<br />

55. Phyllostachys edulis<br />

Industrial kraft pulping Formosa Chen 1958<br />

Pulping suitability; yield; economics Georgia (Soviet) K<strong>and</strong>elaki 1976<br />

Utilization of residue <strong>for</strong> pulping; fibre<br />

dimensions; chemical composition; neutral<br />

sulphate – AQ process<br />

Taiwan Wang <strong>and</strong> Lirn 1984<br />

56. Phyllostachys makinoi<br />

Raitt process; effect of different variables; yield;<br />

fibre length<br />

Taiwan Du 1957<br />

Kraft pulping Taiwan Chao <strong>and</strong> Pan 1972<br />

3- methods of cooking; pulp <strong>for</strong> printing paper;<br />

bleaching; yield; pulp properties<br />

Taiwan Chen et al. 1974<br />

Utilization of residue <strong>for</strong> pulping; fibre<br />

dimensions; chemical composition; neutral<br />

sulphate – AQ process<br />

Taiwan Wang <strong>and</strong> Lirn 1984<br />

Pulping suitability Taiwan Ku <strong>and</strong> Wang 1990


57. Phyllostachys pubescens<br />

Mechanical pulp <strong>for</strong> Chinese “Joss” Taiwan Perdue et al. 1961<br />

(ceremonial) paper<br />

Alkaline sulphite – AQ pulping China Yao <strong>and</strong> Zou 1986<br />

Effect of age on pulping; chemical composition;<br />

pulping properties<br />

China Xia 1989<br />

Pulping suitability Taiwan Ku <strong>and</strong> Wang 1990<br />

58. Phyllostachys reticulata<br />

Industrial kraft pulping Formosa Chen 1958<br />

Fibre morphology; Effect of age on soda pulping Japan Kitamura 1962<br />

Dissolving pulp Japan Tsuji et al. 1965<br />

59. Phyllostachys spp. (2 species)<br />

Chemical composition; pulping suitability;<br />

economics;<br />

60. Pleioblastus amarus<br />

96<br />

Georgia (Soviet) K<strong>and</strong>elaki 1976<br />

Pulping suitability China Zhang et al. 1998<br />

61. Sasa albomarginata; 62. Sasa spp.<br />

Acid pre-hydrolysis; alkaline (soda) pulping,<br />

kraft <strong>and</strong> neutral sulphite semi-chemical pulping<br />

processes; pulp strength<br />

Japan Fukuyama et al. 1955<br />

Pulping trial Japan Fukuyama <strong>and</strong> Kawase<br />

1955<br />

Pulping of young culms Japan Kawase et al. 1986<br />

63. Sasa japonica<br />

Chemical composition <strong>and</strong> paper making<br />

properties<br />

Fibre dimensions; chemical composition; 3methods<br />

of cooking; effect of age on pulp<br />

properties<br />

Fibre dimensions; chemical composition; 3methods<br />

of cooking<br />

Belgian Congo<br />

(Africa)<br />

Belgian Congo<br />

(Africa)<br />

Belgian Congo<br />

(Africa)<br />

Istas <strong>and</strong> Hontoy 1952<br />

Istas et al. 1956<br />

Istas 1958; Istas <strong>and</strong><br />

Raekelboom 1962


64. Sasa kurilensis<br />

Chemical composition <strong>and</strong> paper- making Belgian Congo Istas <strong>and</strong> Hontoy 1952<br />

qualities<br />

(Africa)<br />

Fibre dimensions; chemical composition; 3- Belgian Congo Istas et al. 1956<br />

methods of cooking; effect of age on pulp<br />

properties<br />

(Africa)<br />

Fibre dimensions; chemical composition; 3- Belgian Congo Istas 1958; Istas <strong>and</strong><br />

method of cooking<br />

(Africa)<br />

Raekelboom 1962<br />

Alkaline pulping Japan Ujiie et al. 1986 (b)<br />

Yield Japan Matsui 1963<br />

65. Sasa paniculata<br />

Suitability <strong>for</strong> pulping Belgian Congo<br />

(Africa)<br />

66. Sasa senanensis<br />

97<br />

Istas 1958<br />

Per acetic acid pulping Japan Yamagishi et al. 1970<br />

Semi-kraft pulp Japan Ujiie <strong>and</strong> Matsumato 1967<br />

67. Sasa variabilis<br />

Suitability <strong>for</strong> pulping Belgian Congo<br />

(Africa)<br />

68. Schizostachyum funghomii<br />

Effect of age on chemical composition, pulping<br />

properties<br />

69. Schizostachyum lumampao<br />

Istas 1958<br />

China Xia 1989<br />

Pulping qualities; bleaching Philippines FPRDI 1962<br />

2- stage <strong>and</strong> single- stage sulphate pulping,<br />

bleaching; yield <strong>and</strong> paper- making properties;<br />

types of paper<br />

Philippines Anonymous 1966<br />

Kraft pulping qualities Philippines Semana et al. 1967<br />

70. Sinocalamus latiflorus<br />

Fibre morphology; alkaline pulping (Raitt<br />

process); yield<br />

Taiwan Du 1957<br />

Optimum utilization <strong>for</strong> pulping (bamboo shoot<br />

– sheath pulping); neutral sulphite pulping<br />

India Gupta <strong>and</strong> Jain 1966<br />

Bleaching Taiwan Chen et al. 1973<br />

Rayon grade pulping China Chang <strong>and</strong> Kuo 1976


71. Teinostachyum dullooa (Syn. Neohouzeaua dullooa / Schizostachyum dullooa)<br />

Semi-commercial pulping tests India Bhargava 1946<br />

Fibre morphology; chemical composition; India Singh <strong>and</strong> Mukherjea 1965<br />

method of pulping; yield; types of paper<br />

(Review)<br />

Kraft pulp; optimum cooking conditions Vietnam Nepenin <strong>and</strong> Bang 1969<br />

Fibre morphology Bangladesh Razzaque <strong>and</strong> Siddique<br />

1970<br />

Effect of age on chemical composition, fibre<br />

dimensions, pulp yield <strong>and</strong> strength<br />

Bangladesh Razzaque et al. 1981<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury<br />

1982<br />

Storage; pulping; fibre morphology; bleaching;<br />

beating; pulp sheet properties<br />

India Singh et al. 1988<br />

72. Thyrostachys oliveri<br />

Variation in fibre length India Pattanath 1972<br />

Fibre morphology; chemical composition;<br />

pulping; alkali consumption; pulp yield; beating;<br />

pulp strength; pulp sheet properties<br />

98<br />

India Singh et al. 1976 (a, b,c)<br />

Fibre morphology Bangladesh Siddique <strong>and</strong> Chowdhury<br />

1982<br />

(Species confirmation / clarification reference : Ohrnberger 1999) 114<br />

The following Table consolidates the available in<strong>for</strong>mation on investigation on pulping of different<br />

species whose actual species details are not obtained (original articles not seen) :<br />

1 6 spp. Raitt process (alkaline pulping); Taiwan Du 1957<br />

pulping conditions; effect of<br />

variables;<br />

morphology<br />

pulp yield; fibre<br />

2 33 spp. Fibre structure China Chu <strong>and</strong> Yao 1964<br />

3 13 spp. Fibre morphology Philippines Monsalud 1965<br />

4 11 spp. Bleached<br />

pulping<br />

kraft pulp; mixed Myanmar Mai- Aung et al. 1968<br />

5 5 spp. 3 –cooking conditions Taiwan Chen et al. 1974<br />

6 13 spp. Fibre morphology; suitability <strong>for</strong> Bangladesh Siddique <strong>and</strong> Chowdhury<br />

pulping<br />

1982<br />

7 8 spp. Chemical composition China Xia 1989<br />

8 22 spp. Fibre <strong>and</strong> paper- making<br />

properties<br />

China Zhang 1995


17. APPENDICES<br />

APPENDIX – 1<br />

A. Some st<strong>and</strong>ard terms used in pulping process<br />

Total chemical : All sodium salts, expressed as Na2O<br />

Total alkali : NaOH + Na2S + Na2CO3 + Na2SO4, expressed as Na2O<br />

Active alkali : NaOH + Na2S, expressed as Na2O<br />

Effective alkali : NaOH + ½ Na2S, expressed as Na2O, ie, the NaOH + the portion of<br />

Na2S that gives NaOH when hydrolysed.<br />

Sulphidity : Percentage found by dividing Na2S by Na2S + NaOH, as Na2O, <strong>and</strong><br />

multiplied by 100<br />

Causticity : Percentage found by dividing NaOH by NaOH + Na2CO3, all<br />

expressed as Na2O, <strong>and</strong> multiplied by 100<br />

Alkali recovery : Percentage found by dividing the total alkali delivered to the<br />

digesters minus the sodium salts in new chemical by total alkali to<br />

the digesters <strong>and</strong> multiplying by 100. All figures expressed as Na2O.<br />

Green liquor : Liquor made by dissolving the smelt from the recovery furnace<br />

(recovered chemicals) in water <strong>and</strong> weak liquor preparatory to<br />

causticizing.<br />

White liquor : Liquor made by causticizing the green liquor; the cooking liquor<br />

used in the digesters<br />

Black liquor : Liquor recovered from digesters<br />

Causticizing : Making of white liquor from green liquor by addition of slaked lime<br />

B. Explanation of some general terms used in describing pulp strength properties<br />

Burst strength - is a complex function of tensile strength at various angles to the<br />

machine direction of the paper together with stretch of the<br />

paper in these various directions.<br />

Folding strength - is a very complicated function, involving tensile strength, stretch<br />

modulus <strong>and</strong> toughness or brittleness of the fibres.<br />

Stiffness - is a direction reflection of the stiffness of the individual fibres<br />

assuming an adequate amount of inter-fibre bonding <strong>and</strong> a st<strong>and</strong>ard<br />

density level in the paper.<br />

99


APPENDIX – 2<br />

A. Proximate chemical analysis, fibre dimensions <strong>and</strong> pulp strength of some cellulose raw<br />

materials used in papermaking (all Indian fibres)<br />

Particulars <strong>Bamboo</strong> Pine Eucalypt Bagasse Rice straw Kenaf<br />

Approximate analysis :<br />

Lignin %<br />

Pentosans %<br />

Alpha cellulose %<br />

Ash %<br />

Fibre dimension :<br />

Fibre length (ave.) mm<br />

Fibre diameter (ave.) µm<br />

Unbleached pulp strength :<br />

Initial freeness ml C.S.F.<br />

Final freeness m1C.S.F.<br />

Breaking length m.<br />

Burst factor<br />

Tear factor<br />

Double-folds<br />

Sheet density g/cc<br />

Pulping process<br />

26<br />

15<br />

40<br />

3.0<br />

2.7<br />

15<br />

690<br />

250<br />

5700<br />

42<br />

110<br />

200<br />

0.6<br />

Kraft<br />

27<br />

9<br />

41<br />

0.3<br />

3.6<br />

40<br />

700<br />

300<br />

6900<br />

57<br />

160<br />

600<br />

0.68<br />

Kraft<br />

100<br />

25<br />

20<br />

44<br />

0.5<br />

1.2<br />

24<br />

650<br />

250<br />

6500<br />

50<br />

75<br />

320<br />

0.69<br />

Kraft<br />

Initial freeness : m1 C.S.F. milli-litre Canadian freeness.<br />

Final freeness : m1 C.S.F.<br />

Source : Podder (1979)<br />

18<br />

20<br />

31<br />

4.5<br />

1.7<br />

17<br />

590<br />

250<br />

5100<br />

34<br />

60<br />

38<br />

0.66<br />

Soda<br />

12<br />

23<br />

32<br />

15<br />

1.1<br />

9<br />

400<br />

200<br />

4300<br />

28<br />

50<br />

11<br />

0.63<br />

Soda<br />

18<br />

20<br />

38<br />

2.5<br />

2.0<br />

15<br />

550<br />

250<br />

7000<br />

55<br />

95<br />

400<br />

0.72<br />

Kraft<br />

B. Composition of raw materials used in paper industry. (All values are expressed as<br />

percentage on dry basis)<br />

Raw materials Cellulose<br />

(Cross&<br />

Bevan)<br />

Pentosan Lignin Alcohol<br />

Benzene<br />

Extractables<br />

Ash Silica<br />

(SiO2)<br />

<strong>Bamboo</strong> 57.0 14.0 25 2.0 2.0 1-1.5<br />

Rice straw 51.0 22.0 12 4.0 11.0 4-8<br />

Bhutang grass (stems) 39.3 28.4 22.5 2.1 33.9 1.6<br />

Khagre grass (stems) 36.5 29.0 23.3 4.4 2.7 0.9<br />

Jute (stick) 56.0 20.0 21.0 1.0 2.0 -<br />

Jute 70.0 15.0 11.0 1.0 3.0 -<br />

Sisal hemp 77.0 13.0 6.0 1.0 3.0 -<br />

Bagasse 50.0 25.0 18.0 3.0 4.0 1-1.5<br />

Sal 56.0 13.4 24.9 6.0 1.0 -<br />

Salai 50.7 13.0 27.3 4.3 1.8 0.29<br />

Casuarina 56.7 19.2 23.2 3.4 0.8 -<br />

Pine 61.0 11.0 26.0 1.0 1.0 0.1-0.3<br />

Eucalyptus hybrid 54.0 14.1 30.9 - 0.4 0.03<br />

Source : Podder (1979)


APPENDIX 3<br />

A. Proximate chemical analysis of the two important Indian bamboo species<br />

(Dendrocalamus strictus <strong>and</strong> Bambusa bambos (Syn. B. arundinaceae))<br />

Chemical constituents (%) D. strictus B. bambos<br />

Cellulose (Cross & Bevan) 60.00 57.56<br />

Lignin 23.89 3.09<br />

Pentosans 15.84 19.62<br />

Cold water solubles 7.85 5.95<br />

Alcohol- benzene solubles 1.80 1.22<br />

Other solubles 1.47 0.82<br />

Ash 1.8 3.26<br />

Silica 0.47 1.79<br />

1% caustic soda solubles 23.18 19.35<br />

10% caustic potash solubles 30.52 40.10<br />

Source : Nair (1970)<br />

B. Variation of fibre <strong>and</strong> tissue characteristics of some Indian bamboos<br />

Sl.<br />

No.<br />

Species Mean fibre<br />

length<br />

(mm)<br />

101<br />

Mean fibre<br />

diameter<br />

(µ m)<br />

Mean luman<br />

Diameter<br />

(µ m)<br />

Parenchyma<br />

(%)<br />

1 Bambusa bambos 2.24 16 4 21.7<br />

2 Bambusa nutans 2.40 15 3 20.6<br />

3 Bambusa polymorpha 2.53 16 4 22.4<br />

4 Bambusa tulda 2.10 15 5 18.4<br />

5 Bambusa vulgaris 2.02 15 5 20.0<br />

6 Cephalostachyum pergracile 2.20 16 4 18.3<br />

7 Dendrocalamus hamiltonii 2.40 13 3 26.6<br />

8 Dendrocalamus longispathus 2.70 15 3 17.5<br />

9 Dendrocalamus strictus 2.45 14 2 21.2<br />

10 Melocanna baccifera 2.78 15 3 19.5<br />

11 Oxytenanthera nigrociliata 2.43 15 3 18.7<br />

12 Thyrostachys olivery 2.31 15 3 19.5<br />

Source : Singh (1989)


A. Survey of pulping processes<br />

APPENDIX – 4<br />

Process / Pulp type Chemical treatment Mechanical Wood+ Yield<br />

treatment<br />

(%)<br />

Mechanical pulping 80 - 99<br />

Stone grinding *<br />

Refiner pulping<br />

**<br />

**<br />

Groundwood<br />

(SGW)<br />

Steamed groundwood<br />

Pressure ground-<br />

wood (PGW)<br />

Refiner mechanical<br />

pulp (RMP)<br />

Pressurized refiner<br />

mechanical pulp<br />

(PRMP)<br />

Thermo-mechanical<br />

pulp (TMP)<br />

Asplund pulp<br />

None<br />

Steam<br />

None<br />

None<br />

None<br />

102<br />

Grindstone<br />

Grindstone<br />

Grindstone<br />

(pressure)<br />

Disk refiner<br />

Disk refiner<br />

(pressure)<br />

S<br />

S<br />

S<br />

93- 99<br />

80- 90<br />

Steam<br />

Disk refiner<br />

(pressure)<br />

S 91-98<br />

Steam<br />

Disk refiner S 80-90<br />

Chemimechanical <strong>and</strong> Chemi-thermomechanical pulping 65 - 97<br />

Stone grinding * Chemigroundwood<br />

(CGW)<br />

Refiner pulping Chemi-refiner<br />

mechanical pulp<br />

(CRMP)<br />

Chemi-thermomechanical<br />

pulp<br />

(CTMP)<br />

Neutral sulphite<br />

Or<br />

Acidic sulphite<br />

Or<br />

Na2S + NaOH<br />

NaOH or NaHSO3<br />

Or<br />

Alkaline sulphite<br />

Or<br />

Acidic sulphite<br />

Steam + Na2SO3<br />

+ NaOH<br />

S<br />

S<br />

Grindstone S/ H<br />

Disk refiner<br />

Disk refiner<br />

(pressure)<br />

S/ H<br />

S/ H<br />

S/ H<br />

S/ H<br />

93-98<br />

80-92<br />

80-90<br />

85-90<br />

80-90<br />

65-97<br />

Semichemical pulping 65 - 92<br />

Neutral sulphite<br />

(NSSC-pulp)<br />

Cold soda<br />

Alkaline sulphite<br />

Sulphate<br />

Soda<br />

Green liquor<br />

Nonsulphur<br />

Na2SO3 + Na2CO3<br />

or NaHCO3<br />

NaOH<br />

Na2CO3, Na2S, NaOH<br />

NaOH + Na2S<br />

NaOH<br />

Na2S + Na2CO3<br />

Na2CO3 + NaOH<br />

Disk refiner<br />

Disk refiner<br />

Disk refiner<br />

Disk refiner<br />

Disk refiner<br />

Disk refiner<br />

Disk refiner<br />

H<br />

H<br />

H/ S<br />

H/ S<br />

H<br />

H<br />

H<br />

65-90<br />

85-92<br />

80-90<br />

75-85<br />

65-85<br />

65-85<br />

65-85<br />

High-yield chemical pulping 55 - 70<br />

Kraft<br />

Sulphite<br />

Na2S + NaOH<br />

Acidic sulphite<br />

(Ca, Na, Mg)or<br />

Bisulphite (Na, Mg)<br />

Disk refiner<br />

Disk refiner<br />

S/ H<br />

S<br />

55-65<br />

55-70<br />

(continue next page)


Full chemical pulping 30 - 60<br />

Alkaline pulping Kraft (+ AQ)<br />

Sulphite pulping<br />

Kraft (Polysulphide)<br />

Soda<br />

Soda – AQ<br />

Soda – oxygen, twostage<br />

Acidic sulphite<br />

Bisulphite<br />

Neutral sulphite<br />

Magnefite<br />

Multi-stage sulphite<br />

** Alkaline sulphite<br />

Dissolving pulping Acidic sulphite<br />

Prehydrolysis kraft<br />

NaOH + Na2S<br />

(+ AQ)<br />

(NaOH + Na2S)x<br />

NaOH<br />

NaOH + AQ<br />

NaOH, oxygen<br />

Acidic sulphite<br />

(Ca, Na, Mg, NH3)<br />

Bisulphite<br />

(Na, Mg, NH3)<br />

Neutral sulphite<br />

Mg- bisulphite<br />

Na2SO3 +<br />

NaHSO3/ SO2<br />

or<br />

NaHSO3 +<br />

SO2/ Na2CO3<br />

Na2SO3 + NaOH<br />

Acidic sulphite<br />

(Ca, Na)<br />

Na2S + NaOH<br />

after prehydrolysis<br />

* Wood used in the <strong>for</strong>m of bolts. All the other processes use chips.<br />

+ Wood mainly used (S: softwood, H: hardwood)<br />

** Not commercially established<br />

Source : Fengel <strong>and</strong> Wegener (1984)<br />

103<br />

Mild to none<br />

None<br />

None<br />

Mild to none<br />

Disk refiner<br />

Mild to none<br />

Mild to none<br />

Mild to none<br />

Mild to none<br />

None<br />

None<br />

None<br />

None<br />

S/ H<br />

S/ H<br />

H<br />

H<br />

H<br />

S<br />

(no pine)<br />

S/ H<br />

S/ H<br />

S/ H<br />

S/ H<br />

S/ H<br />

H/ S<br />

H/ S<br />

40-55<br />

45-60<br />

40-55<br />

45-55<br />

45-60<br />

45-55<br />

45-60<br />

45-60<br />

45-60<br />

45-55<br />

35-42<br />

30-35


B. Non-conventional pulping procedures<br />

Procedure Process data<br />

Nitric acid pulping HNO3 (1-60%); 15-150 0 C; 0.25-3h; extraction<br />

with aqueous NH4OH <strong>and</strong> /or NaOH<br />

Hydrotropic pulping Na-m-xylene sulfonate, Na-p-toluene sulfonate,<br />

Na-benzonate, Na-salicylate etc. in H2O or<br />

organic solvents; 150-170 0 C; 0.5-6h<br />

Organosolv puling Ethanol/ H2O (1:1); 180-215 0 C; 20-60 min<br />

Methanol/ H2O (1:1); 150-210 0 C; 30-180 min, 2<br />

steps alkaline medium<br />

Butanol/ H2O or Phenol/ H2O (1:1); 180-205 0 C;<br />

2-12h<br />

Alkali- methanol pulping 4% NaOH in 40% methanol; 140-160 0 C;<br />

30-120 min<br />

Phenol pulping Phenol (+ H2O, HCl); 160-170 0 C; 3-4 h<br />

Holopulping Defibration of alkali-impregnated chips;<br />

ClO2 –delignification; extraction with alkali;<br />

disk refining<br />

Acetic acid pulping CH3COOH/ conc. HCl/ acetone (7:1:2); 70 0 C;<br />

3- 6 h<br />

DMSO pulping DMSO/ H2SO4 (99:1), V/ V); 130- 160 0 C<br />

NO2/ SO2/ H2S or Cl2 in DMSO or DMF;<br />

→ 140 0 C; 0.5- 3 h<br />

DMSO/ EDA, DMSO/ hydrazine;<br />

DMSO/ CH3COOH, H2SO4 or HCl;<br />

145-176 0 C; 20 min- 3 h<br />

NO2 delignification NO2 (2-3%) in coal oil or CCl4; room temp.;<br />

10-30 min; extraction with 1% NaOH<br />

Vapour- phase SO2- process Saturated SO2 vapour; → 110 0 C<br />

Explosion- CO2- process Aqueous CO2 –solution; 160- 200 0 C; 50 bar;<br />

pressure reduction defibration<br />

Autohydrolysis delignification Autohydrolysis (175- 220 0 C); 4- 120 min; also<br />

in the presence of aromatic compounds (e.g. 2naphtol);<br />

extraction with dioxane/ H2O;<br />

defibration<br />

Ketone delignification Acetone, methyl- ethyl ketone; cyclohexanone<br />

or ketone- ammonia mixtures; 175- 210 0 C; 60-<br />

150 min<br />

Formaldehyde pulping HCHO (25-50%); 130-200 0 C; 5-200 min<br />

Source : Fengel <strong>and</strong> Wegner (1984)<br />

104


APPENDIX – 5<br />

A. Alkali consumption, Kappa No., unbleached pulp yield <strong>and</strong> chemical composition of<br />

some Indian bamboos <strong>and</strong> their pulps<br />

Sl.<br />

No.<br />

Species<br />

Caustic<br />

soda<br />

used in<br />

(%)<br />

Kappa<br />

number<br />

Pulp yield (%) Chemical composition (%)<br />

Unscreened Screened Lignin<br />

in<br />

bamboo<br />

105<br />

Lignin<br />

in<br />

pulp<br />

Pentosan<br />

in<br />

bamboo<br />

Pentosan<br />

in<br />

pulp<br />

1 Bambusa bambos 21 27.4 52.1 51.7 24.2 3.1 20.8 16.2<br />

2 Bambusa nutans 20 24.3 54.7 54.5 21.7 2.8 20.0 16.8<br />

3 Bambusa<br />

polymorpha<br />

20 27.2 44.4 43.4 24.7 3.0 18.5 17.0<br />

4 Bambusa tulda 21 28.2 54.8 54.4 23.1 4.7 18.1 11.3<br />

5 Bambusa<br />

vulgaris<br />

22 24.3 44.4 43.8 22.9 3.6 21.0 17.6<br />

6 Cephalostachyum<br />

pergracile<br />

20 28.2 54.5 52.8 24.9 4.3 18.4 15.9<br />

7 Dendrocalamus<br />

hamiltonii<br />

19 27.4 56.6 54.2 22.4 3.7 16.9 16.1<br />

8 Dendrocalamus<br />

longispathus<br />

20 25.2 48.9 48.4 25.0 3.9 18.6 15.8<br />

9 Dendrocalamus<br />

strictus<br />

22 28.0 51.0 50.9 26.0 3.0 23.2 15.3<br />

10 Melocanna<br />

baccifera<br />

25 25.0 43.9 43.8 27.0 4.1 19.6 15.5<br />

11 Oxytenanthera<br />

nigrociliata<br />

23 27.9 52.0 51.8 22.6 3.8 16.2 16.7<br />

12 Thyrostachys<br />

olivery<br />

22 27.2 48.9 47.0 20.9 3.0 18.5 17.0<br />

Source : Singh (1989)<br />

B. Characteristics of unbleached bamboo cold-soda pulp<br />

Characteristics Value<br />

Kappa number 158<br />

Brightness (% ISO) 19.40<br />

Yellowness (%) 53.80<br />

Ash (%) 2.50<br />

Silica (%) 1.20<br />

Solubility (%)<br />

(a) in cold water<br />

(b) in 0.1N NaOH<br />

2.74<br />

11.36<br />

Klason lignin (corrected <strong>for</strong> ash) (%) 23.31<br />

Acid- soluble lignin (%) 0.90<br />

Holocellulose (%) 71.14<br />

Pentosans (%) 15.60<br />

Source : Islam et al. (1989)


C. Characteristics of rayon grade pulp produced from bamboo at M/s.<br />

Gwalior Rayons Silk Manufacturing Company, Kerala, India <strong>and</strong> that<br />

imported from Alaska<br />

Characteristics Indian<br />

bamboo<br />

rayon pulp<br />

106<br />

Imported rayon pulp<br />

from Alaska<br />

(Coniferous softwoods)<br />

Alpha cellulose (%) 95.30 93.03<br />

Hemicelluloses (%) 4.62 4.05<br />

Soda solubles<br />

(solubility in 7.14% NaOH<br />

(%)<br />

6.87 11.18<br />

Ether solubles (%) 0.21 1.3<br />

Swelling index 6.6 6.42<br />

Ash (%) 0.039 0.187<br />

SiO2 (%) 0.011 0.0048<br />

Fe (ppm) 14 15<br />

CaO (%) 0.003 0.025<br />

Mg (%) Traces Traces<br />

Fluidity (cp) 35.6 17.3<br />

Copper number 0.7 1.4<br />

Size (mm) 793 x 595 760 x 600<br />

Basic weight (gm/m 2 ) 400 ------<br />

Source : Nair (1970)


A. Bleaching chemicals<br />

Industrially important Chlorine<br />

Sodium hypochlorite<br />

Calcium hypochlorite<br />

Chlorine dioxide<br />

Hydrogen peroxide<br />

Sodium peroxide<br />

Oxygen<br />

Less important or not<br />

commercially applied<br />

APPENDIX – 6<br />

Oxidizing chemicals Reducing chemicals<br />

Ozone<br />

Sodium chlorite<br />

Peracetic acid<br />

Chlorine monoxide<br />

Thioglycolic acid<br />

Hydrogen<br />

Potassiumpermanganate<br />

Cl2<br />

NaOCl<br />

Ca(OCl)2<br />

ClO2<br />

H2O2<br />

Na2O2<br />

O2<br />

O3<br />

NaClO2<br />

CH3CO3H<br />

Cl2O<br />

CH2SHCOOH<br />

H2<br />

KMnO4<br />

107<br />

Sodium dithionite<br />

Zinc dithionite<br />

Sodium bisulphite<br />

Sulphur dioxide<br />

Sodium borohydride<br />

Calcium dithionite<br />

Aluminium<br />

dithionite<br />

B. General conditions / Parameters governing bleaching processes<br />

Na2S2O4<br />

ZnS2O4<br />

NaHSO3<br />

SO2<br />

NaBH4<br />

CaS2O4<br />

Al2(S2O4)3<br />

Consistency (pounds of fibre in 100 pound of suspension, determined by the specific stage <strong>and</strong><br />

type of equipment used <strong>for</strong> the stage); chemical addition (the percentage of chemical added,<br />

based on the amount of pulp in the stage); chemical/ bleach consumption (the percentage of<br />

active chemical consumed, based on the amount of chemical added); chemical concentration (the<br />

amount of chemical per given volume of liquid in the stage, which is controlled by the chemical<br />

requirement of the pulp <strong>and</strong> the consistency at which the particular stage operates); pH<br />

(determined by conditions of reactions); temperature (detected by the type of reaction <strong>and</strong> the<br />

conditions of the state); <strong>and</strong> time (determined by the type of reaction <strong>and</strong> the conditions <strong>for</strong> the<br />

particular stage).


C. The symbols used to describe the sequences used in multi-stage bleaching of pulps<br />

Stage Symbol Chemicals<br />

Chlorination C Cl2<br />

Alkaline extraction E NaOH<br />

Hypochlorite H NaOCl + NaOH<br />

Chlorine dioxide D ClO2<br />

Peroxide P or P/ E H2O2 + NaOH or<br />

108<br />

Na2O2 + NaOH<br />

Oxygen O O2 + NaOH<br />

Cupriethylenediamine Cu En2 [Cu(H2NCH2CH2NH2)4](OH)2<br />

Chlorination with small amounts of ClO2 CD Cl2 + (ClO2)<br />

Sequential bleaching without intermediate<br />

washing<br />

D/C<br />

C/H<br />

D/H<br />

ClO2/Cl2<br />

Cl2/NaoCl+NaOH<br />

ClO2/NaOCl+NaOH<br />

Bleaching with a mixture of Cl2 <strong>and</strong> ClO2 C + D Cl2 + ClO2<br />

Chlorination at low concentration (C) Cl2<br />

Gas-phase bleaching Cg<br />

Ozone Z O3<br />

Dg<br />

Cl2<br />

ClO2<br />

Acid A e.g. CH3CO3H


D. Common industrial bleaching sequences<br />

SULPHITE AND BISULPHITE<br />

3stages<br />

C-E-H C-E-H-H<br />

PULPS<br />

4- stages 5- stages 3- stages<br />

(semibleached)<br />

C-E-H-D<br />

C-E-D-H<br />

C-C-E-H<br />

C-H-E-H<br />

H-C-E-H<br />

C-E-D-D/H<br />

C+D-E-H-D<br />

E-C-H-D<br />

C-E-H-D-H<br />

C-C-E-H-H<br />

Source : Rydholms (1965)<br />

C-E-H<br />

D/C-O-D<br />

4- stages<br />

(partly<br />

semibleached)<br />

C-E-H-D<br />

C-E-H-P<br />

E. Non-established bleaching sequences<br />

C-E-H-H<br />

C-H-E-H<br />

C-D-E-D<br />

O-C-E-H<br />

O-C-E-D<br />

O-D-E-D<br />

O-D-O-D<br />

Reduced chlorine application (C)-P-H<br />

(C)-P-D-H<br />

(C)-P-H-D-H<br />

Peroxide replacing chlorine P-D-P<br />

P-D-H<br />

P-H-H<br />

P-H-D<br />

D-P-D<br />

P-H-D-H<br />

P-D-P-D<br />

Oxygen bleaching O-P<br />

O-D<br />

O-H<br />

O-P-D<br />

O-D-P<br />

O-C-P<br />

O-H-P<br />

O-C-P-D<br />

O-D-P-D<br />

O-Cg-E-Dg<br />

O- Dg-E- Dg<br />

Ozone bleaching Z-E-P<br />

Z-E-Z<br />

Z-E-Z-P<br />

Peracetic acid P-A-P<br />

A-E-A-E-A<br />

Source : Fengel <strong>and</strong> Wegener (1984)<br />

109<br />

KRAFT PULPS<br />

5- stages 6- stages 7- stages<br />

C-E-H-P-D<br />

C-E-H-D-P<br />

C-E-H-E-H<br />

C-E-D-E-D<br />

C-E-D-P-D<br />

C-E-H-E-D<br />

C-H-D-E-D<br />

D-E-D-E-D<br />

C-C/H-E-H-H<br />

C-H-E-D-E-D<br />

C-E-H-D-E-D<br />

C-E-H-E-H-D<br />

C-E-H-D-P-D<br />

C-E-H-E-D-P<br />

C+D-E-H-D-E-D<br />

C-E-H-D-E-D<br />

O-C-E-D-E-D<br />

O-C+D-E-D-E-D<br />

O-D-E-D-E-D<br />

O-C-D-E-H-D<br />

C-H-H-D-E-D-<br />

P


APPENDIX - 7<br />

Mean values of strength properties of unbeaten <strong>and</strong> beaten pulp of some Indian bamboo<br />

species<br />

Sl.<br />

No.<br />

Species<br />

Breaking length (m) Burst factor Tear factor<br />

Unbeaten Beaten Unbeaten Beaten Unbeaten Beaten<br />

1 Bambusa bambos 2240 6750 8.0 41.3 54.5 122.9<br />

2 Bambusa nutans 1430 7560 4.9 42.8 39.2 166.9<br />

3 Bambusa polymorpha 1990 6320 8.0 51.3 76.4 218.7<br />

4 Bambusa tulda 1060 7460 5.2 50.0 49.0 181.2<br />

5 Bambusa vulgaris 2070 7260 9.1 50.9 88.2 134.9<br />

6 Cephalostachyum<br />

pergracile<br />

7 Dendrocalamus<br />

hamiltonii<br />

8 Dendrocalamus<br />

longispathus<br />

1730 7550 5.1 47.3 36.1 149.8<br />

2620 8320 10.2 53.3 133.9 194.7<br />

1450 7360 4.2 52.0 70.1 164.7<br />

9 Dendrocalamus strictus 1440 6470 4.9 44.7 48.5 190.4<br />

10 Melocanna baccifera 820 5480 2.9 40.0 32.0 210.7<br />

11 Oxytenanthera<br />

nigrociliata<br />

1580 6730 7.0 49.0 31.7 168.0<br />

12 Thyrostachys olivery 1160 5800 2.5 48.4 52.6 164.1<br />

Source : Singh (1989)<br />

110


APPENDIX – 8<br />

Suitability of some Indian bamboo species <strong>for</strong> pulp <strong>and</strong> paper<br />

Sl.<br />

No. Species<br />

Average<br />

fibre length<br />

(mm)<br />

Method of pulping<br />

111<br />

Bleached pulp<br />

yield (%)<br />

Product <strong>for</strong> which the<br />

pulp is suitable<br />

1 Bambusa bambos 2.75 Kraft (sulphate) 39.0 Writing <strong>and</strong> printing paper<br />

Water prehydrolysis<br />

sulphate<br />

28.3 Rayon<br />

2 Bambusa polymorpha 3.19 Kraft 41.3 Writing <strong>and</strong> printing paper<br />

3 Bambusa tulda 2.98 Kraft 41.0 Writing <strong>and</strong> printing paper<br />

Mechanical - Newsprint, cheap paper <strong>and</strong><br />

board<br />

4 Dendrocalamus<br />

hamiltonii<br />

3.36 Kraft 42.5 Writing <strong>and</strong> printing paper<br />

5 Dendrocalamus<br />

longispathus<br />

3.50 Kraft 41.3 Writing <strong>and</strong> printing paper<br />

6 Dendrocalamus strictus 3.06 Kraft 47.2 Writing, printing, wrapping<br />

<strong>and</strong> greaseproof paper<br />

Water prehydrolysis<br />

27.3 Cellulose derivatives <strong>and</strong><br />

sulphate<br />

viscose rayon<br />

Mechanical - Newsprint, cheap paper <strong>and</strong><br />

board, pressed board<br />

NSSC 44.0 Writing, printing <strong>and</strong><br />

7 Melocanna baccifera<br />

(Syn. M. bambusoides)<br />

2.72 Kraft 41.8<br />

wrapping paper<br />

Writing <strong>and</strong> printing paper<br />

Water prehydrolysis<br />

sulphate<br />

32.2 Rayon<br />

8 Ochl<strong>and</strong>ra<br />

travancorica<br />

4.03 Kraft 45.8 Writing <strong>and</strong> printing paper<br />

Water prehydrolysis<br />

sulphate<br />

32.0 Rayon<br />

9 Oxytenanthera<br />

nigrociliata<br />

3.55 Kraft 42.2 Writing <strong>and</strong> printing paper<br />

Source : Nair (1970)


A. Grades of paper<br />

Sl<br />

No.<br />

APPENDIX – 9<br />

Type of paper Made from Description, Properties & Remarks<br />

1 Writing papers<br />

-Ordinary<br />

- High grade<br />

(bond <strong>and</strong> ledger<br />

paper)<br />

- Cheap quality<br />

- Laid papers<br />

- Wove papers<br />

- Water mark paper<br />

Chemical pulps of<br />

wood, bamboo or<br />

grasses.<br />

From rags.<br />

A mixture of<br />

chemical pulps <strong>and</strong><br />

ground wood pulp<br />

For writing purposes, records, letterheads, business <strong>for</strong>ms<br />

etc.<br />

For document paper - High strength, stiffness,<br />

permanence, <strong>and</strong> durability <strong>for</strong> repeated h<strong>and</strong>ling,<br />

resistance to the penetration <strong>and</strong> spreading of ink,<br />

brightness, <strong>and</strong> cleanliness are the desired properties. .<br />

Good appearance, opacity, surface finish, good ink<br />

receptivity, capability to withst<strong>and</strong> action of eraser are<br />

also desired. The principal uses of bond paper are <strong>for</strong><br />

letterhead stationary, advertising pieces, announcements,<br />

leases, deeds, writs, judgements <strong>and</strong> other legal<br />

documents, certificates <strong>and</strong> insurance policies.<br />

Paper with ribbed like appearance; produced by the use<br />

of a d<strong>and</strong>y roll on which the wires are laid side by side.<br />

Do not have the wire marks; the d<strong>and</strong>y is covered with a<br />

wire cloth during preparation.<br />

A design is soldered on the d<strong>and</strong>y roll. The raised portion<br />

of the design lightly touch the wet web of paper on the<br />

<strong>for</strong>drinier wire at a suitable place between the suction<br />

boxes, making the paper slightly thinner at the places of<br />

contact <strong>and</strong> thus producing the water mark.<br />

112


2 Printing papers<br />

- Newsprint<br />

- Ordinary paper<br />

- Low quality paper<br />

- Coated book<br />

papers<br />

(machine-coated<br />

papers)<br />

- Uncoated book<br />

papers<br />

- Bible paper<br />

Ground wood with<br />

small amount of<br />

chemical wood pulp<br />

Chemical pulps from<br />

wood, grasses,<br />

bamboo etc.<br />

Groundwood pulp<br />

mixed with chemical<br />

puls<br />

Soda pulp<br />

Cotton or linen rags<br />

Printing papers are soft- sized since oil-based inks are<br />

used <strong>for</strong> printing. Requires good opacity so that the<br />

printed matter on one side of the paper is not discernible<br />

from the other side. Requires good finish <strong>and</strong> more<br />

absorbent towards printing ink. This is achieved by using<br />

the filler, china clay<br />

For newspapers; low cost magazines, paper bound books,<br />

catalogs, directories <strong>and</strong> <strong>for</strong> general commercial printing.<br />

Desires an even, uni<strong>for</strong>m <strong>for</strong>mation <strong>and</strong> high opacity. Do<br />

not have high whiteness <strong>and</strong> tend to turn yellow when<br />

expose to light <strong>and</strong> after long aging. These papers are<br />

bulky <strong>and</strong> are receptive to printing ink. Cheapness <strong>and</strong><br />

necessary strength are of prime concerns. Halftone<br />

illustrations should be recognizable. The paper is<br />

machine finished <strong>and</strong> has little or no mineral loading.<br />

Durability is not a concern.<br />

Suitable <strong>for</strong> graphic arts; <strong>for</strong> use as book papers, <strong>for</strong> best<br />

reproduction of fine halftone illustrations. With<br />

uni<strong>for</strong>mly smooth surface, with good ink receptivity,<br />

have high brightness <strong>and</strong> gloss, <strong>and</strong> be capable of folding<br />

without cracking.<br />

Uncoated book paper is available in four finishes:<br />

Antique or egg shell – made from slightly beaten stock,<br />

the sheet is only lightly calendared to provide a degree of<br />

surface smoothness while preserving the antique or egg<br />

shell appearance.<br />

Machine finish – has a medium –smooth surface <strong>for</strong> this<br />

finish from a calendar stock at the dry end of the<br />

machine. Use <strong>for</strong> books, catalogs, circulars, <strong>and</strong> other<br />

matter using line etchings <strong>and</strong> <strong>for</strong> halftone illustrations<br />

upto 100-line screen. Machine finish book is a relatively<br />

inexpensive general utility paper.<br />

English finish – a step higher in the book paper scale; by<br />

a higher degree of beaten stock.<br />

Supercalendared – is the smoothest surface that can be<br />

obtained without coating. It is used <strong>for</strong> books, brochures<br />

<strong>and</strong> magazines where halftone printing in the range of<br />

100-120 line screen is required.<br />

Light weight, thin, strong, opaque sheets <strong>for</strong> such books<br />

as bibles, dictionaries, <strong>and</strong> encyclopaedias, which require<br />

minimum bulk. Bible papers are pigmented (loaded) with<br />

such pigments as titanium dioxide <strong>and</strong> barium sulphate<br />

<strong>and</strong> contain long fibres <strong>and</strong> artificial bonding agents.<br />

113


3 Wrapping or bag<br />

papers<br />

- Kraft paper<br />

(multi wall bags)<br />

- Notion bags<br />

- Other bags<br />

- Fancy bags<br />

4 Sanitary papers<br />

(Absorbent<br />

papers)<br />

- Water leaf<br />

5 Wall paper<br />

(Hanging paper)<br />

- Grade 1<br />

- Grade 2<br />

Unbleached light<br />

brown kraft pulp<br />

Kraft pulp from<br />

coniferous species<br />

Mixture of several<br />

pulps<br />

Sulphite pulp<br />

Various proportions<br />

of sulphite <strong>and</strong><br />

bleached kraft pulp.<br />

Bleached chemical<br />

wood pulps <strong>and</strong><br />

small amount of<br />

groundwood pulp.<br />

Major portion is<br />

groundwood pulp<br />

with small quantity<br />

of sulphite pulp.<br />

Requires strength, toughness <strong>and</strong> playability. The colour,<br />

<strong>for</strong>mation <strong>and</strong> surface are of secondary importance only.<br />

Machine glazed <strong>for</strong> paper bag<br />

Requires outst<strong>and</strong>ing tensile <strong>and</strong> tearing strength. Kraft<br />

wrapping is sized to retard wetting when exposed to<br />

water. Wet strength was imparted with special resins. For<br />

multi wall bags (<strong>for</strong> storing or transport of cement,<br />

shipment of bulk materials etc.) require higher strength<br />

properties. In some multi wall bags an inner lining of<br />

specially treated paper was used to provide. Grocer’s<br />

bags are usually made of kraft paper.<br />

For packaging light materials<br />

Requires water resistant papers with high wet strength.<br />

For food packaging<br />

Little refining of the stock to preserve a soft, bulky,<br />

absorbent sheet; further softened by machine creping.<br />

Sanitary papers include :<br />

Towelling, facial tissue, napkins, etc.<br />

Because of the soft bulky texture of sanitary papers, they<br />

are relatively weak. To improve wet strength, they are<br />

treated with resins. The plastic nature of paper fibres<br />

when slightly moist permits the reproduction of surface<br />

patterns by embossing to a remarkable degree in paper<br />

napkins.<br />

Absorbent papers, which are not sized. eg. blotting<br />

papers, cigarette papers, artificial leather paper, <strong>and</strong><br />

vulcanised fibre etc.<br />

The essential properties are softness, playability,<br />

resistance to water, maximum bulk <strong>and</strong> minimum weight.<br />

114


6 Speciality papers :<br />

- Currency paper<br />

- Cheque paper<br />

- Cigarette paper<br />

- Blotting paper<br />

- Manifold paper<br />

- Grease proof<br />

paper<br />

- Glassine paper<br />

- Cartridge paper<br />

(Drawing paper)<br />

- Insulating paper<br />

Pulp from new rags<br />

Pure flax, or linen<br />

fibre, hemp fibre <strong>and</strong><br />

ramie pulps<br />

Rags, linters,<br />

chemical or<br />

mechanical wood<br />

pulps or mixture of<br />

these depending<br />

upon the quality<br />

required.<br />

Chemical wood<br />

pulps which are<br />

highly hydrated in<br />

the process of<br />

beating<br />

Chemical wood pulp<br />

which are highly<br />

beaten (hydrated).<br />

Kraft pulp or a<br />

mixture of karft <strong>and</strong><br />

jute pulp. <strong>Bamboo</strong><br />

kraft pulp is used <strong>for</strong><br />

this purpose in<br />

Indian paper mills.<br />

Tub sized with animal glue. Require high tensile strength,<br />

high folding endurance, <strong>and</strong> resistance to bear. It has also<br />

special features to protect against counterfeiting. Use <strong>for</strong><br />

printing paper currency, Government securities etc.<br />

Not fully sized paper <strong>and</strong> have surface which readily<br />

comes away when strapped with a knife or wetted with an<br />

ink-remover. Some of this contains chemicals which<br />

change in colour when ink-remover is applied, leaving a<br />

characteristic stain. Used <strong>for</strong> cheque <strong>for</strong>ms <strong>and</strong> similar<br />

documents on which the writing is liable to be tampered.<br />

The paper must be thin but opaque <strong>and</strong> must have no<br />

characteristic smell or taste on burning. Opacity is<br />

secured by addition of filler such as calcium carbonate<br />

which gives a good white appearance <strong>and</strong> helps to<br />

promote uni<strong>for</strong>m burning of the paper.<br />

This is an unsized paper used to absorb excess ink from<br />

freshly written letters, manuscripts etc. The paper is<br />

aurous, bulky <strong>and</strong> of little strength.<br />

This a typical bond paper in light basis weights. Finish<br />

<strong>and</strong> porosity are important properties in this type of<br />

paper. Used <strong>for</strong> copies by interleaving with carbon paper.<br />

Impervious to oil or grease. Use <strong>for</strong> wrapping greasy food<br />

products. High hydration imparts greaseproofness to the<br />

paper, which has comparatively few interconnecting<br />

pores between the fibres.<br />

This is a dense glazed greaseproof paper. The<br />

greaseproof paper is put through a special super-calendar<br />

with a number of steam-heated rolls, so as to make it<br />

more smooth <strong>and</strong> transparent. When waxed, this paper<br />

becomes almost impervious to air <strong>and</strong> vapours used as<br />

wrapper <strong>for</strong> food products, tobacco, chemicals <strong>and</strong> also in<br />

the manufacture of bags, envelops, book covers etc<br />

Used <strong>for</strong> making cases <strong>for</strong> cartridges require to be very<br />

strong<br />

Special properties may be given to these papers by<br />

mixing various additives into the pulps. These are divided<br />

into three classes :<br />

Insulating materials – such as floor lining felts, roofing<br />

felts, creep wadding, sheathing, <strong>and</strong> wallboards.<br />

Electrical insulating materials – include cable paper,<br />

condenser tissue vulcanised fibre, vegetable parchment,<br />

<strong>and</strong> paper impregnated with shellac, paraffin or bakelite<br />

Sound insulating materials – such as acoustical board.<br />

<strong>and</strong> paper impregnated with shellac, paraffin or bakelite<br />

Sound insulating materials – such as acoustical board.<br />

115


7 Bristol<br />

8 Paperboards<br />

- Boxboards<br />

- Container boards<br />

- Paperboard<br />

specialities<br />

- Duplex board<br />

- Triplex board<br />

Various<br />

combinations of<br />

chemical wood pulp<br />

Wood, straw, waste<br />

paper pulps or a<br />

combination of these<br />

materials<br />

Sulphite <strong>and</strong><br />

sulphate pulps<br />

The top <strong>and</strong> bottom<br />

layers are made of<br />

rag, wood, or<br />

bamboo pulp or a<br />

mixture of any of<br />

these pulps, while<br />

the middle layer is<br />

of the groundwood<br />

or waste paper pulp.<br />

Bristol refers to a group of stiff, heavy papers with<br />

thicknesses ranging from 0.15mm upward. The stock is<br />

beaten to a medium degree <strong>and</strong> usually well sized to<br />

prevent penetration of moisture. Used <strong>for</strong> punch cards in<br />

tabulating <strong>and</strong> sorting machines.<br />

Paperboard refers products of 0.30mm or more in<br />

thickness made from pulp.<br />

Used <strong>for</strong> such products as food board, food trays, plates,<br />

<strong>and</strong> paper boxes / cartons <strong>for</strong> packaging. A wide range of<br />

properties, including particular strength, bending <strong>and</strong><br />

scoring characteristics <strong>and</strong> a suitable surface <strong>for</strong> printing,<br />

can be built into this grade of paper. Resistance to air,<br />

water, fire, <strong>and</strong> oil can be obtained by appropriate<br />

treatments in the manufacturing process.<br />

For the manufacture of corrugated <strong>and</strong> solid fibre<br />

shipping containers<br />

Include such items as binder’s board, electrical<br />

pressboard, <strong>and</strong> building boards<br />

This is a paperboard made in two layers, the two sides<br />

being of two different colours or the layers may be from<br />

two different grades of stocks. This is made on a paper<br />

machine. The paper is used <strong>for</strong> cover papers, boxboard<br />

etc. Good tear resistance <strong>and</strong> playability are required. The<br />

papers are hard sized <strong>and</strong> are of high machine finish.<br />

Sometimes a high super-calendar finish was used to give<br />

This a paperboard made in three different layers pressed<br />

together. Made on a cylinder mould machine in the same<br />

way as duplex board. This is machine glazed <strong>and</strong> is used<br />

as cover paper<br />

116


B. Types of commercial papers/ paper boards produced in India from bamboos<br />

<strong>Bamboo</strong> pulp is reported to be currently used <strong>for</strong> the production of the following types of paper/<br />

paperboards in India.<br />

1. Printing paper<br />

(a). White printing paper / Coloured printing paper : Hard sized paper of all kinds are<br />

suitable <strong>for</strong> writing. But an even paper of good surface is essential, generally machine<br />

finished.<br />

(b). Imitation art paper : This is a highly finished printing paper manufactured by the<br />

addition of heavy percentage of China clay to the pulp <strong>and</strong> water finished or super-calenderer<br />

to give it a surface, opacity <strong>and</strong> absorbency, may be white or coloured.<br />

(c). Offset printing paper : This type of paper is suitable <strong>for</strong> the offset printing process. It is<br />

normally made from bamboo or grass stock <strong>and</strong> may contain some amount of rag <strong>and</strong> wood<br />

pulp. It may be white or coloured.<br />

(d). M.G. poster paper : A variety of paper which has been machine-glazed (M.G), suitable<br />

<strong>for</strong> printing posters, labels, etc.; may be white/ coloured.<br />

2. Writing papers<br />

(a). Azure laid / Ledger paper : An account book paper usually pale blue in colour <strong>and</strong> with<br />

laid lines.<br />

(b). Airmail / Manifold paper : Lightweight well sized writing paper of a substance not<br />

greater than 35g/m 2 used <strong>for</strong> copying with carbon paper. Airmail papers are similar to<br />

manifold papers but are lighter in weight.<br />

(c). Bond paper : A strong, durable, high class, writing paper with good surface<br />

characteristics <strong>and</strong> erasing quality of substance above 50 g/m 2 .<br />

3. Packing <strong>and</strong> wrapping paper<br />

(a). Match paper : Coloured wrapping paper normally machine glazed (M.G) <strong>and</strong> used <strong>for</strong><br />

the manufacture <strong>and</strong> packing of matchboxes. Normally made from bamboo pulp with a fairly<br />

large proportion of waste paper (usually blue or green).<br />

(b). Common wrapping paper : Cheaper grades or wrapping papers made from bamboo,<br />

grass, rags <strong>and</strong> waste as well as recovered fibre. May be machine glazed or machine finished.<br />

4. Paper boards<br />

(a). Duplex/Triplex board : Two plyboard manufactured wholly from bamboo <strong>and</strong> bagasse<br />

or with one ply made an admixture of bamboo <strong>and</strong> bagasse while the other ply is made from<br />

waste paper/ mechanical pulp; may be white or coloured or may have two different colours in<br />

117


either ply. Board with three or more piles, has inferior furnish in the middle layer; may be<br />

white or coloured or may have different colours in either ply.<br />

(b). Ticket board : Thick paste boards made from ticket middles or white mechanical<br />

bamboo pulp middles <strong>and</strong> white or coloured facing papers of mechanical pulp or sometimes<br />

coated with white or tinted coated liners are employed <strong>and</strong> used <strong>for</strong> show cards <strong>and</strong> window<br />

tickets, price tags, season tickets, etc.<br />

(c). Pulp board / Boxboard : White <strong>and</strong> tinted, made from bamboo pulp on an ordinary<br />

Fourdrinier machine, well sized <strong>and</strong> finished in matt, super-calendared or water finishes in<br />

two sheets. Used <strong>for</strong> all kinds of general printing work such as tickets, cards, menu cards,<br />

price tags, etc.<br />

(d). Post card /Board : Pulp boards are manufactured in one or two plys (simplex board).<br />

The term is used to distinguish it from paste board which consists of two or more layers<br />

pasted together. It is usually made from bamboo or grass pulp <strong>and</strong> may be coloured or white.<br />

It includes postcard boards <strong>and</strong> Bristol boards.<br />

(e). Tag boards : Tag boards are mad from strong stuff furnishes of bamboo pulp. The<br />

boards must be even, hard sized <strong>and</strong> well rolled to give a good writing surface <strong>and</strong> lie<br />

perfectly flat <strong>for</strong> accurate ruling, printing <strong>and</strong> cutting. Made in buff, white <strong>and</strong> tints <strong>for</strong> card<br />

index systems in single thickness, as pasted boards bend <strong>and</strong> split at the corners with frequent<br />

h<strong>and</strong>ling.<br />

5. Newsprint<br />

<strong>Bamboo</strong> chemical pulp mixed with mechanical hardwood pulps are used <strong>for</strong> newsprint.<br />

Source : Podder (1979)<br />

118


119


PART - III<br />

ANNOTATED BIBLIOGRAPHY


Paper Mills <strong>and</strong> History of Pulp <strong>and</strong> Paper<br />

1. Bhat, R.V. 1951. Paper <strong>and</strong> board industry in India. The Madras Forest College<br />

Magazine.<br />

2. Cai Mingde; Wang Guorong; Wang Songxue. 1992. The recent situation of bamboo<br />

utilization in the overseas industry of paper. Journal of <strong>Bamboo</strong> Research 11(2): 66-92.<br />

3. Chief Conservator of Forests, Madhya Pradesh. 1971. Royalty on bamboos to be charged<br />

to the Paper Mills - a report.<br />

It is a report on the royalty charged on bamboos in the states of Maharashtra, Andhra Pradesh,<br />

Mysore, Madras, Kerala, Uttar Pradesh, Bihar, Punjab, West Bengal <strong>and</strong> Orissa to gather in<strong>for</strong>mation<br />

regarding the royalty charged on bamboos.<br />

4. Fellegi, J; Rao, A.R.K. 1980. A new applied research centre <strong>for</strong> the Indian pulp <strong>and</strong><br />

paper industry. Zonal Seminar on High Yielding Pulping <strong>and</strong> Bleaching of Pulps, 20-21<br />

September 1980, Dehra Dun.<br />

5. Goel, S; Goyel, R; Hirknnawar, S; Nerurkar, D.L; Ghosh, P.K; Saksena, U.L; Rajan, T.N.S;<br />

Kocholia, R.S. 1989. Modernization <strong>and</strong> renovation of the paper industry. Paper<br />

presented in the IPPTA Silver Jubilee <strong>International</strong> Seminar <strong>and</strong> Workshop on Appropriate<br />

Technology <strong>for</strong> Pulp <strong>and</strong> Paper Manufacturing in Developing Countries, 1989, IPPTA, New<br />

Delhi: 18p.<br />

6. Guha, S.R.D; Pant, R. 1972. Fibrous raw materials <strong>for</strong> the Indian paper <strong>and</strong> board<br />

industry. Indian Forester 98(7): 409-426.<br />

Presents the results of tests made at Dehra Dun since 1964 on various indigenous materials<br />

(bamboo, grasses <strong>and</strong> reeds, woods <strong>and</strong> agricultural residues).<br />

7. Gupta, T; Shah, N. 1987. Paper <strong>and</strong> Paperboard in India. Ox<strong>for</strong>d <strong>and</strong> IBH Publishing,<br />

Bombay.<br />

7a. Libby, C.E. 1962. History of pulp <strong>and</strong> paper. In: Libby, C.E. (ed.), Pulp <strong>and</strong> Paper<br />

Science <strong>and</strong> Technology, Volume 1. Pulp. Mc Grow-Hill Book Company, New York: 1-19.<br />

8. Monsalud, M.R; Tamolang, F.N. 1962. Pulp <strong>and</strong> paper research in the Philippines Forest<br />

Products Research Institute. TAPPI Journal 45(2): 38A-62A.<br />

Describes in detail the exploratory work being done at the Institute on pulp <strong>and</strong> paper<br />

manufacture, <strong>and</strong> presents preliminary data on fibre measurements, proximate chemical analyses, <strong>and</strong><br />

the evaluation of many native commercial <strong>and</strong> noncommercial fibrous raw materials, including ca. 250<br />

hardwood <strong>and</strong> 10 softwood species, palms, bamboos, <strong>and</strong> agricultural wastes.<br />

9. Nair, P.N. 1970. Wood raw materials in relation to pulp <strong>and</strong> paper industry in Kerala.<br />

Kerala Forest Department, Government of Kerala. Publication No. 3: 14-18.<br />

10. Naiyana Niyomwan; Anchalee Kamolratanakul; Likit Harnjangsit. 1983. Techno-economic<br />

survey on dem<strong>and</strong> <strong>for</strong> research on pulp <strong>and</strong> paper industries. Bangkok: 55 leaves.<br />

Results of the survey indicated that there were several problems deterring the progress of pulp<br />

<strong>and</strong> paper industries in Thail<strong>and</strong>. The degree of problems varied according to the size of industries.<br />

Most industries needed research service, particularly in technical know-how <strong>and</strong> processing methods.<br />

Detailed recommendations <strong>and</strong> research findings useful in solving the problems encountered in pulp<br />

<strong>and</strong> paper industries are included in this report.<br />

11. Notes on the utilisation <strong>and</strong> silviculture of the timbers used in wood based industries<br />

of India III. Paper Industry. Proceedings of the Eighth Silvicultural Conference, 5-14<br />

1


December 1951, Dehra Dun. 1956. Vol.2. Forest Research Institute, Dehra Dun:<br />

118, 131-136.<br />

A review of the Indian paper industry is given. There were 16 paper mills in 1950. Anticipated<br />

consumption of paper in 1956 was 4,00,000 tones. Because of the high quality of pulp, bamboo yield<br />

<strong>and</strong> their availability in large quantities at reasonable prices, bamboo was used as raw material<br />

extensively in paper industry. It was reported that in 1950, above 2,25,000 tones of bamboo was used<br />

in this industry.<br />

12. Ono, K. 1962. Studies on bamboo pulp industry. Resources Bureau, Science <strong>and</strong><br />

Techniques Agency, Prime Minister's Office: 54p.<br />

The report focuses on the physical <strong>and</strong> chemical features of bamboo as raw material <strong>for</strong> pulp <strong>and</strong><br />

views on pulp making methods. The report gives survey results of bamboo <strong>for</strong>ests in Indonesia <strong>and</strong><br />

Burma (Myanmar) <strong>and</strong> discusses the new scientific techniques <strong>for</strong> bamboo pulping industry.<br />

13. P<strong>and</strong>it, S.V; Puntambekar, P.P; Gupte, V.M. 1978. Role of bamboo chipper in pulp mill<br />

economy. USA, Technical Association of the Pulp <strong>and</strong> Paper Industry, Nonwood Plant Fiber<br />

Committee. Nonwood plant fiber pulping. Progress report No. 9. TAPPI Journal: 105-112.<br />

The per<strong>for</strong>mance of the PN bamboo disc chipper (investment, maintenance costs <strong>and</strong> chip quality)<br />

was superior to that of others used in the Indian pulp <strong>and</strong> paper industry. <strong>Bamboo</strong> chipping operations<br />

are described at Central Pulp Mills Ltd. in India.<br />

14. Podder, V. 1959. Paper Industry in India. Rohtas Industrial Ltd., Dalmianagar, India.<br />

15. Podder, V. 1979. Paper Industry in India: A study. In: Grasses <strong>and</strong> Reeds. Ox<strong>for</strong>d & IBH<br />

Publishing, New Delhi: 50-59.<br />

16. Pulp <strong>and</strong> Paper Canada. 2000. SNC-Lavalin completes proposed bamboo pulp mill<br />

study. Pulp <strong>and</strong> Paper Canada 101(5): p9.<br />

A case study is presented of a mill in Fengshun County of the Guangdong Province of China, in<br />

which, using plantation bamboo as a furnish, pulp with quality high enough <strong>for</strong> fine papers could be<br />

produced.<br />

17. Rao, P.J.M. 1989. Working of thous<strong>and</strong>s of mini paper factories in China. Paper<br />

presented in the IPPTA Silver Jubilee <strong>International</strong> Seminar <strong>and</strong> Workshop on Appropriate<br />

Technologies <strong>for</strong> Pulp <strong>and</strong> Paper Manufacture in Developing Countries, 1989, New Delhi:<br />

p2.<br />

18. Seth, V.K. 1972. Planning <strong>for</strong> pulp <strong>and</strong> paper industries in India. Indian Forester 98(4):<br />

213-219.<br />

In the year 1952 there were 17 paper mills in India <strong>and</strong> their installed capacity was 1,37,000<br />

tonnes. In 1972 there were 57 mills with a total installed capacity of 7,30,000 tonnes. The author<br />

advocates <strong>for</strong> a more closer tie up of <strong>for</strong>estry <strong>and</strong> industry <strong>for</strong> the progress of paper industries in India.<br />

Sixty seven percent of raw material <strong>for</strong> pulp <strong>and</strong> paper is bamboo. Rapid growth of paper industry<br />

started depleting bamboo wealth. Advancement of technology made it easy to pulp hardwood also<br />

which reduces pressure on bamboo.<br />

19. Seth, V.K. 1974. The potential of Madhya Pradesh <strong>for</strong> pulp, paper <strong>and</strong> newsprint mills.<br />

Indian Forester 100(1): 20-27.<br />

The study cover on the present production potential of bamboo, with dem<strong>and</strong> projections to 1988-<br />

89. On this basis, proposals are made <strong>for</strong> the numbers, capacity <strong>and</strong> location of paper, paperboard <strong>and</strong><br />

newsprint mills that could be installed in the State, in order to utilize the bamboo resource.<br />

19a. Sieber, R. 1951. Die Chemish – Technischen Untersuchungsmethoden der Zellstoffund<br />

Papierindustrie, 2 nd Edn., Springer, Berlin.<br />

2


20. Sumg, Y.H. 1967. Pulp <strong>and</strong> paper technology in 17th century China. Pulp <strong>and</strong> Paper<br />

Magazine of Canada 68(1): 107-110.<br />

Extract from a translation of the book `Chinese technology in the 17th century' (Pennsylvania<br />

State University Press, University Park). The manufacture of bamboo paper, <strong>and</strong> bark paper from<br />

Broussonetia papyrifera, Hibiscus mutabilis <strong>and</strong> Silk-Mulberry [Morus alba?] is described.<br />

21. Tang, Y.Y. 1999. Current situation <strong>and</strong> future development of bamboo timber<br />

processing industry in China. The Proceedings (I) of the <strong>International</strong> Seminar on<br />

Technologies of the Cultivation, Processing <strong>and</strong> Utilization of <strong>Bamboo</strong> in the '99 <strong>Bamboo</strong><br />

Cultural Festival of China. Journal of <strong>Bamboo</strong> Research 18(4): 5-10.<br />

The industrial exploitation <strong>and</strong> utilization of bamboo timber in China has increased markedly since<br />

the re<strong>for</strong>ming <strong>and</strong> opening up of the country to the outside world. This article discusses the main<br />

products of the bamboo industry (artificial boards, domestic articles, artworks <strong>and</strong> h<strong>and</strong>icrafts, <strong>and</strong><br />

pulping <strong>and</strong> paper-making products), their present production situation <strong>and</strong> development prospects.<br />

General Pulping <strong>and</strong> Paper Making<br />

22. Aggarwal, R.K. 1971. Pulping of hardwoods in Kamyr continuous digester. Paper<br />

presented in the Conference on Utilization of Hardwoods <strong>for</strong> Pulp <strong>and</strong> Paper, 19-20 April<br />

1971, FRI <strong>and</strong> Colleges, Dehra Dun, India: 139-153.<br />

23. American Paper <strong>and</strong> Pulp Association. 1951. The dictionary of paper. 2nd Edn. New York.<br />

24. Atchison, J.E. 1996. Twentyfive years of global progress in nonwood plant fiber<br />

repulping. TAPPI Journal 79(10): 87-95.<br />

25. Belvin, W.L. 1957. Opportunities <strong>for</strong> increased use of hardwoods through improved<br />

pulping technique <strong>and</strong> processes. Forest Products Journal 7(11): 424-426.<br />

Discusses the need <strong>for</strong>, <strong>and</strong> economic advantages of, hardwood pulping, particularly in the<br />

Southern U.S.A., briefly surveying the chief processes-semichemical, chemi-groundwood <strong>and</strong> cold<br />

soda <strong>and</strong> the suitability of the pulps <strong>for</strong> various types of paper, on the basis of U.S. literature. Recent<br />

research into bamboo growing <strong>and</strong> pulping in the south is briefly mentioned. It is thought to be a<br />

promising material.<br />

26. Bhargava, M.P; Chattar Singh. 1942. Manufacture of newsprint, cheap papers <strong>and</strong><br />

boards. Indian Forest Bulletin 108.<br />

Tests have been carried out with materials from three species of conifers, seven species of<br />

broadleaved trees <strong>and</strong> three species of bamboos to determine their use in the manufacture of<br />

newsprint, cheap papers <strong>and</strong> boards. Of the conifers, Abies pindrow <strong>and</strong> Picea morinda are suitable <strong>for</strong><br />

newsprint production, <strong>and</strong> supplies of these species are said to be sufficient in Kashmir <strong>and</strong> Tehri-<br />

Garhwal States to support a moderate-sized newsprint mill. Pinus longifolia saplings are suitable <strong>for</strong><br />

newsprint production, but supplies are uncertain. Of the broadleaved species, Broussonetia papyrifera,<br />

Kydia calycina <strong>and</strong> Excaecaria agallocha show promise <strong>for</strong> newsprint production but are not at present<br />

available in sufficient quantity to support a newsprint mill. Materials from the other four broadleaved<br />

species, mature Pinus longifolia, <strong>and</strong> the bamboo species yielded brown-coloured pulps unsuitable <strong>for</strong><br />

newsprint production, which could, however, be utilized in small proportions in the manufacture of<br />

cheap wrapping papers, duplex boards <strong>and</strong> triplex boards.<br />

27. Bhat, R.V; Guha, S.R.D; Viramani, K.C. 1960. Newsprint grade ground wood pulp from<br />

Abies pindrow Royle. (Silver Fir). Indian Forester 86(5): 302-305.<br />

Laboratory experiments on the production of mechanical pulps from Abies pindrow (Silver fir) are<br />

described. St<strong>and</strong>ard pulp sheets were made from 100 per cent mechanical pulp from this species <strong>and</strong><br />

from a mixture of 70 per cent mechanical pulp <strong>and</strong> 30 per cent bleached bamboo chemical pulp.<br />

3


Strength properties of the st<strong>and</strong>ard sheets prepared from the mechanical pulp produced under suitable<br />

conditions have shown that this wood is a suitable raw material <strong>for</strong> the production of newsprint.<br />

28. Biswas, B. 1971. Some observations on utilization of tropical harwoods <strong>for</strong> pulp <strong>and</strong><br />

paper. Conference on Utilization of Hardwood <strong>for</strong> Pulp <strong>and</strong> Paper, 19-20 April 1971, Dehra<br />

Dun.<br />

29. Bunchu Pakotiprapha. 1976. A study of bamboo pulp <strong>and</strong> fiber cement paste<br />

composites. Asian Institute of Technology, Bangkok: 83p.<br />

This study was examined the feasibility of using bamboo pulp as a suitable substitute <strong>for</strong> asbestos<br />

fiber by using the available technology <strong>and</strong> facilities <strong>for</strong> the mass production of fiber cement boards.<br />

Explicit expressions are given <strong>for</strong> the mechanical properties of the material in compression, tension,<br />

bending <strong>and</strong> torsion, respectively. The minimum volume fraction of each type of fiber as well as an<br />

optimum mix proportion between bamboo pulp <strong>and</strong> fibers are suggested <strong>for</strong> the various composites<br />

being studied to attain specified mechanical properties.<br />

30. Carrasco, N; Salvador. 1961. Mexican raw materials other than wood <strong>for</strong> the preparation<br />

of chemical pulps. ATCP 1(1): 5-14.<br />

31. Ch<strong>and</strong>ra, R. 1975. Production <strong>and</strong> cost of logging <strong>and</strong> transport of bamboo. (FAO<br />

Report: FAO/SWE/TF 157) FAO, Rome: 72p.<br />

A report based on in<strong>for</strong>mation from India, Bangladesh, Burma <strong>and</strong> Thail<strong>and</strong>. The aspects<br />

considered are; structure of bamboo <strong>for</strong>ests, statistical in<strong>for</strong>mation, labour <strong>for</strong>ce, transport systems,<br />

felling <strong>and</strong> conversion, off-road transport, long distance transportation, cost summary <strong>and</strong><br />

mechanization <strong>and</strong> rationalization of harvesting. Difficulties of harvesting peculiar to bamboo are<br />

pointed out <strong>and</strong> fields <strong>for</strong> further research are suggested. A list of principal bamboo species used <strong>for</strong><br />

pulp <strong>and</strong> paper, data on transport systems <strong>and</strong> cost of mechanized felling <strong>and</strong> extraction, etc. are<br />

included as appendices.<br />

32. Cunningham, R.L; Clark, T.F. 1970. A search <strong>for</strong> new fibre crops. XIII. Laboratory scale<br />

pulping studies continued. TAPPI Journal 53(9): 1967-1700.<br />

Mainly an assessment of the pulping potential of a further selection of non-woody plants, but<br />

includes data on the bamboos Guadua amplexifolia from Mexico, Arundinaria alpina from Ethiopia <strong>and</strong><br />

Bambusa vulgaris from Brazil. All three species offer good yields of readily bleachable pulp with<br />

satisfactory strength characteristics (especially resistance to tear), but only G. amplexifolia <strong>and</strong> A.<br />

alpina are likely to withst<strong>and</strong> cold well enough to warrant planting trials in the U.S.A.<br />

33. Ekwebelam, S.A. 1990. Rationale <strong>for</strong> the choice of pines <strong>for</strong> the production of long<br />

fibres <strong>for</strong> paper manufacture in Nigeria. Savanna 11(1): 88-94.<br />

In order to conserve <strong>for</strong>eign exchange <strong>and</strong> reduce dependence on imported paper, the Nigerian<br />

Government has established 3 integrated pulp <strong>and</strong> paper mills. The raw materials used in the mills<br />

have consisted of short fibred pulp from hardwoods, principally Gmelina arborea, <strong>and</strong> long fibres from<br />

exotic conifers, principally Pinus species, in a definite proportion. Available statistics show that besides<br />

conifers, non-wood materials, such as raffia (Raphia spp.) <strong>and</strong> bamboo (Bambusa <strong>and</strong> Dendrocalamus<br />

spp.) can also provide long fibres <strong>for</strong> paper making. Nigeria has very rich reserves of these resources,<br />

but despite their abundance, greater emphasis has been placed on the use of pines <strong>for</strong> the production<br />

of long fibres <strong>for</strong> pulp <strong>and</strong> paper manufacture. This paper reviews the silvicultural, management <strong>and</strong><br />

utilization problems, as well as technological problems relating to the use of raffia <strong>and</strong> bamboo, which<br />

have necessitated this decision; the account includes a discussion of the comparative fibre morphology<br />

of raffia <strong>and</strong> bamboo in relation to pine.<br />

34. FAO. 1984. A report on pulping prospects. Unasylva 36(144): 44-51.<br />

An account of the prospects of pulping in India is presented. The growing stock of bamboo in pure<br />

st<strong>and</strong>s <strong>for</strong> 1980 <strong>and</strong> 1985 are reported. The stock of 12 million in 1980 is reported to decrease to 11.7<br />

million tonnes by 1985. The importance of appropriate management <strong>and</strong> establishment of bamboo<br />

plantations is stressed to increase the utilisation of the stock <strong>for</strong> pulping.<br />

4


35. Fengel, D; Wegner, G. 1984. Pulping Process. In: Wood Chemistry, Ultra Structure<br />

Reactions, Chapter 16. Walter de Gruyter, Berlin.<br />

36. Goswami, T; Saikia, C.N. 1994. Water hyacinth - A potential source of raw material <strong>for</strong><br />

greaseproof paper. Bio-resource Technology 50(3): 235-238.<br />

The potential use of water hyacinth as a pulp material <strong>for</strong> producing greaseproof paper was<br />

investigated using plants collected from freshwater ponds in Jorhat. The proximate chemical analyses<br />

of the raw materials, the morphology, of the water hyacinth stalk <strong>and</strong> fibre, pulp characteristics, <strong>and</strong><br />

data on the physical properties of the paper h<strong>and</strong>sheets <strong>for</strong>med from water hyacinth <strong>and</strong> bamboo pulps<br />

<strong>and</strong> their blends are presented. Blending of water hyacinth <strong>and</strong> bamboo pulps increased the physical<br />

strength. Paper h<strong>and</strong>sheets made with a blend of water hyacinth pulp (75 o SR) <strong>and</strong> bamboo pulp<br />

(80 o SR), at 75:25 proportion, gave a tear index of 4.90 mN m 2 g -1 , tensile index of 51.10 N mg -1 <strong>and</strong><br />

burst index of 7.25 kPa m 2 g -1 . These were higher than values obtained from sheets made with pulp<br />

blends (water hyacinth:bamboo) of 80:20 or 90:10. The pulp sheets at a blend proportion of 75:25 also<br />

gave satisfactory greaseproof properties.<br />

37. Grant, J. 1962. The <strong>for</strong>mation <strong>and</strong> structure of paper. Technical Sessions of the British<br />

Paper Board Maker's Association, London, Volume II.: 573-591.<br />

38. Guha, S.R.D; Sharma, Y.K. 1970. Chemical, semi-chemical <strong>and</strong> mechanical pulps from<br />

Casuarina equisetifolia. Indian Forester 96(11): 830-840.<br />

Gives data on proximate chemical analysis <strong>and</strong> fibre dimensions of C. equsetifolia <strong>and</strong><br />

Dendrocalamus strictus, laboratory observations on chemical pulps of C. equsetifolia <strong>and</strong><br />

Dendrocalamus strictus, <strong>and</strong> pilot plant production of wrapping paper from unbleached pulps of C.<br />

equsetifolia, bamboo <strong>and</strong> a 75:25 mixture of C. equsetifolia <strong>and</strong> bamboo (sample sheets included).<br />

Yield <strong>and</strong> strength properties were higher <strong>for</strong> C. equsetifolia, but it was not suitable <strong>for</strong> mechanical<br />

pulps as the energy consumption <strong>for</strong> grinding was high <strong>and</strong> the pulps were dark.<br />

39. Guha, S.R.D; Sharma, Y.K; Kumar, K. 1973. Pulping of Poplars. Indian Forester 99(5):<br />

296-301.<br />

Data obtained in a study of the fibre dimensions <strong>and</strong> pulping properties of Populus deltoides 'IC',<br />

P. 'I-488' <strong>and</strong> P. 'Heidemij' digested by the sulphate process indicated that the pulping properties were<br />

generally superior to those of P. ciliata <strong>and</strong> Dendrocalamus strictus. From a silvicultural point of view,<br />

P. deltoides 'IC' appears to be the most promising clone <strong>for</strong> large-scale propagation.<br />

40. Guha, S.R.D; Sharma, Y.K; Mathur, C.M. 1970. Pilot plant production of Braille printing<br />

paper from indigenous raw materials. Indian Pulp <strong>and</strong> Paper 24(7): 317-319.<br />

Reports very encouraging results of pilot-plant trials at Dehra Dun on the production of Braille<br />

printing paper from pulp made from bamboo, mixed hardwoods from Maharashtra, or a mixture of<br />

Quercus sp. from Himachal Pradesh, <strong>and</strong> concludes that the products obtainable from these Indian<br />

raw materials can be used in place of imported Braille papers.<br />

41. Guha, S.R.D; Singh, M.M; Bhola, P.P. 1975. Laboratory trials with Eucalyptus hybrid<br />

wood, fresh <strong>and</strong> after storage <strong>for</strong> newsprint. Indian Forester 101(8): 476-483.<br />

Laboratory experiments carried out on the production of newsprint from furnish containing 30<br />

chemical pulp from Eetta reed (Ochl<strong>and</strong>ra travancorica) <strong>and</strong> 70 stone ground wood pulp, refiner<br />

mechanical pulp or cold soda pulp or hot sulphite pulp from stored <strong>and</strong> fresh Eucalyptus hybrid<br />

(Mysore gum) are described. The results show that newsprint of satisfactory strength properties could<br />

be prepared from fresh <strong>and</strong> stored wood. The power consumption in case of fresh wood is lower than<br />

the stored wood in all the cases. Fresh wood gives a brighter <strong>and</strong> easily bleachable pulp.<br />

42. Guha, S.R.D; Singh, M.M; Karira, B.G; Nair, V.K.S. 1980. Laboratory experiments on<br />

Andhra Pradesh hardwoods on behalf of Bhadrachalam Paper Boards Ltd. Indian<br />

Forester 106(7): 490-495.<br />

The yield <strong>and</strong> properties of pulps from bamboo (Dendrocalamus strictus) combined with different<br />

proportions of mixed hardwood pulps (a mixture of 30-40 per cent each of Terminalia tomentosa <strong>and</strong> T.<br />

5


ellirica <strong>and</strong> 2.5 - 5 per cent each of 8 other species). Increase in the percentage of hardwoods slightly<br />

increased yield but decreased strength properties, though the mixed pulps still had satisfactory<br />

properties <strong>for</strong> the manufacture of writing <strong>and</strong> printing paper, wrapping paper <strong>and</strong> 3-layer board.<br />

43. Harris, J.F. 1974. The role of total process concepts in evaluating pulping research.<br />

Proceedings of the TAPPI Non-sulphur Pulping Symposium, Madison: 161-167.<br />

44. Istas, J.R. 1958. Studies on the use of tropical species of papyrus <strong>for</strong> paper-making.<br />

Bulletin, Association Technique de Industries Papetiere, Paris (1): 18p.<br />

Presents results of chemical <strong>and</strong> morphological examinations <strong>and</strong> of various pulping experiments<br />

on raw materials from the Belgian Congo. Although papyrus could be pulped satisfactorily, yields were<br />

too low <strong>for</strong> commercial use. Pulps from individual hardwood species were, with few exceptions, inferior<br />

to Pinus sylvestris; pulps of mixed species had qualities similar but slightly inferior to that of P.<br />

sylvestris. <strong>Bamboo</strong>s are not at presently available in sufficient quantities, but more could be planted.<br />

The dwarf bamboos (Sasa paniculata, S. variabilis, Arundinaria nitida <strong>and</strong> A. simonii) are unsuitable <strong>for</strong><br />

pulping (short, fine stiff fibres); the largest species examined (fibre length 2.7 mm.) gave promising<br />

results, especially Bambusa vulgaris.<br />

45. Joedodibroto, R; Sugiharto, A. 1996. Can bamboo substitute Pinus merkusii in paper<br />

making? An overall comparative study. <strong>Bamboo</strong>, People <strong>and</strong> the Environment Vol.3<br />

Engineering <strong>and</strong> Utilization. Proceedings of the Vth Internation <strong>Bamboo</strong> Workshop, Ubud,<br />

Bali, Indonesia, 19-22 June 1995. INBAR Technical Report 8. <strong>International</strong> <strong>Network</strong> <strong>for</strong><br />

<strong>Bamboo</strong> <strong>and</strong> <strong>Rattan</strong>, New Delhi: 246-257.<br />

<strong>Bamboo</strong> has a woody structure <strong>and</strong> relatively long fibres, <strong>and</strong> the culms can be harvested when 2-<br />

3 years old. Pinus merkusii, on the other h<strong>and</strong>, is a softwood with long fibres <strong>and</strong> its rotation is 15<br />

years. It is of interest to know whether some bamboo species could be used as a substitute <strong>for</strong> P.<br />

merkusii in paper making <strong>and</strong> there by save timber resources <strong>and</strong> promote industrial bamboo<br />

plantations. This paper reports the results of a comparative study. If Gigantochloa apus <strong>and</strong> P.<br />

merkussii with regards to producing pulp <strong>for</strong> making strong paper. The results showed that G. apus<br />

pulp can be used as a substitute <strong>for</strong> P. merkusii pulp in paper making by choosing appropriate pulping<br />

conditions <strong>and</strong> pulp mixture composition.<br />

46. Kadambi, K; Ashong, F.W.A. 1966. Promise of technology in the conversion <strong>and</strong><br />

efficient utilization of wood resources, with particular reference to utilization of wood<br />

waste in Ghana. Paper presented in the IVth World Forestry Congress.<br />

47. Kato, H. 1961. Concerning physico-chemical properties of Japanese paper. TAPPI<br />

Journal 15(8): 549-551.<br />

48. Krishnamachari, K.S; Rangan, S.G; Ravindranathan, N; Reddy, D.V. 1975. Seshasayee<br />

Paper <strong>and</strong> Board's experience in the use of hardwoods <strong>for</strong> papermaking. Chem. Ind.<br />

Devts, Bombay 9(10): 41-45.<br />

Locally available hardwoods are being used to supplement limited supplies of bamboo.<br />

Satisfactory kraft pulps have been obtained with (1) 70% bamboo (Dendrocalamus strictus), 15%<br />

Mysore gum (Eucalyptus tereticornis) <strong>and</strong> 15% dadup (Erythrina suberosa),<strong>and</strong> (2) 50% bamboo, 20%<br />

Acacia arabica, 15% Mysore gum <strong>and</strong> 15% dadup.<br />

49. Kulkarni, A.Y; Parkhe, P.M. 1990. Appropriate technologies <strong>for</strong> pulping <strong>and</strong> paper<br />

making of unconventional raw materials in India. Proceedings of the Pulping<br />

Conference, USA: 313-320.<br />

50. Labarre, E.J. 1952. A Dictionary <strong>and</strong> Encylopedia of Paper <strong>and</strong> Papermaking with<br />

Equvalence of Technical Terms in France, German, Dutch, Italian, Spanish <strong>and</strong><br />

Swedish. 2nd Edn. Amsterdam.<br />

51. Maheshwari, S. 1982. Some basic aspects of high yield pulping. IPPTA 20(2).<br />

6


52. Mall, I.D; Upadhyay, S.N; Singh, A.R; Upadhya, Y.D. 1989. Environmental pollution due<br />

to pulp <strong>and</strong> paper industry. Paper presented in the IPPTA Silver Jubilee <strong>International</strong><br />

Seminar <strong>and</strong> Workshop on Appropriate Technologies <strong>for</strong> Pulp <strong>and</strong> Paper Manufacture in<br />

Developing Countries, New Delhi: p18.<br />

53. Merck, A.G.E. 1957. Chemish - Technishe Untersuchungsmethoden fur die Zellstoffund<br />

Papierfabrikation, Verlag Chemi, Weinheim.<br />

54. Mishra, N.D. 1971. Pulping of hardwoods: Our experience at Sirpur Paper Mills.<br />

Proceedings of the Conference on Utilisation of Hardwoods <strong>for</strong> Pulp <strong>and</strong> Paper, 19-20 April<br />

1971, FRI & Colleges, Dehdra Dun: 71-79.<br />

55. Mishra, N.D. 1973. A tentative method of grading hardwoods <strong>for</strong> chemical grade pulp.<br />

Indian Pulp <strong>and</strong> Paper 27(10): 7-10.<br />

Suggests a system <strong>for</strong> grading Indian hardwood pulpwood, based on nine characteristics that take<br />

into account economy of pulping, suitability <strong>for</strong> paper-making, adaptability to existing manufacturing<br />

processes <strong>and</strong> quality of end product. The system, which distinguishes four grades of suitability <strong>for</strong><br />

pulping, is used to classify 20 species viz. <strong>Bamboo</strong> (Dendrocalamus strictus), kenaf (Hibiscus<br />

cannabinus) <strong>and</strong> 18 hardwoods.<br />

56. Mishra, N.D; Kothari, M.B. 1969. A case study of bamboo fibre stock flow over a<br />

Fourdrinier paper machine. Indian Pulp <strong>and</strong> Paper 23(9): 541-545.<br />

57. Mishra, N.D; Rao, A.V. 1969. Pulping characteristics of Anduk wood (Boswellia serrata<br />

Roxb.) grown in Andhra Pradesh. Indian Pulp <strong>and</strong> Paper 23(12): 669-676.<br />

A laboratory study on sulphate pulping of B. serrata, a hardwood readily available to supplement<br />

the inadequate supply of bamboo in Andhra Pradesh, showed that B. serrata <strong>and</strong> bamboo, have<br />

different cooking characteristics; a better grade of pulp, with less chemical consumption, is produced<br />

from bamboo by the 2- stage temperature treatment method <strong>and</strong> from B. serrata by the impregnation<br />

(4-stage) method; bamboo <strong>and</strong> B. serrata should there<strong>for</strong>e be cooked seprately. The data also show,<br />

however, that the total bleach dem<strong>and</strong> of the two pulps, produced by the same method of cooking to<br />

the same K-number level, is very similar; it thus appears that the pulps can be bleached <strong>and</strong> mixed<br />

together.<br />

58. Monsalud, M.R. 1964. Pulp <strong>and</strong> paper evaluvation of Philippine species. Annual Report<br />

1963-64. Philippine Forest Products Research Institute.<br />

59. Monsalud, M.R; Bawagan, P.V; Escolano, J.O. 1965. Properties of wrapping papers from<br />

Philippine fibrous materials as related to pulp blending. Lumberman 11(33): 10, 12, 16,<br />

54-55.<br />

Data on fibre length, cell-wall thickness, lumen width, Runkel ratio <strong>and</strong> specific gravity <strong>for</strong> 6 long<br />

<strong>and</strong> 9 short-fibred materials including (a) Pinus insularis (b) three bamboos <strong>and</strong> (c) Samanea saman,<br />

Pantacme contorta, <strong>and</strong> other hardwoods are provided. Properties of papers from various pulps <strong>and</strong><br />

blends are tabulated.<br />

60. Nair, V.K.S. 1971. Certain aspects on utilisation of evergreen hardwoods <strong>for</strong> pulp <strong>and</strong><br />

paper making in India. Proceedings of the Conference on Utilisation of Hardwoods <strong>for</strong> Pulp<br />

<strong>and</strong> Paper, 19-20 April 1971, FRI & Colleges, Dehra Dun, India: 21-26.<br />

61. Nelson, G.H. 1966. A search <strong>for</strong> new fibre crops: Analytical evaluations. TAPPI Journal<br />

49(1): 40-48.<br />

An evaluation of 208 monocotyledonous <strong>and</strong> dicotyledonous species, mainly herbaceous annuals,<br />

but including some bamboos (Sinarundinaria murielae, 3 Phyllostachys spp., 2 Arundinaria spp., <strong>and</strong><br />

Oxytenanthera abyssinica), considered promising sources of pulp <strong>for</strong> planting in the S.E. <strong>and</strong> on the<br />

Pacific coast of the U.S.A.<br />

7


62. P<strong>and</strong>e, G.C. 1970. A modified technique <strong>for</strong> steam-vapour phase prehydrolysis of<br />

bamboo (Dendrocalamus strictus). Indian Pulp <strong>and</strong> Paper 25(1/6): 403-407.<br />

Describes a promising new technique in sulphate pulping that permits the removal of sufficient<br />

pentosans to bring the pulp within the limits specified <strong>for</strong> dissolving-grade pulp.<br />

63. Premrasmi, T; Aranyaputi, S. 1965. Rudimentary study of suitability of some Thai<br />

timbers <strong>for</strong> paper <strong>and</strong> pulp. Vanasaran 23(2): 105-106.<br />

64. Qiu, F.G. 1993. An approach to utilization of the bamboo waste left over from its<br />

processing. Journal of <strong>Bamboo</strong> Research 12(2): 28-32.<br />

At the moment the 3 main uses <strong>for</strong> bamboo residues in Zhejiang Province are: (i) pulping; (ii)<br />

bamboo particleboards; <strong>and</strong> (iii) fodder. Alternative uses of the residues are suggested, such as<br />

production of charcoal <strong>and</strong> xylose.<br />

65. Raitt, W. 1911. Suitability of various woods, bamboos <strong>and</strong> grasses <strong>for</strong> paper making.<br />

Indian Forester 37(7): 389-390.<br />

A memor<strong>and</strong>um which contains instructions <strong>for</strong> the selection <strong>and</strong> collection of materials <strong>for</strong> paper<br />

making.<br />

66. Ramaswami, V; Ramanathan, T. 1989. Recent developments in biotechnology related to<br />

pulp <strong>and</strong> paper industry. Paper presented in the IPPTA Silver Jubilee <strong>International</strong><br />

Seminar <strong>and</strong> Workshop on Appropriate Technologies <strong>for</strong> Pulp <strong>and</strong> Paper Manufacture in<br />

Developing Countries, 1989, New Delhi: p15.<br />

67. Ray, A.K; Garceau, J.J; Kokta, B.V; Carrasco, F; Bridgwater, A.V. 1994. Upgrading<br />

Nonwood Fibres by Chemical Impregnation <strong>and</strong> High-pressure Pulping. Advances in<br />

thermochemical biomass conversion Vol 2: 1598-1624. Blackie Academic & Professional,<br />

Glasgow, UK.<br />

Preimpregnated bamboo chips, sugarcane bagasse <strong>and</strong> rice straw of Indian origin were cooked at<br />

463 K (saturated steam pressure 1.26 MPa) in a Stake Technology batch reactor with different<br />

chemical charges <strong>and</strong> different types of chemicals. <strong>Bamboo</strong> required much more drastic impregnation<br />

<strong>for</strong> a protracted time with severe chemical treatment, <strong>and</strong>, <strong>for</strong> improved pulp quality, the most effective<br />

pulping agents were either caustic soda alone at high charge or an optimum mixture of sodium sulfite<br />

<strong>and</strong> alkali. Loss of pulp yield was observed <strong>for</strong> all species when impregnated with NaOH. The optical<br />

properties of unbleached pulp were acceptable <strong>for</strong> newsprint-quality pulp. A combination of Na2SO3<br />

with a lower per centage of NaOH may be a compromise between pulp yield loss <strong>and</strong> a gain in<br />

strength properties <strong>for</strong> bamboo. The drainage times of bamboo pulp were greatly superior to those of<br />

bagasse <strong>and</strong> rice straw pulps.<br />

68. Razzaque, M.A; Siddique, A.B. 1970. Fibre analysis of 20 tropical hardwoods <strong>and</strong> 20<br />

grass species of East Pakistan. Bulletin No. 10 Pulp <strong>and</strong> Paper Series 3/6, Forest<br />

Research Institute, Chittagong, Bangladesh.<br />

69. Rodriguez, S.K; Torres, M. 1995. Use of Chusquea culeou <strong>for</strong> producing chemical pulp.<br />

Ciencia e Investigacion Forestal 9(2): 165-175.<br />

Samples of Chusquea culeou, which is abundant in Chile, were processed to produce unbleached<br />

kraft pulp. Variables tested included 14 <strong>and</strong> 18 alkali, maximum temperature of 160 <strong>and</strong> 170°C, <strong>and</strong> 15<br />

or 30 min <strong>and</strong> maximum temperature. Total yields ranged between 46 <strong>and</strong> 55; Kappa number was 7-<br />

20. Strength properties were similar <strong>for</strong> 2 pulps with H factor 431 <strong>and</strong> 195. Under the experimental<br />

conditions, pulps of C. culeou had physical <strong>and</strong> mechanical properties that were lower than those from<br />

softwoods <strong>and</strong> several hardwoods.<br />

70. Rydholm, S.A. 1965. Pulping Process. Interscience Publishers, New York: 1269p.<br />

The book begins with a survey of the <strong>for</strong>ests of the world <strong>and</strong> includes <strong>and</strong> discusses data on<br />

wood species, the gross <strong>and</strong> minute structure of trees <strong>and</strong> wood fibres, <strong>and</strong> the chemical composition<br />

8


<strong>and</strong> reactions of their components. The operations involved in the preparation of cellulose pulp from<br />

the <strong>for</strong>est to the finished product are then described <strong>and</strong> discussed. The section headings comprise the<br />

manufacture of unbleached <strong>and</strong> of bleached pulp. A final chapter surveys the properties <strong>and</strong> uses of<br />

pulp <strong>and</strong> the world pulp industry. Emphasis is on the physical <strong>and</strong> chemical processes involved rather<br />

than the purely technological aspects. The influence of process variables on yields <strong>and</strong> properties of<br />

pulps are demonstrated <strong>and</strong> analysed. The chemical reactions involved, the preparation <strong>and</strong> recovery<br />

of pulping chemicals, <strong>and</strong> the manufacture of organic byproducts are also dealt with.<br />

71. Rydholm, S.A. 1966. Wood quality <strong>and</strong> cost requirement <strong>for</strong> <strong>for</strong>est industries <strong>and</strong><br />

dissolving pulp. Proceedings of the Sixth World Forestry Congress: 3301-3302.<br />

72. Sato, A; Kitamura, T; Higuchi, T. 1976. Studies on wood phenolics (Part V). Chemical<br />

properties <strong>and</strong> NMR analysis of milled wood lignins. Wood Research 59(60): 93-100.<br />

Milled wood (Bjorkman) lignins of Metasequoia glyptostroboides, Fagus crenata <strong>and</strong> the bamboo<br />

Phyllostachys pubescens were analysed by nuclear magnetic resonance spectrometry, <strong>and</strong> some<br />

chemical properties of the lignins were also examined. The molecular weight of the milled wood lignins<br />

of the three species were 2610, 2700 <strong>and</strong> 1740 respectively.<br />

73. Satyanarayana, G; Vaikuntam, K; Raghuveer, S. 1992. Improved per<strong>for</strong>mances of<br />

evaporators <strong>and</strong> chemical recovery boiler with the increased utilisation of hard woods<br />

at ITC Bhadrachalam Paperboards Limited. IPPTA 4(3): 121-122.<br />

Adaptations were made to black liquor evaporators so that a mixture of bamboo <strong>and</strong> hardwood<br />

pulp (at a ratio of 70:30) could be processed as efficiently as bamboo.<br />

74. Schwenzon, K. 1963. The hydrotropic pulping of some plant materials. Zellstoff Papier<br />

12(10): 290-296.<br />

75. Schwenzon, K. 1965. The hydrotropic pulping of plants. Zellstoff. Papier. 14(7): 199-201.<br />

76. Singh, M.M. 1960. Pressed boards from bamboo dusts. Indian Pulp <strong>and</strong> Paper 15(3):<br />

201-203.<br />

77. Singh, M.M. 1989. Raw materials <strong>for</strong> pulp <strong>and</strong> paper industry. Paper presented in the<br />

Silver Jubilee <strong>International</strong> Seminar <strong>and</strong> Workshop on Appropriate Technologies <strong>for</strong> Pulp<br />

<strong>and</strong> Paper Manufacture in Developing Countries, September-October 1989, New Delhi: p35.<br />

78. Singh, M.M; Madan, R.N; Dhawan, R; Kaira, K.K; Kaira, B.G. 1981. Investigations on<br />

Andaman & Nicobar Isl<strong>and</strong>s woods <strong>for</strong> different grades of paper. Indian Forester<br />

107(6): 377-383.<br />

Laboratory scale experiments were carried out on the production of wrapping, writing, printing <strong>and</strong><br />

newsprint grade pulps from seven species by different pulping processes like sulphate, neutral<br />

sulphite, semi-chemical (N.S.S.C) <strong>and</strong> cold soda. Unbleached pulps suitable <strong>for</strong> wrapping paper were<br />

obtained in satisfactory yields <strong>and</strong> having satisfactory strength properties by using sulphate <strong>and</strong><br />

(N.S.S.C) process. For writing <strong>and</strong> printing paper the pulps were bleached by CEH sequence.<br />

Bleached pulps in satisfactory yield <strong>and</strong> good strength properties were obtained. Pulps in high yield<br />

could be obtained by cold soda process, which when admixed with 28 bamboo sulphate pulp were<br />

considered to be suitable <strong>for</strong> newsprint. Comparative suitability indices of woods <strong>for</strong> wrapping <strong>and</strong><br />

writing <strong>and</strong> printing papers were calculated. From the reults it can be concluded that all the seven<br />

species are suitable <strong>for</strong> wrapping, writing, printing <strong>and</strong> newsprint grade pulps.<br />

79. Singh, M.M; Mukherjea, V.N. 1965. Fibrous raw materials <strong>for</strong> the Indian pulp, paper <strong>and</strong><br />

board industry. Indian Forester 91(7): 505-529.<br />

Data on fibre dimensions, proximate chemical analysis, method of pulping, yield of pulping,<br />

suitability of pulp <strong>for</strong> a varietis of paper, board <strong>and</strong> rayon of bamboos are provided.<br />

9


80. Stevens, R.H. 1958. <strong>Bamboo</strong> or wood. Southern Pulp <strong>and</strong> Paper Manufacturer 21(3):<br />

93-94, 108.<br />

Work at the Harty Foundation has shown that bamboos can be pulped readily, with less chemical<br />

<strong>and</strong> power than wood, by the kraft <strong>and</strong> a 2-stage alkali process. Fresh culms <strong>and</strong> those cut <strong>for</strong> a year<br />

<strong>and</strong> protected against insect damage gave equally good results. Chemical composition of the culms<br />

<strong>and</strong> of the pulps was similar to that of pulpwood species <strong>and</strong> wood pulps respectively. Only minor<br />

differences were found between pulps of 21 bamboo species. The fibres are shorter than those of<br />

conifers <strong>and</strong> longer than those of hardwoods, <strong>and</strong> narrower than wood fibres used in papermaking.<br />

Properties of the pulps <strong>and</strong> papers are discussed.<br />

81. Zhang, M; Kawai, S; Sasaki, H. 1994. Production <strong>and</strong> properties of composite<br />

fibreboard. Wood Research 81: 31-33.<br />

Fibreboards were made from combinations of lauan (Shorea sp.), jute (Corchorus capsularis),<br />

bamboo (Phyllostachys pubescens) <strong>and</strong> bagasse <strong>and</strong> properties were investigated.<br />

82. Zhang, M; Kawai, S; Sasaki, H; Yamawaki, T; Yoshida, Y; Kashihara, M. 1995. Manufacture<br />

<strong>and</strong> properties of composite fiberboard II. Fabrication of board manufacturing<br />

apparatus <strong>and</strong> properties of bamboo/wood composite fiberboard. Journal of Japan<br />

Wood Research Society 41(10): 903-910.<br />

<strong>Bamboo</strong>/wood composites fibreboards were manufactured using bamboo <strong>and</strong> wood fibres as raw<br />

material at various fibre mix ratios. An apparatus <strong>for</strong> drying fibre with an adhesive blending device was<br />

set up <strong>and</strong> an apparatus <strong>for</strong> <strong>for</strong>ming fibre mats was also made <strong>for</strong> this experiment. A carding machine<br />

was used to mix the fibres. The mixing ratios of bamboo to wood were 1/0, 3/1, 1/1, 1/3, <strong>and</strong> 0/1, <strong>and</strong><br />

the target board specific gravities were 0.60 <strong>and</strong> 0.80. The amount of isocyanate resin added was 10<br />

of the oven-dry weight of fibres. The MOR <strong>and</strong> MOE in both dry <strong>and</strong> wet conditions, internal bond<br />

strength, thickness swelling <strong>and</strong> linear expansion were determined. Increasing the ratio of bamboo<br />

fibre improved the MOR, MOE retention ratio <strong>and</strong> linear expansion after boiling.<br />

<strong>Bamboo</strong> Resources <strong>and</strong> Distribution<br />

83. <strong>Bamboo</strong> resources - Andhra Pradesh - Status paper. Proceedings of the National<br />

Seminar on <strong>Bamboo</strong>s, 19-20 December 1990, Bangalore. <strong>Bamboo</strong> Society of India. 1992.<br />

Bangalore: 208-209.<br />

Discusses briefly the state of bamboo resources of Andhra Pradesh. The species Dendrocalamus<br />

strictus grows extensively in the State. It is estimated that bamboo occurs over 9,883 sq. km. of the<br />

total <strong>for</strong>est area of 63,770 sq. km. <strong>and</strong> total growing stock is estimated as 38 lakh metric tonnes. Large<br />

scale pure bamboo plantations are raised by Andhra Pradesh Forest Department <strong>and</strong> Forest<br />

Development Corporation in various places. A survey conducted of the bamboo areas shows that the<br />

clump <strong>for</strong>mation is completed by nine years <strong>and</strong> bamboo extraction can be taken up from ninth year.<br />

84. <strong>Bamboo</strong> supplies in India. Indian Forester 39(11): 1913: p552.<br />

The possibility of starting a paper manufacturing industry in Cochin is stated.<br />

85. <strong>Bamboo</strong> supplies <strong>for</strong> paper making. Indian Forester 53(6). 1927: 349-351.<br />

An editorial on bamboo supplies <strong>for</strong> paper making. It is a reprint of the article on bamboo supplies<br />

<strong>for</strong> paper making by Mr. W. Raitt of Forest Research Institute, Dehra Dun.<br />

86. Bhat, A.S. 1970. Economics of industrial plantations of Bambusa arundinacea.<br />

My<strong>for</strong>est 7(1): 57-64.<br />

Discussed the economics of industrial plantations of Bambusa arundinacea <strong>for</strong> pulp <strong>and</strong> paper.<br />

10


87. Chaudhari, R.R. 1960. <strong>Bamboo</strong> surveys in the Bombay State. Proceedings of the Ninth<br />

Silvicultural Conference, 7, 10-19 December 1956, Dehra Dun. Forest Research Institute<br />

<strong>and</strong> Colleges, Dehra Dun Vol.2: 205-215.<br />

An account of a detailed systematic strip enumerations (involving clump analysis <strong>and</strong> problems of<br />

sustained yield) undertaken in the richer tracts of Dendrocalamus strictus <strong>and</strong> Bambusa arundinacea in<br />

the Kanara, Dangs <strong>and</strong> Vyara <strong>for</strong>ests with a view to explore the possibilities of establishing pulp <strong>and</strong><br />

paper mills in the State is given.<br />

88. CSIR, India. 1948. <strong>Bamboo</strong>s. Wealth of India, Raw Materials. Council of Scientific <strong>and</strong><br />

Industrial Research, New Delhi. Vol.1: 145-155.<br />

As per the in<strong>for</strong>mation furnished, about 30 genera <strong>and</strong> 550 species inhabiting the humid tropical<br />

<strong>and</strong> extra-tropical regions are known. Of these, 136 species occur in India, 39 in Burma, 29 in<br />

Malaysia <strong>and</strong> the Andamans, 9 in Japan, 30 in the Philippines, 8 in New Guinea <strong>and</strong> a few in South<br />

Africa <strong>and</strong> Queensl<strong>and</strong>. It also covers the varieties of bamboo, diseases <strong>and</strong> insect pests. Uses,<br />

including manufacture of paper-pulp <strong>and</strong> production of bamboo are discussed.<br />

89. CSIR, India. 1966. Neohouzeaua (Gramineae). Wealth of India, Raw Materials. Council of<br />

Scientific <strong>and</strong> Industrial Research, New Delhi. Vol.7: 9-10.<br />

A short description of the genus Neohouzeaua is given here. N. dullooa is a suitable raw material<br />

<strong>for</strong> paper pulp.<br />

90. Deb, D.B. 1978. Economic plants of Tripura State VII. Plants used <strong>for</strong> manufacture of<br />

paper <strong>and</strong> boards. Indian Forester 104(9): 609-614.<br />

Plants used <strong>for</strong> manufacture of paper <strong>and</strong> boards, which are found in the State are discussed in<br />

this paper. Eleven species of bamboo found in the State are reported to be suitable <strong>for</strong> the<br />

manufacture <strong>for</strong> pulp <strong>and</strong> paper.<br />

91. Desai, B.P. 1980. Management of bamboos in Ch<strong>and</strong>rapur Circle, Maharashtra State.<br />

Proceedings of the Third Southern Silviculturists <strong>and</strong> Forest Research Officers Conference,<br />

3-5 March 1980, Dharwad. Karnataka Forest Department: 25-32.<br />

The paper indicates the extent of bamboo resources available in Ch<strong>and</strong>rapur Circle, Maharashtra<br />

highlighting the species <strong>and</strong> its distribution in various <strong>for</strong>est types. The importance of scientific<br />

management of bamboos <strong>and</strong> the dem<strong>and</strong> <strong>for</strong> this raw material are discussed. The existing felling<br />

rules in the circle <strong>and</strong> the extent of exploitation <strong>for</strong> meeting the dem<strong>and</strong>s of the paper mills are<br />

presented.<br />

92. Desai, B.P; Subramanian, K. 1980. A note on bamboos in Maharashtra. Proceedings of<br />

the Third Southern Silviculturists <strong>and</strong> Forest Research Officers Conference, 3-5 March 1980,<br />

Dharwad. Karnataka Forest Department: 39-60.<br />

Three important species of bamboo occurring in Maharashtra are Dendrocalamus strictus,<br />

Bambusa arundinacea <strong>and</strong> Oxytenanthera monostigma. The first two are the principal species utilized<br />

as raw material <strong>for</strong> paper <strong>and</strong> pulp industries. The distribution of bamboos, their ecology, botany <strong>and</strong><br />

silviculture are discussed. The achievements in creating man made bamboo <strong>for</strong>ests by artificial<br />

regeneration upto 1978-79 are highlighted. Details of gregarious flowering are summarised.<br />

Management <strong>and</strong> utilization aspects are discussed.<br />

93. Deshmukh, D.K. <strong>Bamboo</strong> plantations by West Coast Paper Mills Ltd. D<strong>and</strong>eli. A new<br />

<strong>for</strong>est development strategy. West Coast Paper Mills, D<strong>and</strong>eli: 5-17.<br />

The West Coast Paper Mills with the cooperation of Mysore Forest Department launched a<br />

programme of raising bamboo plantation in D<strong>and</strong>eli in 1964 with the objective of 1. Filling the natural<br />

gaps <strong>and</strong> improve the bamboo stocking 2. To convert low yielding bamboo areas into high yielding<br />

bamboo areas <strong>and</strong> 3. To hasten up the development of natural bamboo crop. Here discusses the soil<br />

type, climate of the area, vegetation type, selection of species, planting programme, natural<br />

regeneration, yield <strong>and</strong> financial aspect of raising such plantation.<br />

11


94. Gamble, J.S. 1896. The bambuseae of British India. Annals of Royal Botanic Garden 7(1):<br />

1-133.<br />

An illustrated account of the bamuseae of India is given. Detailed in<strong>for</strong>mation on the taxonomy,<br />

distribution, propagation of species are presented. Extensive notes on uses including rural dwellings<br />

<strong>and</strong> geotechnical applications are also given.<br />

95. Gu, X.P; Xiao, J.H; Liang, W.Y; Lin, Y.F; Zhang, C. 1998. The effects of N, P <strong>and</strong> K<br />

fertilizer applied in pulp bamboo st<strong>and</strong>. Scientia Silvae Sinicae 34(1): 25-32.<br />

A quadratic regression model was used to determine the effects of N, P <strong>and</strong> K fertilizers on<br />

relative growth rate of culms of Phyllostachys pubescens. The analysis of the principal effect of<br />

fertilizer shows that N, P <strong>and</strong> K have different effects on the increase of the output of P. pubescens<br />

st<strong>and</strong>, <strong>and</strong> the action order is: N > K > P in this test. 2-factor interaction analysis shows that there is a<br />

positive interaction between N <strong>and</strong> K to a certain extent, but there is no significant interaction between<br />

N <strong>and</strong> P, or P <strong>and</strong> K. Computer simulation showed that the optimum fertilizer combination is (within the<br />

confidence limits of 95): urea 325.5-413.5 kg/hm 2 , superphosphate 208.5-295.5 kg/hm 2 <strong>and</strong> potassium<br />

chloride 198-267 kg/hm 2 .<br />

96. Guha, S.R.D. 1961. Tour report of Dr. S.R.D. Guha to Culcutta <strong>and</strong> Luknow on February<br />

1961. File on <strong>Bamboo</strong>, Doc. Section, Forest Research Institute <strong>and</strong> Colleges, Dehra Dun.<br />

97. Hasan, S.M; Skoupy, J; Vaclav, E. 1976. Recent trends in <strong>Bamboo</strong> growing <strong>and</strong> use in<br />

Bangladesh. Silvaeculture Tropica et Subtropica 5: 59-69.<br />

In an assessment of the <strong>Bamboo</strong> resources of Bangladesh, it is pointed out that naturally<br />

occurring <strong>Bamboo</strong> species (the most common of which is Melocanna bambusoides) have thin-walled<br />

culms, whereas cultivated species, including Bambusa vulgaris, B. balcooa <strong>and</strong> B. nutans, have thickwalled<br />

culms. There are differences in utilization of the two groups of species, <strong>and</strong> cultivated species<br />

give higher yields <strong>for</strong> pulp production. Over-exploitation of accessible naturally occurring species has<br />

caused their disappearance from some areas <strong>and</strong> a decrease in yield. New management systems <strong>for</strong><br />

growing <strong>Bamboo</strong> in plantations are suggested. Their introduction is dependent on the development of<br />

methods of propagation. Cultivated species are normally propagated by offsets <strong>and</strong> recently have been<br />

successfully propagated from 18- to 20-in-long branch cuttings with swollen basal nodes.<br />

98. Hegde, N.G. 1993. Scope <strong>for</strong> production of industrial raw materials through farmers.<br />

Vaniki S<strong>and</strong>esh 17(3): 1-23.<br />

The introduction to this paper discusses the dem<strong>and</strong> <strong>for</strong> wood in India, <strong>and</strong> gives data <strong>for</strong> wood<br />

consumption in 1985. A significant proportion of this consumption (42) is fuelwood, some 64 of which is<br />

collected free of cost by the poorer sections of society, <strong>and</strong> as such, offers no scope <strong>for</strong><br />

commercialization. The next highest proportion of wood consumption is <strong>for</strong> the paper <strong>and</strong> paperboard<br />

industry (16.8), <strong>and</strong> the paper mainly concentrates on this industry, giving projected dem<strong>and</strong>s <strong>and</strong><br />

production capacities (with some data <strong>for</strong> other overall wood dem<strong>and</strong> <strong>and</strong> <strong>for</strong> wood <strong>for</strong> panelwood),<br />

<strong>and</strong> discussing sources of raw material (wood, bamboo, <strong>and</strong> agricultural residues), of which there is an<br />

anticipated shortage. Strategies <strong>for</strong> meeting industrial dem<strong>and</strong> <strong>for</strong> pulpwood are outlined, <strong>and</strong> include<br />

af<strong>for</strong>esting degraded <strong>for</strong>est l<strong>and</strong>s (which needs legislation to allow leasing to industry, <strong>and</strong> has met<br />

with environmental objections) <strong>and</strong> waste l<strong>and</strong>s (some of which are either encroached or unsuitable).<br />

The available options are: (1) procuring wood from the Forest Department <strong>and</strong> Forest Plantation<br />

Corporation, from plantations on both <strong>for</strong>est <strong>and</strong> non-<strong>for</strong>est l<strong>and</strong>; (2) leasing government <strong>and</strong> private<br />

l<strong>and</strong>s to wood based industries <strong>for</strong> their own wood production; (3) leasing government l<strong>and</strong> to farmers,<br />

with coordination of wood production by the industries concerned; <strong>and</strong> (4) the growing of trees by<br />

farmers on their own l<strong>and</strong>, which is then procured by the wood based industries. The last option is<br />

considered to be the best, <strong>and</strong> theremainder of the paper discusses the involvement of farmers in<br />

industrial <strong>for</strong>estry, addressing profitability, <strong>and</strong> suitable species - the bamboos Bambusa arundinacea<br />

<strong>and</strong> Dendrocalamus strictus, <strong>and</strong> Eucalyptus spp. are those in most dem<strong>and</strong> by the paper industry, but<br />

various other (multipurpose) species are also suitable <strong>for</strong> promotion under farm <strong>for</strong>estry <strong>and</strong><br />

agro<strong>for</strong>estry systems. Steps to ensure profitability <strong>for</strong> the farmer include the selection of high yielding<br />

species <strong>and</strong> superior provenances, the use ofsuperior planting material (including micropropagated<br />

stock), improved silvicultural practices, improved harvesting <strong>and</strong> processing, <strong>and</strong> motivation <strong>and</strong><br />

extension. Planning <strong>for</strong> product mix through farmers' organizations is also suggested.<br />

12


99. Hodge, W.H. 1957. <strong>Bamboo</strong>s, their economic future in America. Gdn. J. N.Y. Bot. Gdn.<br />

7(4): 124-128.<br />

A general note on the introduction <strong>and</strong> use of bamboos in the U.S.A., <strong>and</strong> on research in progress<br />

there on their utilization. The yield/acre/year of cellulosic material is 6 times that of Southern Pine, <strong>and</strong><br />

some species yield regularly on a 5-year cycle.<br />

100. Indian Council of Forestry Research <strong>and</strong> Education. 1991. <strong>Bamboo</strong>: The poorman's<br />

timber. ICFRE, Dehra Dun: 24p.<br />

101. Jha, Y.P. 1964. A short note on the management of bamboos (Dendrocalamus strictus)<br />

with special reference to its exploitation <strong>and</strong> mode of leasing out to paper mills in<br />

Daltonganj South Division, Bihar. All India <strong>Bamboo</strong> Study Tour <strong>and</strong> Symposium 1963-64,<br />

Dehra Dun. Forest Research Institute, Dehra Dun: 166-174.<br />

A short note on the management of bamboos (Dendrocalamus strictus) in Daltonganj South Forest<br />

Division, Bihar is given. The mode of leasing out bamboos to paper mills, the manner in which the<br />

leases are granted in the past <strong>and</strong> present, the minimum royalty, method of calculation of royalty are<br />

discussed briefly.<br />

102. Kaitpraneet, W; Suwannapinant, W; Thaiutsa, B; Sahunalu, P. 1978. Management of<br />

bamboo <strong>for</strong>est <strong>for</strong> pulp <strong>and</strong> paper industry. Research Note, Faculty of Forestry,<br />

Kasetsart University 26: 9p.<br />

The results of a study in a pure st<strong>and</strong> of Thyrsostachys siamensis at Hin Lap, Changwat<br />

Kanchanaburi, Thail<strong>and</strong> in 1974-77. Plots of 15X15 m were treated by clear felling or selection felling<br />

with or without the application of mixed [NPK] fertilizer, <strong>and</strong> the numbers of new culms recorded <strong>for</strong> 3<br />

yr. The greatest number of new culms was in the selection system plots (av. 239/plot without NPK <strong>and</strong><br />

220 with NPK). Clear felled plots had an average of 94 new culms without NPK <strong>and</strong> 103 with NPK.<br />

103. K<strong>and</strong>elaki, T.E. 1976. The economics of utilizing bamboo. Lesmoe Khozyaistvo No. 12:<br />

61-62.<br />

Describes investigations in Soviet Georgia on the technical <strong>and</strong> economic feasibility of utilising<br />

home-grown bamboos as raw material in the pulp <strong>and</strong> paper industry. Data are given on the chemical<br />

composition of the wood of 3-year-old culms of three species of Phyllostachys, <strong>and</strong> literature data on<br />

plantation yields <strong>and</strong> management from Georgia <strong>and</strong> other countries are discussed. It is concluded<br />

that selective harvesting of 3-year culms is appropriate, <strong>and</strong> that P. edulis gives the best yields; the<br />

mean number of culms harvested per year in a high-yielding plantation is 2520 culms/year. The total<br />

yield from 1 ha of P. edulis plantation over a period of 80 years is 4218 t (as against only 360 t <strong>for</strong> a fir<br />

plantation <strong>and</strong> 440 t <strong>for</strong> Alder). The cost of 1 t bamboo free-at-mill is calculated at 11.77 roubles, vs.<br />

44 roubles <strong>for</strong> conifer pulpwood grown in Georgia. The pay-back period (break-even point) <strong>for</strong> a P.<br />

edulis plantation is 7 years from establishment.<br />

104. Karnik, M.G. 1956. Varieties of paper. Indian Forester 82(1): 203-205.<br />

In this article important varieties of paper like 1. writing, 2. printing, 3. newsprint, 4. wrapping <strong>and</strong><br />

5. speciality paper are described along with the raw materials <strong>and</strong> method of preparation.<br />

105. Khristova, P; Gabir, S; Khristov, T. 1981. Raw material resources <strong>for</strong> obtaining fibrous<br />

semiproducts <strong>for</strong> pulp <strong>and</strong> papermaking in Sudan. Sudan Silva 4(24): 6-10.<br />

Eucalyptus camaldulensis from Sudanese plantations <strong>and</strong> the indigenous bamboo Oxytenanthera<br />

abyssinica were studied to see whether they were suitable <strong>for</strong> pulp production. They were pulped by<br />

the 'high temperature shock' chemithermomechanical process. Pulping was successful with both soda<br />

<strong>and</strong> sulphate liquors, E. camaldulensis gave a yield of 80-83 <strong>and</strong> O. abyssinica 70-74. The pulps are<br />

suitable <strong>for</strong> the manufacture of cardboard. The eucalyptus pulp is best mixed with 30 of long-fibre pulps<br />

to give it better strength properties.<br />

106. Lakshmana, A.C. 1992. <strong>Bamboo</strong>: A potential employment generator; Its present status<br />

<strong>and</strong> future prospects. Proceedings of the National Seminar on <strong>Bamboo</strong>s, 19-20 December<br />

1990, Bangalore: 75-81. <strong>Bamboo</strong> Society of India, Bangalore.<br />

13


The suitability of bamboo species <strong>for</strong> social <strong>for</strong>estry programmes is highlighted. Discusses<br />

bamboo yield in Karnataka, the type <strong>and</strong> extent of its use <strong>and</strong> its high capacity to generate employment<br />

<strong>and</strong> income especially among tribal people, marginal farmers <strong>and</strong> others living in the vicinity of <strong>for</strong>ests.<br />

The estimated bamboo <strong>for</strong>est in Karnataka is about four lakhs hectares, out of which the annual<br />

production is about 100,000 tonnes of bamboo. The estimated dem<strong>and</strong> <strong>for</strong> bamboo <strong>for</strong> selected few<br />

items in the State is 646,000 tonnes. Thus a short supply of 546,000 tonnes of bamboo is reported.<br />

Recommendations are made to increase the production of bamboo in the State.<br />

107. Madhav Gadgil; Narendra Prasad, S. Conservation of bamboo resources of Karnataka:<br />

Report on the State-wide availability of bamboo resources. Centre <strong>for</strong> Theoretical<br />

Studies, Bangalore: 13p.<br />

The report deals with the status of bamboo resources of Karnataka State <strong>and</strong> the impact of the<br />

industrial consumption on the resources. The need <strong>for</strong> raising bamboo plantations by paper mills is<br />

stressed.<br />

107a. Martin, M. 1996. Where have the groves gone? Down to Earth, June 15: 27-31<br />

108. McCormac, C.W. 1987. Economics <strong>for</strong> bamboo <strong>for</strong>estry research: Some suggested<br />

approaches. In: Rao, A.N, Dhanarajan, G <strong>and</strong> Sastry, C.B (Eds.). Recent Research on<br />

<strong>Bamboo</strong>s: Proceedings of the <strong>International</strong> <strong>Bamboo</strong> Workshop, 6-14 October 1985,<br />

Kangshou, China. Chinese Academy of Forestry, Beijing <strong>and</strong> IDRC, Canada: 370-377.<br />

109. Mohanty, A.P. 1959. <strong>Bamboo</strong> resource of Orissa. Indian Forester 85(2): 115-118.<br />

A survey is carried out in Orissa to estimate the quantity of bamboo available <strong>for</strong> paper making.<br />

The method adopted <strong>for</strong> the survey <strong>and</strong> the results obtained are briefly discussed in this paper.<br />

110. Mooney, H.F. 1959. A report on the bamboo <strong>for</strong>ests of Wallega Province (Abyssinia)<br />

with a view to their possible utilisation <strong>for</strong> paper <strong>and</strong> pulp. British Middle East Division,<br />

Addis Ababa: 8p.<br />

A descripion of ca. 2200 sq. miles of <strong>for</strong>est Oxytenanthera abyssinica. Assuming a yield of 5 tons<br />

air-dry culms per acre <strong>and</strong> a 4-year cutting cycle 24,000-30,000 acres would provide the 30,000 tons<br />

required <strong>for</strong> 10,000 tons of paper. With water also plentiful, the project is recommended <strong>for</strong> serious<br />

exploration.<br />

111. Moulik, S. 1997. The Grasses <strong>and</strong> <strong>Bamboo</strong>s of India. 2 Vols. Scientific Publishers,<br />

Jodhpur: 700p.<br />

112. Nair, K.S. 1980. A base paper on bamboos in Kerala. Proceedings of the Third Southern<br />

Silviculturists <strong>and</strong> Forest Research Officers Conference, 3-5 March 1980, Dharwad.<br />

Karnataka Forest Department: 131-141.<br />

The paper deals with <strong>for</strong>est types of Kerala <strong>and</strong> the distribution of bamboos. Details about<br />

indigenous <strong>and</strong> exotic species, silviculture <strong>and</strong> agronomy, crop associations <strong>and</strong> regeneration, seed<br />

production <strong>and</strong> growth, natural regeneration <strong>and</strong> management, utilization, pests <strong>and</strong> diseases etc. are<br />

given.<br />

113. Nicholson, J.W. 1922. Report of the bamboo <strong>for</strong>ests of the lower Mahanadi basin. Indian<br />

Forester 48(11): 607-608.<br />

A survey of the bamboo resources of the Angul Division <strong>and</strong> the neighbouring states is made to<br />

ascertain whether sufficient supplies of bamboo can be made available to the paper-pulp factory to be<br />

set up at Cuttack. The results of the survey are reported here.<br />

114. Ohrnberger, D. 1999. <strong>Bamboo</strong>s of the World. Elsevier, The Netherl<strong>and</strong>s. 585p.<br />

115. Pesantes Rebaza, M.A. 1985. Study on the possibilities to establish bamboo<br />

plantations <strong>for</strong> pulp <strong>and</strong> paper production in Pucallpa. Lima: 93p. Universidad Nacional<br />

Agraria, Lima, Facultad de Ciencias Forestales.<br />

14


116. Prasad, J. 1948. Silviculture of ten species of bamboo suitable <strong>for</strong> paper manufacture.<br />

Indian Forester 74(3): 122-130.<br />

A general description, distribution, habitat, growth, development, cultivation, felling methods,<br />

extraction, flowering, seeding <strong>and</strong> supplies of ten Indian bamboos, suitable <strong>for</strong> paper manufacture are<br />

presented. The species described are Dendrocalamus strictus, D. hamiltonii, D. longispathus,<br />

Bambusa polymorpha, B. arundinacea, B. tulda, Melocanna bambusoides, Neohouzeaua dullooa,<br />

Ochl<strong>and</strong>ra travancorica <strong>and</strong> Oxytenanthera nigrociliata.<br />

117. Sagreiya, K.P; Khan, M.A.W; Chacko, V.J. 1961. <strong>Bamboo</strong> potential surveys. Proceedings<br />

of the Tenth Silvicultural Conference, 15-25 November 1961, Dehra Dun. Forest Research<br />

Institute <strong>and</strong> Colleges, Dehra Dun. 2: 840-843.<br />

For the full utilisation of the bamboo resources of the country <strong>and</strong> also <strong>for</strong> a planned development<br />

of paper-pulp industry, an investigation of the resources of bamboo is planned on all India basis. Here<br />

describes the techniques, procedure <strong>and</strong> objectives of the survey.<br />

118. Seethalakshmi, K.K; Kumar, M. 1998. <strong>Bamboo</strong>s of India: A Compendium. Kerala Forest<br />

Research Institute, Peechi, Kerala, India <strong>and</strong> INBAR, Beijing, China: 342p.<br />

In this book 128 bamboo species found in India are described. In the introduction part, the<br />

bamboo is dealt with in general. There after 18 genera naturally occuring <strong>and</strong> cultivated in India are<br />

described. Morphology, flowering <strong>and</strong> fruiting, distribution <strong>and</strong> ecology, antomy <strong>and</strong> fibre<br />

characteristics, chemistry, silviculture <strong>and</strong> management, pests <strong>and</strong> diseases, physical <strong>and</strong> mechanical<br />

properties, natural durability <strong>and</strong> preservation <strong>and</strong> uses are given whereever in<strong>for</strong>mation is available.<br />

Illustrations <strong>and</strong> photographs are profusely given.<br />

119. Shanmughavel, P; Francis, K; George, M. 1997. Plantation <strong>Bamboo</strong>. <strong>International</strong> Book<br />

Distributors, Dehra Dun, India: 191p.<br />

This book addresses techniques <strong>for</strong> bamboo cultivation in South <strong>and</strong> South East Asia. It is<br />

arranged in 13 chapters, <strong>and</strong> includes separate colour plates <strong>and</strong> a section at the end providing tables<br />

of data on various aspects of bamboo plantations <strong>and</strong> use. The first 5 chapters are introductory: (1)<br />

Introduction; (2) Distribution; (3) Taxonomy; (4) Ecological requirements; <strong>and</strong> (5) Growth<br />

characteristics. The remaining 8 chapters address plantation establishment, management <strong>and</strong> use: (6)<br />

Establishment <strong>and</strong> management - mostly sowing <strong>and</strong> planting stock production, with a small section on<br />

management; (7) Growth <strong>and</strong> development; (8) Biomass <strong>and</strong> yield; (9) Felling cycle <strong>and</strong> fertilizer<br />

application; (10) Introduction of social <strong>for</strong>estry - strip planting,community <strong>for</strong>estry, limitations,<br />

agro<strong>for</strong>estry, rehabilitation of degraded <strong>for</strong>est, af<strong>for</strong>estation, reclamation of waste l<strong>and</strong>; (11) Need <strong>for</strong><br />

raising bamboo plantation - with reference to use as raw material <strong>for</strong> the pulp <strong>and</strong> paper industry; (12)<br />

Problems <strong>and</strong>prospects of bamboo plantations - with regard to cultivation <strong>and</strong> socioeconomic aspects;<br />

<strong>and</strong> (13) Utilization - consumption pattern in India, <strong>and</strong> uses as parquet, laminates, in aircraft, concrete<br />

rein<strong>for</strong>cement, growing in artificial shapes, <strong>and</strong> as raw material <strong>for</strong> phytosterols.<br />

120. Sharma, Y.M.L. 1977. R<strong>and</strong>om notes on bamboos of Asia <strong>and</strong> the Pacific. Forest News<br />

<strong>for</strong> Asia <strong>and</strong> the Pacific 1(2): 34-35.<br />

Author discusses briefly the important role of bamboo in the rural economy. The species of<br />

bamboo used much by the people <strong>and</strong> in paper industry are also listed.<br />

121. Sharma, Y.M.L. 1982. Some aspects of bamboo in Asia <strong>and</strong> the Pacific. RAPA, Bangkok,<br />

Thail<strong>and</strong>: 56p.<br />

122. Singh, S. 1973. The cheapest, quickest <strong>and</strong> surest way to solve raw material shortage<br />

problem <strong>for</strong> pulp <strong>and</strong> paper industries in India. Indian Pulp <strong>and</strong> Paper 27(12/9): p20.<br />

Draws attention to the declining yield of bamboo (Dendrocalamus strictus) from successive felling<br />

cycles in many of the Indian deciduous hardwood <strong>for</strong>ests <strong>and</strong> to the consequent increasing shortage of<br />

raw materials <strong>for</strong> pulp <strong>and</strong> paper manufacture in India, <strong>and</strong> suggests silvicultural measures <strong>for</strong><br />

achieving a rapid improvement in bamboo recruitment.<br />

15


123. Surendran, P.N. Status paper on Kerala man-made <strong>for</strong>ests: 5p.<br />

124. Tewari, D.N. 1992. A Monograph on <strong>Bamboo</strong>. <strong>International</strong> Book Distributors, Dehra Dun,<br />

India: 172p.<br />

This book provides a comphrehensive review <strong>and</strong> bibliography of all aspects of bamboos with<br />

particular emphasis on India <strong>and</strong> is presented in 13 chapters: (1) Introduction - including brief accounts<br />

of the current status of bamboo utilization <strong>and</strong> of proposed research programmes; (2) Distribution of<br />

bamboos in the world; (3) <strong>Bamboo</strong>s in India; (4) <strong>Bamboo</strong> taxonomy; (5) Silviculture <strong>and</strong> management<br />

of bamboos in India; (6) Genetic improvement; (7) Growth, yield <strong>and</strong> economics; (8) Utilisation of<br />

bamboos; (9) <strong>Bamboo</strong> products; (10) Pulp <strong>and</strong> paper manufacture; (11) Insect pests of bamboos; (12)<br />

Diseases <strong>and</strong> decay of bamboo; <strong>and</strong> (13) General bibliography on bamboo. A subject index is<br />

included.<br />

125. Uppin, S.F. 1964. A note on Bambusa arundinacea in the leased area of the West Coast<br />

Paper Mills Ltd; D<strong>and</strong>eli in Kanara Northern Division, Mysore State. All India <strong>Bamboo</strong><br />

Study Tour <strong>and</strong> Symposium 1963-64, Dehra Dun. Forest Research Institute, Dehra Dun:<br />

187-196.<br />

A note on the bamboo Bambusa arundinacea in the leased area of the West Coast paper Mill,<br />

D<strong>and</strong>eli of Mysore state is given in this paper. Some of the observations made on the flowering pattern<br />

of the species are also presented. Cost of planting bamboo seedlings is calculated.<br />

126. Venkatappa Setty, K.R. 1962. Management <strong>and</strong> Exploitation of <strong>Bamboo</strong>s (Paper <strong>for</strong> the<br />

Diploma of Associate of Indian Forest College, Dehra Dun). Indian Forest College, Dehra<br />

Dun: 84p.<br />

A brief account of silviculture, management <strong>and</strong> exploitation of bamboos with reference to Mysore<br />

State is given. Bambusa arundinacea, Dendrocalamus strictus, Oxytenanthera monostigma, Ochl<strong>and</strong>ra<br />

travancorica <strong>and</strong> Oxytenanthera stocksii are the species reported from the State. To meet the local<br />

dem<strong>and</strong> as well as the requirement of paper industries it is suggested to save bamboo <strong>for</strong>ests<br />

departmental working of the bamboo <strong>for</strong>ests is to be encouraged. The influence of bamboo flowering<br />

on the supply of bamboos <strong>for</strong> paper mills is also discussed. <strong>Bamboo</strong>s from the <strong>for</strong>ests are exploited by<br />

various agencies like department, contractors, permit holders, etc. <strong>and</strong> a comparative study of the<br />

working of bamboo by these agencies are studied. A working scheme <strong>for</strong> supply of bamboos <strong>for</strong> the<br />

West Coast Paper mills, D<strong>and</strong>eli is worked out.<br />

127. Waheed khan, M.A. 1972. Creation of bamboo <strong>for</strong>ests <strong>for</strong> paper industry in Madhya<br />

Pradesh. IPPTA Seminar, Dehra Dun: p4.<br />

National Newsprint <strong>and</strong> Paper Mills, Nepanagar <strong>and</strong> Orient Paper Mills, Amlai are the main<br />

pulpwood consuming industries in Madhya Pradesh. Large scale bamboo plantations are raised<br />

around Nepanagar by the Forest Department <strong>for</strong> meeting the dem<strong>and</strong> <strong>for</strong> raw material. The author<br />

suggests here necessary changes to be made in raising bamboo plantations <strong>for</strong> the mills in the State.<br />

128. Waheed khan, M.A. 1972. Management of bamboo <strong>for</strong>ests in Madhya Pradesh as<br />

producers of raw material <strong>for</strong> pulp <strong>and</strong> paper industry. IPPTA Seminar, Dehra Dun: p5.<br />

It is predicted that the bamboo areas will become totally unproductive if the present system of<br />

protection <strong>and</strong> management continues unchecked <strong>and</strong> unattended. Measures to be taken to halt<br />

degradation of bamboo <strong>for</strong>ests <strong>and</strong> to revive their full production are suggested.<br />

129. Yang, X.S; Shi, Q.T; Huang, Y.C; Liang, W.Y; Lin, Y.F. 1999. The effect of silvicultural<br />

management on the production of moso bamboo plantations <strong>for</strong> pulp-making. Forest<br />

Research 12(3): 268-274.<br />

A series of tests on pulpwood production in moso bamboo (Phyllostachys pubescens) st<strong>and</strong>s were<br />

conducted systematically in Anji County (Zhejiang Province), Shaowu County (Fujian Province) <strong>and</strong><br />

Fengxin County (Jiangxi Province) in China. The silvicultural practices established were used in<br />

establishing a 20 hm2 high-yield model st<strong>and</strong> of moso bamboo <strong>for</strong> pulpwood production. The<br />

productivity of moso bamboo st<strong>and</strong>s was determined by habitat <strong>and</strong> management, with significant<br />

differences found between different management regimes, site qualities or status of the original<br />

16


amboo st<strong>and</strong>. A bamboo <strong>for</strong>est in an undesirable state on a poor site could be guided towards an<br />

ideal or normal state by using measures such as loosening the soil, fertilizing, felling, adjusting st<strong>and</strong><br />

structure, etc. A management model is proposed which involves suiting silvicultural measures to local<br />

conditions <strong>and</strong> classifying management actions to improve st<strong>and</strong> economics/yields.<br />

130. Yuan, Y.P; Xiao, J.H; Chen, H.L; Zhu, W.S. 1999. New management type of<br />

Phyllostachys pubescens <strong>for</strong>est. Journal of Zhejiang Forestry College 16(3): 270-273.<br />

<strong>Bamboo</strong> <strong>for</strong> Pulp, Paper <strong>and</strong> Rayon<br />

131. Adkoli, N.S. 1992. <strong>Bamboo</strong> in pulp production. Proceedings of the National Seminar on<br />

<strong>Bamboo</strong>s, 19-20 December 1990, Bangalore. <strong>Bamboo</strong> Society of India, Bangalore: 45-52.<br />

The present availability of the raw material bamboo <strong>for</strong> production of pulp <strong>and</strong> paper is assessed<br />

<strong>and</strong> an attempt is made to analyse the proposals made in the revised <strong>for</strong>est policy of 1988 regarding<br />

the supply of raw material to industries. Availabilityof wastel<strong>and</strong>s <strong>for</strong> bamboo plantations, investments<br />

<strong>and</strong> ef<strong>for</strong>ts needed to raise such plantations are described.<br />

132. Adkoli, N.S. 1994. <strong>Bamboo</strong> in Indian pulp industry. <strong>Bamboo</strong> in Asia <strong>and</strong> the Pacific.<br />

Proceedings of the Fourth <strong>International</strong> <strong>Bamboo</strong> Workshop, Chiangmai, Thail<strong>and</strong>. (FORSPA<br />

Publication: 6) <strong>International</strong> Development Research Centre <strong>and</strong> FORSPA, Bangkok,<br />

Thail<strong>and</strong>, Canada: 250-254.<br />

Author presents an overview of the raw material, bamboo in Indian pulp industry. The annual<br />

output of bamboo is estimated about 4.6 million tonnes of which about 1.9 million tonnes is reported to<br />

be used by pulp industries. Three main species of bamboos, Dendrocalamus strictus, Bambusa<br />

arundinacea <strong>and</strong> Melocanna baccifera are reported to constitute 83 percent of the total growing stock.<br />

<strong>Bamboo</strong> is reported to be used <strong>for</strong> pulp <strong>and</strong> paper since 1936. Use of bamboo <strong>for</strong> pulping is reported to<br />

be declined from 73.5 percent in 1952 to 26.53 percent in 1988. One rayon-grade pulp mill uses<br />

bamboo as part of raw material. Shortage of about 20.28 million tonnes of raw material by the year<br />

2015 <strong>for</strong> pulp <strong>and</strong> newsprint production is predicted. <strong>Bamboo</strong> yield can be increased 4 to 5 times in<br />

about 5-6 years if scientific harvesting, protection to clumps from fire, grazing <strong>and</strong> biotic influences,<br />

silvicultural tending of clumps are taken care of. The need of raising bamboo plantations in wastel<strong>and</strong>s<br />

<strong>for</strong> increasing the supply of bamboo <strong>for</strong> various purposes including pulp industries is stressed.<br />

133. Azzini, A. 1980. Agronomic aspects of industrial production of bamboo. Papel 41:<br />

87-95.<br />

<strong>Bamboo</strong> is examined in detail with regard to:botanic classification; anatomical <strong>and</strong> agronomic<br />

characteristics; vegetative propagation; flowering <strong>and</strong> fruiting; sexual propagation; production (effect of<br />

spacing, cutting system <strong>and</strong> fertilizer application); potential as a raw material <strong>for</strong> paper making (fibre<br />

dimensions <strong>and</strong> kraft pulp yields <strong>and</strong> strength properties); chemical composition; <strong>and</strong> potential as a<br />

source of alcohol.<br />

134. <strong>Bamboo</strong> <strong>for</strong> paper mills. My<strong>for</strong>est 12(2). 1976: 88-90.<br />

Allotment of bamboo <strong>for</strong>ests <strong>for</strong> paper mills of Karnataka is discussed <strong>and</strong> estimated the yield of<br />

bamboo from the bamboo <strong>for</strong>ests.<br />

135. Beri, R.M; Karnik, M.G; Pharasi, S.C. 1967. A note on Dowga bamboo wax. Indian <strong>for</strong>ester<br />

93(3): 188-189.<br />

Dowga bamboo, Bambusa arundinacea Willd. West Coast Paper Mills Ltd at D<strong>and</strong>eli uses Dowga<br />

bamboo as a supplementary raw materials <strong>for</strong> paper making. They find this species contains a certain<br />

amount of waxin which makes the bamboo difficult to cut in to uni<strong>for</strong>m chips during the culling action<br />

<strong>and</strong> does not permit proper penetration of chemicals during cooking.<br />

136. Bhargava, M.P. 1945. <strong>Bamboo</strong> <strong>for</strong> pulp <strong>and</strong> paper manufacture. Part I - III. Indian Forest<br />

Bulletin (N.S.) Utilization 129.<br />

17


Part I gives an account of investigations from 1860 to 1944 <strong>and</strong> an outline of future investigations.<br />

Part II deals with the digestion of bamboo, <strong>and</strong> part III with its proximate chemical analyses. A series<br />

of appendixes give data on semi-commercial pulping tests, strength properties of kraft pulps, annual<br />

Indian production of papers, <strong>and</strong> proximate chemical analyses of the following species:-<br />

Dendrocalamus strictus(of 8 provenances <strong>and</strong> various stages of development), D. hamiltonii, D.<br />

longispathus, Melocanna bambusoides, Bambusa arundinacea, B. polymorpha, B. tulda, Ochl<strong>and</strong>ra<br />

travancorica, Oxytenanthera nigrociliata <strong>and</strong> Teinostachyum dullooa.<br />

137. Bhargava, M.P; Chattar Singh. 1942. Interim report on the pulping qualities of crushed<br />

<strong>and</strong> uncrushed bamboo chips. Indian Forest Bulletin (N.S.) Utilization. 112: 13p<br />

Samples of chips from Dendrocalamus strictus, (1) crushed, (2) partially : crushed, <strong>and</strong> (3)<br />

uncrushed, were tested <strong>for</strong> uni<strong>for</strong>mity, bleachability <strong>and</strong> pulp yield under the same conditions of<br />

digestion. The most satisfactory in every way was (1), but from a practical point of view, thorough or<br />

even partial crushing of <strong>Bamboo</strong> stems has the disadvantages that power consumed is high, <strong>and</strong> size<br />

of crushed chips is more irregular <strong>and</strong> uneven that that of chips obtained by oblique chipping. An ideal<br />

method would be to cut the <strong>Bamboo</strong> into more or less uni<strong>for</strong>m chips <strong>and</strong> crush the chips, so that the<br />

bundle sheaths of the fibro-vascular bundles would be loosened <strong>and</strong> separated out from the ground<br />

tissues <strong>and</strong> their rigidity reduced, thus giving an easier <strong>and</strong> quicker penetration of the cooking liquors.<br />

It is doubtful, however, whether such a method is practicable.<br />

138. Bourdillon, T.F. 1899. More in<strong>for</strong>mation about bamboos. Indian Forester 25(4): 152-154.<br />

This article is a continuation of author's earlier comments on the article Indian bamboos by D.<br />

Br<strong>and</strong>is which presents some useful in<strong>for</strong>mation like growth <strong>and</strong> flowering of bamboos <strong>and</strong> its use <strong>for</strong><br />

pulp <strong>and</strong> paper.<br />

139. Chang, F.J; Duh, M.H. 1978. Utilization of bamboo residue <strong>for</strong> pulp <strong>and</strong> paper making.<br />

Quarterly Journal of Chinese Forestry 11(3): 51-68.<br />

140. Chen, W.L. 1958. Newest kraft pulp <strong>and</strong> paper mill in Formosa uses bamboo. Paper<br />

Trade Journal 142(36): 40-46.<br />

Describes the preparation of raw material, layout, equipment <strong>and</strong> methods at the mill of the<br />

Longlived Pulp <strong>and</strong> Paper Corp. Ltd., at Chu Nan. Species successfully used are Phyllostachys<br />

retuculata, P. edulis, Bambusa stenostachya <strong>and</strong> Dendrocalamus latiflorus.<br />

141. Ciaramello, D. 1970. <strong>Bamboo</strong> as a papermaking raw material: Study of processes <strong>for</strong><br />

cooking material from Bambusa tuldoides Munro. Bragantia 29(2): 11-22.<br />

142. Ciaramello, D; Azzini, A. 1971. <strong>Bamboo</strong> as a raw material <strong>for</strong> paper. Papel 32: 33-40.<br />

Compare Bambusa vulgaris, B. var. vittata, <strong>and</strong> B. oldhami <strong>for</strong> kraft pulping. B. oldhamii had the<br />

shortest fibres, but was the best suited to kraft pulping, giving the highest yields <strong>and</strong> pulps with the<br />

lowest permanganate number.<br />

143. Correa de A; Luz, C.N.R; Frazao, F.J.L. 1977. Papermaking characteristics of the<br />

bamboos of the State of Acre, Brazil. Acta Amazonica 7(4): 529-550<br />

The bamboos, known locally as tabocas, comprise Guadua angustifolia, G. glomerata, G. morim,<br />

G. superba <strong>and</strong> Nastus [Cenchrus] amazonicus. Data are given on the physical characteristics of the<br />

woods <strong>and</strong> on the properties of chemical, semichemical, chemimechanical <strong>and</strong> mechanical pulps<br />

derived from them. It is concluded that Acre bamboos can be used to make pulp <strong>and</strong> paper, especially<br />

<strong>for</strong> the manufacture of paperboard.<br />

143a. Desp<strong>and</strong>e, P.R. 1953. Indian Pulp <strong>and</strong> Paper 8(3): 167.<br />

144. Dhondiyal, S.N; Bahadur, O; Mathur, G.M. 1973. Pulping of freshly flowered bamboo.<br />

Forestry Product Conference, Dehra Dun.<br />

145. Dobriyal, P.B; Satish Kumar. 1991. Utilization of bamboo in pulp <strong>and</strong> paper. Vigyanik.<br />

18


146. El Bassam, N; Jakob, K. 1996. <strong>Bamboo</strong> - A new source <strong>for</strong> raw materials. First<br />

experimental results. L<strong>and</strong>bau<strong>for</strong>schung- Volkenrode 46(2): 76-83.<br />

147. Escolano, J.O; Semana, J.A. 1970. Bag <strong>and</strong> wrapping papers from Kayuan - Kiling<br />

(Bambusa vulgaris Schrad). The Philippine Lumberman 16(5): 36-40.<br />

Kauayan-kiling (Bambusa vulgaris Schrad) pulped by the sulfate process, using an active alkali of<br />

15.6 gave a screened yield of 41.4 <strong>and</strong> permanganate No. of 15.0. The pulp produced was<br />

characterized by very high tearing resistance but low bursting strengh. The folding <strong>and</strong> tensile<br />

strengths were within the range of imported commercial kraft pulps which were tested <strong>and</strong> used as<br />

st<strong>and</strong>ards. The experimental bag <strong>and</strong> wrapping papers, produced from this pulp were higher in tearing<br />

resistance but lower in burst, folds <strong>and</strong> tensile strengths, compared with those of commercial papers<br />

tested at the Institute. However, when beater adhesives such as starch, guar gum <strong>and</strong> locust-beam<br />

gum were incorporated in pulp furnishes, the burst, folds <strong>and</strong> tensile strengths were considerably<br />

improved, producing high quality bag <strong>and</strong> wraping papers.The resulting papers gave strength<br />

properties superior to those of the commercial papers tested, <strong>and</strong> exceeded the U.S. Federal<br />

Specifications.<br />

148. Forest Products Research <strong>and</strong> Development Institute. 1962. <strong>Bamboo</strong> <strong>for</strong> pulp <strong>and</strong> paper<br />

making. FPRDI, Philippines. Technical Note No. 28: 5p.<br />

149. Frison, E. 1951. <strong>Bamboo</strong> <strong>and</strong> the problem of paper manufacture in the Belgian Congo.<br />

Bull. Agric. Congo Belg. 42(4): 965-986.<br />

Discusses (1) the suitability of Bambusa vulgaris <strong>and</strong> Oxytenanthera abyssinica <strong>for</strong> pulp<br />

manufacture, <strong>and</strong> (2) possible supplies of bamboo <strong>and</strong> hardwoods <strong>for</strong> pulp manufacture in the Belgian<br />

Congo.<br />

150. Fukuyama, G; Kawase, K. 1955. Production of furfural from `Sasa'. II. Production of<br />

furfural <strong>and</strong> plup from `Sasa'. Research Bulletin of Experimental Forestry, Hokkaido<br />

University, Japan 17(2): 383-438.<br />

(1) The highest yield of furfural obtained (11.6%) in these tests was when 100g. of Kumazasa<br />

[Sasa albo-marginata] were autoclaved with 1 litre of 1.5 % H2SO4 at 80 lb./sq. in. <strong>for</strong> 3 hours. (2)<br />

When 200 g. of chips were autoclaved with 1 litre of 0.5 % H2SO4 under various conditions, 58-65% of<br />

the residue was found suitable <strong>for</strong> pulp. When the extraction liquor, adjusted to 1.5 % H2SO4, was<br />

autoclaved at 80 lb./sq. in. <strong>for</strong> 3 hours, a yield of furfural 5.4-6.7% of the oven-dry weight of the chips<br />

was obtained.<br />

151. Garg, R.K; Sharma, R.K; Kothari, R.M. 1998. Some insight on the death of bamboo after<br />

flowering. Indian Forester 124(5): 342-346.<br />

After vegetative growth from rhizomes <strong>for</strong> a period of 50-80 yr, clumps of the bamboo<br />

Dendrocalamus strictus in a particular area undergo flowering, setting free enormous quantities of<br />

seeds <strong>and</strong> die synchronously. Changes in some major chemical constituents (alpha-cellulose,<br />

hemicellulose, reducing sugars, starch, lignin, moisture <strong>and</strong> ash) of stems were monitored at different<br />

stages of the flowering process in specimens from 5 compartments of the Fulchera area of<br />

Bhamragarh Forest Division, Maharashtra, in March (at the start of flowering) <strong>and</strong> May (after flowering)<br />

1994. This was done because there is some evidence in the literature that plant composition may be<br />

related to bamboo mortality after flowering. The analyses suggested that bamboo death may have<br />

been caused by excessive deprivation of reducing sugars <strong>and</strong> moisture content, leading to loss in<br />

vitality <strong>and</strong> osmotic shock along with toxicity generated by an enormous increase in lignin content.<br />

152. Guha, S.R.D. 1960. <strong>Bamboo</strong> <strong>for</strong> pulp <strong>and</strong> paper manufacture - a summary of<br />

investigation at the Forest Research Institute Dehra Dun. ECAFE-FAO-BTAO<br />

Conference on Pulp <strong>and</strong> Paper Development in Asia <strong>and</strong> the far East, October, 1960.<br />

153. Guha, S.R.D. 1960. <strong>Bamboo</strong> pulping in India. ECAFE-FAO-BTAO Conference on Pulp<br />

<strong>and</strong> Paper Development in Asia <strong>and</strong> the far East, 17-31 October 1960.<br />

19


154. Guha, S.R.D. 1961. <strong>Bamboo</strong> as a raw material <strong>for</strong> paper <strong>and</strong> board making. Indian Buyer<br />

1(2).<br />

155. Guha, S.R.D. 1962. <strong>Bamboo</strong> <strong>for</strong> pulp <strong>and</strong> paper manufacture. A summary of the<br />

investigations at the Forest Research Institute, Dehra Dun. In: FAO Pulp <strong>and</strong> Paper<br />

Prospects in Asia <strong>and</strong> the far East Vol.2.<br />

156. Guha, S.R.D. 1962. <strong>Bamboo</strong> pulping in India. In: FAO, Pulp <strong>and</strong> Paper Prospects in Asia<br />

<strong>and</strong> the far East Vol.2.<br />

157. Hunter, I.R. 2002. Writing on bamboo. INBAR News Magazine 9(1): p14.<br />

158. <strong>International</strong> <strong>Network</strong> <strong>for</strong> <strong>Bamboo</strong> <strong>and</strong> <strong>Rattan</strong>. 1977. <strong>Bamboo</strong> <strong>for</strong> pulp <strong>and</strong> paper. INBAR<br />

News Magazine 5(3): p29.<br />

159. Istas, J.R; Heremans, R; Raekaelboom, E.L. 1956. The paper making qualities of some<br />

bamboos grown in the Belgium Congo. Bulletin Agriculture Congo belge 47(5):<br />

1299-1325.<br />

Tabulates the mineral, cellulose <strong>and</strong> lignin composition <strong>and</strong> the fibre dimensions of 10 exotic<br />

bamboos, from culm samples of different age <strong>and</strong>, in one species, from 3 different soils. Also<br />

tabulated are the properties of the pulps <strong>and</strong> papers prepared from some of them, using 3 methods of<br />

cooking. Good sulphate pulps are obtainable but, except in tearing strength, the resulting papers are<br />

inferior to those of a medium-quality kraft. It is possible that pressure-impregnation cooking would<br />

improve quality. Bambusa vulgaris <strong>and</strong> its var. striata gave the best pulps. Sasa kurilensis <strong>and</strong> S.<br />

japonica do not appear suitable <strong>for</strong> unbleached pulp. Three months of water storage did not reduce<br />

Dinoderus attack. Though one-year culms are usable, it is better to use older ones. Soil affects paper<br />

quality <strong>and</strong> more investigations of the effect of site are required. In addition to those mentioned, the<br />

samples included Dendrocalamus strictus, Gigantochloa ater, Ochl<strong>and</strong>ra travancorica (<strong>for</strong> all of which<br />

pulp <strong>and</strong> paper data are presented), Dendrocalamus longispathus, Gigantochloa apus <strong>and</strong> G.<br />

varticillata.<br />

160. Istas, J.R; Raekaelboom, E.L. 1962. A biometric, chemical <strong>and</strong> paper making study of<br />

Congo bamboos. Publ. Inst. Nat. Etude Agron. Congo (Ser. Tech.) No. 67: 53p.<br />

Gives data on wood density, fibre characteristics, chemistry, cooking schedules <strong>and</strong> pulp <strong>and</strong><br />

paper properties of (a) Bambusa vulgaris, (b) Oxytenanthera abyssinica, (c) Arundinaria alpina, <strong>and</strong> (d)<br />

Gigantochloa aspera, with general notes on production, storage, addition of hardwood or softwood pulp<br />

to improve pulp quality, etc. The best papermaking pulps were got from (a) which can be cut, on a 2year<br />

cycle to produce 50 tons of culms/ha. A good yield of pulp, inferior in quality to that of the other<br />

species is obtained from (b); (c) appears best suited <strong>for</strong> the (weaker) bleached pulps, <strong>and</strong> (d) gives<br />

pulps similar in quality to those of (a).<br />

161. Jamaludin K; Jalil A.A; Abd. Latif Mohmod. 1993. Pulp <strong>and</strong> papermaking properties of 1-,<br />

2- <strong>and</strong> 3-year old Gigantochloa scortechinii. <strong>Bamboo</strong> <strong>and</strong> its Use. <strong>International</strong><br />

Symposium on Industrial Use of <strong>Bamboo</strong>, 7-11 December 1992, Beijing, China. Inernational<br />

Tropical Timber Organization, Beijing: 264-273.<br />

The effects of age, active alkali <strong>and</strong> beating revolutions on the pulping characteristics of one to<br />

three years old Gigantochloa scortechinii were determined <strong>and</strong> the results are discussed in this paper.<br />

The proximate chemical analysis <strong>and</strong> fiber morphology are also determined. The fibers of the bamboo<br />

are long about 3.0 - 3.7 mm with thick cell wall of 7µ m. It is reported that the high Runkel <strong>and</strong> low<br />

flexibility ratio which imply to its unsuitability <strong>for</strong> papermaking can be compensated by the high<br />

slenderness ratio <strong>and</strong> high holo-cellulose content. The low ash content in G. scortechnii is beneficial to<br />

the pulping process. Pulp properties of one to three year old bamboo shows satisfactory strength<br />

properties.<br />

162. Joglekar, M.H; Donofrio, C.P. 1951. Disolving pulp from bamboos. TAPPI Journal 34(6).<br />

20


163. Kiang, T; Lin, W.C. 1978. A research on bamboo resources in Sabah [including<br />

potential uses <strong>and</strong> processing facilities]. Quarterly Journal of Chinese Forestry 11(3):<br />

17-33.<br />

164. Kitamura, H; Sakamoto, I; Nagashima, T. 1974. On the quadrangular bamboo culms -<br />

Forms of culms <strong>and</strong> the anatomy, with special reference to their fibres <strong>and</strong> vascular<br />

bundles. Bulletin of the Utsunomiya University Forests No. 11: 71-86.<br />

<strong>Bamboo</strong> square in section can be grown artificially; in Japan Phyllostachys heterocycla f.<br />

pubescens is usually chosen because of the thickness of its culm. Square culms of P.h.f. pubescens<br />

were produced by placing a wooden frame round each sprout <strong>and</strong> <strong>for</strong>cing it to grow inside. The <strong>for</strong>m of<br />

the culms, the size of the vascular bundles <strong>and</strong> the characteristics of the fibres <strong>and</strong> parenchyma cells<br />

were investigated in comparison with normal culms. Internode length was shorter than in a normal<br />

culm. Vascular bundles with values of


173. Maheshwari, S; Satpathy, K.C. 1984. Pulp <strong>and</strong> papermaking characteristics of bamboos<br />

of different age. Indian Pulp <strong>and</strong> Paper 38(4).<br />

174. Maheshwari, S; Satpathy, K.C. 1984. Studies on pulp <strong>and</strong> paper-making characteristics<br />

of bamboo of different ages. Indian Pulp <strong>and</strong> Paper 38.<br />

175. Maheshwari, S; Satpathy, K.C. 1988. Pulp <strong>and</strong> papermaking characteristics of nodes,<br />

internodes <strong>and</strong> culm of bamboo, Dendrocalamus strictus. IPPTA 25(1): 15-19.<br />

This paper deals with the evaluation of nodes <strong>and</strong> internodes of D. strictus <strong>and</strong> comparison of their<br />

pulp <strong>and</strong> paper making properties. The study reveals that nodal <strong>and</strong> internodal portions of bamboo<br />

culm differ in their chemical constituents. Internodal portion of bamboo has higher holocellulose <strong>and</strong><br />

lower pentosions, extractives, ash <strong>and</strong> lignin compared to nodal portion. The pulp yield is lower with<br />

more rejects in case of nodal portion. The chemical requirement <strong>and</strong> bleachability are same under the<br />

identical conditions. The bleached pulp viscocity is lower in case of pulp from nodal portion. The fibre<br />

morphological characters <strong>and</strong> Bauer Mc Nett classification results show that pulp from nodal portion<br />

has comparatively lower fiber length than internodal portion. The strength properties of bleached pulp<br />

of nodal portion are comparatively lower. As such bamboo culm show the intermediate trend in all the<br />

properties.<br />

176. Maheshwari, S; Satpathy, K.C. 1988. The efficient utilization of bamboo <strong>for</strong> pulp <strong>and</strong><br />

paper making. In: <strong>Bamboo</strong>s: Current Research. Proceedings of the <strong>International</strong> <strong>Bamboo</strong><br />

Workshop, 14-18 November 1988, Cochin, India (edited by Rao, I.V.R., Gnanaharan, R.,<br />

Sastry, C.B), Kerala Forest Research Institute, Peechi <strong>and</strong> IDRC, Canada.<br />

The pulping characteristics of (a) bamboo of different ages (b) different portions of the culm <strong>and</strong><br />

(c) a few common varieties of bamboo are studied <strong>and</strong> the results are discussed. Effective methods of<br />

proper h<strong>and</strong>ling <strong>and</strong> storage of bamboo are also suggested.<br />

177. Mai-Aung, U; Fleury, J.E. 1960. Breakthrough in bamboo pulping. Pulp <strong>and</strong> Paper<br />

<strong>International</strong> 2(5): 21-23.<br />

178. Matsui, Z. 1963. On the ecological <strong>and</strong> silvicultural treatment of Sasa bamboo <strong>and</strong> its<br />

industrial utilisation in Hokkaido. Annul Report of Forest Experimental Station, Hokkaido,<br />

Japan: 186-229.<br />

On account of the importance of Sasa bamboo (including Sasa, Sasamorpha <strong>and</strong><br />

Neosasamorpha) <strong>for</strong> <strong>for</strong>estry in Hokkaido. It is estimated that 70 of the <strong>for</strong>est undergrowth is<br />

composed of Sasa s.l. The larger species (e.g. Sasa kurilensis) provide a raw material <strong>for</strong> pulp <strong>and</strong><br />

chipboard, yielding 50-60 tons/ha. when clear-cut be<strong>for</strong>e af<strong>for</strong>estation. Smaller species (e.g. S.<br />

nipponica) are used as fodder. Utilization costs are tabulated. All species supress the regeneration of<br />

useful trees: the power of regrowth of different species after weeding <strong>and</strong> other control methods under<br />

experimental conditions is recorded.<br />

179. Mazzei, F.M; Rediko, B.V.P. 1967. Pulp <strong>for</strong> paper making from bamboo. Publicacao,<br />

Instituto de Pesquisas Technologicas, Sao Paulo, No. 796: 7p.<br />

Describes trials in the sulphate pulping of 1- to 5-year-old culms of Bambusa vulgaris, B. vulgaris<br />

var. vittata, <strong>and</strong> B. tuldoides, the most common <strong>Bamboo</strong>s found in southern Brazil. Preliminary results<br />

indicate that high yields <strong>and</strong> pulp of good quality, especially as regards tearing strength, can be<br />

obtained. One-year-old culms gave the best results.<br />

180. McGorovern, J.N. 1967. Progress <strong>and</strong> problems in production of pulp from bamboo.<br />

Paper Trade Journal 151: 33-35.<br />

181. Medina, J.C; Ciaramello, D. 1965. The effect of culm age on the paper making qualities<br />

of Bambusa vulgaris. Bergantia Compinas 24(32): 411-435.<br />

Culms (from 15 years-old clumps at Campinas, Brazil) ranging from 1 to 4 years in age were<br />

pulped by the soda process. The effect of culm age on pulp yield was singnificant at the 5 level <strong>for</strong> 2year-old<br />

culms only. No effect on tearing, tensile, or folding strength could be attributed to culm age.<br />

22


Paper from 2-year-old culms; however, had a significantly higher bursting strength. Pulps were in<br />

general highly porous. B. vulgaris can produce paper in tearing strength. From the industrial<br />

st<strong>and</strong>point no advantage is gained by selecting culms of a particular age.<br />

182. Mukherjea, V.N. 1967. Utilisation of bamboos <strong>for</strong> cheap grade paper. Indian Pulp <strong>and</strong><br />

Paper 22(3): 181-186.<br />

Discusses an investigation on the efficiency of a binary pulping process (patented) <strong>for</strong> bamboo<br />

(Dendrocalamus strictus). The chips (dry or steamed) are disintergrated by a kollergang or a refiner,<br />

<strong>and</strong> separated by screening into (a) prosenchymatous <strong>and</strong> (b) parenchymatous tissues. These tissues<br />

are pulped separately, (a) by the sulphate process <strong>and</strong> (b) mechanically. The pulps are then mixed to<br />

obtain the maximum yield of paper of acceptable strength. It is concluded from the results (tabulated)<br />

of 10 different experimental treatments of (a) <strong>and</strong> (b) that: a yield of satisfactory pulp of up to 75 (based<br />

on oven-dry chips) is obtainable; pulping procedures that give yields of ca. 40-45 bleached chemical<br />

pulp from (a) <strong>and</strong> ca. 29-25 mechanical pulp from (b), enabling pulp mixtures with >50 chemical pulp<br />

to be used, are recommended; chips should be steamed; <strong>and</strong> a refiner is more suitable than a<br />

kollergang, both <strong>for</strong> disintegrating chips <strong>and</strong> <strong>for</strong> grinding (b).<br />

183. Nomura, T. 1999. <strong>Bamboo</strong> utilization in Myanmar. Wood Research No. 86: 9-18.<br />

The role of bamboo in Myanmar, smoke drying <strong>and</strong> use in pulping <strong>and</strong> charcoal manufacture are<br />

outlined.<br />

184. Ono, K. 1996. Tropical bamboo <strong>for</strong> remarkable pulp resources. Nippon Nogeikagaku<br />

Kaishi 70(4): 469-474.<br />

Including brief data on Gigantochloa apus, Bambusa vulgaris, G. nigro-ciliata, G. verticillata.<br />

185. Papers from the First National <strong>Bamboo</strong> Symposium-Workshop, 27th February <strong>and</strong> 1st<br />

March, 1989. Sylvatrop 13(1/2). 1988: 93p.<br />

Ten papers are presented in this symposium-workshop which was sponsored by the Philippines<br />

<strong>Bamboo</strong> Research <strong>and</strong> Development Project. The project was started in 1987 by the Philippines<br />

Ecosystems Research <strong>and</strong> Development Bureau (<strong>for</strong>merly the Forest Research Institute), assisted by<br />

UNDP, <strong>and</strong> with FAO as the executing agency. The primary function of the 5-yr project is<br />

experimental/pilot plantation establishment <strong>and</strong> associated research, <strong>and</strong> the aims are to create new<br />

sources of employment <strong>and</strong> income inrural areas of the country.<br />

186. Pearson, R.S. 1912. Note on the utilization of bamboo <strong>for</strong> the manufacture of paperpulp.<br />

Indian Forest Records: 4(5): 159-277<br />

An investigation is carried out to see the possibility of manufacturing pulp from bamboos. The<br />

report deals with areas from which bamboos could be exploited easily <strong>for</strong> the purpose of manufacturing<br />

pulp in Burma <strong>and</strong> West Coast of India. The places are inspected <strong>and</strong> figures of yield are also given.<br />

Possible sites <strong>for</strong> bamboo paper-pulp mills in the Bombay <strong>and</strong> Madras presidency are also given. A<br />

history of work carried out with a view of ascertaining the possibility of manufacturing paper-pulp from<br />

bamboo is also given. General conditions necessary <strong>for</strong> the successful establishment of a paper-pulp<br />

mill <strong>and</strong> the mode of growth <strong>and</strong> the possible outturn are also discussed. Flowering, felling, cost of<br />

extraction <strong>and</strong> cost of manufacturing bamboo paper-pulp are also briefly discussed. Cost of plant<br />

required <strong>for</strong> a mill <strong>and</strong> the chemicals available are also discussed.<br />

187. Pearson, R.S. 1920. The utilisation of bamboo <strong>for</strong> the manufacture of paper-pulp.<br />

Indian Forester 46(12): 603-631.<br />

Suitable areas <strong>for</strong> extracting bamboos <strong>for</strong> pulp <strong>and</strong> paper in India <strong>and</strong> Burma are recorded in this<br />

paper. Descriptions of the bamboo <strong>for</strong>ests, means of transporting the extracted bamboo, cost of cutting<br />

<strong>and</strong> extraction <strong>and</strong> possible factory sites are also discussed.<br />

188. Pearson, R.S. 1920. The utilization of bamboo <strong>for</strong> the manufacture of paper-pulp. Indian<br />

Forester 46(11): 547-561.<br />

23


A brief review of pre-<strong>and</strong> post-war conditions of the utilisation of bamboo <strong>for</strong> the manufacture of<br />

paper-pulp is given by the author. Descriptions of some of the bamboo areas in Burma <strong>and</strong> India are<br />

also given.<br />

189. Seabra, L-de. 1954. <strong>Bamboo</strong>s in the pulping industry. Estude Ensaios e Dpcum. Junta<br />

Invest. Ultramar, Lisboa 13: 91p.<br />

Presents some general in<strong>for</strong>mation on the characteristics of bamboo compared with other papermaking<br />

species (viz. size <strong>and</strong> shape of fibres, chemical properties of the wood <strong>and</strong> cellulose, <strong>and</strong> the<br />

industrial value of bamboo pulps) <strong>and</strong> gives the results of preliminary trials with Oxytenanthera<br />

abyssinica from Mozambique <strong>and</strong> Guinea to determine its suitability <strong>for</strong> commercial pulping. The<br />

investigations deal with the dimensions of the fibres, the chemical properties of the sawdust <strong>and</strong> of<br />

pulps, <strong>and</strong> the physical <strong>and</strong> mechanical properties of the pulps. It is concluded that pulps from these<br />

African bamboos have properties equal or superior to Indian bamboo pulps, but more data is needed<br />

be<strong>for</strong>e they can be recommended <strong>for</strong> commercial production.<br />

190. Shanmughavel, P. 1995. Bambusa bambos - an ideal species <strong>for</strong> commercial<br />

plantation. <strong>International</strong> Tree Crops Journal 8(4): 203-212.<br />

Over-exploitation <strong>and</strong> shrinkage of their natural habitats is depleting the bamboo resource in India<br />

at an alarming rate. Sustained availability can be ensured only by plantations. This paper describes the<br />

establishment, growth <strong>and</strong> biomass production of a trial plantation of Bambusa bambos at Kallipatty,<br />

Tamil Nadu. This proved to be an ideal species <strong>for</strong> large-scale plantations. Pulp characteristics<br />

including proximate chemical analysis data <strong>for</strong> 1-6 yr old culms, utilization <strong>and</strong> economic aspects, costs<br />

<strong>and</strong> returns from a 6-yr-old plantation are discussed.<br />

191. Sheikh, M.A. 1983. The environmental aspects of using bamboo in the manufacture of<br />

pulp <strong>and</strong> paper in Bangladesh. Industry <strong>and</strong> Environment 6(1): 14-17.<br />

192. Sindall, R.W. 1909. <strong>Bamboo</strong> <strong>for</strong> Papermaking. Marchant Singer & Co, London: 59p.<br />

An account of the results of the experimental work done <strong>for</strong> the conversion of bamboo into paper<br />

is given here. It reports that the utilization of bamboo as a regular source of supply <strong>for</strong> paper pulp was<br />

initiated in 1870. It attempts to collect the available data on bamboo pulping <strong>and</strong> present it in a<br />

condensed <strong>for</strong>m. It is also discussed the habit <strong>and</strong> growth, flowering, propagation of bamboos <strong>and</strong> the<br />

supply of the material to the paper mills. <strong>Bamboo</strong> is found to be suitable <strong>for</strong> paper making as it is<br />

capable of st<strong>and</strong>ing considerable wear <strong>and</strong> tear. A small plant capable of making 8-12 tons of bamboo<br />

pulp is erected <strong>and</strong> the method of working of this plant is described. Table is provided to show the<br />

behaviour of bamboo paper when compared with an ordinary super-calendered printing of similar<br />

quality. Plant required <strong>for</strong> a paper mill having a weekly output of 200 tons of unbleached pulp is also<br />

discussed.<br />

193. Singh, S.V; Bh<strong>and</strong>ari, S.S; Singh, S.P. 1989. Organosolve pulping of Dendrocalamus<br />

strictus <strong>and</strong> Eucalyptus tereticornis with aquous ethanol. Paper presented in the IPPTA<br />

Silver Jubilee <strong>International</strong> Seminar <strong>and</strong> Workshop on Appropriate Technologies <strong>for</strong> Pulp<br />

<strong>and</strong> Paper Manufacture in Developing Countries. 1989, New Delhi.<br />

194. Singh, S.V; Guha, S.R.D. 1981. Indian experience of papermaking from bamboo.<br />

Proceedings of <strong>Bamboo</strong> Production <strong>and</strong> Utilization XVII IUFRO World Congress, 6-17<br />

September 1981, Kyoto, Japan. Wood Research Institute, Kyoto University, Kyoto: 33-38.<br />

This paper gives a brief account of various kinds of bamboos occurring in India <strong>and</strong> of the<br />

chemical <strong>and</strong> morphological characteristics of major species used <strong>for</strong> paper making. Research carried<br />

out on pulping <strong>and</strong> bleaching, effect of morphological characteristics <strong>and</strong> sheet properties, beating<br />

properties <strong>and</strong> decay on storage <strong>and</strong> its effect on pulp properties are reviewed. A brief description<br />

about industrial paper making is also given.<br />

195. Stracey, P.D. 1957. The rational utilisation of India's cellulosic raw materials with<br />

particular reference to Assam. Indian Forester 83(4): 253-259.<br />

Author brings out the importance of the vast untapped reserve of bamboos in Assam in the light of<br />

the country's potential requirements.<br />

24


196. Suleiman, K.M. 1994. <strong>Bamboo</strong> as a source of long fiber pulp in Pakistan. Pakistan<br />

Journal of Forestry 44(3): 130-135.<br />

Three bamboo species (Dendrocalamus hamiltonii, D. strictus, Bambusa tulda) were pulped<br />

successfully by the soda process. D. hamiltonii gave the highest yield <strong>and</strong> best tearing strength<br />

properties - which were comparable to those of kraft pulp from Pinus roxburghii <strong>and</strong> imported Southern<br />

pine kraft pulp. However, the bonding properties of bamboo pulp were inferior to those of softwood<br />

kraft pulp. The advantages of using bamboos <strong>for</strong> pulpwood production <strong>and</strong> pulping are outlined.<br />

197. Susuki, S. 1977. The range of the genus Sasa Makino et Shibata, S. quelpratensis <strong>and</strong><br />

S. chartacea. Hikobia 8(1/2): 165-167.<br />

Septate fibres were found to occur in Dendrocalamus latiflorus, Phyllostachys edulis,<br />

Schizostachyum brachycladum <strong>and</strong> Oxytenanthera abyssinica. Their characteristics <strong>and</strong> fine structure<br />

are described <strong>and</strong> illustrated with electron micrographs.<br />

198. Tissot, M. 1970. <strong>Bamboo</strong> as raw material <strong>for</strong> the Indian paper industry. Bios. For. Trop.<br />

129: 21-45.<br />

Discusses the problems of making pulp <strong>and</strong> paper from bamboo on the basis of a study of four<br />

Indian mills at which bamboo (mainly Dendrocalamus strictus) is being successfully used, although the<br />

pulps have relatively poor mechanical properties. The cooking processes used (kraft, sulphate <strong>and</strong><br />

neutral sulphite) are reviewed, details of the bleaching <strong>and</strong> refining procesures are given, <strong>and</strong> the<br />

solutions devised to overcome problems of blade wear <strong>and</strong> the presence of Si are described. Data on<br />

costs of the raw material <strong>and</strong> pulps are included.<br />

199. Tshiamala T. 1984. The technology of bamboo as raw material <strong>for</strong> the paper industries<br />

<strong>and</strong> fermentation industries. Gembloux, Belgium. Faculte des Sciences Agronomiques de<br />

l' Etat, Gembloux: 174p.<br />

200. Tshiamala, T; Mottet, A; Fraipont, L; Thonart, P; Paquot, M. 1985. The <strong>Bamboo</strong>: Raw<br />

material <strong>for</strong> Paper Industries or Fermentation Industries. Energy from biomass: 3rd E.C.<br />

conference, held Venice 25-29 March 1985. Elsevier Applied Science Publishers, London,<br />

UK: 1122-1125.<br />

A summary of published work including the characteristics of pulps produced by sulphate, sulphite,<br />

lime <strong>and</strong> thermomechanical methods.<br />

201. Tutiya, M; Hukuhara, S; Kato, Y. 1941. <strong>Bamboo</strong>s in Taiwan as a raw material <strong>for</strong> pulp.<br />

Part V. Journal of Agric. Chem. Soc. Japan 17: 479-482.<br />

202. Tutiya, M; Imai, M. 1940. Researches on bamboo in Taiwan as a raw material <strong>for</strong> pulp.<br />

Part IV. On the ashes <strong>and</strong> some characters of pulps <strong>and</strong> alpha-cellulose obtained by<br />

different digesting methods. Journal of Agric. Chem. Soc. Japan 16: 126-129, 755-760.<br />

203. Ukil, T. 1961. <strong>Bamboo</strong> <strong>and</strong> its paper making value. Zellstoff 4. Papier 10(4): 149-151.<br />

204. Villavicencio, E.J. 1990. Process <strong>for</strong> making a pulp from bamboo. Makati, Metro Manila,<br />

Philippines, Philippine Patents Office. Process Evaluation <strong>and</strong> Development Corporation,<br />

Dallas, Texas, Delaware: 18p.<br />

<strong>Bamboo</strong> can be <strong>for</strong>med into a suitable pulp if prior to digestion, it undergoes a process of<br />

shredding, washing, <strong>and</strong> wet depithing. The fibers are then chemically digested preferably by a<br />

process which uses rapid pressure drops to open the fibers using the energy contained in the wet<br />

superheated fibers.<br />

205. Vincent, H. 1911. <strong>Bamboo</strong> pulp as the paper material of the future. Indian Forester<br />

37(11): 627-630.<br />

The advantages of using bamboo pulp as the paper material are pointed out by the author.<br />

25


206. Virtucio, F.D; Uriate, M.T; Uriate, N.S. 1992. Pulp yield <strong>and</strong> physico-mechanical<br />

properties of six Philippine bamboo species <strong>and</strong> the implications on optimal<br />

harvesting age. Proceedings of the Second National <strong>Bamboo</strong> Research <strong>and</strong> Development<br />

Symposium, College, Laguna 14th December 1990. Ecosystems Research <strong>and</strong><br />

Development Bureau, College, Laguna, United Nations Development Programme, Makati,<br />

Metro Manila, Food <strong>and</strong> Agriculture, Manila: 78-92.<br />

The effect of culm age on pulp yield <strong>and</strong> some physico-mechanical properties of six important<br />

bamboo species: kauayan tinik (Bambusa blumeana), bayog (B. blumeana var. luzonensis), grant<br />

bamboo (Dendrocalamus asper), bolo (Gigantochloa levis), buho (Schizostachyum lumampao) <strong>and</strong><br />

kauayan kiling (Bambusa vulgaris) were studied. The study revealed that there was considerable<br />

variation with regard to specific gravity, shrinkage, compressive strength, stress at proportional limit,<br />

modulus of rupture, modulusof elasticity, <strong>and</strong> pulp yield among the six bamboo species relative to culm<br />

age. In general, the maximum physico-mechanical properties <strong>and</strong> pulp yield were attained between<br />

pulp ages of 2 to 5 years-old which could provide a vital in<strong>for</strong>mation in determining the optimum culm<br />

age <strong>for</strong> harvesting which vary among the six bamboo species.<br />

207. Waheed Khan, M.A. 1972. Sporadic <strong>and</strong> gregarious bamboo flowering in relation to<br />

pulpwood production <strong>and</strong> management. IPPTA Seminar, Dehra Dun: 2 p.<br />

The paper discusses sporadic <strong>and</strong> gregarious flowering of bamboos <strong>and</strong> the methods of<br />

management of the flowered areas.<br />

208. Wai, N.N; Murakami, K. 1983. Papermaking characteristics of Burmese bamboo<br />

Bambusa polymorpha fiber in comparison with wood fiber. Journal of the Japan Wood<br />

Research Society 29(10): 708-715.<br />

209. Wilson, J; Hayes, M.H.B; Schallinger, K.M. 1983. <strong>Bamboo</strong>, grown on blanket peats, as a<br />

raw material <strong>for</strong> cellulosic pulp. Proceedings of the Second <strong>International</strong> Symposium:<br />

Peat in Agriculture <strong>and</strong> Horticulture. Hebrew University of Jerusalem, Rehovot, Israel:<br />

223-239.<br />

The bamboo varieties Arundinaria anceps <strong>and</strong> A. japonica can be grown on Blanket peats to<br />

provide economic yields of pulp appropriate <strong>for</strong> paper manufacture. A. anceps provided the higher<br />

quality pulp <strong>and</strong> was more suitable <strong>for</strong> mechanical harvesting. <strong>Bamboo</strong> grown on relatively poorly<br />

humified Blanket peat will incur plasmolysis when supplied solely with soil-applied commercial<br />

fertilizers. Applications of slow release fertilizers, <strong>and</strong> of boron <strong>and</strong> copper avoids plasmolysis while<br />

supplying N, P <strong>and</strong> K, <strong>and</strong> confers resistance to frost <strong>and</strong> to flowering, respectively. Proposals are<br />

made <strong>for</strong> the preparation of Blanket peats to support bamboo st<strong>and</strong>s, <strong>for</strong> the management of the<br />

st<strong>and</strong>s, <strong>and</strong> <strong>for</strong> the selection of improved varieties.<br />

210. Witkoski, C.J. 1964. <strong>Bamboo</strong> in pulp <strong>and</strong> paper manufacture. ATCP 4(2): 122-129.<br />

211. Ye, K.L. 1993. The characteristics <strong>and</strong> industrial utilization of bamboo. Wood Industry<br />

Beijing 7(2): 33-36.<br />

An outline of the characteristics <strong>and</strong> uses of bamboo in structural applications <strong>and</strong> <strong>for</strong> pulping in<br />

China is given.<br />

212. Zhang, Q.S; Luo, L.F; Wu, H.Y; Lin, J.H; Tian, X.P. 1998. Pleioblastus amarus - an elite<br />

cash bamboo. Journal of <strong>Bamboo</strong> Research 17(4): 51-53.<br />

The shoots of Pleioblastus amarus, a Chinese bamboo species, are edible, with a good taste, <strong>and</strong><br />

have medicinal properties (antipyretic <strong>and</strong> detoxifying). The species can also be used <strong>for</strong> pulp <strong>and</strong><br />

papermaking <strong>and</strong> other wood products, including silk umbrellas <strong>for</strong> tourists, folding fans, curtains,<br />

musical instruments, <strong>and</strong> chopsticks. It is, there<strong>for</strong>e, of high economic value <strong>and</strong> suitable <strong>for</strong> increased<br />

exploitation in the Chinese bamboo industry.<br />

26


213. Zhang, W.Y; Zhou, D.S; Ma, N.X; Yi, C.Q; Cao, D.Y; Zhang, H.M. 1997. A propagation test<br />

with culm nodes of sympodial bamboo species <strong>for</strong> pulping. Forest Research 10(4):<br />

425-428.<br />

The vegetative propagation 5 bamboo species suitable <strong>for</strong> pulpwood production (Bambusa textilis<br />

var. fasca, B. multiplex, B. gibba, B. chungii, Neosinocalamus affinis) was investigated using culm<br />

node cuttings. Of the 3 planting methods tested, flat planting was better than slanted or vertical<br />

planting. There were significant differences in survival of cuttings between between species <strong>and</strong> node<br />

ages, but no significant differences between growing seasons (March or May). The results of tests with<br />

cuttings of different thickness (2.5 <strong>and</strong> 4.6 cm in diameter), from different positions (higher <strong>and</strong> lower),<br />

<strong>and</strong> with single- or double-internodes suggested that survival rates were better with cuttings taken from<br />

thinner culms, a higher position, <strong>and</strong> with doublThe possibility of growing endemic species of rattan<br />

(Calamus spp.) under rubber in Sri Lanka as a secondary crop <strong>for</strong> production of h<strong>and</strong>icrafts is briefly<br />

discussed with reference to the success of such operations in Malaysia.<br />

214. Zhang, X. 1995. Fibre <strong>and</strong> paper-making properties of the main bamboo species in<br />

Guizhou. Journal of <strong>Bamboo</strong> Research 14(4): 14-30.<br />

The fibre <strong>and</strong> paper-making properties of 22 bamboos species are described.<br />

215. Zhen-xing,S; Tian-jian, H; Guang-zhi, Z; Shao-nan, C. 1990. Development of a bamboo<br />

base <strong>and</strong> its use as a raw material in the paper industry. <strong>Bamboo</strong>s: Current Research.<br />

Proceedings of the <strong>International</strong> <strong>Bamboo</strong> Workshop, 14-18 November 1988, Cochin, India.<br />

Kerala Forest Research Institute, Peechi <strong>and</strong> IDRC, Canada: 283-285.<br />

The importance of replacing wood with bamboo <strong>for</strong> paper-making is emphasized. A case history<br />

of raising bamboo plantation as a joint ef<strong>for</strong>t between a big paper industry <strong>and</strong> government is<br />

illustrated.<br />

Species Suitability <strong>for</strong> Pulp <strong>and</strong> Paper<br />

216. <strong>Bamboo</strong>s in Siam suitable <strong>for</strong> pulp. Indian Forester 52(4). 1926: p146<br />

<strong>Bamboo</strong>s Cephalostachyum pergracile, Bambusa polymorpha <strong>and</strong> Bambusa arundinacea which<br />

are suitable <strong>for</strong> making pulp are reported from Siam.<br />

217. Bhargava, G.G; Dwivedi, R.P; Mohan, S.M. 1985. Pulping studies on bamboos (Assam<br />

green bamboo <strong>and</strong> old bamboo) hard woods (sal scantling <strong>and</strong> salai), mixed bamboos<br />

+ mixed hard wood (70: 30) <strong>and</strong> mills chips. IPPTA 22(3): 12-18.<br />

Assam green bamboo, old bamboo, mixed bamboo (A), sal scantling, salai, mixed hard wood (B),<br />

mixed bamboo (A) + mixed hard woods (B) (70:30) <strong>and</strong> mill chips are evaluated <strong>for</strong> chips classification,<br />

bulk density, proximate chemical analysis, kraft pulping, bleaching <strong>and</strong> physical strength properties. It<br />

is reported that hardwoods need higher alkali than bamboo <strong>for</strong> producing bleachable grade pulp. It is<br />

also reported that the pulps in higher yield can be produced by separate digestions <strong>and</strong> separate<br />

bleaching of bamboos <strong>and</strong> mixed hard woods instead of mixed digestion of these two raw materials of<br />

heterogenous nature. Mixed hard woods used upto 30 per cent in the mixed furnish has no detrimental<br />

effect on pulping quality <strong>and</strong> the physical strength properties.<br />

218. Bhola, P.P. 1976. Pulping studies of hill jati bamboo (Bambusa tulda) from Cachar<br />

Hills. Indian Forester 102(4): 242-246.<br />

Proximate chemical analysis <strong>and</strong> fibre dimensions of Hill Jati <strong>Bamboo</strong> growing in Cachar Hills<br />

(Bambusa tulda) are given. The paper present results of pulping <strong>and</strong> bleaching studies. It is suggested,<br />

based on the results, that this species of bamboo issuitable <strong>for</strong> manufacturing wrapping, writing <strong>and</strong><br />

printing papers.<br />

219. Istas, J.R; Hontoy, J. 1952. The chemical composition <strong>and</strong> paper making qualities of<br />

some bamboos harvested in Belgium Congo. Publ. Inst. Nat. Etude agron Congo belge<br />

(Ser. Tech) No. 41: 23p.<br />

27


Gives the results of chemical analyses <strong>and</strong> pulping <strong>and</strong> paper-making tests of Sasa japonica, S.<br />

kurilensis, Bambusa hoffii, B. vulgaris, Gigantochloa asper <strong>and</strong> Ochl<strong>and</strong>ra travancorica.<br />

220. Istas, J.R; Raekaelboom, E.L. 1960. Paper making from a mixture of M. smithii <strong>and</strong> B.<br />

vulgaris. Bulletin of Agriculture. Congo Belge 51(2): 393-402.<br />

221. Kala, R.P. 1973. Flowering of bamboo in relation to paper manufacture. Northern Forest<br />

Rangers College Magazine 27: 5p.<br />

The phenomenon of flowering is described with particular reference to bamboo species used <strong>for</strong><br />

paper manufacture. The difficulties experienced by paper mills in exploitation of the flowered bamboos<br />

are described <strong>and</strong> solutions to these problems are suggested.<br />

222. Kang, Z.Y; Hwang, S.G; Kang, T.Y; Huang, S.K. 1975. Adaptability study on Bambusa<br />

beecheyana var. pubescens grown in Taiwan. Bulletin, Taiwan Forestry Research<br />

Institute 264: 7p.<br />

This variety is the fastest-growing <strong>Bamboo</strong> in Taiwan <strong>and</strong> has the thickest culm wall; it is<br />

recommended <strong>for</strong> pulping. The results of 5-year-old trials (begun in 1965) on three contrasting sites in<br />

S. central Taiwan are reported. The yield of culms was considerably greater on a good lowl<strong>and</strong> site<br />

(Chia-Yi) than on a fairly poor hill site (Lien-Hua-Chi); however, the size of the culms <strong>and</strong> the total<br />

weight of rhizomes varied relatively little between sites.<br />

223. Kedharnath, S; Chatterji, R.N. 1966. A valuable exotic bamboo (Phyllostachys<br />

bambusoides) in Himachal Pradesh. Indian Forester 92(6): 428-431.<br />

The bamboo collected from Himachal Pradesh is identified as Phyllostachys bambusoides, a<br />

valuable exotic bamboo. It is tested <strong>and</strong> found good <strong>for</strong> paper manufacture. Descriptions of the species<br />

are also given.<br />

224. Ku, Y.C; Pan, T.T. 1975. Experiments on using shoot-sheath of bamboo <strong>for</strong> pulping<br />

<strong>and</strong> papermaking. Quarterly Journal of Chinese Forestry 8(4): 101-107.<br />

At present, bamboo shoot-sheath (BSS) is not utilized in Taiwan. After steam treatment of BSS,<br />

[from Sinocalamus latiflorus], av. fibre length was 1.6 mm, equal to or longer than values <strong>for</strong><br />

hardwoods, rice straw or bagasse. Pulps produced by soda pulping in the laboratory, <strong>and</strong> by neutral<br />

sodium sulphite pulping in a paper mill, were found suitable <strong>for</strong> making good-quality printing paper <strong>and</strong><br />

corrugating medium, or <strong>for</strong> blending with other pulps. However, the yield of chemical pulp was low (25<br />

oven-dry BSS). The bulkiness <strong>and</strong> short storage life of BSS also present problems <strong>for</strong> its use on a<br />

commercial scale.<br />

225. Maheshwari, S. 1981. Pulp <strong>and</strong> paper making characteristics of Dendrocalamus<br />

strictus from Karnataka, Madhya Pradesh, Orissa <strong>and</strong> Andhra Pradesh. Indian Pulp <strong>and</strong><br />

Paper.<br />

226. Maheshwari, S. 1982. Studies on some aspects of pulp <strong>and</strong> papermaking<br />

characteristics of Orissa bamboo. Ph.D Thesis. Sambalpur University.<br />

227. Maheshwari, S; Jaspal, N.S; Bhargava, R.L. 1976. Pulping <strong>and</strong> paper making<br />

characteristics of North Kanara (India) bamboos. IPPTA 13(4): 299-306.<br />

Data are presented on st<strong>and</strong> characteristics, physical <strong>and</strong> chemical properties, fibre morphology<br />

<strong>and</strong> pulping characteristics of Bambusa arundinacea, Dendrocalamus strictus <strong>and</strong> Oxytenanthera<br />

monostigma.<br />

228. Maheshwari, S; Satpathy, K.C. 1990. The efficient utilization of bamboo <strong>for</strong> pulp <strong>and</strong><br />

paper making. <strong>Bamboo</strong>s: Current Research. Proceedings of the <strong>International</strong> <strong>Bamboo</strong><br />

Workshop, 14-18 November 1988, Cochin, India. Kerala Forest Research Institute, Peechi<br />

<strong>and</strong> IDRC, Canada: 286-290.<br />

28


The pulping characteristics of (a) bamboo of different ages (b) different portions of the culm <strong>and</strong><br />

(c) a few common varieties of bamboo are studied <strong>and</strong> the results are discussed. Effective methods of<br />

proper h<strong>and</strong>ling <strong>and</strong> storage of bamboo are also suggested.<br />

229. Mishra, N.D; Nagaiah, K; Kumar, P.P; Parekh, M.C. 1979. Pulping properties of bamboo<br />

from Assam, Orissa <strong>and</strong> Bhadrachalam areas of Andhra Pradesh. Indian Pulp <strong>and</strong><br />

Paper 33(6): 13-15.<br />

230. Pakotiprapha, B; Pama, R.P; Lee, S.L. 1979. Study <strong>for</strong> bamboo pulp <strong>and</strong> fibre cement<br />

composites. <strong>International</strong> Journal <strong>for</strong> Housing Science <strong>and</strong> its Applications 3(3): 167-190.<br />

Important characteristics of bamboo fibre rein<strong>for</strong>ced composites are presented. Benefical effects<br />

of bamboo pulp in imporving the first crack strength of the composite <strong>and</strong> of bamboo fibres in providing<br />

post cracking ductibililty are identified. Results of experiments to evaluate the per<strong>for</strong>mance of the<br />

composites under service conditions (as per ASTM requirement <strong>for</strong> building boards) are also<br />

presented.<br />

231. Raitt, W. 1912. Report on the investigation of bamboo as material <strong>for</strong> production of<br />

paper pulp. Indian Forest Records 3(3): 26p.<br />

232. Raitt, W. 1929. The Burma bamboo pulp survey. Indian Forest Records ( Economy series<br />

- Paper pulp) 14(1) : 48p.<br />

The report sums up the in<strong>for</strong>mation available on the subject of areas considered suitable <strong>for</strong><br />

pioneer enterprise in bamboo pulp production in Burma. It is the result of the survey made by the<br />

author through the districts Arakan of North <strong>and</strong> South Forest Divisions, Tavoy Forest Division <strong>and</strong><br />

Mergui Forest Division. It is found that a secured supply of bamboos exist in Burma, but the problem is<br />

in getting the supply to the mill. Also include the report of Robertson, W.A, Conservator of Forests on<br />

tour inTavoy <strong>and</strong> Mergui Divisions.<br />

233. Razzaque, M.A; Das, P; Sayeed, M; Chowdhury, A.R; Das, S.C. 1981. Age factor<br />

influencing the pulping characteristics of some bamboo species of Bangladesh. Bano<br />

Bigyan Patrika 10(1/2): 49-58.<br />

Fibre analysis, chemical analysis, pulping <strong>and</strong> pulp testing experiments were conducted on Muli,<br />

Mitinga, Kali, Orah <strong>and</strong> Dalu bamboos of ages ranging from 6 to 36 months. No appreciable change in<br />

chemical composition, fibre dimensions, pulp yields <strong>and</strong> physical strength properties of pulps could be<br />

monitored with increasing age. The results indicate that probably these bamboo species attain their<br />

maturity during the first year of growth. For pulping purposes, these species seems to be suitable <strong>for</strong> a<br />

twelve months cutting cycle.<br />

234. Sekyere, D. 1994. Potential of bamboo (Bambusa vulgaris) as a source of raw material<br />

<strong>for</strong> pulp <strong>and</strong> paper in Ghana. Ghana Journal of Forestry 1: 49-56.<br />

Laboratory studies were carried out to determine the pulping characteristics of a local variety of<br />

Bambusa vulgaris. The fibre length of 2.65 mm <strong>and</strong> Runkel Ratio of 1.03 suggest that bamboo fibres<br />

might be suitable <strong>for</strong> pulping <strong>and</strong> paper-making. The bamboo with a lignin content of 26.8 <strong>and</strong> cellulose<br />

content of 61.2 was cooked with 18 active alkali <strong>for</strong> 90 mins to obtain a yield of 54.2 <strong>and</strong> kappa number<br />

of 48.2. The pulp evaluations showed that it is not necessary to separate the node from the internode<br />

during pulping. The physical <strong>and</strong> strength properties of the pulp produced also showed that the<br />

bamboo can make good papers.<br />

235. Shanmughavel, P. 1997. The optimum age <strong>for</strong> felling of plantation bamboo (Bambusa<br />

bambos) <strong>for</strong> pulp <strong>and</strong> papermaking. Journal of Tropical Forest Products 2(2): 286-288.<br />

236. Singh, S.V; Mantri, T.C; Deb, U.K; Ghosh, D; Kulkarni, A.G; Murthy, K.S; Bharathi, S; Sude,<br />

Y; Kapur, S.K; Roy, T.K. 1977. Properties of ETA reed pulps. Research Report No. 1, FRI<br />

& Colleges, Dehra Dun, India.<br />

29


237. Singh, S.V; Rai, A.K; Singh, S.P. 1988. Aspects of pulping <strong>and</strong> papermaking from<br />

bamboos. Indian Forester 114(10): 701-710.<br />

A brief account of the chemical <strong>and</strong> morphological characteristics of major species of bamboo<br />

used <strong>for</strong> paper making in India is given in this paper. Research carried out on (a) pulping <strong>and</strong><br />

bleaching, (b) effect of morphological characteristics on sheetproperties, (c) beating properties <strong>and</strong> (d)<br />

decay on storage <strong>and</strong> its effect on pulp properties is reviewed <strong>and</strong> discussed. A brief description of<br />

industrial pulping <strong>and</strong> papermaking is given.<br />

238. Tamolang, F.N; Lopez, F.R; Semana, J.A; Casin, R.F; Espiloy, Z.B. 1980. Properties <strong>and</strong><br />

utilization of Philippine erect bamboos. <strong>Bamboo</strong> Research in Asia. Proceedings of a<br />

Workshop, 28-30 May 1980, Singapore. IDRC, Ottawa: 189-200.<br />

Of the 48 bamboo species in the Philippines, 29 are erect <strong>and</strong> the rest are climbing. Of these 10<br />

species have been studied <strong>for</strong> their anatomic structure, pulp <strong>and</strong> paper making characteristics, fibre<br />

morphology, chemical composition, edibility of theirshoots, physical <strong>and</strong> mechanical properties, new<br />

industrial uses, seasoning <strong>and</strong> preservation aptitudes. The results of these studies are presented in<br />

this paper. The studies on the properties <strong>and</strong> the utilization of bamboos in Philippines by the Forest<br />

Products Research <strong>and</strong> Industries Development Commission are not comprehensive. Areas which<br />

require further investigation are indicated.<br />

239. Ujiie, M; Kawase, K; Imagawa, H. 1986. Studies of utilization of Sasa-bamboos as <strong>for</strong>est<br />

resources III. Pulp from soft young culms by the alkaline process. Mokuzai Gakkaishi<br />

Journal of the Japan Wood Research Society 32(1): 28-33.<br />

Young culms, 1.5-2.0 m long, of Sasa kurilensis were pulped easily with 1 NaOH. The pulp had a<br />

good quality <strong>and</strong> high strength, comparable with that of sulphate pulps of full-grown culms.<br />

240. Wu, Z.H; Xu, Q.F. 1987. Paper making with bamboo <strong>and</strong> its economic benefit in the<br />

world. Journal of <strong>Bamboo</strong> Research 6(1): 46-53.<br />

241. Xia, N.H. 1989. Studies on the pulping properties of bamboo. Acta Botanica Austro<br />

Sinica No. 4: 207-217.<br />

Chemical constituents <strong>and</strong> fibre length were determined <strong>for</strong> 8 bamboo species, including moso<br />

bamboo (Phyllostachys pubescens). Samples (1 kg) of each species were processed under identical<br />

pulping conditions. The average unbleached pulp yield was 49.76 (Kappa number 28.3). Pulp<br />

strengths were satisfactory. Based on the unbleached pulp yield <strong>and</strong> strength properties,<br />

Schizostachyum funghomii exhibited the best qualities <strong>and</strong> Bambusa textilis <strong>and</strong> B. pervariabilis were<br />

ranked second <strong>and</strong> third. Under thesecriteria P. pubescens was ranked last. The pulping properties of<br />

bamboo of different ages were investigated. It was found that 1- to 2-yr-old bamboos were suitable <strong>for</strong><br />

pulping.<br />

242. Xie, J.H; Fu, M.Y; Chen, J.Y; Zhang, A.L; Li, R.G. 1999. Study on high-yield structure of<br />

Moso bamboo pulp st<strong>and</strong>s. Proceedings of the First <strong>International</strong> Seminar on<br />

Technologies of the Cultivation, Processing <strong>and</strong> Utilization of <strong>Bamboo</strong> in the '99 <strong>Bamboo</strong><br />

Cultural Festival of China. Journal of <strong>Bamboo</strong> Research 18(4): 65-72.<br />

The structures of two types of high-yield Moso bamboo (Phyllostachys pubescens) pulpwood<br />

st<strong>and</strong>s were studied in Anji County, Zhejiang Province, <strong>and</strong> in Jianyang County, Fujian Province, from<br />

1991 to 1995. Aspects investigated included st<strong>and</strong> density, culm age components, <strong>and</strong> tree<br />

components. The best high-yield structure <strong>for</strong> pure Moso st<strong>and</strong>s was a st<strong>and</strong>ing density of 3000<br />

culms/ha, <strong>and</strong> culm age proportions of 1-2 year old to 3-4 year old of 7:3. St<strong>and</strong>s of this structure will<br />

produce a new culm yield of 31.1 t/ha every 2 yr. A model <strong>for</strong> calculating new culm yield was also<br />

established, based on the nonlinear relationship between new culm yield, <strong>and</strong> bamboo st<strong>and</strong> density<br />

<strong>and</strong> culm age components. In mixed Moso <strong>and</strong> broadleaved tree st<strong>and</strong>s, the most importantstructural<br />

factor influencing productivity was the bamboo <strong>and</strong> tree [density] ratio, <strong>and</strong> the second most important<br />

the bamboo st<strong>and</strong>ing density. In this trial, the best bamboo/tree ratio was ∑DB 2 :∑DT 2 thin=thin 8:2<br />

[where D is density], <strong>and</strong> a bamboo st<strong>and</strong>ing density of 2100 culms/ha. This structure of<br />

Moso/broadleaved tree mixed st<strong>and</strong> will produce 22.8 t/ha of new culms every 2 yr.<br />

30


Anatomy <strong>and</strong> Chemical Constituents<br />

243. Chen, Y.D; Quin, W.L; Li, X.L; Gong, J.P; Ni, M.A. 1985. Study on chemical composition<br />

of ten species of bamboo. Chemistry <strong>and</strong> Industry of Forest Products 5(4): 32-39.<br />

Results are presented of chemical analyses of 10 species from Guangdong <strong>and</strong> Zhejiang<br />

provinces. Phyllostachys heteroclada contains larger amounts of holocellulose <strong>and</strong> less lignin than the<br />

other species <strong>and</strong> appears to be useful <strong>for</strong> chemical utilization. Chemical components change with age<br />

of the bamboo, amounts of holocellulose <strong>and</strong> alpha-cellulose decreasing after 1 yr <strong>and</strong> amount of lignin<br />

increasing slightly or remaining unchanged. Prolonging the growth period of bamboos is not desirable<br />

<strong>for</strong> chemical utilization purposes.<br />

244. Fengel, D; Shao, X. 1984. A chemical <strong>and</strong> ultra structural study of bamboo species<br />

Phyllostachys makinoi Hay. Wood Science <strong>and</strong> Technology 18(2): 103-112.<br />

A culm sample of Phyllostachys makinoi was investigated by analysis of its chemical composition,<br />

<strong>and</strong> by electron microscopic observations of the cell wall structure be<strong>for</strong>e <strong>and</strong> after extraction <strong>and</strong><br />

degradation procedures. Quantitative determination of the components resulted in 2.6 extractives,<br />

25.5 lignin, 45.3 alpha-cellulose, <strong>and</strong> 24.3 polyoses. The main polyose was an arabinoxylan with a<br />

Xyl: Ara ratio of about 17:1. The electron micrographs show a lamellar deposition of lignin <strong>and</strong><br />

polyoses within the secondary walls. Lignin was soluble by parts in alkaline as well as in acidic<br />

reagents. Sodium hydroxide solution removed cell wall aubstance mainly from the secondary walls,<br />

whereas trifluroacetic acid removed substance from compound middle lamellae.<br />

245. Fujii, Y; Azuma, J; Marchessault, R.H; Morin, F.G; Aibara, S; Okamura, K. 1993. Chemical<br />

composition change of bamboo accompanying its growth. Holz<strong>for</strong>schung 47(2):<br />

109-115.<br />

An immature culm of a moso-bamboo (Phyllostachys pubescens) 6 m in height was divided into<br />

six 1-m portions; their chemical composition was analysed <strong>and</strong> compared with results <strong>for</strong> an edible<br />

bamboo shoot (2 m high). In immature bamboo, the content of cellulose (<strong>and</strong> its crystallinity), <strong>and</strong><br />

hemicelluloses <strong>and</strong> lignin content were higher in the lower portions. Similar changes were observed in<br />

uronic acid, acetyl group content, phenolic acid <strong>and</strong> phenolic aldehyde. Protein, starch <strong>and</strong> ash<br />

contents were higher in the upper portions. About 90 of the phenolic acid was composed of p-coumaric<br />

acid <strong>and</strong> ferulic acid, both being exclusively in the trans <strong>for</strong>m, but their distribution profile was<br />

different:p-coumaric acid increased from the top to the bottom of the culm in relation to lignin content,<br />

while the reverse relation was observed <strong>for</strong> ferulic acid. Sixteen free amino acids were detected of<br />

which\small-cap\L-tyrosine was predominant.\small-cap\L-Tyrosine content was highest at the top <strong>and</strong><br />

decreased rapidly in the middle portion of the immature bamboo culm where lignin biosynthesis was<br />

progressing rapidly. 13C-NMR spectroscopy was found to be useful <strong>for</strong> analysing the distribution<br />

of\small-cap\L-tyrosine. The results indicated that 6 m high immature bamboo could appropriately be<br />

used to study growth <strong>and</strong> development.<br />

246. Ghosh, S.S; Negi, S.S. 1958. Salient anatomical structure of Dendrocalamus strictus<br />

Nees <strong>and</strong> Bambusa arundinacea Willd. used <strong>for</strong> paper manufacture. Symposium on<br />

Cellulose Research.<br />

247. Giri, S.S; Janmejay, L.S. 1991. Studies on the cell wall components of plain <strong>and</strong> hill<br />

bamboos of Manipur. Advances in Plant Sciences: 235-243.<br />

An analysis of the variations in the contents of fibre <strong>and</strong> it components such as cellulose,<br />

hemicellulose <strong>and</strong> lignin in bamboos collected from plain <strong>and</strong> hill areas is carried out <strong>and</strong> the results<br />

are presented. Six samples such as base internode, middle internode, top internode, base node,<br />

middle node <strong>and</strong> top node from plain <strong>and</strong> hill grown bamboos are studied. The fibre contents are<br />

reported higher in plain bamboos than in hill ones. The weakness of the hill bamboo culms is reported<br />

due to the lower percentage of fibre. A decrease in the contents of cellulose <strong>and</strong> hemicellulose from<br />

the base to top both in node <strong>and</strong> internode is reported.<br />

248. Gomide, J.L; Vivone, R.R; Vilar, R. 1985. Effect of parenchyma cell content on<br />

characteristics <strong>and</strong> properties of kraft pulp from Bambusa vulgaris with an optimum<br />

31


degree of delignification. ABCP 18th annual meeting held during paper week, 18-22<br />

November, Paulo, Brazil. ABCP, Sao Paulo, Brazil. Vol. 1: 139-147.<br />

Different amounts of parenchyma cells (0, 11.8, 23.6 <strong>and</strong> 35.4) were added to the fibre fraction of<br />

kraft pulp <strong>and</strong> the characteristics of the pulp were assessed. Pulp of high strength was obtained with B.<br />

vulgaris; presence of parenchyma cells generally reduced pulp strength.<br />

249. Hwang, J.S; Chiang, P.Y. 1998. Studies of the changes of texture <strong>and</strong> chemical<br />

compositions of Ma-<strong>Bamboo</strong> shoots (Dendrocalamus latiflorus) during cooking.<br />

Journal of Agricultural <strong>and</strong> Forestry 47(2): 89-100.<br />

The effect of heat treatment on the texture, chemical composition <strong>and</strong> observed microstructure<br />

was investigated in Ma-<strong>Bamboo</strong> shoots. Pectic substances tended to increase after being heated<br />

between 40 <strong>and</strong> 80 o C <strong>for</strong> 100 min. Pectic substances decreased sharply from 880 to 505 mg by<br />

heating to 100 o C <strong>for</strong> 200 min, however, cellulose hemicellulose, lignin changed slightly. The change in<br />

chemical composition <strong>and</strong> cell microstructure was slight <strong>and</strong> the cell wall kept shape, even during<br />

dehydration <strong>and</strong> construction of cells. It is concluded that during heating, the loss of pectic substances<br />

simultaneous resulted in the softeing <strong>and</strong> the contraction <strong>and</strong> de<strong>for</strong>mation of cell walls.<br />

250. Liese, W; Weiner, G; Chapman, G.P. 1997. Modifications of bamboo culm structures<br />

due to ageing <strong>and</strong> wounding. The bamboos. Proceedings of an <strong>International</strong> Symposium,<br />

London, 25-29 March 1996. Academic Press <strong>for</strong> the Linnean Society of London, San Diego,<br />

USA: 313-322.<br />

Structural modifications that can occur during the life span of a bamboo culm due to wounding <strong>and</strong><br />

ageing are described. A bamboo culm grows <strong>for</strong> only a few months with minor anatomical differences<br />

within the internode <strong>and</strong> along the culm length. Structural modifications occur within a maturation<br />

period of 1-2 years, followed by further changes in older culms due to ageing, such as cell wall<br />

thickening of fibres <strong>and</strong> parenchyma. In order to ensure long-term competent physiological functioning,<br />

any damagecaused by culm injury has to be blocked off, especially as the secondary meristem cannot<br />

provide new pathways. Protective mechanisms include <strong>for</strong>mation of slime substances, tyloses,<br />

phenolic compounds <strong>and</strong> lignification. Special features of wound responsesin comparison to<br />

hardwoods are suberinization <strong>and</strong> additional wall lamellae.<br />

251. Lin, J.G; Dong, J.W; Fan, X.F; Lin, S.D. 2000. The variation tendency of chemical<br />

composition contents in Dendrocalamus latiflorus culm-wood. Journal of Plant<br />

Resources <strong>and</strong> Environment 9(1): 55-56.<br />

Variation in the chemical composition of Dendrocalamus latiflorus culm wood were systematically<br />

analysed using samples from different sites (3), ages (1, 2 or 3 yr old), planting methods (3, transplants<br />

from the maternal bamboo, <strong>and</strong> cuttings from mainor secondary branches), <strong>and</strong> planting positions (2,<br />

horizontal or vertical) in [Fujian Province], China. Components analysed were ash, hot water, NaOH<br />

<strong>and</strong> benzene/alcohol extractives, nitric acid/alcohol cellulose, pentosans <strong>and</strong> Klason lignin. The<br />

resultsshowed that age <strong>and</strong> bamboo planting position are the main factors which affect wood chemical<br />

composition, while site <strong>and</strong> planting mode are insignificant.<br />

252. Madan, R.N; Vijan, A.R. 1995. Physico-chemical properties of Dendrocalamus<br />

giganteus kraft spent liquor. Proceedings of the international seminar on 'Management of<br />

MFP', 13-15 November 1994. Journal of Non Timber Forest Products 2(3/4): 160-164.<br />

253. Montalvao, Filho, A; Gomide, J.L; Conde, A.R. 1984. Variability in chemical constitution<br />

<strong>and</strong> dimensional characteristics of Bambusa vulgaris fibres. Revista Arvore 8(1): 12-27.<br />

A study of holocellulose, pentosan, lignin <strong>and</strong> ash contents, solubility in various solvents <strong>and</strong> fibre<br />

dimensions of stem <strong>and</strong> branch samples of 6.5-yr-old plants grown in plantations in Bahia.<br />

254. Parameswaran, N; Liese, W. 1977. Occurrence of warts in bamboo species.<br />

Woodscience <strong>and</strong> Technology 11(4): 313-318.<br />

Warts have been observed on the walls of wood cells(under SCM <strong>and</strong> TEM) in several bamboo<br />

species; they can be presented not only in vessel members <strong>and</strong> fibres, but also in the highly lignified<br />

parenchyma cells, especially in those of the elongated type. Among the 34 species studied only<br />

32


Melocanna bambusoides possessed warts in all three cell types. The sizes of warts lie with in the<br />

range observed <strong>for</strong> dicots <strong>and</strong> gymnosperms. There is no recognizable correlation between the<br />

occurrence of warts <strong>and</strong> the taxonomic grouping of bamboos. It has been suggested that the<br />

development of warts is associated with the lignification of the cell wall.<br />

255. Paremeswaran, N; Liese, W. 1981. The fine structure of bamboo. Proceedings of <strong>Bamboo</strong><br />

Production <strong>and</strong> Utilization XVII IUFRO World Congress, 6-17 September 1981, Kyoto,<br />

Japan. Wood Research Institute, Kyoto University, Kyoto: 178-183.<br />

The fine structural aspects of the diverse cells like fibres, parenchyma, metaxylem vessels,<br />

protoxylem <strong>and</strong> phloem are briefly discussed. Special emphasis is laid on the wall construction as<br />

realated to the physical properties of the culm.<br />

256. Patnaik, J.K; Rao, P.J.M; Gantayet, R.G; Bhargava, K.S. 1984. Effect <strong>and</strong> utilisation of<br />

bamboo pin chip. IPPTA 21(3): 20-23.<br />

With the increase of the cost of bamboo, ef<strong>for</strong>ts are made to utilise bamboo at the maximum <strong>for</strong><br />

pulping. A study was conducted on the cooking of pin chips, which are removed as bamboo dust<br />

during the screening of the chips. Studies show that the small quantity pulp obtained from separate<br />

cooking of pin chips can be mixed with normal kraft pulp <strong>for</strong> the manufacture of the kraft paper without<br />

any significant effect on the physical strength properties of paper. It is reported that by mixing small<br />

quantity(5 percent) of pin chips with the usual chip the quality of pulp does not deteriorate much.<br />

257. Samapuddhi, K. 1959. A preliminary study in the structure of some Thai bamboos.<br />

Royal Forest Department, Ministry of Agriculture, Bangkok: 13p.<br />

Results of a preliminary study made on the anatomical structure, silica content, fibre length <strong>and</strong><br />

starch content of some Thai bamboos are presented.<br />

258. Sekhar, T; Balasubramanian, A. 1994. Structural diversity of culm in Bambusa vulgaris.<br />

Journal of the Indian Academy of Wood Science 25(1/2): 25-31.<br />

Bambusa vulgaris is one of the valuable <strong>and</strong> much used bamboos <strong>for</strong> structural purposes <strong>and</strong> in<br />

the paper industry. The variations in the fibro-vascular bundle organization, mechanical tissue<br />

distribution <strong>and</strong> the fibre charcterestics in in culm internodes were used <strong>for</strong> the identification <strong>and</strong><br />

delimitaiton of of Bambusa vulgaris <strong>and</strong> its varieties viz. B. vulgaris var. striata <strong>and</strong> B. vulagaris cv.<br />

wamin. The significance of the structural diversity of the culm wall in taxonomy is discussed <strong>and</strong> the<br />

elevation of the above varieties to the species level is supported.<br />

259. Shin, D.S; Jung, T.M. 1962. Studies on the chemical components of bamboo produced<br />

in Korea-(1)-On the chemical composition of kat-tae. Research Bulletin of Chinju<br />

Agricultural College 1: 31-34.<br />

260. Tomazello, Filho, M; Azzini, A. 1987. Anatomical structure, fibre dimensions <strong>and</strong> basic<br />

density of Bambusa vulgaris culms. IPEF 36: 43-50.<br />

Examination of sections of 3-yr-old culms showed a decrease in fibre length from internal to<br />

external culm layers at all culm heights. Fibre length increased longitudinally upto 25-75 culm height<br />

<strong>and</strong> then decreased towarse the apex. Basic density increased from internal to external layers <strong>and</strong><br />

from the base to the apex.<br />

261. Tono, T. 1963. Chemical studies on bamboo fibre as a raw material <strong>for</strong> pulp. Bulletin of<br />

the University of Osaka Prefecture Ser. B. 14: 127-161.<br />

262. Varshney, M.C. 1965. The effect of anatomical characteristics of bamboo on pulping.<br />

Sirpur Industries Journal 4(2): 116-118.<br />

263. Vijan, A.R; Madan, R.N. 1996. Study on the chemistry of Dendrocalamus giganteus<br />

lignin. Van Vigyan 34(1/2): 43-49.<br />

33


With a view to possible utilization of kraft lignin as a byproduct, lignin was isolated from the spent<br />

liquor left from pulping by the kraft process, using bamboo samples from sound <strong>and</strong> flowered<br />

specimens of D. giganteus. Data are tabulated on the C, H, O <strong>and</strong> S contents of the lignins, on the<br />

contents of Klason lignin <strong>and</strong> functional groups (methoxyl, hydroxy <strong>and</strong> carboxylic) <strong>and</strong> correlations<br />

between them, <strong>and</strong> on the relative retention time <strong>and</strong> percentage of alkaline nitrobenzene oxidation<br />

products of the lignins. The results indicate clear differences in structure between lignin isolates from<br />

sound <strong>and</strong> flowered bamboos.<br />

264. Wu, S.C; Sheng, H.J; Liou, J.L. 1996. The anatomical properties of some bamboo<br />

species grown in mainl<strong>and</strong> China (III). Quarterly Journal of the Experimental Forest of<br />

National Taiwan University 10(2): 37-59.<br />

The middle internode of a bamboo culm was cut from each of 23 species belonging to 7 genera<br />

(Brachystachyum [Semiarundinaria], Clavinodum [Arundinaria], Indocalamus, Oligostachyum<br />

[Arundinaria], Phyllostachys, Pseudosasa <strong>and</strong> Sinobambusa), native to Zhejiang. Sectioning,<br />

maceration <strong>and</strong> computer image analysis were used to investigate their anatomical properties. The<br />

characteristics recorded were: vascular bundle size; number of vascular bundles/mm2; culm wall<br />

thickness; distribution of small <strong>and</strong> large diameter vessels; fibre length, diameter <strong>and</strong> cell wall<br />

thickness; diameter, length <strong>and</strong> type of parenchyma; <strong>and</strong> the proportion of various anatomical<br />

elements.<br />

Cellulose, Hemicellulose <strong>and</strong> Lignin<br />

265. Ahmad, N; Karnik, M.G. 1944. A technical survey of cellulose bearing materials of India.<br />

Journal of Scientific <strong>and</strong> Industrial Research 2: 275-290.<br />

The chief object of this investigation was to determine the alpha-cellulose content of the cellulosebearing<br />

materials of India under the optimum conditions of Kier boiling <strong>and</strong> bleaching. The materials<br />

tested included <strong>Bamboo</strong>s, grasses, straws, fibres, <strong>and</strong> the tree species Fir, Spruce, Salai (Boswellia<br />

serrata), Karai (Sterculia urens). Four processes were used-soda, sulphate, sulphite, <strong>and</strong> sodium<br />

sulphite; the last of these gave the best results. Addition of sodium aluminate as an auxiliary was found<br />

to increase the alpha-cellulose content of the pulp, but also increased the ash content. The Fir <strong>and</strong><br />

Spruce samples gave good results <strong>and</strong> seem to be promising raw materials <strong>for</strong> the rayon industry.<br />

Salai <strong>and</strong> Karai did not give satisfactory results; the pulp obtained consisted of short fibres <strong>and</strong> had a<br />

low alpha-cellulose content. The results of the experiments on all types of materials are given in tabular<br />

<strong>for</strong>m. The <strong>Bamboo</strong>s include Dendrocalamus strictus. Bambusa arundinacea, <strong>and</strong> Eetta <strong>Bamboo</strong>.<br />

266. Azzini, A; Arruda M.C.Q. de; Ciaramello, D; Salgado, A.L de B; Tomazello Filho, M. 1987.<br />

Combined production of cellulose fibres <strong>and</strong> ethanol from bamboo. Bragantia 46(1):<br />

17-25.<br />

In a study using 1-, 3- or 5-yr-old Bambusa vulgaris culms, shredded <strong>and</strong> treated with dilute<br />

H2SO4, fibre yield <strong>for</strong> paper making was higher in younger culms. Potential ethanol yield (by<br />

fermentation of glucose) <strong>and</strong> glucose <strong>and</strong> starch contents were higher in samples from the middle <strong>and</strong><br />

upper portions of the culms. Density did not vary with age but was higher in the middle <strong>and</strong> top portions<br />

of the culms. Combined production of ethanol <strong>and</strong> fibres was considered to be feasible.<br />

267. Azzini, A; Arruda M.C.Q. de; Tomazello Filho, M; Salgado, A.L. de B; Ciaramello, D. 1987.<br />

Variation in cellulose fibre <strong>and</strong> starch contents in bamboo culms. Bragantia 46(1):<br />

141-145.<br />

In a study of 3-yr-old Bambusa vulgaris culms, density was lowest in the basal portion of the culm<br />

<strong>and</strong> in the inner parts of the culm wall. Cellulose fibre <strong>and</strong> starch contents did not vary significantly<br />

along culm length, although higher fibre contentwas found in the outer portion of the culm. The highest<br />

starch contents were found in the inner portion of the culm.<br />

268. Bawagan, P.V. 1968. Studies on bamboo (Bambusa vulgaris Schrad. ex. Wendl.)<br />

cellulose <strong>and</strong> its isolation by analytical <strong>and</strong> industrial methods. Philippine Lumbermann<br />

14(11): 18-24, 32, 34.<br />

34


The results suggested that the prehydrolysis/sulphate process may be the only effective means of<br />

removing the pentosan from the <strong>Bamboo</strong> chips (though at a cost of considerable loss of alphacellulose)<br />

<strong>and</strong> thus enabling a dissolving-grade pulp to be obtained.<br />

269. Bhat, R.V; Guha, S.R.D. 1952. Indigenous cellulosic raw materials <strong>for</strong> the production of<br />

pulp, paper <strong>and</strong> board. Part IV. Writing <strong>and</strong> printing paper from paper mulberry<br />

(Broussonetia papyrifera). Indian Forester 78(2): 93-99.<br />

Experiments conducted in Madras State <strong>and</strong> Travancore-Cochin State indicate that paper<br />

mulberry (Broussonetia papyrifera, Vent.) can be easily raised in plantations from seeds. The species<br />

reproduces itself naturally <strong>and</strong> is a fast grower <strong>and</strong> a good coppicer. The bast fibre is used in Japan<br />

<strong>for</strong> the preparation of extremely strong <strong>and</strong> high quality papers. Laboratory experiments as well as<br />

pilot plant trials carried out in this Branch indicated that the wood of this species is a useful raw<br />

materials <strong>for</strong> the production of writing <strong>and</strong> printing papers. Since the chemical pulp from this wood is<br />

short-fibred, an addition of about 25 of long-fibred pulp such as bamboo pulp in the furnish improves<br />

the strength properties of the paper.<br />

270. Bhat, R.V; Guha, S.R.D. 1953. Indigenous cellulosic raw materials <strong>for</strong> the production of<br />

pulp, paper <strong>and</strong> board. Part XV. Chemical pulps <strong>and</strong> writing <strong>and</strong> <strong>and</strong> printing paper<br />

from Albizzia stipulata Bolvin. Indian Forester 79(9): 475-483.<br />

Laboratory experiments on the production of chemical pulps by the sulphate process from the<br />

wood of Albizzia stipulata are described. The wood was obtained from <strong>for</strong>ests of Bihar. Results of four<br />

pilot plant experiments on the preparation of writing <strong>and</strong> printing papers from this wood are also<br />

included. This investigation has shown that chemical pulps in satisfactory yields can be prepared from<br />

this wood. The whiteness of the bleached pulps was good. Although the average fibre length of the<br />

pulps was only 1.02 mm., writing <strong>and</strong> printing papers made on the pilot plant from the furnish containg<br />

entirely the pulp from this wood were characterised by good strength properties. The <strong>for</strong>mation of the<br />

papers was satisfactory.<br />

271. Bhat, R.V; Guha, S.R.D; P<strong>and</strong>e, S.P. 1952. Indigenous cellulosic raw materials <strong>for</strong> the<br />

production of pulp, paper <strong>and</strong> board. Part VIII. Writing <strong>and</strong> printing papers from<br />

Boswellia serrata Roxb. Indian Forester 78(4): 169-175.<br />

Laboratory experiments carried out in this Institute on the production of bleached chemical pulp<br />

from Boswellia serrata (salai) are described. The results of pilot plant experiments are also included.<br />

Two samples of printing paper made from mixtures of Boswellia serrata pulp <strong>and</strong> bamboo pulp are<br />

appended. These experiments have shown that writing <strong>and</strong> printing papers with suitable strength<br />

properties can be prepared from Boswellia serrata using 25-40 of bamboo pulp in the furnish. As the<br />

chemical pulp from Boswellia serrata is short-fibred, it is essential to add bamboo or other long-fibred<br />

pulp to the furnish.<br />

272. Bhat, R.V; Jaspal, N.S. 1957. Indigenous cellulosic raw materials <strong>for</strong> the production of<br />

pulp, paper <strong>and</strong> board. Part XXX. Wrapping papers from castor stem (Ricinus<br />

communis Linn.). Indian Forester 83(10): 614-620.<br />

Laboratory experiments on the production of wrapping papers from castor stem (Ricinus<br />

communis Linn.) of the annual variety are described. Wrapping papers were made on the pilot plant of<br />

the Forest Research Institute from 100 castor stem pulp <strong>and</strong> also from a mixture of 70 of this pulp <strong>and</strong><br />

30 bamboo kraft pulp. These papers were characterised by good <strong>for</strong>mation <strong>and</strong> satisfactory strength<br />

properties. The utilization of castor stalk <strong>for</strong> the manufacture of wrapping papers will depend upon the<br />

price at which it can be made available at the mill site.<br />

273. Bhat, R.V; Viramani, K.C. 1957. Indian Forest Leaflet No. 123. FRI & Colleges, Dehradun.<br />

274. Bhowmick, K; Mian, A.J; Akhteruzzaman, A.F.M. 1994. The kinetics of delignification in<br />

low sulphidity kraft anthraquinone <strong>and</strong> soda anthraquinone pulping of muli bamboo<br />

(Melocanna baccifera). IPPTA.<br />

275. Bist, D.P.S; Singh, S.V; Singh, M.M; Guha, S.R.D. 1974. Oxidation of bamboo- dioxane<br />

lignin by alkaline potassium ferricyanide. Indian Pulp <strong>and</strong> Paper 29(4): p3.<br />

35


276. Bist, D.P.S; Singh, S.V; Singh, M.M; Guha, S.R.D. 1975. Oxidation of dioxane <strong>and</strong> soda<br />

lignins of bamboo by alkaline cupric sulphate. Indian Pulp <strong>and</strong> Paper 29(6): p17.<br />

277. Cellulose yield of bamboo. My<strong>for</strong>est 2(1)1965: 51-52.<br />

A note on the visiting of Mr. John Wilson the various bamboo areas of Mysore State. It is reported<br />

that the cellulose yield of bamboo is 4 to 5 times more per acre, per year than that obtained from the<br />

best managed southern pines in U.S.A.<br />

278. Dhawan, R; Singh, S.V. 1982. Chemical characterization of hemicelluloses isolated<br />

from three species of bamboo - Dendrocalamus strictus, Dendrocalamus hamiltonii<br />

<strong>and</strong> Melocanna baccifera. Journal of the Indian Academy of Wood Science 13(2): p62.<br />

GLC hemicelluloses showed that xylose is the main constituent (80-92 of hemicellulose in all 3<br />

species. Glucose, arabinose, rhamnose <strong>and</strong> glusuronis acid were also found in small amounts. The<br />

yield of sugars was highest <strong>for</strong> D. strictus, whereas the yield of pentosans <strong>and</strong> methoxyl compounds<br />

were highest <strong>for</strong> D. hamiltonii, M. baccifera had the lowest content of sugars, pentosans <strong>and</strong> methoxyl<br />

compounds.<br />

279. Doat, J. 1967. <strong>Bamboo</strong>s: A possible source of cellulose <strong>for</strong> Africa. Bios. For. Trop. 113:<br />

41-59.<br />

280. Espiloy, Z.B. 1982. Silica content in spiny bamboo Bambusa blumeana Blume ex<br />

Schultes. NSTA Technology Journal 7(4): 38-43.<br />

Determination of silica, which affects the pulping quality in the species, Bambusa blumeana is<br />

dealt with in this paper. It is reported that a positive correlation exists between specific gravity, cell wall<br />

thickness <strong>and</strong> silica content in the bamboo.<br />

281. Faix, O; Jakab, E; Till, F; Szekely, T. 1988. Study on low mass thermal degradation<br />

products of milled wood lignins by thermogravimetry-mass-spectrometry. Wood<br />

Science <strong>and</strong> Technology 22(4): 323-334.<br />

Thermogravimetry-mass-spectrometry (TGMS) as a sophisticated analytical technique is<br />

described <strong>for</strong> the thermal analysis of milled wood lignins from spruce (Picea abies), beech (Fagus<br />

sylvatica), <strong>and</strong> bamboo (Bambusa sp.). The samples were heated on thethermobalance in an inert gas<br />

atmosphere (Ar) with 20°C/min heating rate. The weight loss curves (TG) <strong>and</strong> their 1st derivatives<br />

(DTG) were recorded. The evolution of 10 low mass degradation products with m/z below 44 was<br />

monitored as a function of temp. by means of a quadrupol mass spectrometer; their intensity profiles<br />

were recorded <strong>and</strong> interpreted in terms of lignin structure <strong>and</strong> the course of carbonization. The results<br />

are in agreement with the results of differential scanning calorimetry <strong>and</strong> pyrolysis-gas-chromatography<br />

mass-spectrometry of the phenolics.<br />

282. Faix, O; Lange, W; Beinhoff, O. 1980. Molecular weights <strong>and</strong> molecular weight<br />

distributions of milled wood lignins of some wood <strong>and</strong> Bambusoideae species.<br />

Holz<strong>for</strong>schung 34(5): 174-176.<br />

Mol. wt. measurements were made on milled wood lignins from spruce, beech, aspen [Populus<br />

spp.], birch, dabema [Piptadeniastrum africanum], bamboo <strong>and</strong> rattan using high pressure liquid<br />

chromatography. The yields of milled wood lignin were between 1.7 <strong>and</strong> 5.9 <strong>and</strong> considerable<br />

differences in their molecular properties were found between species.<br />

283. Faix, O; Meier, D. 1989. Pyrolytic <strong>and</strong> hydrogenolytic degradation studies on<br />

lignocellulosics, pulps <strong>and</strong> lignins. Holz als Roh und Werkstoff 47(2): 67-72.<br />

Wood <strong>and</strong> milled-wood lignin from beech, Norway spruce <strong>and</strong> bamboo, as well as teak wood <strong>and</strong><br />

teak HCl-lignin, were subjected to analytical pyrolysis using the off-line approach, <strong>and</strong> to<br />

hydrogenolysis. Gas chromatography-mass spectrometry was used <strong>for</strong> product identification <strong>and</strong><br />

assignment as derivatives from 4-hydroxyphenylpropane, guaiacylpropane <strong>and</strong> syringylpropane basic<br />

units, followed by capillary gas chromatography <strong>for</strong> quantitative determination of the phenolics. The<br />

results are compared with thoseof nitrobenzene oxidation <strong>and</strong> quantitative non-degradative FTIR-<br />

36


spectroscopy. Pyrolysis-GC <strong>and</strong> hydrogenolysis-GC studies were also used <strong>for</strong> the characterization of<br />

residual lignins in kraft <strong>and</strong> alkaline-sulphite-anthraquinone-methanol (ASAM) pulps from beech, pine<br />

<strong>and</strong> sugar cane bagasse. It is concluded that analytical pyrolysis of biomass, in both on-line <strong>and</strong> offline<br />

approaches, is well suited <strong>for</strong> lignin classification even without previous lignin isolation;<br />

hydrogenolysis is more suitable <strong>for</strong> the characterization of residual lignins in pulps.<br />

284. Fengel, D; Shao, X. 1985. Studies on the lignin of the bamboo species Phyllostachys<br />

makinoi Hay. Wood Science <strong>and</strong> Technology 19(2): 131-137.<br />

Milled wood lignin (MWL) isolated from Phyllostachys makinoi was investigated by chemical <strong>and</strong><br />

physical methods. The bamboo lignin was rich in syringyl units which is indicated by a high methoxyl<br />

content <strong>and</strong> respective b<strong>and</strong>s in the IR spectrum. The distinct absorption b<strong>and</strong>s <strong>for</strong> aromatic ring<br />

vibrations were attributed to final p-coumaryl ester groups. In the UV spectrum the extinction maximum<br />

in the range of 280 nm is shifted to longer wavelengths compared with those of wood lignin. With<br />

NaOH <strong>and</strong> trifluoroacetic acid (TFA) mainly an arabinoxylan with a Xyl :Ara ratio of 14:1 was extracted<br />

from bamboo saw dust. The lignin proportion in the NaOH extract, which is derived mainly from the<br />

secondary walls, has a lower methoxyl content; the lignin proportion in the TFA extract, which is<br />

derived from the compound middle lamellae, has a higher methoxyl content compared with MWL.<br />

285. Guha, S.R.D; Pant, P.C. 1967. Hemicelluloses from bamboo (Bambusa arundinaceae).<br />

Indian Pulp <strong>and</strong> Paper 21(7): p14.<br />

286. Han, H; Zu, Z.W; Zhang, J.W; Ma Naixun; Ma, L.F. 1996. Ash <strong>and</strong> lignin contents <strong>for</strong> 76<br />

species of bamboo wood. Journal of the Zhejiang Forestry College 13(3): 276-279.<br />

The ash content <strong>and</strong> lignin content <strong>for</strong> 76 species of bamboo wood from Guangxi <strong>and</strong> Zhejiang<br />

were determined. The ash content ranged from 0.88 to 7.23, averaging 2.65, <strong>and</strong> the lignin content<br />

ranged from 2.36 to 30.4, averaging 24.95.<br />

287. Hasegava, T; Ito, M. 1959. The behaviour of xyloses during hydrotropic pulping. Journal<br />

of Chemical Society of Japan, Industrial Chemical Section 62(9): 1435-1438.<br />

288. Higuchi, T. 1958. Studies on the chemical properties of the lignin of bamboo-stalk.<br />

Journal of Biochemistry 45(9): 675-685.<br />

Results of an investigation made on the lignin of bamboo are described in this paper. It is conclued<br />

from ethanolysis <strong>and</strong> hydrolysis of stalks of Phyllostachys edulis that a part of the lignin is <strong>for</strong>med by<br />

oxidative condensation of beta-guaiacyl ethers of guaiacyl-, syringyl-, <strong>and</strong> p-hydroxyphenyl-propanes.<br />

289. Higuchi, T; Kawamura, I. 1966. Occurrence of p-hydroxy phenylglycerol-B-aryl ether<br />

structure in lignins. Holz<strong>for</strong>schung 20(1): 16-21.<br />

Describes experiments which showed that this structure is not specific to the lignin of gramineous<br />

plants but also occurs in various other lignins, the amount being almost the same in conifers <strong>and</strong><br />

gramineous plants, <strong>and</strong> a little less in broadleaved trees.<br />

290. Higuchi, T; Tanahashi, M; Sato, A. 1972. Acidolysis of <strong>Bamboo</strong> lignin. I. Gas-liquid<br />

chromatography <strong>and</strong> mass spectrometry of acidolysis monomers. Mokuzai Gakkaishi<br />

Journal of the Japan Wood Research Society 18(4): 183-189.<br />

Milled wood lignins from Phyllostachys pubescens <strong>and</strong> from four tree species were subjected to<br />

acidolysis in dioxan/water containing 0.2N HCl. Examination of the products showed that guaiacyl- <strong>and</strong><br />

syringyl-glycerol- beta -aryl ethers are present in approximately equal amounts in the <strong>Bamboo</strong> lignin,<br />

<strong>and</strong> that these two components account <strong>for</strong> 50-60 of the phenylpropane units of the lignin.<br />

291. Higuchi, T; Tanahashi, M; Nakatsubo, F. 1973. Acidolysis of <strong>Bamboo</strong> lignin III.<br />

Estimation of arylglycerol- beta -aryl ether groups in lignins. Wood Research 54: 9-18.<br />

The concentrations of both condensed <strong>and</strong> uncondensed <strong>for</strong>ms of arylglycerol- alpha, beta -diaryl<br />

ether groups in Phyllostachys pubescens, Fagus crenata <strong>and</strong> Thuja st<strong>and</strong>ishii were estimated by<br />

gas/liquid chromatography <strong>and</strong> spectral analysis. Results arecompared <strong>and</strong> discussed.<br />

37


292. Idei, T. 1981. D.P [degree of polymerization] <strong>and</strong> crystallinity of cellulose in the<br />

different growth stage of bamboo culms. Bulletin, Utsunomiya University Forests 17:<br />

59-73.<br />

Including data on chlorophyll <strong>and</strong> lignin contents in Phyllostachys heterocycla var. pubescens [P.<br />

pubescens].<br />

293. Ingle, T.R; Bose, J.L. 1969. Nature of hemicelluloses of bamboo (Dendrocalamus<br />

strictus). Indian Journal of Chemistry 7: 783-785.<br />

Two hemi cellulose fractions are isolated from <strong>Bamboo</strong> (Dedrocalamus strictus) powder, <strong>and</strong><br />

holocellulose prepared from it. The behaviour of some of these fractions towards water <strong>and</strong> potassium<br />

hydroxide is studied. The main hemicellulose fraction from holocellulose is found to be a<br />

glucuronoxylan of molecular weight of 6600, containing D-xylose <strong>and</strong> D-glucuronic acid units in the<br />

molar preportion of about 9:1.<br />

294. Jamaludin K; Abd. Latif Mohmod. 1993. Variability of specific gravity, fibre morphology<br />

<strong>and</strong> chemical properties in three Malaesian bamboos. BIC India Bulletin 3(2): 7-13.<br />

The paper discusses physical properties like specific gravity <strong>and</strong> fibre morphology <strong>and</strong> chemical<br />

properties of three commercialy imporatant bamboo species in Peninsular Malaysia, namely Bambusa<br />

vulgaris. B. heterostachya <strong>and</strong> Gigantochloa scortechinii. Specific gravity is reported increase from<br />

basal to top portion. The fibre properties especially the fibre diameter <strong>and</strong> fibre cell wall thickness are<br />

reported increase with the increasing height.<br />

295. Kapoor, S.K; Guha, S.R.D. 1984. Infrared studies on wood lignin of eta-reed (Ochl<strong>and</strong>ra<br />

travancorica). IPPTA 21(3): 24-28.<br />

Presents the results of an investigation carried out to elucidate the chemical character of milled<br />

wood lignin isolated from Ochl<strong>and</strong>ra travancorica which is proved to be a very good raw material <strong>for</strong><br />

chemical pulping.<br />

296. Karnik, M.G. 1960. The nature of hemicelluloses from bamboo (Dendrocalamus<br />

strictus). Part I. Preliminary investigations. Indian Pulp <strong>and</strong> Paper 14(9): 427-429.<br />

Reports the results of a study of the nature of hemicelluloses in bamboo following chemical<br />

analysis of 0.25 mm. x 2.5 cm. air-dried shavings from 3-year-old culms. The material was found to<br />

contain 64.8 of holocellulose (oven-dry wt. basis), 10.6 of "hemicellulose A" <strong>and</strong> 3.77 of "hemicellulose<br />

B". The higher value of the "hemicellulose A" fraction indicates that bamboo contains more<br />

hemicelluloses of a lower degree of polymerization, which are likely to be dissolved <strong>and</strong> destroyed in<br />

the process of alkaline pulping, resulting in the production of a pulp of low hemicellulose content. Data<br />

from chemical analysis of the holocellulose, alpha-cellulose, <strong>and</strong> hemicelluloses isolated from the<br />

bamboo, showed that of the 21 of pentosans present in holocelluloses ca. 2.73 are alkali resistant <strong>and</strong><br />

retained in alpha-cellulose. Hemicellulose B contained 20.9 more pentosans than hemicellulose A.<br />

The high pentosan content of both fractions indicated that the bamboo hemicelluloses contained more<br />

pentosans than hexosans.<br />

297. Karnik, M.G; Morak, A.J; Ward, K. 1963. Hemicelluloses <strong>and</strong> dissolving pulp from Indian<br />

bamboo (Dendrocalmus strictus). TAPPI Journal 46(2): 130-134.<br />

A more quantitative treatment of Karnik's preliminary investigation into the hemicelluloses of D.<br />

strictus, in which the main hemicellulose of the bamboo would seem to be consistent with the structure<br />

of 4-0-methylglucuronoarabinoxylan (though the only basis <strong>for</strong> this so far is analogy with the wood<br />

hemicelluloses).<br />

298. Kawase, K; Sato, K; Imagawa, H; Ujiie, M. 1986. Studies on utilization of Sasa bamboos<br />

as <strong>for</strong>est resources. 4. Pulping of young culms <strong>and</strong> histological change of cell<br />

structure of the culms in growing process. Research Bulletins of the College Experiment<br />

Forests, Hokkaido University 43(1): 73-97.<br />

Young culms of S. kurilensis (up to 4 yr old) were pulped by boiling with 1-2 KOH. This produced<br />

pulps suitable <strong>for</strong> folk art paper, because of the presence of thin-walled fibres, unlike the<br />

38


sclerenchymatous adult fibres. Underground buds <strong>and</strong> culms


Acidolysis products of milled wood lignin of Phyllostachys pubescens were fractionated by gel<br />

filtration on Sephadex, <strong>and</strong> individual compounds in both monomeric <strong>and</strong> dimeric fractions were<br />

identified by infra-red, nuclear-magnetic-resonance <strong>and</strong> mass spectrometry. The results confirmed<br />

those of the earlier study, showing that the <strong>Bamboo</strong> lignin is a mixed polymer of guaiacyl <strong>and</strong> syringyl<br />

propanes <strong>and</strong> a small amount of p-hydroxyphenylpropane connected by linkages similar to those found<br />

in spruce lignin.<br />

309. Negi, J.S. 1969. Chemical composition of hemicellulose of bamboo (Dendrocalamus<br />

strictus). Ph.D Thesis, Agra University, Agra, India.<br />

310. Negi, J.S. 1970. Effect of hemicellulose on paper making properties of bamboo<br />

(Dendrocalamus strictus) sulphate pulp. Indian Pulp <strong>and</strong> Paper 24(8): p347.<br />

311. Pant, R; Singh, M.M; Guha, S.R.D. 1975. Studies on bamboo lignins. Journal of the Indian<br />

Academy of Wood Science 6(2): 61-71.<br />

Lignins were extracted from Dendrocalamus strictus by several methods, <strong>and</strong> analysed in several<br />

ways. The results indicate that there are 2 main fractions present: (A) amounting to 52, with a higher<br />

methoxyl value, easily extracted by organic acids <strong>and</strong>in which guaiacyl <strong>and</strong> syringyl repeating units<br />

dominate <strong>and</strong> (B) with a lower methoxyl value, extractable with more drastic treatment (periodic <strong>and</strong><br />

sulphuric acid) <strong>and</strong> in which there are more p-hydroxy-phenyl propane units.<br />

312. Rita Dhawan; Singh, S.V. 1982. Chemical characterization of hemicelluloses isolated<br />

from three species of bamboo Dendrocalamus strictus, Dendrocalamus hamiltonii<br />

<strong>and</strong> Melocanna baccifera. Journal of the Indian Academy of Wood Science 13(2): 62-66.<br />

A comparison of the chemical composition of hemicelluloses (Beta 17-20 percent yield) from three<br />

bamboo species viz. Dendrocalamus strictus, D.hamiltonii <strong>and</strong> Melocanna baccifera is reported. The<br />

gas liquid chromotography (GLC) of hemicelluloses indicated that xylose (=82-92 percent yield) is the<br />

main constituent of the hemicelluloses from all the three species. Glucose, arabinose, rhimnose <strong>and</strong><br />

glucuronic acid were also found to be present in small amounts in all the hemicelluloses. The yield of<br />

sugars was highest in case of D.strictus, whereas pentosans <strong>and</strong> methoxyl content were the highest in<br />

the case of D.hamiltonii. M.baccifera had the lowest yield of sugars, pentosans <strong>and</strong> methoxyl content.<br />

313. Sabharwal, H.S; Singh, S.V; Singh, M.M; Guha, S.R.D; Jain, K.D. 1962. Chlorination of<br />

bamboo protolignin. Indian Pulp <strong>and</strong> Paper 31(1): p13.<br />

314. Schowing, A.G; Johansson, G. 1965. Determination of acid soluble lignin in<br />

semichemical bisulphite pulps <strong>and</strong> in some wood <strong>and</strong> plants. Syensk Paperstard<br />

68(18): 607-613.<br />

315. Shimada, M. 1972. Biochemical studies on <strong>Bamboo</strong> lignin <strong>and</strong> methoxylation in<br />

hardwood <strong>and</strong> softwood lignins. Wood Research No.53: 19-65.<br />

Gives a detailed account of research on the mechanism governing the biochemical <strong>for</strong>mation of<br />

lignins in higher plants, based on an extensive review of world literature <strong>and</strong> on the author's studies of<br />

lignin from <strong>Bamboo</strong> (Phyllostachys sp.), Pine (Pinus thunbergii) <strong>and</strong> Ginkgo biloba.<br />

316. Singh, M.M; Bhola, P.P. 1978. Chemical nature of soda lignins <strong>and</strong> pulp sheet<br />

properties of Indian bamboos. Indian Forester 104(6): 438-449.<br />

The difference in the lignin content of different species of Indian bamboo is very negligible (24+-3)<br />

percent. The carbon <strong>and</strong> hydrogen content of these lignins are 59.7 percent with a variation of 3<br />

percent respectively. The number of c9 units varies from 12 to 21 with an average of 14 indicating that<br />

the structure of carbon lignin skeleton is more similar to hardwoods than conifers. The I.R. spectra is<br />

similar <strong>and</strong> show bamboo lignin composed of polymer. There is a correlation between the number of c9<br />

units of different bamboos <strong>and</strong> breaking length of the beaten pulps.<br />

40


317. Singh, M.M; Mathur, G.M; Jain, K.D. 1974. Isolation of carbohydrates <strong>and</strong> preparation of<br />

alphacellulose from bamboo (Dendrocalamus strictus) to study alkali resistance of<br />

hemicelluloses. Indian Pulp <strong>and</strong> Paper 24(4/5): 19-21.<br />

318. Singh, S.V; Singh, S.P; Bh<strong>and</strong>ari, S.S; Saini, B.K. 1987. Chemical modification of lignin in<br />

high yield pulps - A new approach to improve strength properties <strong>and</strong> bleachability.<br />

IPPTA 24(1): 27-31.<br />

The paper gives an account of the improvement achieved in strength properties <strong>and</strong> bleachability<br />

of high yield pulps through chemical modification of their lignin. Soda thermo mechanical (STM) <strong>and</strong><br />

soda-sulphite thermomechanical (SSTM) pulps of bamboo are modified using chlorine sodium sulphite<br />

<strong>and</strong> hypochlorite.<br />

319. Takei, T; Kato, N; Iijima, T; Higaki, M. 1995. Raman spectroscopic analysis of wood <strong>and</strong><br />

bamboo lignin. Mokuzai Gakkaishi, Journal of the Japan Wood Research Society 41(2):<br />

229-236.<br />

Fundamental conditions to record near-infrared excited Fourier-trans<strong>for</strong>m Raman spectra from<br />

wood meal samples were studied. Favourable Raman spectra were obtained at 150-200 mW of laser<br />

power with more than 100 scanning. The size of meal samples, in the range of 20-200 mesh, had no<br />

influence on the spectra. Under these conditions Raman spectra were recorded from meal samples of<br />

Fagus crenata, Cryptomeria japonica <strong>and</strong> Phyllostachys pubescens as typical hardwood, softwood,<br />

<strong>and</strong> bamboo species, respectively. On F. crenata, a weak Raman b<strong>and</strong> at 1740 cm <strong>and</strong> a strong one at<br />

1330 cm were observed, whereas on C. japonica no Raman b<strong>and</strong> at 1740 cm <strong>and</strong> a weak one at 1330<br />

cm were observed. In addition, on C. japonica, the relative intensity at 1600 cm, which was assigned to<br />

the lignin, was stronger than on F. crenata. On P. pubescens, extremely strong b<strong>and</strong>s, which were<br />

assigned to the lignin <strong>and</strong> phenolic acids, were observed at 1630 cm <strong>and</strong> 1604 cm. Upon<br />

delignification of F. crenata <strong>and</strong> C. japonica meal samples,the Raman b<strong>and</strong> intensities decreased at<br />

1660 cm, 1600 cm, 1460 cm, 1330 cm, 1030 cm <strong>and</strong> 800 cm. In the case of P. pubescens, the same<br />

b<strong>and</strong>s as F. crenata <strong>and</strong> C. japonica, except 1660 cm, <strong>and</strong> the b<strong>and</strong>s at 1630 cm decreased as a<br />

result of delignification. These results indicate that the Raman b<strong>and</strong>s decreased by delignification are<br />

assigned to lignin. By recording Raman spectra from meal samples, the in<strong>for</strong>mation on native-state<br />

lignin may be obtained directly <strong>and</strong> easily.<br />

320. Yoshinaga, A; Fujita, M; Saiki, H. 1989. Evaluation of the varieties of lignins in wood <strong>and</strong><br />

bamboo cell walls by Maule colour reaction coupled with microscopic<br />

spectrophotometry. Bulletin of the Kyoto University Forests No. 61: 276-284.<br />

Variations in lignin structure were compared <strong>for</strong> hinoki (Chamaecyparis obtusa), makanba (Betula<br />

maximowicziana), buna (Fagus crenata), mizunara (Quercus crispula), hinoki compression wood, <strong>and</strong><br />

the bamboo mousouchiku (Phyllostachys pubescens). Fibre walls of makanba <strong>and</strong> mizunara, rich in<br />

syringyl lignin, stained red <strong>and</strong> showed light absorption at 510-520 nm. Walls of makanba vessels,<br />

mizunara earlywood vessels <strong>and</strong> hinoki tracheids, rich in guaiacyl lignin, were stained yellow-brown<br />

with no absorption at 510-520 nm. Amount of cell wall syringyl lignin decreased in the order: fibre ><br />

fibre/tracheid > tracheid = vessel. Compression wood tracheids <strong>and</strong> some bamboo cells stained dark<br />

brown, <strong>and</strong> exhibited light absorption at 300-400 nm, perhaps due to the presence of p-hydroxyphenyl<br />

propane <strong>and</strong> p-coumaric acid. Results suggest that cells rich in syringyl lignin act as mechanical or<br />

physical supports rather than as water conductors.<br />

321. Yoshizawa, N; Idei, T. 1980. Sugar composition of bamboo hemicellulose. On the<br />

fractionation of the mannan-containing hemicellulose. Bulletin, Utsunomiya University<br />

Forests No. 16: 57-64.<br />

It samples from 1-yr-old Phyllostachys heterocycla var. pubescens P. pubescens.<br />

322. Zafar, S.I; Abdullah, N. 1987. <strong>Bamboo</strong> wood delignification by Coriolus versicolor. The<br />

Malaysian Forester 50(1): 121-123.<br />

Coriolus versicolor is found to degrade lignin in bamboo. The study deals with the bamboo - C.<br />

versicolor solid state fermentation interaction. Contents of lignin, cellulose <strong>and</strong> water soluble<br />

substances, be<strong>for</strong>e <strong>and</strong> after the bamboo wood degradation by C. versicolor as well as organic matter<br />

loss during the solid state fermentation period of 14 days are presented in a table. <strong>Bamboo</strong> wood<br />

41


lignin content fell from 36.5 to 29.9 per cent which represents 18.1 per cent degradation of lignin in 14<br />

days.<br />

323. Zeng, M.C; Xiang, Y.M. 1987. Study on bamboo cellulose triacetate. Journal of <strong>Bamboo</strong><br />

Research 6(2): 39-49.<br />

The quality of bamboo cellulose triacetate (CTA) <strong>and</strong> ultrafiltration membranes produced from it<br />

was equal to or better than that of cotton CTA <strong>and</strong> membranes.<br />

Fibre Morphology <strong>and</strong> Characteristics<br />

324. Abdul Latif Mohamod; Khoo, K.C; Jamaludin, K; Jalil, A.A. 1994. Fibre morphology <strong>and</strong><br />

chemical properties of Gigantochloa scortechinii. Journal of Tropical Forest Science<br />

6(4): 397-407.<br />

325. Alvin, K.L; Murphy, R.J. 1988. Variation in fibre <strong>and</strong> parenchyma wall thickness in culms<br />

of the bamboo Sinobambusa tootsik. IAWA Bulletin 9(4): 353-361.<br />

In order to elucidate whether perceptible anatomical changes occur with aging, 3 culms whose<br />

ages were estimated to be less than 1 yr, between 1 <strong>and</strong> 2 yr, <strong>and</strong> more than 2 yr, were cut from a<br />

plant in greenhouse cultivation in the UK <strong>and</strong> the middle 1 cm portions of the 6th <strong>and</strong> 12th internodes<br />

were examined. There were significant increases in av. cell wall thickness of the fibres <strong>and</strong> ground<br />

tissue parenchyma with age. Of the 4 different tissues examined, only the cortical parenchyma<br />

remained unchanged. The basic density of the culms also increased with age. There was clear<br />

evidence of the persistence of living protoplasts in fibres <strong>and</strong> parenchyma with the possible exception<br />

of the thickest walled fibres. Progressive thickening of the cell walls with time is consistent with the<br />

reported increase in mechanical strength of bamboo culms over a period of time. It is stressed that<br />

these observations need to be verified using accurately aged culms of a range of species growing<br />

naturally.<br />

326. Chu, W.F; Yao, H.S. 1964. Studies on the fibre structure of 33 Chinese bamboos<br />

available <strong>for</strong> pulp manufacture. Sci. Silvae, Peking 9(4): 311-327.<br />

A detailed study (with 2-page English summary) of fibre length, cell-wall thickness, percentages of<br />

fibres <strong>and</strong> other elements, <strong>and</strong> density. Of the 33 species examined, 21 are listed as promising <strong>for</strong><br />

yielding high-quality pulp.<br />

327. Foelkel, C.E.B; Barrichelo, L.E.G; Manfredi, V; Fazanaro, R. 1976. Quantitative analysis of<br />

cellulosic fibres. Papel 37: 59-64.<br />

Microscopic analyses of cellulose fibres were made to determine weight factors <strong>and</strong> 'coarseness'<br />

of papermaking pulps commonly encountered in Brazil (unbleached kraft pulps from Araucaria<br />

angustifolia, Bambusa vulgaris, Eucalyptus saligna, Pinus elliottii <strong>and</strong> Joannesia princeps; bleached<br />

kraft pulp from E. saligna; bagasse soda pulp; NSSC, thermomechanical <strong>and</strong> chemimechanical pulps<br />

from eucalypts; <strong>and</strong> mechanical pulp from A. angustifolia). The determination of the quantitative<br />

composition of fibre mixtures in commercial pulps <strong>and</strong> papers from weight factors is outlined.<br />

328. Hu, C.Z; Zhou, J.Y; Lan, X.G; Yang, L.P. 1986. Changes in nutrient composition of<br />

bamboo shoots of different ages. Journal of <strong>Bamboo</strong> Research 5(1): 89-95.<br />

M.c. <strong>and</strong> fibre content increased with age in Phyllostachys pubescens, while proteins, amino<br />

acids, fats, sugars, inorganic salt contents, P, Ca <strong>and</strong> Fe concentration decreased.<br />

329. Huang, L.Y; Zhu, L.F; Hu, A.Q. 1992. Study on the fibre length <strong>and</strong> culm properties of<br />

five bamboo species in Hunan, China. <strong>Bamboo</strong> <strong>and</strong> its Use. <strong>International</strong> Symposium<br />

on Industrial Use of <strong>Bamboo</strong>, 7-11 December 1992, Bejing, China. Chinese Academy of<br />

Forestry <strong>and</strong> <strong>International</strong> Tropical Timber Organization: 129-132.<br />

The length of fibre, amount of vascular bundles <strong>and</strong> properties of physical mechanics have been<br />

determined <strong>for</strong> Indosasa levigata, Phyllostachys kwangsiensis, P. bambusoides, P. heteroclada <strong>and</strong> P.<br />

42


virdis in Yiyang, Hunan. The results show that the length of fibre is variation in different parts of the<br />

bamboo culm, such as the fibre of tabashir is longer than that of green skin at the base of culm, no any<br />

difference in the middle <strong>and</strong> shorter at the top. The thickness of culm wall is thicker at the base <strong>and</strong><br />

thinner at the top. The internodes are longest in the middle of culm <strong>and</strong> the amount of vascular bundle<br />

is maximum at the top. The five species are excellent ones.<br />

330. Jamaludin K; Jalil, A.A. 1994. Fiber <strong>and</strong> chemical properties of Bambusa vulgaris<br />

Schrad.. <strong>Bamboo</strong> in Asia <strong>and</strong> the Pacific. Proceedings of the Fourth <strong>International</strong><br />

<strong>Bamboo</strong> Workshop, Chiangmai, Thail<strong>and</strong>. IDRC, Canada <strong>and</strong> FORSPA, Bangkok: 218-229.<br />

The paper discusses the variation of fiber <strong>and</strong> chemical properties of different portions of<br />

Bambusa vulgaris. A significant effect of bamboo portion, location position on cell wall thickness,<br />

fibrelength, slenderness ratio, holocellulose <strong>and</strong> ash content is reported. A significant effect of bamboo<br />

portion, location on specific gravity <strong>and</strong> 1 percent NaOH solubility is also shown. Fibre <strong>and</strong> chemical<br />

properties are found to have significant effect. The base portion is reported to have the longest<br />

fibrelength 3.51mm), highest slenderness ratio (245.0), lowest holocellulose content(70.8 percent) <strong>and</strong><br />

highest one percent NaOH solubility(26.5 percent) as compared to the middle <strong>and</strong> top portions.<br />

331. Jamaludin K; Jalil A.A; Abd. Latif Mohmod; Khoo, K.C. 1994. A note on the proximate<br />

chemical <strong>and</strong> fibre morphology of Bambusa vulgaris. Journal of Tropical Forest Science<br />

6(3): 356-358.<br />

Data on the proximate chemical composition <strong>and</strong> density <strong>and</strong> fibre dimensions are tabulated <strong>and</strong><br />

briefly discussed based on an analysis of 50 mature culms of Bambusa vulgaris from Malaysia, as part<br />

of a study of the suitability of the species as a pulping material.<br />

332. Kitamura, H. 1962. Studies on the physical properties of bamboo. IX. On the fibre<br />

content. Journal Japan Wood Research Society 8(6): 249-252.<br />

Tabulates data on the variation of fibre content of 1- to 6-year Phyllostachys reticulata after<br />

pulping by the soda process. Age played no significant part, but fibre content was found to increase<br />

with culm height <strong>and</strong> to decrease from the outer to the inner parts of culms.<br />

333. Krishnagopalan, A. 1973. Paper <strong>for</strong>ming properties of bamboo in relation to its fiber<br />

characteristics. MSc Thesis. University of Maine at Orono.<br />

334. Ku, Y.C; Chiou, C.H; Chiu, C.H. 1972. Tests on fibre morphology <strong>and</strong> composition of<br />

important bamboos in Taiwan. Co-operative Bulletin, Taiwan Forestry Research Institute<br />

with Joint Commission on Rural Reconstruction No. 20: 8p.<br />

Tables with English caption give the results of measurements of fibre length <strong>and</strong> width, <strong>and</strong> of<br />

proximate chemical analyses(by TAPPI st<strong>and</strong>ard method Tllm-59) of the wood, of Bambusa<br />

beecheyana var. pubescens, B. stenostachya, Lelebba dolichoclada, L. oldhamii, Phyllostachys edulis,<br />

P. makinoi <strong>and</strong> Sinocalamus latiflorus.<br />

335. Li, Q. 1984. On the relation between internode length <strong>and</strong> fibre length of Pseudosasa<br />

amabilis <strong>and</strong> Bambusa pervariabilis. Journal of <strong>Bamboo</strong> Research 3(1): 89-94.<br />

For P. amabilis, correlation coefficients between internode <strong>and</strong> fibre length in inner- middle- <strong>and</strong><br />

outer- parts were respectively 0.725, 0.337 <strong>and</strong> 0.574 <strong>and</strong> generally greater than the critical value of<br />

0.381. For B. pervariabilis they were respectively 0.629, 0.638 <strong>and</strong> 0.618 <strong>and</strong> the critical value was<br />

0.361. It is suggest that the linear correlations between internode <strong>and</strong> fibre length are marked <strong>and</strong> that<br />

fibre stretch is one of the causes of internode stretching; when intercalary meristems devide, there<br />

derivative cells stretch fully be<strong>for</strong>e secondary thickening, resulting in simultaneous internode stretching.<br />

336. Liese, W; Grosser, D. 1972. Investigations on the variability of the fibre length in<br />

bamboo. Holz<strong>for</strong>schung 26(6): 202-211.<br />

Published in<strong>for</strong>mation on the fibre dimensions of 78 species of bamboo is assembled in a table.<br />

The variations in fibre length <strong>and</strong> width within one internode has been investigated in five species.<br />

Generally, the fibre length increases across the wall from the periphery <strong>and</strong> decreases again towardse<br />

the center, but the longest fibres are some times found in the outer zone. The fibre width does not<br />

43


follow a similar pattern. A considerable variation exists longitudinally within one internode, the shortest<br />

fibres occuring at or near the nodes. A small decrease in fibre length occurs with increasing height in<br />

culm.<br />

337. Ma, L.F; Zhu, L.Q. 1990. Fibre <strong>for</strong>ms <strong>and</strong> tissue percentage of six species of sympodial<br />

bamboos in Zhejiang Province. Journal of the Zhejiang Forestry College 7(1): 63-68.<br />

Fibre length (L) width (W), L/W, cell wall thickness (T), lumen diameter (D), T/D <strong>and</strong> the<br />

percentage of fibre tissue were recorded <strong>for</strong> Lingnania wenchouensis, L. chungii, Bambusa oldhamii,<br />

B. textilis var. fusca, Sinocalamus (Dendrocalamus) latiflorus <strong>and</strong> S. (D.) beechayana. Fibre lengths<br />

were gratest in the middle of the bamboo shaft, while w decreased from ground level upwards. The<br />

percentage of fibre tissue decreased from the outside of the stem inwards <strong>and</strong> from the top of the stem<br />

downwards.<br />

338. Monsalud, M.R. 1965. Fibre characteristics of bamboo species in the Philippines.<br />

Conference on Pulp <strong>and</strong> Paper Development in Africa <strong>and</strong> Near East Cairo.<br />

Fibre characteristics of thirteen bamboo species of Philippines are discussed.<br />

339. Murphy, R.J; Alvin, K.L. 1992. Variation in fibre wall structure in bamboo. IAWA Bulletin<br />

13(4): 403-410.<br />

The degree of polylamellation in the fibre cell walls of Phyllostachys virideglaucescens was<br />

investigated. The extent of polylamellation was found to be influenced by position of the vascular<br />

bundle in the culm wall, in certain positions by age of the culm <strong>and</strong>, most strikingly, with position within<br />

the vascular bundle. The number of wall lamellae was variable but tended to the greatest in fibres<br />

adjacent to either vascular elements or ground tissue at the periphery of the fibre bundles. A similar<br />

pattern of variation in fibre wall lamellation was also observed in two other species of bamboo.<br />

340. Murphy, R.J; Alvin, K.L. 1997. Fibre maturation in the bamboo Gigantochloa<br />

scortechinii. IAWA Journal 18(2): 147-156.<br />

Fibre maturation, which has been shown in a number of bamboos to be a process extending over<br />

a long period after the culm has reached its full height, was investigated in comparable internodes (6th<br />

above ground level) in culms of Gigantochloa scortechinii up to three years old, with special reference<br />

to the fibres constituting the free fibre str<strong>and</strong>s immersed in the ground tissue. The possession of such<br />

str<strong>and</strong>s is characteristic of this pachymorph species. The fibres of the free str<strong>and</strong>s were notable more<br />

heterogeneous in terms of their diameter than those of the fibre cape adjacent to the vascular tissues.<br />

It is in some of the larger fibres of the free str<strong>and</strong>s that wall thickening is longest delayed, so that, even<br />

after three years, many still remain comparatively thin walled, especially in the inner region of the culm<br />

wall. Fibres retain a living protoplast <strong>and</strong> appear to undergo progressive septation.<br />

341. Murphy, R.J; Alvin, K.L; Chapman, G.P. 1997. Fibre maturation in bamboos. The<br />

bamboos. Proceedings of an <strong>International</strong> Symposium, London, 25-29 March 1996. Linnean<br />

Society Symposium Series No. 19. Academic Press <strong>for</strong> the Linnean Society of London, San<br />

Diego, USA: 293-303.<br />

Cell diameter, cell wall thickness, degree of cell wall lamellation, development of lignification <strong>and</strong><br />

culm density were studied in Phyllostachys viridi-glaucescens <strong>and</strong> Sinobambusa tootsik cultivated at<br />

the Royal Botanic Gardens, Kew, <strong>and</strong> in Gigantochloa scortechinii from a natural st<strong>and</strong> in peninsular<br />

Malaysia. Maturation of fibres was extremely heterogeneous <strong>and</strong> influenced by height in the culm,<br />

location of the vascular bundle across the culm wall <strong>and</strong> location of the fibres within vascular bundles.<br />

Fibres which matured earliest in development occurred in the lower internodes around the periphery of<br />

the culm wall <strong>and</strong> immediately adjacent to vascular tissue. In middle <strong>and</strong> inner parts of the culm wall,<br />

fibre maturation was observed to take place over at least 3 growing seasons with progressive cell wall<br />

thickening <strong>and</strong> lignification of the newly <strong>for</strong>med wall material. These findings are discussed with<br />

reference to mechanical properties of bamboos.<br />

342. Nomura, T; Yamada, T. 1977. On the discrete diffraction of small angle X-ray scattering<br />

of bamboo (Phyllostachys mitis). Wood Research No. 62: 11-18.<br />

44


Discrete diffraction depending on periodically recurring elements (interparticle interference) was<br />

observed both parellel <strong>and</strong> perpendicular to the fibre direction. Crystallite length <strong>and</strong> width were<br />

calculated to be about 11µ m <strong>and</strong> 4.8 µ m respectively.<br />

343. Ota, M. 1955. Studies on the properties of bamboo stem. Part II: On the fibresaturation<br />

point obtained from the effect of the moisture content on the swelling <strong>and</strong><br />

shrinkage of bamboo splint. Bulletin Kyushu University Forestry 24: 61-72.<br />

Full research report on the subject mentioned in the title. Full statistical analysis is provided.<br />

Contains eleven tables <strong>and</strong> three figures.<br />

344. Paremeswaran, N; Liese, W. 1976. On the fine structure of bamboo fibres. Woodscience<br />

<strong>and</strong> Technology 10: 231-246.<br />

The ultrstructure of bamboo fibres are investigated using various techniques. Studies are made<br />

on the following seven species, Cephalostachyum pergracile, Dendrocalamus latiflorus, D. strictus,<br />

Melocanna bambusoides, Oxytenanthera abyssinica, Phyllostachys edulis <strong>and</strong> Thyrsostachys oliveri.<br />

345. Patel, M; Trivedi, R. 1994. Variations in strength <strong>and</strong> bonding properties of fines from<br />

filler, fiber, <strong>and</strong> their aggregates. TAPPI Journal 77(3): 185-192.<br />

346. Pattanath, P.G. 1972. Trend of variation in fibre length in bamboos. Indian Forester<br />

98(4): 241-243.<br />

The trend in the variation of fibre length within a culm has been studied <strong>for</strong> twelve different species<br />

of bamboos. While the fibre length in the lower portion of the culm is more than at higher levels, the<br />

pat1tern of variation differ from species to species. Fibre length also does not show any consistent<br />

relationship with internode length in the species investigated.<br />

347. Preston, R.D; Singh, K. 1950. The fine strcture of bamboo fibres. I. Optical properties<br />

<strong>and</strong> X-ray data. Journal of Experimental Botany 1(2): 214-226.<br />

A detailed investigation is made on the fine structure of a wide variety of bamboo fibres. A<br />

combination of X-ray analysis, measurement of refractive indices in longitudinal view <strong>and</strong> of phase<br />

differences in transverse section has presented a complete picture of cellulose chain orientation.<br />

Attention is given to the general molecular architecture of bamboo fibres <strong>and</strong> particularly the relation of<br />

molecular structure to fibre dimensions.<br />

348. Rajulu, A.V; Reddy, G.R; Chary, K.N. 1996. Chemical resistance <strong>and</strong> tensile properties<br />

of epoxy-coated bamboo fibres. Indian Journal of Fibre <strong>and</strong> Textile Research 21: 223-224.<br />

The chemical resistance <strong>and</strong> tensile load at break of bamboo fibres (Dendrocalamus strictus)<br />

be<strong>for</strong>e <strong>and</strong> after coating with a high per<strong>for</strong>mance epoxy resin(Araldite LY 5052/Hardner 5052 system)<br />

have been studied. It is observed that the tensile load at break <strong>and</strong> chemical resistance of bamboo<br />

fibres increase on coating, indicating that epoxy resin <strong>and</strong> bamboo fibres are favourable materials <strong>for</strong><br />

making the composites.<br />

349. Sahu, A.K; Patel, M. 1996. Effect of fibres on the optical properties of bamboo pulp.<br />

IPPTA 8(1): 43-47.<br />

350. Shanmughavel, P; Francis, K. 1996. Trend of variation in fibre-length in an age series of<br />

Bambusa bambos. Journal of Tropical Forestry 12(4): 208-211.<br />

Analyses were made of fibre length <strong>and</strong> fibre classification in pulps prepared from chips of<br />

Bambusa bambos from plantations of ages ranging from 1 to 6 yr old. No appreciable change in fibre<br />

length <strong>and</strong> percentage content of +50, +65, +100 <strong>and</strong> -100 mesh fibres in both unbleached pulp <strong>and</strong><br />

bleached pulps was found with increasing age. The results indicate this bamboo species attains<br />

maturity during the first year of growth, so that <strong>for</strong> pulping purposes, it is suitable <strong>for</strong> a 1-yr cutting<br />

cycle.<br />

45


351. Shanmughavel, P; Francis, K. 1998. Comparison of fibre-length of plantation grown<br />

bamboos with natural st<strong>and</strong> bamboos. Van Vigyan 36(2/3/4): 125-127.<br />

Comparisons between the fibre dimensions (length, diameter <strong>and</strong> wall thickness) of 10 bamboo<br />

species (3 Bambusa spp. including B. bambos, 4 Dendrocalamus spp., Melocanna baccifera,<br />

Schizostachyus dullooa [Schizostachyum dullooa], Ochl<strong>and</strong>ra travancoricaPhyllostachys<br />

bambusoides) in [a] natural st<strong>and</strong> in [Tamil Nadu] India, <strong>and</strong> 2 species in plantations (Gigantochloa<br />

scortechinii, 3 yr old; <strong>and</strong> B. bambos, 1-6 yr old) showed no significant differences between them.<br />

There were no significant correlations between fibre length, diameter <strong>and</strong> wall thickness. There was<br />

only a minimal increase in fibre length with increasing age of plantation-grown B. bambos. However,<br />

there was a significant difference in fibre length across culms. The investigation was carriedout from<br />

the viewpoint of utilizing bamboos <strong>for</strong> pulpwood.<br />

352. Siddique, A.B; Chowdhury, A.R. 1982. Fibre dimensions of some wood, bamboo <strong>and</strong><br />

green species with special reference to their usefulness in paper making. Bano Bigyan<br />

Patrika 11(1/2): 56-62.<br />

Fibre dimensions of various wood, bamboo <strong>and</strong> grass species <strong>and</strong> miscellaneous fibrous materials<br />

of Bangladesh were studied in the Pulp <strong>and</strong> Paper Division of the Forest Research Institute,<br />

Chittagong. The data from these studies are compiled in this review <strong>and</strong> the species graded as very<br />

good, good or poor <strong>for</strong> paper making on the basis of Runkel ratio. The other properties, viz, flexibility<br />

co-efficient <strong>and</strong> relative fibre length have also been determined, since these properties are reported to<br />

be correlated to the tensile strength <strong>and</strong> tearing resistance of paper. Out of the species studied, 33<br />

wood, 3 bamboo, 2 grass <strong>and</strong> 4 miscellaneous species have been found promising <strong>for</strong> paper making.<br />

353. Singh, M.M; Purkayastha, S.K; Bhola, P.P; Lal, K; Singh, S. 1976. Fibre morphology <strong>and</strong><br />

pulp sheet properties of Indian bamboos. Indian Forester 102(9): 579-595.<br />

Fibre morphology <strong>and</strong> pulp strength of twelve species of bamboos studied in two sets of pulps. In<br />

all species fibre dimensions <strong>and</strong> parenchyma properties varied widely. But there was no significant<br />

difference in respect of chemical composition <strong>and</strong> alkali consumed during pulping. In respect of<br />

strength properties there was marked difference between beaten <strong>and</strong> unbeaten pulps. No relationship<br />

could be observed between fibre characteristics <strong>and</strong> the pulp strength properties. The study revealed<br />

that fibre characteristics cannot be used as a criterion <strong>for</strong> selecting bamboos <strong>for</strong> pulp <strong>and</strong> paper<br />

production.<br />

354. Singh, M.M; Purkayastha, S.K; Bhola, P.P; Lakshmi Sharma. 1971. Influence of variation<br />

in fibre dimensions <strong>and</strong> parenchyma proportion on sheet properties in bamboo. Indian<br />

Forester 97(7): 412-421.<br />

The effect of variations in fibre dimensions on strength properties are studied by testing<br />

h<strong>and</strong>sheets made from 32 mixtures of different fractions of pulp of Dendrocalamus strictus, beaten to<br />

250 ml (CSF). Fibre length, determined from unbeaten pulpaccounts <strong>for</strong> 77 to 90 per cent of the<br />

variations in strength properties. Parenchyma proportion shows a high negative correlation with the<br />

sheet properties. Fibre length <strong>and</strong> parenchyma proportion together account <strong>for</strong> 94 percent of the<br />

variation in strength properties.<br />

355. Tamolang, F.N. 1962. Fibre dimensions of some Phillipine fibrous materials. Philippine<br />

Journal of Forestry 18(1/4): 59-60.<br />

Gives tabulated data <strong>for</strong> hardwoods, softwoods, palms, bamboos, agricultural crops <strong>and</strong> wastes,<br />

grasses etc. It seems likely that, as in India, <strong>Bamboo</strong>s will become an increasingly important source of<br />

long-fibred paper pulps.<br />

356. Wai, N.N; Murakami, K. 1984. Relationship between fiber morphology <strong>and</strong> sheet<br />

properties of Burmese bamboos. Journal of the Japan Wood Research Society 30(2):<br />

156-165.<br />

Fibre morphology <strong>and</strong> papermaking properties of whole <strong>and</strong> fines-free pulps were investigated <strong>for</strong><br />

6 major species of Burmese bamboo. Based on the distribution of the Runkel ratio of the fibres in a<br />

cross section of the tissue, the bamboo species used inthis study were placed in 3 groups: group A<br />

(Melocanna bambusoides) that contains a substantial number of thin-walled fibres; group B (Bambusa<br />

46


polymorpha <strong>and</strong> Dendrocalamus membranaceus) that contain a small number of thin-walled fibres;<br />

<strong>and</strong> group C (Cephalostachyum pergracile, B. tulda, <strong>and</strong> D. longispathus) that consist almost entirely<br />

of thick-walled fibres with very small lumen. It was found that this grouping is very useful in evaluating<br />

<strong>and</strong> explaining sheet properties. The influence of fibre morphology on sheet properties was much<br />

greater in the fines-free pulp sheets than in the whole pulp sheets. The sheets of group A pulp were<br />

denser <strong>and</strong> had significantly better sheet-strength properties, except <strong>for</strong> tear index, than the sheets of<br />

other pulp groups of the same beating levels. The small amount of thin-walled fibres contributed to the<br />

burst index <strong>and</strong> the folding endurance of the group B fines-free pulp sheets. The effect of the presence<br />

of fines on sheet properties is also discussed.<br />

357. Wai, N.N; Nanko, H; Murakami, K. 1985. A morphological study on the behavior of<br />

bamboo pulp fibers in the beating process. Wood Science <strong>and</strong> Technology 19(3):<br />

211-222.<br />

<strong>Bamboo</strong> pulp fibres respond to beating more rapidly than do wood fibres; this is probably due to<br />

the difference in secondary wall structure between the fibres. In a study on the fibre morphology of<br />

Bambusa polymorpha, the secondary wall was seen to consist of alternately arranged broad <strong>and</strong><br />

narrow layers. During the beating process, a number of transverse <strong>and</strong> concentric cracks are<br />

generated in the broad layers, which causes an internal fibrillation. The outer broad layers with their<br />

numerous cracks separate from the inner layers <strong>and</strong> swell greatly toward the outside. The outer<br />

secondary wall layer of bamboo fibres has a microfibril angle of about 20° with respect to the fibre axis<br />

which is much smaller than that of the S1 layer of wood fibres. As a result, this layer appears to offer<br />

little resistance to prevent the external swelling of the broad layers.<br />

358. Xia, Y.F; Zeng, J. 1996. Studies on the fibre morphology of Bambusa distegus of<br />

different ages. Journal of <strong>Bamboo</strong> Research 15(1): 45-51.<br />

This species is one of the main raw materials <strong>for</strong> papermaking in Chishui, Guizhou Province,<br />

China. Details are given of ranges found in fibre length, width, cell wall thickness <strong>and</strong> cavity diameter.<br />

Fibre length <strong>and</strong> cell wall thickness increased with age, while cavity diameter decreased.<br />

359. Zamuco, G.I.T. 1972. Fibre length variability in relation to the anatomical structure of<br />

bamboo. Technical Note No. 115, Forest Products Research <strong>and</strong> Development<br />

Commission, Philippines: 4p.<br />

Briefly discusses fibre-length variability in <strong>Bamboo</strong>s, with particular reference to the species<br />

suitable <strong>for</strong> manufacturing pulp <strong>and</strong> paper that are grown in the Philippines.<br />

Mechanical Pulping<br />

360. Chao, S.C; Pan, T.T. 1963. Studies on magnifite process <strong>for</strong> bamboo pulp <strong>and</strong> paper<br />

making. Bulletin of Taiwan Forest Research Institute with Joint Commission on Rural<br />

Reconstruction No. 19: 10p.<br />

Advantages of the process <strong>for</strong> pulping Dendrocalamus latiflorus were: increased pulp yield, a<br />

stronger pulp, shorter cooking times <strong>and</strong> reduced consumption of SO.<br />

361. Chen, S.C; Lin, S.J; Lin, S.C. 1974. The multistage digestion of Taiwan bamboo <strong>for</strong><br />

pulping. Bulletin of Taiwan Forestry Research Institute No. 242: 16p.<br />

Pulps <strong>for</strong> printing papers were prepared from 5 species of bamboo by three pulping processes:(a)<br />

two-stage digestion with hot water (150 o C) followed by NaOH; (b) two-stage digestion with dilute<br />

NaOH (at 100 o C) followed by more concentrated NaOH; <strong>and</strong> (c) single-stage digestion with NaOH. In<br />

each trial the pulp was bleached in three stages be<strong>for</strong>e testing. Process (a) gave the highest yield <strong>and</strong><br />

best physical properties of pulp <strong>and</strong> the lowest bleaching ratio, resulting in economical pulping. The<br />

pulps with the best physical properties were from Bambusa beecheyana var. pubescens <strong>and</strong> B.<br />

dolichoclada, followed by B. stenostachya <strong>and</strong> Dendrocalamus latiflorus; Phyllostachys makinoi was<br />

judged the least suitable. Since B. beecheyana var. pubescens can be grown on a 3-year rotation, its<br />

planting is recommended as a solution to the raw material supply problem in the Taiwan paper<br />

industry.<br />

47


362. Eberhardt, L. 1968. Hi-yield <strong>and</strong> mechanical type pulp from raw materials of India.<br />

Indian Pulp <strong>and</strong> Paper 23(1): 49-51.<br />

Tabulates <strong>and</strong> discusses the suitability of Indian materials, including tropical hardwoods, eucalypts<br />

<strong>and</strong> bamboo, <strong>for</strong> high-yield <strong>and</strong> refiner mechanical pulping.<br />

362a. Lund, H. 1942. Mechanical disintegrator of wood <strong>for</strong> production of fibres. German<br />

Petant No. 720190, April 2, 1942.<br />

363. Perdue, R.E; Kraebel, C.J; Kiang, T. 1961. <strong>Bamboo</strong> mechanical pulp <strong>for</strong> manufacture of<br />

Chinese ceremonial paper. Economic Botany 15(2): 161-164.<br />

Total Taiwan production of this "joss" paper is 4500-5000 tons/year, a large proportion h<strong>and</strong>-made<br />

in 500 small mills from bamboo. Bambusa stenostachya, Dendrocalamus latiflorus, <strong>and</strong> E. oldhamii<br />

are chiefly used <strong>for</strong> the machine-made groundwood paper of the Kung-chin mill, the operation of which<br />

is described. Phyllostachys pubescens is chiefly used in the mainl<strong>and</strong>.<br />

364. Rao, M.S; Rao, B.Y; Agshikar, B.M. 1962. H<strong>and</strong> made paper from bamboo by cold soda<br />

process. Indian Pulp <strong>and</strong> Paper 17(4): 261-263.<br />

Chemical Pulping<br />

365. Alam, M.R; Barua, I.B; Khan, A.B. 1997. Innovation to the high yield alkaline semi<br />

chemical pulping of muli bamboo. Bangladesh Journal of Scientific <strong>and</strong> Industrial<br />

Research 32(1): 79-83.<br />

An experimental study was carried out to evaluate the possibilities of producing semichemical pulp<br />

<strong>for</strong> different end uses from muli bamboo (Melocanna baccifera) by cooking with white liquor from the<br />

recovery cycle, i.e. by adopting the kraft semichemical process. The yield <strong>and</strong> other pulping<br />

characteristics were encouraging <strong>and</strong> well within the acceptable range of <strong>for</strong> semichemical pulps. The<br />

physical strength properties <strong>and</strong> other characteristics of the pulp <strong>and</strong> h<strong>and</strong>-made sheets were tested.<br />

The strength properties of the semichemical pulps were relatively lower than those of conventional<br />

kraft pulp, but it was possible to produce an acceptable grade of pulp from under carefully chosen<br />

cooking conditions. The yield was higher (72-74) than that of conventional kraft pulp (45-48). The<br />

approximate cost of production of paper from this semichemical pulp was attractive. The investment<br />

<strong>and</strong> process modifications required to incorporate this type of pulping in the Karnaphuli Paper Mills at<br />

Ch<strong>and</strong>raghona in Bangladesh were also not major.<br />

366. Azzini, A. 1976. Influence of dimensions of culms of Bambusa vulgaris Schrad. On the<br />

yield rejects percentage, kappa number <strong>and</strong> brightness of pulp obtained by the<br />

sulphate process. Papel 37: 125-127.<br />

The best overall results were obtained with chips of 6.0 x 0.8 x 0.6 cm. Most rejects, minimum<br />

brightness <strong>and</strong> highest kappa number were obtained with the largest size of chips studied (6.0 x 1.2 x<br />

1.0 cm). Data are also given <strong>for</strong> density, void vol., fibre dimensions <strong>and</strong> chemical composition of the<br />

bamboo.<br />

367. Azzini, A; Gondim, T.R.M.A. 1996. Starch extraction from bamboo chips treated with<br />

diluted sodium hydroxide solution. Bragantia 55(2): 215-219.<br />

In culms of Bambusa vulgaris (1 <strong>and</strong> 5 years of old), the contents of starch fibrous materials <strong>and</strong><br />

parenchymatous residue were determined using sodium hydroxide solution concentrations of 0.25,<br />

0.50 <strong>and</strong> 0.75 <strong>for</strong> 5, 10 <strong>and</strong> 15 hours <strong>and</strong> shredding times of 30, 60 <strong>and</strong> 90 seconds. The contents of<br />

starch , fibrous materials <strong>and</strong> parenchymatous residue were not affected by sodium hydroxide<br />

concentration <strong>and</strong> treatment time. The highest starch quantity (75.22 g/kg) was obtained at the<br />

highest shredding time (90 seconds) from the 5 year bamboo culms. This study showed the starch<br />

extraction is feasible technically as a pretreatment of the bamboo chips employed to produce pulp <strong>and</strong><br />

paper.<br />

48


368. Azzini, A; Nagai, V; Ciaramello, D. 1979. Alkaline monosulphite pulping of Bambusa<br />

vulgaris schrad [<strong>Bamboo</strong>: Fiber]. Bragantia 38(14): 131-144.<br />

369. Banthia, K.M; Mishra, N.D. 1968. Recovery of bamboo dust <strong>and</strong> knotter rejects (nodes)<br />

in a bamboo kraft pulp mill. Indian Pulp <strong>and</strong> Paper 23(2): 171-174.<br />

369a. Banthia, K.M; Mishra, N.D; Rao, A.V; Rao, G.M. 1970. Some studies on high yield<br />

pulping of <strong>Bamboo</strong>. Part I – Alkali penetration behaviour of bamboo (<strong>for</strong> chemical <strong>and</strong><br />

semi-chemical pulp). Indian Pulp <strong>and</strong> Paper 25(1/6): 420-430.<br />

370. Banthia, K.M; Mishra, N.D; Rao, A.V; Rao, G.M. 1972. Some studies on high yield<br />

pulping of <strong>Bamboo</strong>. Part II - Alkali treatment of brown stock. Indian Pulp <strong>and</strong> Paper<br />

26(8/9): 101-113.<br />

Describes laboratory studies on the use of mild alkali treatments on hard, moderately hard <strong>and</strong><br />

normally cooked chemical <strong>and</strong> semichemical pulps of <strong>Bamboo</strong> [unspecified] to produce soft pulps with<br />

minimum loss of yield <strong>and</strong> properties.<br />

371. Banthia, K.M; Mishra, N.D; Rao, A.V; Rao, G.M. 1972. Some studies on high yield<br />

pulping of <strong>Bamboo</strong>. Part III - Pulp yield vis-a-vis a cooking system <strong>and</strong> re-use of<br />

wastes from <strong>Bamboo</strong>. Indian Pulp <strong>and</strong> Paper 27(1/2): 16-25.<br />

In continued work, the authors give results of a study of (1) factors affecting the relative yield of<br />

sulphate pulp obtainable from <strong>Bamboo</strong> (Dendrocalamus strictus) by two different cooking systems, <strong>and</strong><br />

(2) the potential value of recovering <strong>and</strong> using <strong>Bamboo</strong> screenings from the clipping plant, <strong>and</strong><br />

'buntings' <strong>and</strong> branches from the <strong>for</strong>est, as additional pulping material. It is concluded that recovery of<br />

available wastes could contribute to a substantial increase in <strong>Bamboo</strong> pulp yield without much difficulty<br />

or extra expense.<br />

372. Banthia, K.M; Mishra, N.D; Rao, A.V; Rao, G.M. 1972. Some studies on high yield<br />

pulping of <strong>Bamboo</strong>. Part IV - Pulp yield versus bleaching variability <strong>for</strong> <strong>Bamboo</strong> pulp.<br />

Indian Pulp <strong>and</strong> Paper. 27(3/4): 57-59, 61-67.<br />

Describes promising results of attempts to devise a practical <strong>and</strong> economical procedure <strong>for</strong><br />

improving the bleaching of <strong>Bamboo</strong> sulphate pulp without loss of pulp yield or quality. The procedure<br />

consists essentially of controlled hypochlorite bleaching followed by a mild H2O2/SO2 treatment.<br />

373. Barrichello, L.E.G; Foelkel, C.E.B. 1975. Production of sulphate pulp from mixtures of<br />

wood of Eucalyptus saligna with small proportions of chips of Bambusa vulgaris var.<br />

vittata. IPEF 10: 93-99.<br />

Different blends were made of E. saligna chips with B.v. var. vittata chips, <strong>and</strong> sulphate pulping of<br />

the mixed material was studied. Pulps made from (a) blends containing 5 <strong>and</strong> 10 <strong>Bamboo</strong> (total chip<br />

weight basis) <strong>and</strong> (b) 100 E. saligna were compared. Pulp yield <strong>and</strong> tear strength of pulps made from<br />

(a) were significantly superior to those of pulp made from (b), while there was no difference between<br />

the pulps in beating time, h<strong>and</strong>-sheet density, tensile strength <strong>and</strong> burst strength.<br />

374. Barrichello, L.E.G; Foelkel, C.E.B. 1975. Rapid alkaline pulping <strong>for</strong> the production of<br />

chemical pulp from Bambusa vulgaris var. vittata. IPEF No. 11: 83-90.<br />

Briefly describes Kleinert's rapid alkaline pulping process <strong>and</strong> gives results of an experiment on<br />

the use of this method in the production of pulp from B. v. var. vittata grown in Sao Paulo. Pulp yields<br />

<strong>and</strong> strengths comparable with those obtained by the normal sulphate process were achieved, <strong>and</strong><br />

there were savings in time <strong>and</strong> energy.<br />

375. Bharatia, D.K; Veeramani, H. 1974. Technical feasibility of vanillin production from<br />

bamboo black liquor. Indian Pulp <strong>and</strong> Paper 29: 6-11, 13-16.<br />

376. Bhowmick, K; Mian, A.J; Akhtaruzzaman, A.F.M. 1992. Effect of anthraquinone in soda<br />

pulping of muli bamboo (Melocanna baccifera). IPPTA 4(4): 36-44.<br />

49


Conventional soda pulping results in lower pulp yield <strong>and</strong> strength properties Anthraquinone (AQ)<br />

is used as an additive in soda pulping to overcome the problems. Laboratory studies on soda+AQ<br />

pulping of mill-cut mull bamboo (Melocanna baccifera) show that AQ accelerated delignification,<br />

improved pulp yield at a particular kappa number <strong>and</strong> reduced the active alkali dose or cooking time<br />

compared to normal soda cook. An addition of AQ as low as 0.05 on OD raw material lowered the<br />

alkali dem<strong>and</strong> by 4 on OD bamboo. Such a low dose of the catalysis increased the pulp yield by 3 on<br />

OD bamboo. The yield was almost similar to the kraft control. Use of 0.10 AQ further increased the<br />

pulp yield to surpass the kraft control. But the gain in yield with 0.10 AQ was not as remarkable as with<br />

0.05 AQ. The beating characteristics <strong>and</strong> strength properties of pulp improved by the addition of AQ<br />

during soda pulping. The soda+AQ pulp is almost equal to the kraft control. This investigation has<br />

shown that AQ is a promising additive in soda pulping of muli bamboo.<br />

377. Biyani, B.P. 1966. Nitric acid pulping of Bambusa arundinacea Willd. Abstracts of<br />

Thesis. Forest Product Journal 16(11): p60.<br />

378. Biyani, B.P; Gorbatsovisch, S.N; Lorey, F.W. 1967. Nitric acid pulping of bamboo. TAPPI<br />

Journal 50(1): 87A-91A.<br />

Describes trials of this process at Syracuse, N.Y., <strong>for</strong> making paper-grade chemical pulps from<br />

Bambusa arundinacea. Highest screened-pulp yield (40.9) was obtained by cooking with 10 HNO3 at<br />

80 o C. For 6 hr. <strong>and</strong> extracting with 1 NaOH at 120 o C. <strong>for</strong> 1 hr. It is concluded that, in view of the low<br />

pentosan content of the pulps, the process is promising.<br />

379. Bolker, H.I; Singh, M.M. 1965. Delignification by nitrogen compounds. II. Pulping of<br />

spruce, birch, bamboo <strong>and</strong> bagasse with nitric - nitrous acid mixtures. Pulp <strong>and</strong> Paper<br />

Magazine of Canada 66: T165-T170.<br />

It is concluded inter alia that, under some economic conditions, the pulping of <strong>Bamboo</strong> [not<br />

specified] with HNO3 may be worth commercial consideration.<br />

380. Bose, S.K; Chowdhury, A.R; Akhtaruzzaman, A.F.M. 1998. Neutral sulphite<br />

anthraquinone (NS-AQ) pulping of muli bamboo (Melocanna baccifera). Journal of<br />

Tropical Forest Products 4(1): 45-51.<br />

Neutral sulfite (NS) anthraquinone (AQ) pulping of muli bamboo (Melocanna baccifera) was<br />

conducted in the laboratory. Normal NS <strong>and</strong> kraft pulping were also conducted <strong>for</strong> comparison. The<br />

total yield gain in the NS-AQ process was 6 to 7.9 units more than that of the kraft control at Kappa<br />

number 20. The Kappa number could not be lowered below 32 in the normal NS pulping. The use of<br />

0.1 AQ was sufficient to give the desired effect. The strength properties of unbleached NS-AQ pulps<br />

were lower than those of kraft pulps.<br />

381. Browning B.L. 1952. The chemical analysis of wood. In: Wise, L.E. <strong>and</strong> Jahn, E.C. (Eds.),<br />

Wood Chemistry. Vol. II, Part VII. Reinhold, New York.<br />

382. Chang, F.J; Kuo, L.S. 1976. Studies on manufacturing of dissolving pulp from bamboo<br />

Sinocalamus latiflorus <strong>and</strong> Bambusa stenostachya. Quarterly Journal of Chinese<br />

Forestry 9(1): 97-106.<br />

383. Chen, S.C; Lin, S.J; Lin, S.C. 1973. Semichemical pulping of Taiwan <strong>Bamboo</strong>s. Co<br />

operative Bulletin, Taiwan Forestry Research Institute with Joint Commission on Rural<br />

Reconstruction No. 21: 16p.<br />

Reports pulping trials on five <strong>Bamboo</strong> species by the cold-soda, neutral sulphite (NSSC) <strong>and</strong><br />

sulphate processes. The NSSC pulps, although the lowest in yield, showed good strength (near that of<br />

imported Canadian kraft pulp) <strong>and</strong> were bleached to 72-88 GE brightness by the CEH<br />

(chlorination/alkali extraction/hypochlorite bleaching) sequence. The net yield of 48.3-53.2 <strong>for</strong> the<br />

bleached pulp was well above that obtained from fully cooked pulps. <strong>Bamboo</strong> NSSC pulps may<br />

there<strong>for</strong>e replace imported long-fibrepulps in high-grade papers. The sulphate pulps were darker <strong>and</strong><br />

hard to bleach, but were strong enough <strong>for</strong> packaging products. It is concluded that the best properties<br />

where shown by pulps from Bambusa beecheyana var. pubescens, followedin order by Leleba<br />

50


dolichoclada, Bambusa stenostachya, Sinocalamus latiflorus <strong>and</strong> Phyllostachys makinoi, the last two<br />

being unsuitable.<br />

384. Devi, N; Bhola, P.P; Singh, M.M; Guha, S.R.D. 1982. Prehydrolysis of bamboo - Effect of<br />

pH. Indian Forester 108(5): 342-353.<br />

Studies in this paper have been carried out with a view in underst<strong>and</strong> the effect of pH on<br />

prehydrolysis of bamboo (Dendrocalamus strictus). The bamboo chips have been cooked with 1 of<br />

H2SO4, H2O <strong>and</strong> 10 of NaOH <strong>for</strong> 90 minutes <strong>and</strong> 150 minutes. The acidic, aqueous <strong>and</strong> soda lignins<br />

have been analysed. These results show that pulp yield decreases at higher pH <strong>and</strong> at more cooking<br />

time, <strong>and</strong> is also effected by the final pH of the prehydrolysates. The lignin yield from prehydrolysate<br />

decreases as the pH goes towards acidic side. The methoxyl content in isolated lignins decreases with<br />

the increase of lignin yield, while total-OH increases with the increase in lignin yield. The ratio of<br />

syringaldehyde to vanillin is less in lignins obtained at higher prehydrolysis time. The acidic <strong>and</strong><br />

aqueous lignins are less condensed than soda lignin.<br />

385. Dhawan, R. 1980. Nitric acid pulping of Dendrocalmus strictus. Indian Forester 106(2):<br />

122-125.<br />

Dendrocalamus strictus was pulped by nitric acid process. Air-dry chips were cooked with nitric<br />

acid <strong>and</strong> sodium nitrite. The residual wood was extracted with dilute solution of caustic soda. The<br />

material was washed disintegrated <strong>and</strong> screened. The yield of the pulps was determined. It was<br />

oberved that by the addition of sodium nitrite upto a certain extent, delignification was enhanced.<br />

Pulps were analysed <strong>for</strong> Kiason lignin content, pentosan content, nitrogen content, ash content <strong>and</strong><br />

permanganate number. It was observed that the yield, Klason lignin content, pentosan content <strong>and</strong><br />

permanganate number of pulps decrease with increase in concentration of nitric acid, cooking time <strong>and</strong><br />

temperature.<br />

386. Du, H.T. 1957. Studies on the alkaline pulping of bamboo. Bulletin of Taiwan Forestry<br />

Research Institute No. 47: 12p.<br />

387. Escolano, J.O; Nicholas, P.O; Felix, G.T. 1964. Pulping, bleaching <strong>and</strong> paper<br />

experiments on Kauayan-Tinik Bambusa blumeana Schlt.F. Philippine Lumberman<br />

10(4): 33-36.<br />

Results of an investigation carried out to determine the suitability of Bambusa blumeana <strong>for</strong> pulp<br />

<strong>and</strong> papermaking. This species is reported easily digested by the single stage sulphate pulping<br />

process <strong>and</strong> the pulps produced responded well to st<strong>and</strong>ard three-stage bleaching process. It shows<br />

that good quality bond, airmail bond, onionskin, offset book, kraft wrapping <strong>and</strong> bag papers can be<br />

produced from this species of bamboo.<br />

388. Fukuyama, G; Kawase, K; Satonaka, S. 1955. (I) Alkaline (soda), (II) Kraft <strong>and</strong> (III) NSSC<br />

(Neutral sulphite semi-chemical) pulps from Sasa spp.. Research Bulletin of Forestry,<br />

Hokkaido University, Japan 17(2): 321-381.<br />

Details are given of the compositions <strong>and</strong> strengths of the pulps obtained by these 3 processes<br />

under varying conditions of cooking. The kraft process gave the strongest pulps. The NSSCP, when<br />

yield was 54-77%, produced fibreboards stronger than those from wood chips; pulps from this yield<br />

range were weaker than Birch NSSCP but showed excellent tearing strength <strong>and</strong> their alpha-cellulose<br />

content was 59.81 %. Both the kraft <strong>and</strong> NSSCP processes are recommended.<br />

389. Gajdos, J; Farkas, J; Janci, J. 1971. Bleaching of sulphate pulps from <strong>Bamboo</strong>. Papir a<br />

Celuloza 26(6): 69-79.<br />

Gives results of laboratory trials with pulps made from air-dry <strong>Bamboo</strong> with yields of 39-58. A<br />

comparison with typical pulps made from central European conifers <strong>and</strong> hardwoods shows that<br />

<strong>Bamboo</strong> pulps are more difficult to bleach <strong>and</strong> are generally inferior in mechanical properties.<br />

390. Gonzalez, T; Escolano, J.O. 1965. The fiber fractions of giant bamboo sulfate pulp <strong>and</strong><br />

their strength properties. Philippine Lumberman 11(6): 12-14, 16, 20.<br />

51


391. Gremler, E.R; McGorovern, J.N. 1960. Low-power cold soda pulping. TAPPI Journal<br />

43(8): 200A-205A.<br />

Reviews briefly the history of cold soda pulping, emphasizing the various continuous methods<br />

used. Pulping data on Aspen, Birch, Oak, Bambusa polymorpha, <strong>and</strong> a hardwood mixture suggest that<br />

short impregnation periods <strong>and</strong> low h.p. result in completely defibrated pulp at high freeness. The<br />

principle of a new defibrating machine, the Chemifiner, <strong>and</strong> its contribution to the process described,<br />

are explained.<br />

392. Guha, S.R.D; Dhoundiyal, S.N; Mathur, G.M. 1975. Sulphate pulping of giant bamboo<br />

(Dendrocalamus giganteus). Indian Forester 101(5): 296-300.<br />

The results of a comparative laboratory scale investigation of the pulping of Dendrocalamus<br />

giganteus <strong>and</strong> Dendrocalamus strictus are recorded in this paper. The results show that D. giganteus<br />

is a better raw material than D. strictus <strong>for</strong> both unbleached grade pulps <strong>and</strong> bleached grade pulps.<br />

393. Guha, S.R.D; Jadhav, A.G; Sharma, Y.K. 1970. Effect of wet end additives on bamboo<br />

pulp. IPPTA 7(3): 235-240.<br />

Investigations on the effect of sixteen natural gums available commercially, two varieties of<br />

commercial carboxymethyl cellulose, viz; Cellpro LSH <strong>and</strong> Cellpro LVE <strong>and</strong> six samples of seed gums<br />

on bleached bamboo pulp are reported in this paper.<br />

394. Guha, S.R.D; Negi, J.S. 1972. The alkali resistant pentosans in bamboo. Indian Pulp <strong>and</strong><br />

Paper 27(3/4): 69-71.<br />

A study of alkali-resistant pentosans in bamboo (Dendrocalamus strictus) showed that treatment<br />

with alkali be<strong>for</strong>e chlorite treatment alone makes the pentosans non-resistant to alkali extraction, <strong>and</strong><br />

that once pentosans are rendered non-resistant they cannot be converted into resistant pentosans.<br />

Fibre structure was found to play an important role in determining the alkali resistance of pentosans.<br />

Fragmentation of fibre permitted the removal of more pentosan.<br />

395. Guha, S.R.D; Pant, P.C. 1961. <strong>Bamboo</strong> pulps by neutral sulphite semi-chemical<br />

process. Research <strong>and</strong> Industry 6(2): 49-51.<br />

Pulps are made from cellulosic raw materials by the sulphate process. An investigation is carried<br />

out on the pulping of the bamboo, Dendrocalamus strictus by the neutral sulphite semi-chemical<br />

process with the aim of improving the yield <strong>and</strong> quality of the pulp <strong>and</strong> the results are presented in this<br />

paper. It is found that unbleached pulps (yield 56-68 percent) of satisfactory strength properties can be<br />

prepared from bamboo by NSSC process. When bleached, these pulps (yield 37-44 percent) are found<br />

to have satisfactory brightness <strong>and</strong> strength properties <strong>for</strong> the production of white papers.<br />

396. Guha, S.R.D; Pant, P.C. 1966. Sulphate pulping of Phyllostachys bambusoides. Indian<br />

Forester 92(7): 467-468.<br />

<strong>Bamboo</strong>, Phyllostachys bambusoides is tested <strong>for</strong> its suitability <strong>for</strong> paper pulp. The result shows<br />

that the yield, bleach consumption <strong>and</strong> strength properties of pulps obtained are comparable to those<br />

obtained from Dendrocalamus strictus except in the case of tear factor <strong>and</strong> folding endurance which<br />

are found lower in case of P. bambusoides. But the strength obtained is found sufficient <strong>for</strong> production<br />

of writing <strong>and</strong> printing papers. Results are tabulated.<br />

397. Guha, S.R.D; Sharma, Y.K; Jain, R.C; Jadhav, A.G. 1966. Chemical pulps <strong>for</strong> writing <strong>and</strong><br />

printing papers from ringal (Arundinaria spp.). Indian Forester 92(10): 634-636.<br />

Laboratory experiments on the production of chemical pulp from ringal (Arundinaria sp.) <strong>for</strong><br />

production of writing <strong>and</strong> printing papers by sulphate process are described. The average fibre length<br />

of pulp was 1.01 mm <strong>and</strong> average fibre diameter was 11 microns. It is reported that bleaching pulps in<br />

satisfactory yields can be prepared under suitable conditions of digestion.<br />

398. Guha, S.R.D; Singh, M.M; Mithal, K.C. 1966. Sulphate pulping of mixture of bamboo <strong>and</strong><br />

mixed hardwoods. Indian Pulp <strong>and</strong> Paper 21(3).<br />

52


Laboratory experiments are described on production of kraft papers from mixtures of bamboo<br />

chips <strong>and</strong> mixed hardwoods.<br />

399. Isono, Z; Ono, K. 1967. Desilicification of high silica containing kraft liquors. Part I.<br />

Desilicification of black liquor by carbon dioxide treatment. Journal of Agricultural <strong>and</strong><br />

Chemical Society of Japan 41: 220-225.<br />

400. Isono, Z; Ono, K. 1968. Desilicification of kraft green liquor by aluminium sulphate.<br />

Part II. Journal of Agricultural <strong>and</strong> Chemical Society of Japan 42: 18-23.<br />

401. Isono, Z; Ono, K. 1968. Desilicification of kraft liquors high in silica. Part III.<br />

Desilicification of kraft black liquor by aluminium sulphate. Journal of Agricultural <strong>and</strong><br />

Chemical Society of Japan 42: 24-28.<br />

402. Isono, Z; Ono, K. 1968. Desilicification of kraft liquors high in silica. Part IV.<br />

Desilicification of kraft black liquor by magnesium sulphate <strong>and</strong> general consideration<br />

of the subject. Journal of Agricultural <strong>and</strong> Chemical Society of Japan 42: 29-32.<br />

403. Janci, J; Farkas, J; Gajdos, J. 1971. Neutral sulfite semichemical <strong>Bamboo</strong> pulps. Papir a<br />

Celuloza 26(12): 139-151.<br />

The results of a laboratory study of these pulps (made from Bambusa vulgaris) showed that they<br />

were suitable as a basic material <strong>for</strong> the middle layer of corrugated paper.<br />

404. Jauhari, M.B; Ghosh, P.C. 1984. High yield alkaline sulphite-anthraquinone pulping of<br />

bamboo. IPPTA 21(1): 45-50.<br />

An improved approach to produce high yield bleached chemical pulps is described. Alkaline<br />

sulphite solution with <strong>and</strong> without anthraquinone (AQ) under high temperature <strong>and</strong> pressure produced<br />

pulp of 25 <strong>and</strong> 32 Kappa number with unbleached screened yield of 61 <strong>and</strong> 60 percent respectively.<br />

Addition of 0.1 percent AQ on chips offered the advantage of producing pulp of low Kappa number with<br />

high pulp yield <strong>and</strong> also enabled to carry out the cooking at a much lower maximum temperature<br />

compared to where no AQ was added. The pulps could be easily bleached in three stages of calcium<br />

hypochlorite bleaching to brightness of 78 <strong>and</strong> 76 per cent with bleached pulp yield of 59.4 <strong>and</strong> 57.4<br />

percent respectively. The physical strength properties <strong>and</strong> opecity were matchingwith those of sulphate<br />

pulp in comparison with sulphate pulp. The alkaline sulphite -AQ pulp is obtained in about 7.7 percent<br />

greater pulp yield both in the unbleached <strong>and</strong> bleached state. The process offers advantages of higher<br />

unbleached/bleached pulp yield. Higher unbleached pulp brightness <strong>and</strong> greater ease of bleaching, are<br />

advantages over sulphate process <strong>for</strong> bamboo pulping.<br />

405. Kadarisman, D; Silitonga, T. 1974. Sulphate pulping of bamboo. Bulletin Penelitan Tek<br />

Hasil Pertanian 40: 14-17.<br />

406. Kar, S.K; Jena, S.C; Maheshwari, S. 1987. Effect of variation of moisture in bamboo<br />

chips on pulp <strong>and</strong> paper making characteristics. IPPTA 24(2): 49-54<br />

The storage of bamboo, the conventional raw material <strong>for</strong> papermaking in India, is necessary <strong>for</strong><br />

continuous supply of this raw material throughout the year. It has been observed that due to storage,<br />

particularly in summer season, the moisture content reaches a very low level, which adversely affects<br />

the pulp <strong>and</strong> papaermaking properties. The present study reveals that though it is not practicable to<br />

attain higher percentage of moisture in bamboo as such by soaking in water but chips can be brought<br />

to a desired level of moisture content by soaking <strong>for</strong> a very short period in water pond. With increasing<br />

moisture content active alkali requirement in pulping decreases while the uni<strong>for</strong>mity <strong>and</strong> pulp quality<br />

improve. The physical strength properties have aslo shown increasing moisture content. However, it<br />

may adversely affect the black liquor characteristics which will be obtained in less concentrated <strong>for</strong>m.<br />

It has been concluded that an optimum moiture content may be maintained so as to get the uni<strong>for</strong>m<br />

pulping <strong>and</strong> better quality of the pulp.<br />

53


407. Karim, M.S; Islam, M.A; Khalid ul Islam, M. 1994. Studies on muli bamboo (Bambusa<br />

baccifera) [pulped] by soda process <strong>and</strong> laboratory evaluation of unbleached <strong>and</strong><br />

bleached pulps. Bangladesh Journal of Scientific <strong>and</strong> Industrial Research 29(1): 10-19.<br />

Data are presented on the chemical composition of muli bamboo (Bambusa baccifera [Melocanna<br />

baccifera]) be<strong>for</strong>e <strong>and</strong> after pulping, <strong>and</strong> on pulp properties be<strong>for</strong>e <strong>and</strong> after bleaching. The bleached<br />

pulps were suitable <strong>for</strong> making good quality writing <strong>and</strong> printing paper, <strong>and</strong> the unbleached pulps <strong>for</strong><br />

packing <strong>and</strong> wrapping papers.<br />

408. Kato, F. 1955. On the digestion of bamboo pulp. Part 1. TAPPI Journal 9(3).<br />

409. Kato, F. 1955. On the digestion of bamboo pulp. Part 2. TAPPI Journal 9(5).<br />

410. Kh<strong>and</strong>uri, S.C; Biswas, B. 1960. Some observations on the cold caustic treatment of<br />

Ringal (Arundinaria jaunsarensis) bamboo. Indian Pulp <strong>and</strong> Paper 14(10): 475-476.<br />

Discusses the effect of alkali treatment of A. jaunsarensis at 30 o C. The ash, pentosan, <strong>and</strong> lignin<br />

contents of the soaked material were found to decrease with increases in cellulose content <strong>and</strong> in the<br />

concentration of alkali in the soaking liquor.<br />

411. Mahanta, D; Chaliha, P.B. 1970. Pulping of bamboo by nitric acid. Chemical Age India<br />

20(2).<br />

412. Mahanta, D; Gohain, P.D; Rehman, A; Chaliha, P.B. 1979. Non-sulphur pulping of<br />

bamboo. Indian Pulp <strong>and</strong> Paper 34(1).<br />

413. Maheshwari, S; Gopich<strong>and</strong>, K. 1990. Studies on peroxide addition in extraction stage<br />

(CEpH) on optical properties of bamboo pulp. Pulping Conference: Proceedings 2: 481-<br />

485.<br />

414. McGorovern, J.N. 1962. Semichemical <strong>and</strong> mechanical pulping. In: Libby, C.E (Editor).<br />

Pulp <strong>and</strong> Paper Sicence <strong>and</strong> Technology Vol. I. McGraw - Hill, New York: 281-316.<br />

415. Mishra, B.P; Joshi, R.C; Banthia, U.S; Singh, M.M. 1984. Effect of sulfidity on alkaline<br />

pulping of bamboo, mixed hardwoods <strong>and</strong> a mixture of bamboo <strong>and</strong> mixed<br />

hardwoods. Indian Pulp <strong>and</strong> Paper 39(3): 7-16.<br />

Increasing sulphidity from 0 to 20 increased the yield, reduced the of rejects <strong>and</strong> the dem<strong>and</strong> <strong>for</strong><br />

bleach, <strong>and</strong> generally improved strength properties. The effects were greatest in the 60:40 mixture of<br />

bamboo <strong>and</strong> mixed hardwoods <strong>and</strong> least in bamboo only. Optimum sulphidity is 16 <strong>for</strong> bamboo, 20 <strong>for</strong><br />

mixed hardwoods <strong>and</strong> 18 <strong>for</strong> bamboo/mixed hardwoods.<br />

416. Mukherjea, V.N; Guha, S.R.D. 1965. High-yield pulps by a hot caustic soda process.<br />

Indian Pulp <strong>and</strong> Paper 20(2): 139-144.<br />

417. Nafziger, T.R; Clark, T.F; Wolff, I.A. 1960. Dissolving pulps from domestic timber<br />

bamboo, Phyllostachys bambusoides. TAPPI Journal 43(6): 591-596.<br />

418. Nafziger, T.R; Clark, T.F; Wolff, I.A. 1961. Newsprint from domestic timber bamboo,<br />

Phyllostachys bambusoides. TAPPI Journal 47(7): 472-475.<br />

Culms of P. bambusoides of not more than15 years, from Savannah, Ga., were used in tests to<br />

prepare chemical, semichemical <strong>and</strong> mechanical pulps, <strong>for</strong> newsprint. Yields of 82 <strong>and</strong> 62% <strong>for</strong> cold<br />

soda semichemical <strong>and</strong> neutral sulphite pulps respectively were attained, but stone grinding with <strong>and</strong><br />

without chemical pre-treatment failed to produce satisfactory pulps from the mature culms. Strength<br />

characteristics of experimental newsprint from a furnish comprising 80% cold soda <strong>and</strong> 20% neutral<br />

sulphite pulps, 1% alum, 0.05% rosin, <strong>and</strong> 7% clay, were comparable to those of a control paper from<br />

a similar furnish of 80% Aspen groundwood <strong>and</strong> 20% unbeaten softwood sulphite pulps. Blends of<br />

<strong>Bamboo</strong> <strong>and</strong> wood pulps gave sheets of inferior strength in all combinations tried. It is suggested that<br />

further study of treatment be<strong>for</strong>e grinding <strong>and</strong> of the use of green <strong>Bamboo</strong>, <strong>and</strong> of the variables in the<br />

54


preparation of both chemical <strong>and</strong> mechanical pulps <strong>and</strong> of machine furnishes, might indicate the best<br />

treatments <strong>and</strong> also lead to end products superior to those here reported.<br />

419. Nicholas, P.M; Navarro, J.R. 1964. St<strong>and</strong>ard cold soda pulping evaluation of Philippine<br />

woods <strong>and</strong> bamboos. TAPPI Journal 47(2): 98-105.<br />

420. Nirankari Devi; Bhola, P.P; Singh, M.M; Guha, S.R.D. 1982. Prehydrolysis of bamboo -<br />

effect of pH. Indian Forester 108(5): 342-353.<br />

The effect of pH on prehydrolysis of bamboo (Dendrocalamus strictus) is examined. Acidic<br />

aqueous <strong>and</strong> soda lignins analysed by cooking bamboo chips in a solution of one per cent sulphuric<br />

acid, water <strong>and</strong> 10 percent sodium hydroxide <strong>for</strong> 90-150 minutes. The result shows that pulp yield<br />

decreases at higher pH <strong>and</strong> at more cooking time. The lignin yield from prehydrolysate decreases as<br />

the pH goes towards acidic side. The methoxyl content in isolated lignin decreases with the increase of<br />

lignin yield, while total OH increases. The acidic <strong>and</strong> aqueous lignins are less condensed than soda<br />

lignin.<br />

421. Oye, R; Mizuno, T. 1970. Studies on bamboo dissolving pulp, reactivity of bamboo pulp<br />

<strong>for</strong> viscose. Journal of Japan Wood Research Society 16(2): 92-96.<br />

Examines the relation between pulping conditions <strong>and</strong> the reactivity of dissolving pulp prepared<br />

from bamboo (Melocanna bambusoides) by the prehydrolysis sulphate process. <strong>Bamboo</strong> pulp has<br />

lower resistance to mercerization than hardwood pulp made by a similar process, <strong>and</strong> has low<br />

resistance to sulphidation. Its filterability is similar to that of wood pulps. Figures <strong>and</strong> tables have<br />

English legends.<br />

422. Oye, R; Mizuno, T. 1970. Studies on dissolving pulp characteristics of the bamboo<br />

pulp. Journal of Japan Wood Research Society 16(3): 135-139.<br />

Properties of dissolving pulp prepared from bamboo (Melocanna bambusoides?) by the<br />

prehydrolysis sulphate process influencing its suitability <strong>for</strong> viscose manudfacture were determined. In<br />

comparison with wood pulp bamboo pulp has a higher rate of depolymerization during ageing, low<br />

cold-alkali but comparatively high hot-alkali solubility, <strong>and</strong> a similar degree of crystallinity, but a higher<br />

rate of acid hydrolysis <strong>and</strong> lower levelling-off DP.<br />

423. Oye, R; Mizuno, T. 1972. Prehydrolysis sulphate cooking of bamboo. TAPPI Journal<br />

26(7): 363-371.<br />

424. Raitt, W. 1931. The digestion of bamboo <strong>and</strong> grasses <strong>for</strong> paper making. Crosby<br />

Lockwood & Son, London.<br />

425. Sanyal, A.K; Devgan, R.C. 1964. Use of elemental sulphur in soda cooking of bamboo<br />

(Dendrocalamus strictus). Indian Pulp <strong>and</strong> Paper 18(9): 521-523.<br />

426. Semana, J.A. 1965. Study of the variable in sulphate pulping of giant bamboo<br />

(Gigantochloa aspera Kurz.). Indian Pulp <strong>and</strong> Paper 20(6): 395, 397-399, 401, 403-406.<br />

427. Singh, M.M; Sharma, Y.K; Pant, R. 1970. High yield pulps - two stage pulping. Journal of<br />

the Indian Academy of Wood Science 1(1): 39-42.<br />

To increase the yield of pulp <strong>for</strong> the production of kraft papers from bamboo <strong>and</strong> Eucalyptus<br />

gr<strong>and</strong>is, experiments were conducted by splitting the digestion into two stages with an intermediate<br />

refining stage <strong>and</strong> the results were presented. The yield of bamboo pulp was found increased from<br />

47.1 to 53.3 percent without any significant effect on the strength properties of the pulp.<br />

428. Singh, S.P; Joshi, H.C. 1988. Plywood adhesives from black liquor of bamboo<br />

Dendrocalamus strictus. Journal of the Indian Academy of Wood Science 19(1): 47-51.<br />

Black liquor, a lignin-rich byproduct from the pulping of D. strictus, was used as a replacement <strong>for</strong><br />

phenol (at 10-60) in the preparation of phenolic adhesives <strong>for</strong> plywood. The resulting adhesive (a<br />

phenol-lignin <strong>for</strong>maldehyde resin) was tested <strong>for</strong> use in making 3-ply plywood from veneers of Vateria<br />

55


indica <strong>and</strong> Ulmus [Pinus] wallichiana. The boards were tested <strong>for</strong> glue adhesion strength in dry, hot<br />

wet, <strong>and</strong> mycological tests. The black liquor itself had 12.94 solids, 3.8 ash <strong>and</strong> pH 9.5. Replacement<br />

of phenol by black liquor progressively decreased the solid content of the adhesive, <strong>and</strong> the glue<br />

spread. At up to 50 of phenol replacement the adhesive met the strength requirements of Indian<br />

St<strong>and</strong>ard IS:848-1974 <strong>for</strong> the BWR adhesive grade, but at 60 the BWR grade was not met with V.<br />

indica plywood.<br />

429. Singh, S.V; Guha, S.R.D. 1975. Kinetics of alkaline pulping of <strong>Bamboo</strong>. Indian Pulp <strong>and</strong><br />

Paper 30(3): 15-25.<br />

Changes in yield, chemical composition <strong>and</strong> strength properties of chemical <strong>and</strong> semi-chemical<br />

pulps were determined during the kraft pulping of Dendrocalamus strictus, throughout the cooking<br />

cycle. Up to 70 yield, there was a linear correlation between lignin in pulp <strong>and</strong> pulp kappa number, <strong>and</strong><br />

also between lignin to carbohydrate ratio <strong>and</strong> yield. Regression equations were developed from which<br />

kappa number, or lignin in pulp can be predicted <strong>for</strong> controlling the pulping process up to a yield of 70.<br />

430. Singh, S.V; Guha, S.R.D. 1976. The H factor of bamboo sulphate pulping: A device to<br />

control pulp mill operation. IPPTA 13(1): 57-60.<br />

The sulphate pulping of bamboo (Dendrocalamus strictus) is studied from beginning to the end of<br />

cook, applying the concept of representing the times <strong>and</strong> temperatures of the cooking cycle by Vroom'<br />

H factor. The experimental results showed that the Hfactor can be employed as a means of predicting<br />

compensating adjustments of cooking times <strong>and</strong> temperatures to give the same yield of pulp, kappa<br />

number <strong>and</strong> lignin content with varying cooking cycles. This indicated that the concept of H factor can<br />

suitably be applied as a guide <strong>for</strong> controlling sulphate pulping process of bamboo in mills by predicting<br />

times <strong>for</strong> a variety of temperatures or vice-versa to make necessary adjustments in the cooking cycle,<br />

so as to get equivalent pulp yield. For the experimental st<strong>and</strong>ard cooking cycle employed in this<br />

investigation (90 min. from 80 to 170 degree C <strong>and</strong> 90 min. at 170 degree C) the H factor was found to<br />

be 91982.<br />

431. Tshiamala, T; Fraipont, L; Paquot, M; Thonart, P; Mottet, A. 1984. Comparative study of<br />

different bamboo pulps. Holz<strong>for</strong>schung 38(5): 281-288.<br />

Sulphate, neutral sulphite, lime <strong>and</strong> thermo-mechanical pulps were prepared from Bambusa<br />

vulgaris, B. viridi, Gigantochloa apus <strong>and</strong> G. aspera. The chemical properties of the pulps were<br />

analysed in relation to their effect on paper properties. Neutral sulphite pulp gave the best results, with<br />

high yield <strong>and</strong> satisfactory paper mechanical properties.<br />

432. Tsuji, H; Isono, Z; Ono, K. 1965. Studies on the dissolving bamboo pulp. Bulletin of the<br />

University of Osaka Prefecture, Sakai, 16B(January): 89-104.<br />

Dissolving pulp can be prepared by pre-hydrolysis cooking at 160o or 165 o C <strong>for</strong> 4 hr., followed by<br />

sulphate cooking at 160 o C <strong>for</strong> 2 hr., with total NaOH 20, <strong>and</strong> sulphidity 20. With these pre-hydrolysis<br />

conditions, pentosans were


435. Vyas, G.M; Bhat, R.V; Chowdhury, K.A. A process <strong>for</strong> the treatment of bamboo to further<br />

its utilization in the manufacture of pulp, paper or the like. Indian Patent No. 49054.<br />

436. Vyas, G.M; Bhat, R.V; Chowdhury, K.A. An improved process <strong>for</strong> the treatment of<br />

bamboo to further its utilization in the manufacture of pulp, paper or the like. Indian<br />

Patent No. 57267.<br />

437. Wang, H. 1981. The application of anthraquinone in the pulping of bamboo waste.<br />

Proceedings of <strong>Bamboo</strong> Production <strong>and</strong> Utilization. XVII IUFRO World Congress, 6-17<br />

September 1981, Kyoto, Japan. Wood Research Institute, Kyoto University, Japan: 131-135.<br />

438. Wang, H; Lirn, T.R. 1984. Study on the high yield pulping of bamboo waste. Forest<br />

Products Industries 3(1): 32-48.<br />

Shavings <strong>and</strong> nodes of Dendrocalamus latiflorus, Phyllostachys edulis <strong>and</strong> P. makino [makinoi]<br />

were pulped using the neutral sulphite-anthraquinone process. Fibre dimensions were measured <strong>and</strong><br />

chemical composition (ash, lignin, cellulose etc.) <strong>and</strong> mechanical properties were recorded. On av.<br />

fibres were 2.05-2.84 µm long <strong>and</strong> 15.1-21.2 µm wide, with length/width ratios of 135-162. D. latiflorus<br />

had the longest fibres. Ash <strong>and</strong> extractive contents of bamboo wastes were higher than those of wood.<br />

Lignin content was lower than that of softwood, but similar to that of hardwood. The lignin content of P.<br />

edulis was the highest. Yields <strong>and</strong> pulp strength (breaking length, burst <strong>and</strong> tear factors) are tabulated<br />

<strong>for</strong> varying total alkali, alkali ratio <strong>and</strong> anthraquinone in the pulping process.<br />

439. Wang, K.T. 1982. Alkaline sulphite pulping of Bambusa arundinacea with the addition<br />

of anthraquinone. Bulletin, Taiwan Forestry Research Institute 378: 12p.<br />

440. Yamagishi, K; Satonaka, S; Hanzawa, M. 1970. Studies on pulping of Sasa with per<br />

acetic acid. Research Bulletin on Experimental Forestry, Hokkaido University, Japan 27(2):<br />

459-486.<br />

Sasa <strong>Bamboo</strong> (S. senanensis etc.) is plentiful on high l<strong>and</strong> in Hokkaido, where st<strong>and</strong>s may contain<br />

ca. 700,000 stems/ha. with a weight of ca. 60 [metric] tons/ha.; this important <strong>for</strong>est resource has<br />

hitherto scarcely been used. Powdered wood meal of Sasa was effectively delignified by treatment with<br />

peracetic acid (PA) at 70°C., <strong>and</strong> the pulp yield was 57.3%. A high yield of pulp with a low lignin<br />

content was also obtained by pulping Sasa chips with PA; the brightness of this pulp was high but the<br />

pentosan content was >20%. As regards its strength properties, the PA pulp was markedly superior in<br />

breaking length <strong>and</strong> burst factor, <strong>and</strong> slightly superior in tear factor, to a semi-kraft pulp of similar yield<br />

<strong>and</strong> lignin content, while its folding endurance was satisfactory. The strength properties of a Birch<br />

(Betula platyphylla var. japonica) pulp obtained by PA pulping were, however, superior to those of the<br />

Sasa pulp. Microscopic observation of the latter revealed fibres with an intact structure, accompanied<br />

by many small parenchyma cells.<br />

441. Yamaguchi, H; Nagamori, N; Sakata, I. 1991. Applications of the dehydrogenative<br />

polymerization of vanillic acid to bonding of woody fibres. Journal of the Japan Wood<br />

Research Society 37(3): 220-226.<br />

Composite boards were made by treating thermomechanical pulp with vanillic acid that had been<br />

dehydrogenatively polymerized by a crude peroxidase prepared from madake (Phyllostachys<br />

bambusoides) bamboo shoots.<br />

442. Yao, G.Y; Zou, Z.X. 1986. The pulping of bamboo (Phyllostachys pubescens) with<br />

alkaline sodium sulfite-anthraquinone. Journal of Nanjing Forestry University No. 4:<br />

50-58.<br />

57


Kraft Pulping<br />

443. Alam, M.R; Barua, I.B; Islam, N. 1997. To study the effect of sulphidity variation in kraft<br />

pulping of muli bamboo (Melocanna bambusoides). Bangladesh Journal of Scientific <strong>and</strong><br />

Industrial Research 32(1): 111-114.<br />

The optimum limit of sulfidity in kraft (sulfate) pulping of muli bamboo (Melocanna bambusoides)<br />

was studied in the process used at Karnaphuli Paper Mills in Ch<strong>and</strong>raghona, Bangladesh. About 17<br />

sulfidity gave the best quality of pulp.<br />

444. Bajpai, P; Bajpai, P.K. 1996. Application of xylanases in prebleaching of bamboo kraft<br />

pulp. TAPPI Journal 79(4): 225-230.<br />

The effectiveness of 12 commercial enzymes was evaluated <strong>for</strong> prebleaching bamboo [Bambusa<br />

arundinacea <strong>and</strong> Dendrocalamus strictus] kraft pulp. Different xylanases varied in the maximum<br />

obtainable effect. The enzymes Bleachzyme F <strong>and</strong> Irgazyme 40S were able to decrease the active Cl2<br />

requirement in the first stage of bleaching by 20 or decrease the ClO2 in the last stage of brightening<br />

by 4 kg/metric tonne of pulp in the CDEHD sequence. Alternatively, at the same chemical charge, it<br />

was possible to increase the final brightness approaching 89 ISO. The use of enzymes had no adverse<br />

effect on the pulp viscosity <strong>and</strong> strength properties.<br />

445. Bh<strong>and</strong>ari, K.S. 1981. Kraft pulping of Oxytenanthera ritcheyi. Indian Forester 107(7):<br />

454-458.<br />

Kraft pulps from Oxytenanthera ritcheyi are produced in laboratory at three different cooking<br />

schedule <strong>and</strong> chemical concentrations. On the basis of pulp evaluation <strong>for</strong> various strength properties<br />

kappa number <strong>and</strong> unbleached pulp yield, optimum pulping conditions are reported. Kraft pulp<br />

obtained at optimum conditions is bleached <strong>and</strong> bleaching conditions, bleached pulp yield, brightness<br />

<strong>and</strong> various strength properties of bleached pulp sheets are also reported. It is found that<br />

Oxytenanthera ritcheyi is a suitable raw material <strong>for</strong> the production of wrapping, writing <strong>and</strong> printing<br />

paper.<br />

446. Bhargava, M.P; Chattar Singh. 1942. Interim report on the manufacture of kraft paper<br />

from bamboos. Indian Forest Bulletin (New Series) Utilisation 112: 13p.<br />

Investigations are carried out at the Forest Research Institute, Dehra Dun to explore the<br />

possibilities of manufacturing kraft paper. It is established the suitability of bamboo as a raw material<br />

<strong>for</strong> the manufacture of kraft paper.<br />

447. Bhowmick, K; Mian, A.J; Akhteruzzaman, A.F.M. 1991. Anthraquinone as an aditive in<br />

kraft pulping of muli bamboo (Melocanna baccifera). Forpride News 3(5).<br />

448. Bhowmick, K; Mian, A.J; Akhtaruzzaman, A.F.M. 1991. Effect of anthraquinone in low<br />

sulphidity kraft pulping of muli bamboo (Melocanna baccifera). IPPTA 3(4): 26-33.<br />

Low sulphidity kraft pulping of mill-cut muli bamboo (Melocanna baccifera) with anthraquinone<br />

(AQ) addition was studied in the laboratory scale. AQ acted as a pulping catalyst <strong>and</strong> increased the<br />

rate of delignification or decreased the alkali dem<strong>and</strong>. The viscosity of AQ catalysed low sulphidity<br />

kraft pulps was almost equal to the kraft control <strong>and</strong> better than the pulp of 15 percent sulphidity. It<br />

was also observed that the burst, tear <strong>and</strong> tensile strength properties of the pulp increased on addition<br />

of AQ. The strength properties were almost same or better than the pulp obtained in normal kraft<br />

pulping. The use of AQ is beneficial at a low sulphidity level in preserving the pulp yield <strong>and</strong> improving<br />

the quality of the pulp. This will reduce the air pollution problems because of a lower sulphidity input in<br />

the cooling.<br />

449. Bhowmick, K; Akhtaruzzaman, A.F.M; Mian, A.J. 1992. Economic benefits of soda <strong>and</strong><br />

kraft anthraquinone pulping of muli bamboo (Melocanna baccifera). Bangladesh<br />

Journal of Forest Science 21(1/2): 13-19.<br />

Results of a tentative economic analysis made on kraft <strong>and</strong> soda anthraquinone pulping of muli<br />

bamboo (Melocanna baccifera) are presented. It shows that compared to soda pulping better benefits<br />

58


can be achieved in soda + AQ pulping. Reports that a mill producing 30,000 tons of pulp annually can<br />

save TK 52.5 million by using soda + AQ process. Addition of AQ in low sulphidity kraft pulping is also<br />

reported profitable. Kraft 15 + AQ pulping of muli bamboo is capable of saving TK 30 million compared<br />

to kraft 15 without AQ <strong>and</strong> TK 7.6 million compared to normal kraft pulping. Addition of AQ in normal<br />

kraft pulping is reported not very encouraging where only TK 5 million is saved compared to normal<br />

kraft cook.<br />

450. Bhowmick, K; Akhtaruzzaman, A.F.M; Jabbar Mian, A. 1994. Soda-anthraquinone <strong>and</strong> low<br />

sulphidity kraft anthraquinone pulping of Muli bamboo (Melocanna baccifera) <strong>and</strong><br />

mixed wood in a mixture in Bangladesh. Bangladesh Journal of Forest Science,<br />

Bangladesh 23(1): 20-25.<br />

Pulping of bamboo-hardwoods in a mixture showed that H-factor required in soda plus AQ <strong>and</strong> low<br />

sulphidity kraft plus AQ was slightly lower than the calculated value from the mixture of the<br />

components. The total pulp yield <strong>for</strong> kraft15 plus AQ was higher than the calculated value. But <strong>for</strong> soda<br />

plus AQ it was lower from the theoretical value. The tensile strength of the pulp obtained in soda plus<br />

AQ process was better upto 60 bamboo chips in the mixture. It showed superior quality with more than<br />

60 bamboo in the component in low sulphidity kraft pulping. The bursting strength of the pulp<br />

decreased as the bamboo chips increased in kraft15 plus AQ pulping. The tear strength behaved<br />

almost linearly with any proportion of bamboo chips with wood chips.<br />

451. Bose, S.K; Chowdhury, A.R; Akhtaruzzaman, A.F.M. 1988. Influence of age on kraft<br />

pulping of Muli bamboo (Melocanna baccifera). Bano Bigyan Patrika 17(1/2): 41-45.<br />

In this study an attempt has been made to find out the optimum cutting cycle <strong>for</strong> Muli bamboo<br />

(Melocanna baccifera) from the point of view of pulp yield <strong>and</strong> quality. The results show that bleachable<br />

grade of pulp is obtained at a lower cooking time with younger bamboos (9 months old) than those of<br />

higher age groups. The pulp yield at a given point of delignification is the highest with 21 months old<br />

bamboos. Physical strength properties of the pulp are independent of age. Thus, it seems that 21<br />

months old Muli bamboo is better <strong>for</strong> pulping.<br />

452. Chao, S.C; Pan, T.T. 1972. Manufacture of kraft pulp from Taiwan <strong>Bamboo</strong>s. Co<br />

operative Bulletin, Taiwan Forestry Research Institute with Joint Commission on Rural<br />

Reconstruction 19: 10p.<br />

Gives the results of sulphate pulping tests on Bambusa beecheyana var. pubescens, B.<br />

dolichoclada, B. stenostachya, Dendrocalamus latiflorus <strong>and</strong> Phyllostachys makinoi. All the pulps had<br />

good strength properties, <strong>and</strong> tearing strengths were especially high. Pulp yields varied with cooking<br />

conditions from 41 to 47. Results of bleaching tests are also given.<br />

453. Chen, J.X; Yu, J.L; Zhan, H.Y. 1987. Study on mechanisms of kraft <strong>and</strong> AS-AQ pulping<br />

of bamboo. Cellul. Chem. Technol. 21(6).<br />

454. Gomide, J.L; Colodette, J.L; Oliveira R.C. de. 1981. Influence of active alkali <strong>and</strong><br />

temperature on the kraft pulping of Bambusa vulgaris. Revista Arvore 5(2): 181-193.<br />

455. Goyal, P; Misra, N.D. 1980. Economics of bamboo <strong>and</strong> mixed hardwoods pulping by<br />

AQ-catalysed kraft process. Zonal Seminar on High Yielding <strong>and</strong> Pulping <strong>and</strong> Bleaching of<br />

Pulps, 20-21 September, Dehra Dun.<br />

456. Goyal, P; Mishra, N.D. 1982. Vapour phase kraft pulping of bamboo (Dendrocalamus<br />

strictus). Indian Pulp <strong>and</strong> Paper 37(3).<br />

457. Guha, S.R.D; Om Bahadur; Mathur, G.M. 1980. Production of kraft paper from bamboo<br />

(Melocanna baccifera) of Mizoram. Indian Forester 106(8): 578-582.<br />

To identify the appropriate bamboo species <strong>for</strong> the production of Kraft paper, Cellulose <strong>and</strong> Paper<br />

branch of FRI Dehra Dun, made a study on Melacanna baccifera which is the main species available in<br />

Mizoram. Investigations carried out, on the production of unbleached <strong>and</strong> bleached grades of pulps<br />

from M.baccifera (syn. M. bambusoides) by sulphate. Result of the experiments showed that M.<br />

baccifera was the suitable fibrous raw material <strong>for</strong> Kraft paper making.<br />

59


457a. Guha, S.R.D; Singh, M.M; Sharma, Y.K; Gulati, A.S. 1966. Wrapping, writing <strong>and</strong><br />

printing papers from bamboo dust. Indian Pulp <strong>and</strong> Paper 21(3): 187.<br />

458. Jamaludin K; Jalil A.A; Abdul Latif Mohamod. 1993. Kraft pulping of Bambusa vulgaris.<br />

BIC-India Bulletin 3(1): 7-10.<br />

The sutablility of Bambusa vulgaris as a raw material <strong>for</strong> pulp by the kraft process is examined.<br />

Pulp yield ranged from 45 to 53 percent. Results from this preliminary study indicate that B. vulgaris is<br />

a moderate to poor material <strong>for</strong> pulping.<br />

459. Koorse, G.M; Veeramani, H. 1976. Engineering properties of spent pulping liquors. I.<br />

Specific gravity of bamboo, bagasse <strong>and</strong> eucalyptus kraft black liquors. Indian Pulp<br />

<strong>and</strong> Paper 31(1).<br />

460. Koorse, G.M; Veeramani, H. 1976. Engineering properties spents pulping liquors. II.<br />

Thermal conductivity of bamboo <strong>and</strong> bagasse <strong>and</strong> eucalyptus kraft black liquors.<br />

Indian Pulp <strong>and</strong> Paper 31(4).<br />

461. Kuang, S.J; Revol, J.F; Goring, D.A.I. 1985. A comparison of the mercerization of kraft<br />

pulp from spruce <strong>and</strong> bamboo. Cellul. Chem. Technol. 19(2).<br />

462. Kulkarni, A.G; Kolambe, S.L; Mathur, R.M; Pant, R. 1984. Studies on desilication of<br />

bamboo kraft black liquor. IPPTA 21(1): 37-44.<br />

An attempt is made <strong>for</strong> desilication by the method of lowering the pH of the black liquor by<br />

carbonation. The bamboo kraft black liquor usually contains silica in the range of 5-8 g/l as SiO2}. It is<br />

tried to see the effect of pH <strong>and</strong> temperature on silica precipitation <strong>and</strong> also to achieve selective<br />

precipitation of silica. Studies revealed that temperature <strong>and</strong> pH are the two important parameters to<br />

be optimised. The pH range <strong>for</strong> silica precipitation is largely influenced by the temperature during<br />

carbonation. It is revealed that at all temperature <strong>and</strong> pH levels there was a coprecipitation of lignin.<br />

Studies are also made <strong>for</strong> achieving selective precipitation of silica. Treatment of sludge with calcium<br />

oxide or aluminium hydroxide at 80 o C helps in redissolution of coprecipitated lignin without dissolving<br />

silica portion. Leaf filter studies indicated that the carbonated black liquor could be filtered easily on<br />

600 mesh nylon cloth under reduced pressure of about 0.3 kg/cm 2 }.<br />

463. Luo, C.C; Wang, Y.F. 1991. A modified design to produce kraft liner board using<br />

bamboo pulp. In: Selected Papers on Recent <strong>Bamboo</strong> Research in China. Chinese<br />

Academy of Forestry, Beijing <strong>and</strong> <strong>Bamboo</strong> In<strong>for</strong>mation Centre, China: 247-255.<br />

464. Maheshwari, S. 1979. Anthraquinone as additive in kraft pulping of bamboo<br />

(Dendrocalamus strictus). Indian Pulp <strong>and</strong> Paper 33(5).<br />

465. Nazak, R.G; H<strong>and</strong>igol, M.P.H; Deb, V.K; Jaspal, N.S. 1979. AQ as an aditive in kraft<br />

pulping of bamboo (Dendrocalamus strictus). Indian Pulp <strong>and</strong> Paper 33(5): p17.<br />

466. Nazak, R.G; H<strong>and</strong>igol, M.P.H; Deb, V.K; Jaspal, N.S. 1979. Studies on kraft pulping of<br />

mixed tropical hardwoods in the presence of AQ. Paper presented in the IPPTA<br />

Seminar, March 1979.<br />

467. Nepenin, N; Bang, D.S. 1969. Obtaining kraft pulp from Vietnam bamboo. Cellulose<br />

Chemistry <strong>and</strong> Technology 3(6): 681-700.<br />

Laboratory studies have shown that by maintaining optimum conditions <strong>for</strong> sulphate cooking it is<br />

possible to obtain good-quality kraft pulp with a yield of 45 from old Neohouzeaua dullooa.<br />

468. Pravin, G. 1987. Improved process control strategy <strong>for</strong> liquid phase kraft pulping of<br />

bamboo (Dendrocalamus strictus). IPPTA 24(4): 41-47.<br />

60


Conventional liquid phase kraft pulping of bamboo is studied to develop an improved process<br />

control strategy so as to produce pulp of uni<strong>for</strong>m quality.<br />

469. Rao, V.G; Murthy, N.V.S.R; Annam Raju, P.V; Sharma, G.S.R.P. 1983. Effect of pulp<br />

extractives on sizing. Journal of Wood Chemistry <strong>and</strong> Technology 3(3): 371-376.<br />

The effect of specific extractive components of bamboo (Dendrocalamus strictus) <strong>and</strong> tropical<br />

mixed hardwoods kraft pulps on sizing is studied. It is found that the removal of the extractive<br />

components by diethyl ether improves sizing substantially, which may be attributed to the presence of<br />

oleic acid <strong>and</strong> its derivatives in the extractives. To substantiate this, the effect of added oleic acid <strong>and</strong><br />

methyl oleate on sizing is also studied. The possible mechanism of action of these compounds is also<br />

postulated.<br />

470. Rawat Rajesh; Sharma, G.D; Bhargava, G.G; Mohan, S.M. 1985. Kraft anthraquinone<br />

pulping of bamboo + mixed hard woods (70:30) bamboo (100 percent) <strong>and</strong> mixed hard<br />

woods (100 percent). IPPTA 22(3): 39-47.<br />

Laboratory scale kraft pulping studies are carried out at 17 percent sulphidity on bamboo + mixed<br />

hard woods (70:30) <strong>and</strong> compared the findings with bamboo (100 per cent) <strong>and</strong> mixed hard woods<br />

(100 per cent) using anthraquinone. It is reported that by adding different anthraquinone dosages (0.05<br />

per cent to 0.25 per cent) the kappa no. of bamboo + mixed hardwoods (70:30) reduces. The bleach<br />

consumption of all the anthraquinone based pulps is lower <strong>and</strong> physical strength properties are<br />

superior to the pulps without anthraquinone additive. It is reported that anthraquinone in small dosage<br />

(0.05 per cent) is more effective in improving the yield of bamboo + mixed hard woods (70:30) digested<br />

at higher kappa no. than with lower kappa no. digested bamboo <strong>and</strong> mixed hardwoods.<br />

471. Semana, J.A; Escolano, J.O; Monsalud, M.R. 1967. The kraft pulping qualities of some<br />

Philippine bamboos. TAPPI Journal 50(8): 416-419.<br />

The kraft pulping properties of Gigantochloa levis, G.aspera, Schizostachyum lumampao,<br />

Bambusa vulgaris, B. vulgaris var.striata <strong>and</strong> B.blumeana are studied. These bamboos are reported to<br />

have higher range of ash <strong>and</strong> silica contents than those ofother Asian species but lower lignin contents<br />

than those of Indian species. The Philippine bamboos are easily digested <strong>and</strong> bleachable pulps with<br />

permanganate numbers from 13.0 to 18.2 <strong>and</strong> screened pulp yield from 41.3 to 48.0 are obtained. The<br />

bamboos gave pulp with higher tearing resistance but lower folding endurance bursting strength <strong>and</strong><br />

tensile strength than <strong>for</strong>eign softwood kraft pulps <strong>and</strong> Philippine hardwood kraft pulps. The relative<br />

rigidity <strong>and</strong> moderate length of the bamboo fibres are associated with the strength differences between<br />

bamboo pulps <strong>and</strong> the other pulps.<br />

472. Shah, M.A; Goswami, N.C; Akhtaruzzaman, A.F.M. 1991. Influence of active alkali on the<br />

kinetics of kraft pulping of muli bamboo (Melocanna baccifera). IPPTA 3(2): 62-68.<br />

A study is made to find out to what extent the cooking is to be continued in kraft pulping of muli<br />

bamboo (Melocanna baccifera). The effect of active alkali charge is also studied. The investigation<br />

shows three distinct phases in delignification during kraft pulping of this bamboo. The rate of<br />

delignification increase with an increase in active alkali charge. The transition points between the<br />

initial <strong>and</strong> bulk, <strong>and</strong> between the bulk <strong>and</strong> residual phases shifted to a lower lignin content with an<br />

increase in alkali charge. The use of an active alkali charge of 16 per cent as NaOH seems to be<br />

insufficient to confine the cook in the bulk delignification phase. On increasing the active alkali charge<br />

to 18 per cent as NaOH, the situation has improved.<br />

472a. Sproull, R.C. 1955. TAPPI Journal 38: 593.<br />

473. Ujiie, M; Matsumoto, A. 1967. Studies on semi-kraft pulps from Sasa senanensis. Part I.<br />

Selection of the cooking conditions <strong>and</strong> comparison with Birch <strong>and</strong> Larch semi-kraft<br />

pulps. Research Bulletin of Experimental Forestry, Hokkaido University, Japan 25(1):<br />

287-321.<br />

Kraft semichemical pulps were prepared from culms of S. senanensis from Teshio (Hokkaido)<br />

under various conditions, <strong>and</strong> their yield <strong>and</strong> chemical <strong>and</strong> physical properties were compared with<br />

those of S. senanensis water-cooked pulps <strong>and</strong> of Betula platyphylla var. japonica <strong>and</strong> Larix leptolepis<br />

similarly prepared, or with previous data on sulphate pulps of S. senanensis <strong>and</strong> hardwoods. The<br />

61


<strong>Bamboo</strong> pulps with the best physical properties were prepared with the use of 15% active alkali, which<br />

also enabled the yield to be increased by ca. 5% compared with that of conventional S. senanensis<br />

sulphate pulps, <strong>and</strong> gave a pulp with excellent chemical properties (superior to those of the Larch<br />

pulps <strong>and</strong> a little inferior to those of the Birch pulps). Fibre length (mean 1.26 mm.) slightly exceeded<br />

that of Birch. The low yield of the <strong>Bamboo</strong> pulp compared with that of hardwoods (unavoidable<br />

because of the high extractive content) can be reduced at the expense of strength by pulping with only<br />

10% or even 5% active alkali.<br />

474. Vivone, R.R; Gomide, J.L. 1985. Effect of storage time of straw <strong>and</strong> moisture content of<br />

chips on the characteristics <strong>and</strong> properties of kraft pulp from bamboo. ABCP 18th<br />

annual meeting held during paper week, 18-22 November 1985 in Sao Paulo, Brazil. ABCP,<br />

Sao Paulo, Brazil. Vol. 1: 129-137.<br />

Pulps from recently-gathered bamboo (Bambusa vulgaris), with <strong>and</strong> without air drying, <strong>and</strong><br />

bamboo stored <strong>for</strong> 4 months after collection were compared. Results indicate that storing bamboos <strong>for</strong><br />

relatively long periods (4 months) should be avoided <strong>and</strong> that air drying facilitates processing without<br />

reducing pulp quality.<br />

Rayon Grade Pulping<br />

475. Bhat, R.V; Viramani, K.C. 1961. Viscose rayon pulp from Ochl<strong>and</strong>ra travancorica by<br />

prehydrolysis sulphate process. Indian Pulp <strong>and</strong> Paper 16(5).<br />

476. Ch<strong>and</strong>rasekharan, C. 1968. Indian <strong>for</strong>est resources <strong>for</strong> rayon grade pulp. Indian Forester<br />

94(12): 871-877.<br />

Only bamboo is used commercially in India <strong>for</strong> dissolving pulp. Recent analyses of other Indiangrown<br />

tree species <strong>and</strong> of hardwood mixtures are tabulated.<br />

477. Gupta, N.K; Jain, S.C. 1966. Utilization of bamboo dust (1) Paper <strong>and</strong> rayon grade<br />

pulps. Indian Pulp <strong>and</strong> Paper 20(7).<br />

477a. Horio, M; Takhama, M. 1958. Bulletin of the Institute of Chemical Research, Kyoto<br />

University Japan 36(5): p157.<br />

477b. Karnik, M.G. 1958. Indian Pulp <strong>and</strong> Paper 13(6): p283.<br />

478. Karnik, M.G. 1961. Viscose rayon grade pulps from bamboo (Dendrocalamus strictus)<br />

by water prehydrolysis sulphate process. Indian Pulp <strong>and</strong> Paper 15(11).<br />

479. Karnik, M.G. 1961. Viscose rayon grade pulps from bamboo (Dendrocalamus strictus),<br />

Preliminary investigation. Indian Pulp <strong>and</strong> Paper 14.<br />

480. Karnik, M.G; Sen, D.L. 1948. Some promising cellulose-bearing materials (other than<br />

cotton) <strong>for</strong> the manufacture of rayon. Journal of Scientific <strong>and</strong> Industrial Research 7(8):<br />

351-356.<br />

Pulps from reeds, bamboo species (Bambusa arundinacea, Dendrocalamus strictus <strong>and</strong> Kamti<br />

bamboo), bagasse pulp <strong>and</strong> jute fibres compared favourably with an American alpha-pulp <strong>and</strong> a<br />

Swedish sulphite pulp. The analytical values obtained came within the limits <strong>for</strong> rayon pulp. Results<br />

are tabulated.<br />

480a. Karnik, M.G; Sen, D.L. 1958. Journal of Scientific <strong>and</strong> Industrial Research (India) 7(8): p35.<br />

480b. Lele, P.S. 1964. Investigation of the Indian raw materials <strong>for</strong> the production of pulp<br />

suitable <strong>for</strong> the rayon industry. Chemical Age India 15(2): 173-176.<br />

62


481. Ramsarma, B.V. 1962. Manufacture of rayon grade pulp from bamboo. Sirpur Industrial<br />

Journal 1(2): 97-99.<br />

482. Saboo, R.N. 1992. Role of bamboo in the manufacture of rayon grade pulp. Proceedings<br />

of the National Seminar on <strong>Bamboo</strong>s, 19-20 December 1990, Bangalore. <strong>Bamboo</strong> Society<br />

of India, Bangalore: 53-59.<br />

Need <strong>for</strong> raising plantations suitable <strong>for</strong> pulp <strong>and</strong> paper is stressed. A general picture of the<br />

process of manufacturing dissolving grade pulp is projected here. Fibre length, pentosans present <strong>and</strong><br />

ash analysis of various raw materials used <strong>for</strong> making pulp are also presented.<br />

482a. Simionescu, C. 1956. Celluloza Hirtie (Bucharest 5(7): p156.<br />

482b. Simionescu, C. 1957. Papeterie 79: p589.<br />

482c. Simionescu, C. 1958. Celluloza Hirtie (Bucharest) 5(5): p171.<br />

483. Singh, M.M; Bhola, P.P. 1968. Production of rayon grade pulp. Proceedings of the<br />

Symposium on Utilization of Hardwoods <strong>for</strong> Pulp <strong>and</strong> Paper. August 1968, FRI & Colleges,<br />

Dehra Dun, India: 73-85.<br />

484. Suzuki, H. 1964. Rayon pulp from bamboo. Chemical Age 15(6): p582.<br />

485. Wang, Z.W. 1991. Status <strong>and</strong> prospects of textile shuttles made from bamboo fibre.<br />

Chongquing Forest Science Technology (2): 56-57.<br />

This paper gives the status <strong>and</strong> prospects of textile shuttles made from bamboo fibre.<br />

Mixed Pulping<br />

486. Bhargava, K.S. 1968. Utilization of mixed hardwoods at Bengal Paper Mills. Proceedings<br />

of the Symposium on Utilization of Hardwoods <strong>for</strong> Pulp <strong>and</strong> Paper, 1-3 August 1968.<br />

487. Bhargava, K.S; Sharma, M.C; Maheshwari, D.K. 1969. The effect of impregnation<br />

temperature <strong>and</strong> alkali concentration on cooking of mixture of bamboo <strong>and</strong> mixed<br />

hardwoods. Indian Pulp <strong>and</strong> Paper 24(5): 257-258.<br />

In a laboratory study on pulping a mixture of 60 Dendrocalamus strictus <strong>and</strong> 40 mixed hardwoods<br />

(70) Boswellia serrata in Bengal, the optimum unbleached pulp yield from chips cooked with 18.5-20<br />

active alkali (NaOH) was obtained at an impregnation temperature of 125 o C. With a higher alkali<br />

concentration, a lower impregnation temperature can be used, but the total yield of unbleached pulp is<br />

reduced.<br />

488. Bhat, R.V; Karnik, M.G. 1958. <strong>Bamboo</strong> <strong>and</strong> blue gum pulps <strong>for</strong> grease proof paper.<br />

Research <strong>and</strong> Industry 3(9).<br />

489. Chiou, C.H; Tsai, L.H. 1982. Pulping experiments on a mixture of bamboo <strong>and</strong> mixed<br />

hardwoods. Bulletin, Taiwan Forestry Research Institute No. 366: 5p.<br />

Trials to investigate sulphate pulping of different proportions of bamboo residue <strong>and</strong> mixed<br />

hardwoods revealed that a mixture containing 30 or 40 bamboo residue gave a satisfactory yield with<br />

good strength properties.<br />

490. Dwivedi, R.P; Dubey, R.K; Kaul, S.S; Singh, M.M. 1983. High yield semichemical pulping<br />

of mixture of bamboo <strong>and</strong> mixed hardwoods. IPPTA 20(3): p43.<br />

63


491. Ghosh, S.R; Saikia, C.N. 1996. Mixed pulping of bamboo <strong>and</strong> khagra reed <strong>and</strong><br />

evaluation of paper characteristics. IPPTA 8(1): 19-32.<br />

Khagra reed, Neyraudia reynaudiana is one of the important non-wood plants, that grows<br />

abundantly in the <strong>for</strong>ests of the North Eastern states. Laboratory scale experiments were carried out<br />

<strong>for</strong> mixed pulping of bamboo <strong>and</strong> khagra reed chips <strong>and</strong> conditions of pulping were optimised. It was<br />

found that bamboo <strong>and</strong> reed chips mixed in the ratio 4:1, when cooked with 16 active alkali (as Na2O),<br />

<strong>for</strong> 2 h at 170±2 o C gave unbleached pulp with 44.4 yield, which was easily bleachable. St<strong>and</strong>ard paper<br />

sheets from both unbleached <strong>and</strong> bleached pulps were <strong>for</strong>med <strong>and</strong> their physical strength properties<br />

were evaluated. The study carried out has indicated that mixed pulping of bamboo <strong>and</strong> reed is possible<br />

<strong>and</strong> khagra reed may be a potential source of supplementary cellulosic raw material <strong>for</strong> paper industry.<br />

492. Goyal, P; Mishra, N.D. 1982. Economics of bamboo <strong>and</strong> hardwood pulping by<br />

anthraquinone catalysed-kraft process. Zonal Seminar on High Yielding Pulping <strong>and</strong><br />

Bleaching of Pulps at F.R.I, Dehra Dun, 20-21 September 1980. IPPTA 19(1): 1-5.<br />

With a view to study the economy of pulping bamboo <strong>and</strong> tropical mixed hardwoods using<br />

anthraquinone, laboratory studies were conducted to confirm the benefits of AQ-addition in kraft<br />

pulping liquor. A test case showed that the cost of pulp production can be reduced by Rs.80/ per M.T.<br />

<strong>for</strong> bamboo <strong>and</strong> tropical mixed hardwoods in a medium-sized pulp milk.<br />

493. Guha, S.R.D; Singh, M.M; Bhola, P.P. 1977. Pulping of Anogeissus spp. <strong>and</strong> Tectona<br />

gr<strong>and</strong>is (lops <strong>and</strong> tops) <strong>for</strong> newsprint. Indian Forester 103(3): 196-202.<br />

A report on a pulping trial by semi-chemical processes (soda <strong>and</strong> kraft). Optimum conditions of<br />

chemical concn., sulphidity, temp. <strong>and</strong> time were found. The pulps of Anogeissus spp. were darker <strong>and</strong><br />

required bleaching. Satisfactory newsprint was made by mixing Anogeissus or Tectona with 40<br />

bamboo pulp.<br />

493a. Jurasck, L. 1987. Proceedings of the Symposium on Bioconversion <strong>and</strong> Utilization of Wood<br />

Material, University of Maine, College of Forest Resources.<br />

494. Khare, A; Joshi, R.C; Bhargava, G.G; Singh, M.M. 1984. Behaviour of mill bamboo,<br />

bamboo + mixed hard woods (70: 30) percent, bamboo + mixed hardwoods (50: 50)<br />

percent <strong>and</strong> mixed-hardwoods kraft black liquor on evaporation <strong>and</strong> addition of alkali.<br />

IPPTA 21(3): 29-36.<br />

Mill weak black liquor, bamboo, bamboo + mixed hard woods (70:30), bamboo + mixed<br />

hardwoods (50:50) <strong>and</strong> hard woods black liquor are evaporated to different total solid contents to see<br />

the behavior of these liquor especially on black liquor viscosity <strong>and</strong> density. It is observed that mixed<br />

hardwoods black liquor has higher viscosity as compared to bamboo <strong>and</strong> with increase in hard wood<br />

percentage the viscosity of black liquor increase as go on increasing the percentage of total solids. It is<br />

reported that the black liquor viscosity of bamboo, bamboo + mixed hard woods in different proportion<br />

<strong>and</strong> mixed hard woods can be reduced with increase in initial residual alkali of the black liquor. This will<br />

help in reducing the clogging of the evaporator tubes <strong>and</strong> better per<strong>for</strong>mance of the recovery.<br />

495. Maheshwari, S. 1975. Studies on chlorination of sulfate pulps of bamboo, eucalyptus<br />

<strong>and</strong> hard woods. Indian Pulp <strong>and</strong> Paper 30(1).<br />

496. Mai-Aung, U; Htway, D.K; Kyaw, Z.U. 1968. Mixed pulping of bamboo grown in Pegu<br />

Yoma. Part II.. Union of Burma Journal of Science <strong>and</strong> Technology 1(3): 561-569.<br />

Describes trials which showed that all 11 species of <strong>Bamboo</strong> known to grow in the Pegu Yoma<br />

could be used in mixture <strong>for</strong> the production of bleached kraft pulp, using techniques developed <strong>for</strong> the<br />

two most abundant species Cephalostachyum pergracile <strong>and</strong> Bambusa polymorpha. Resulting pulps<br />

had similar brightness <strong>and</strong> strength values, though inclusion of Dendrocalamus br<strong>and</strong>isii could slightly<br />

decrease brightness values.<br />

497. Pasaribu, R.A; Silitonga, T. 1974. Mixed pulping of hardwood <strong>and</strong> <strong>Bamboo</strong>. Laporan,<br />

Lembaga Penelitian Hasil Hutan 35: 24p.<br />

64


Reports pulping trials by the sulphate process on a 3-component mixture of Anthocephalus<br />

cadamba, Aleurites moluccana <strong>and</strong> a mixture of four <strong>Bamboo</strong>s (Bambusa bambos, B. vulgaris,<br />

Dendrocalamus asper <strong>and</strong> Gigantochloa ater) all from Sulawesi (Celebes). Data on fibre dimensions<br />

<strong>and</strong> wall thickness are also tabulated (with English captions):all species had low Runkel ratios,<br />

showing their suitability <strong>for</strong> pulping. Cooking conditions are recommended <strong>for</strong> mixed pulping of<br />

hardwoods <strong>and</strong> <strong>Bamboo</strong> or mixed hardwoods alone. The strength properties of pulps containing<br />

different component ratios are discussed.<br />

498. Rai, P.A; Jaspal, N.S. 1976. Mixed pulping of bamboo <strong>and</strong> hardwoods. IPPTA 13(4):<br />

328-339.<br />

Kraft pulps were made from mixtures of bamboo <strong>and</strong> Indian hardwoods (Lagerstroemia lanceolata,<br />

Adina cordifolia, Mitragyna parvifolia, Grewia tiliaefolia, Terminalia belerica, Kydia calycina,<br />

Anogeissus latifolia <strong>and</strong> Tectona gr<strong>and</strong>is).<br />

499. Romana, M.S.S; Exconde, T.A.R; Moredo, C.C. 1985. Suitability of fast growing wood<br />

species <strong>and</strong> bamboo <strong>for</strong> the production of dissolving pulp as base of cellulose<br />

derivatives. Terminal report. 16 leaves Forest Products Research <strong>and</strong> Development Inst.,<br />

College, Laguna, Philippine Council <strong>for</strong> Agriculture <strong>and</strong> Resources Research <strong>and</strong><br />

Development, Los Banos, Laguna.<br />

Prehydrolysis-sulfate pulping of three-year old bolo (Gigantochloa levis (Blanco) Merr.) <strong>and</strong> bagras<br />

(Eucalyptus deglupta Blume) were conducted using varied prehydrolysis <strong>and</strong> pulping conditions.<br />

Three, four <strong>and</strong> five multi-stage bleaching sequences were used in the purification process. Pulp yields<br />

ranged from 27.98 to 32.72 <strong>and</strong> from 23.89 to 29.55 (based on the original material) <strong>for</strong> bolo <strong>and</strong><br />

bagras, respectively. The experimental dissolving pulps from both samples have chemical <strong>and</strong> physical<br />

properties comparable to commercial dissolving rayon-grade pulp.<br />

Bleaching <strong>and</strong> Beating<br />

500. Bapna, S; Maheshwari, S; Jivendra; Kulkarni, A.Y. 1981. Colour reversion of bamboo<br />

pulp bleached with CEH sequence. IPPTA 18(1).<br />

501. Bhat, R.K; Soundararajan, T.N; Reddy, V.G; Bhargava, R.L. 1972. Bleaching of cold<br />

caustic soda pulps of Dendrocalamus strictus <strong>and</strong> mixed hardwoods. IPPTA 9(2):<br />

94-108.<br />

The unbleached pulps of the bamboo <strong>and</strong> hardwoods obtained by cold caustic soda process<br />

possessed low initial brightness <strong>and</strong> consequently were hard to bleach. Various bleaching methods<br />

were tried to study its effects on yields <strong>and</strong> the efficacy of the methods to improve the brightness of the<br />

pulps. The results of the methods tried are presented.<br />

502. Doat, J. 1970. The bleaching of chemical pulps made from tropical woods. Bois. For.<br />

Trop. 132: 47-68.<br />

503. Eriksson, K.E; Kirk, T.K. 1985. Bio-pulping, bio-bleaching <strong>and</strong> treatment of kraft<br />

bleaching effluents by white rot fungi. In: Robinson, C.W. (Ed.), Comprehensive<br />

Biotechnology, Volume 4, Chapter 15. Pergamon Press Ltd., Ox<strong>for</strong>d.<br />

504. Faul, K.K. 1982. Effect of chlorination <strong>and</strong> pH on final bleached bamboo pulp<br />

characteristics. Indian Pulp <strong>and</strong> Paper 36(4).<br />

505. Gopal, A.V. 1968. Heterogeneity in bleached bamboo pulp. Indian Pulp <strong>and</strong> Paper<br />

22(12): 675-678.<br />

Briefly analyses the two main causes of variation in quality of sulphate pulp made from bamboo in<br />

India, viz. the age <strong>and</strong> decay of the bamboo at the time of processing, <strong>and</strong> the process variables in<br />

pulping.<br />

65


506. Grant, J. 1964. Beating characteristics of non-woody pulps. Paper Trade Journal<br />

148(45).<br />

507. Guha, S.R.D; Sharma, Y.K; Singh, S.P. 1968. Studies on the effects of pulp blending.<br />

Indian Pulp 23(2): 157-161.<br />

Results (tabulated) of an investigation on the blending of pulps of bamboo with Eucalyptus<br />

gr<strong>and</strong>is, Boswellia serrata <strong>and</strong> bagasse showed that the strongest pulps were obtained by blending<br />

after separately pulping <strong>and</strong> beating the constituents. By this means, the propagation of bamboo (<strong>and</strong><br />

consequently the cost) can be reduced.<br />

508. Guha, S.R.D; Singh, M.M; Bhola, P.P. 1976. Beating characteristics of bamboo pulp in<br />

valley beater: Effect of temperature <strong>and</strong> consistency on power consumption <strong>and</strong> pulp<br />

sheet properties. IPPTA 13(1): 54-56.<br />

Results of the study made on the beating characteristics of bamboo pulp in valley beater are<br />

presented. Control of the temperature <strong>and</strong> consistency during the beating process is required to<br />

develop proper fibre to fibre bonding during the course of sheet <strong>for</strong>mation. It is found that the optimum<br />

temperature <strong>for</strong> beating is 35 degree C <strong>for</strong> bamboo pulp <strong>and</strong> the optimum consistency is 1.5 degree.<br />

Power consumption is reported more at higher temperature <strong>and</strong> less at higher consistencies.<br />

509. Guha, S.R.D; Singh, M.M; Mithal, K.C. 1966. Production of bleached pulps from mixture<br />

of bamboo <strong>and</strong> mixed hardwoods. Indian Pulp <strong>and</strong> Paper 20(10).<br />

510. Guha, S.R.D; Singh, M.M; Singh, S.P. 1978. High brightness pulps as filler <strong>for</strong> the<br />

production of urea <strong>for</strong>maldehyde <strong>and</strong> melamine <strong>for</strong>maldehyde moulding powder.<br />

Indian Forester 104(1): 51-58.<br />

Suitable pulps were prepared from commercially available bamboo pulps (bleached <strong>and</strong><br />

unbleached) <strong>and</strong> from Eucalyptus hybrid pulp. Details are given of the bleaching processes used.<br />

511. Islam, S; Bist, V; Ch<strong>and</strong>, S; Pant, R. 1989. Hypochlorite bleaching of bamboo cold-soda<br />

high yield pulping <strong>for</strong> newsprint furnishes. Paper presented in the IPPTA Silver Jubilee<br />

<strong>International</strong> Seminar & Workshop on Appropriate Technology <strong>for</strong> Pulp <strong>and</strong> Paper<br />

Manufacture in Developing Countries, IPPTA, New Delhi: 12p.<br />

512. Jain, D.K; Singh, S.V; Guha, S.R.D. 1976. Bleaching of kraft pulp changes in properties<br />

throughout bleaching sequence CEH. IPPTA Souvenir.<br />

513. Khanna,P.P; Swaleh, M. 1981. Analysis of bamboo (Dendrocalamus strictus) black<br />

liquor. Indian Pulp <strong>and</strong> Paper 36(1).<br />

514. Krishnagopalan, A; Kutscha, N.P; Simar, G.L. 1975. The effect of refining on the<br />

morphology <strong>and</strong> properties of bamboo paper. IPPTA 12.<br />

515. Kumar, A; Singh, S.V; Singh, M.M; Guha, S.R.D. 1974. Kinetics of chlorination stage of<br />

bleaching bamboo kraft pulp. IPPTA 22(4).<br />

516. Ledoux, P; Interox, S.A; Agnihotri, V.G. 1981. Peroxide spray bleaching of CEHH<br />

bleached pulp. IPPTA 18(1).<br />

517. Maheshwari, S. 1981. Studies on colour reversion of bamboo sulfate pulp. IPPTA 18(1).<br />

518. Maheshwari, S. 1982. Effect of bamboo bleached pulp viscosity on strength properties.<br />

IPPTA 14(2).<br />

66


519. Maheshwari, S; Bapna, S; Jivendra; Kulkarni, A.Y. 1980. Studies on colour reversion of<br />

bamboo pulps bleached with CEH sequence. Zonal Seminar on High Yielding Pulping<br />

<strong>and</strong> Bleaching of Pulps, 20-21 September 1980, Dehra Dun.<br />

520. Mai-Aung, U. 1961. Bleachable pulp from Burmese bamboo by chlorination process.<br />

Pulp <strong>and</strong> Paper Magazine of Canada 62(3): 230-232.<br />

Reports experiments showing that bleachable pulp could be made by the chlorination process<br />

from shredded Cephalostachyum pergracile.<br />

521. Misra, D.K. 1980. Pulping <strong>and</strong> bleaching of nonwood fibres. In: Casey, J.P (Ed.). Pulp<br />

<strong>and</strong> Paper Chemistry <strong>and</strong> Chemical Technology 3rd Ed. Wiley - Interscience, New York:<br />

504-568.<br />

522. Oye, R. 1981. The effect of beating on bamboo pulps -- characterization of bamboo<br />

dissolving pulp. Proceedings of <strong>Bamboo</strong> Production <strong>and</strong> Utilization. XVII IUFRO World<br />

Congress, 6-17 September 1981, Kyoto, Japan. Wood Research Institute, Kyoto University,<br />

Japan: 39-44.<br />

Comparing with wood pulps, bamboo pulp cellulose has some characteristics, one of which is a<br />

higher mercerization resistance. This could be improved by mechanical treatment or heating of the<br />

bamboo pulp, though no effect was admited on linter <strong>and</strong> wood pulps.<br />

523. P<strong>and</strong>e, G.C. 1966. Studies on bleaching <strong>for</strong> dissolving grade pulp from bamboo<br />

(Dendrocalamus strictus) I. Indian Pulp <strong>and</strong> Paper: 20: 10-12.<br />

Describes trials of improves sulphate pulping procedures <strong>for</strong> preparing dissolving-grade pulp from<br />

bamboo (in which nearly 25 of the total lignin is held in the lumen <strong>and</strong> between the primary <strong>and</strong><br />

secondary walls of the fibres). Optimum viscosity was achieved by replacing the chlorination stage by<br />

CIO, treatment; after further bleaching, a most satisfactory bleached pulp was obtained.<br />

524. P<strong>and</strong>e, G.C. 1966. Studies on bleaching <strong>for</strong> dissolving grade pulp from bamboo<br />

(Dendrocalamus strictus) II. Indian Pulp <strong>and</strong> Paper 20: 599, 601-605 & 703-707.<br />

525. P<strong>and</strong>e, G.C. 1967. Studies on bleaching <strong>for</strong> dissolving grade pulp from bamboo<br />

(Dendrocalamus strictus) III. Indian Pulp <strong>and</strong> Paper 21(12): 735-741, 749.<br />

526. Rao, A.R.K; Srinivasan, G; Maheshwari, H.K. 1978. Effect of beating on bamboo fibres.<br />

Indian Pulp <strong>and</strong> Paper 32(5): 35-46.<br />

Chips of bamboo (Dendrocalamus strictus) were pulped by the sulphate process, <strong>and</strong> the pulp<br />

was beaten to different degrees. Effects of beating on fibre dimensions <strong>and</strong> the strength <strong>and</strong> optical<br />

properties of the pulp are shown in tables <strong>and</strong> figures. Morphological changes in the fibres are<br />

illustrated in photomicrographs. The changes are discussed in relation to the observed critical beating<br />

value, above which tensile strength <strong>and</strong> bursting strength declined.<br />

527. Rao, M.N.R; Harikishore; Pant, R. Bleaching of bamboo cold soda pulp. Central Pulp <strong>and</strong><br />

Paper Research Institute Research Report No. 8312.<br />

528. Rao, M.N.R; Pant, R; Mathur, R.M; Rao, A.R.K; Fellegi, J. 1980. Improves hypochlorite<br />

bleaching of bamboo pulp. Paper presented in the Zonal Seminar on High-yield Pulping<br />

<strong>and</strong> Bleaching of Pulp. 20-21 September 1980, FRI & Colleges, Dehra Dun, India.<br />

529. Rao, V.G; Murthy, N.V.S.R; Annam Raju, P.V; Vidyasagar, C.H.V; Sharma, G.S.R.P. 1988.<br />

Effect of hydrogen peroxide adition in the bleaching of bamboo pulp in CEH <strong>and</strong> CED<br />

sequences. IPPTA 25(1): 20-23.<br />

67


530. Roy, T.K; Bist, V; Pant, R. Bleaching investigations of high-yield pulp from bamboo:<br />

Influence of chromophoric groups. Centre Pulp <strong>and</strong> Paper Research Institute. Research<br />

Report No. 8512.<br />

531. Singh, M.M; Bhargava, K.S; Gupta, R.K. 1971. Beating evaluation of Bengal Pulp Mill's<br />

pulps. Proceeding of the Conference on Utilisation of Hardwoods <strong>for</strong> Pulp <strong>and</strong> Paper. April<br />

1971, FRI & Colleges, Dehra Dun, India: 119-121.<br />

532. Singh, M.M; Bhargava, K.S; Sharma, M.C; Oberoi, M.S. 1968. Pulping <strong>and</strong> bleaching<br />

studies on a mixture of bamboo <strong>and</strong> mixed hardwoods. Indian Pulp <strong>and</strong> Paper 23(3):<br />

211-212.<br />

Results (tabulated) oflaboratory experiments at Dehra Dun on the sulphate pulping of bamboo <strong>and</strong><br />

mixed hardwoods (unspecified) showed that satisfactory high- <strong>and</strong> lo- brightness pulps <strong>and</strong> semibleached<br />

pulps could be obtained from a 50:50 mixture of bamboo <strong>and</strong> mixed hardwoods.<br />

533. Singh, M.M; Bhola, P.P; Purkayastha, S.K; Sharma, L. 1976. Effect of beating variables<br />

on sheet <strong>for</strong>mation of bamboo pulp. IPPTA 14(2): 178-185.<br />

The effect of beating variables like consistency <strong>and</strong> temperature on strength development in<br />

bamboo pulp was studied. Variations in fibre morphology as well as orientation of the fibres in the h<strong>and</strong><br />

sheets were also investigated. No significant difference was found in the strength properties of the<br />

h<strong>and</strong> sheets examined, but significant difference in fibre dimensions was observed when the<br />

temperature was varied. On beating, various cell wall layers of bamboo fibre open up leaving a gap<br />

between them. This gap not only increases the percentage of void area in the sheet but also does not<br />

allow the fibres to bind to a compact mass. This appears to be the main h<strong>and</strong>icap of the bamboo fibres.<br />

534. Singh, M.M; Sharma, Y.K; Bhola, P.P. 1976. Beating characteristics of bamboo pulp in<br />

banning beaters: Effect of consistency on power consumption <strong>and</strong> pulp sheet<br />

properties. IPPTA 13(1): 49-53.<br />

Bleached bamboo pulp of Central Pulp Mills was beaten in two pilot plant banning beaters, one<br />

having phosphorbronze tackle <strong>and</strong> the other having basalt lava stone roll <strong>and</strong> bed plate. The<br />

consistency of the stock during beating was kept at 4 percent, 6 percent <strong>and</strong> 8 percent. The results<br />

indicate that at higher consistencies, less power is consumed. Stone roll beater consumes less energy<br />

<strong>for</strong> the same degree of beating. Breaking length <strong>and</strong> burst factor are higher when the pulp is beaten<br />

with phophorbronze tackle <strong>and</strong> the difference is more pronounced at lower consistency, whereas stone<br />

roll beater gives a higher tear factor <strong>and</strong> the difference is more pronounced at higher consistency.<br />

535. Suman, S; Subhash, M. 1987. Studies on bleaching of bamboo pulp with CHH <strong>and</strong> CEH<br />

sequences. IPPTA 24(1): 8-11.<br />

This paper deals with the comparative investigations of bleaching of bamboo sulfate pulp of<br />

varying kappa number with CHH <strong>and</strong> CEHH sequences. It has been observed that bleaching of pulp<br />

can be done to desired level of brightness with CHH sequence. However total chlorine requirement<br />

<strong>and</strong> post colour number are higher while the strength properties are lower of CHH bleached pulp<br />

compared to CEHH bleached pulp. For CHH bleached pulp of low kappa number these adverse<br />

effects are not much. As the alkali extraction stage is eliminated the alkali consumption will be lower<br />

<strong>and</strong> colour of combined effluent of CHH sequence will be very light compared to CEHH sequence. It<br />

has been finally concluded that CHH sequence can be followed if we maintain the pulp kappa number<br />

on lower side i.e. below 25.<br />

536. Venkobarao, G; Murthy, N.V.S.R; Annam Raju, P.V; Vidyasagar, C.H.V; Sharma, G.S.R.P.<br />

1988. Effect of hydrogen peroxide addition in the bleaching of bamboo pulp in C.E.H.<br />

& C.E.D. sequence. IPPTA 25(1): 20-23.<br />

The results of laboratory trials on the effect of hydrogen peroxide addition in the alkaline extraction<br />

stage of C.E.H as well as C.E.D bleaching of bamboo pulp, on the final bleached pulp properties are<br />

presented. The overall advantages by the inclusion of Hydrogen peroxide in the Extraction stage (Ep)<br />

are also discussed in this paper.<br />

68


537. Wang, H; Lirn, T.R. 1985. Study on the bleaching of high yield pulp from bamboo<br />

waste. Forest Products Industries 4(1): 2-11.<br />

Wastes of Phyllostachys edulis, P. makinoi <strong>and</strong> Dendrocalamus latiflorus were investigated.<br />

538. Xie, T.M; Lu, Z.J. 1987. A preliminary study of chlorophenolics in nonwood pulp<br />

bleaching effluents [incl. reeds, Chinese alpine rush, chlorination, chlorine<br />

compounds, chlorophenols, hypochlorites]. Nordic Pulp <strong>and</strong> Paper Research Journal<br />

2(2): 56-60.<br />

Storage of <strong>Bamboo</strong> <strong>and</strong> Pulp<br />

539. Bakshi, B.K; Guha, S.R.D; Gupta, S. 1960. Effects of fungal damage to bamboo on the<br />

yield <strong>and</strong> quality of pulp. Research <strong>and</strong> Industries 5(2): 38-39.<br />

Results of an investigation made to find the effect of fungal damage to the bamboo, Bambusa<br />

tulda on the yield <strong>and</strong> quality of pulp are presented. It is reported that decayed bamboo gives lower<br />

yields. Sheets made from decayed <strong>and</strong> stained bamboo pulpare found to have lower strength than<br />

from healthy bamboo pulp.<br />

540. Bakshi, B.K; Guha, S.R.D; Singh, S; Pant, R.K; Taneja, K. 1968. Decay in flowered<br />

bamboo <strong>and</strong> its effect on pulp. Indian Pulp <strong>and</strong> Paper 22(9): 503-506.<br />

A recent pulping study of dead <strong>and</strong> decayed Bambusa arundinacea that had flowered gregariously<br />

since 1958 around D<strong>and</strong>eli, Mysore State, showed that decay, mainly attributable to white rot, resulted<br />

in loss of wood substances <strong>and</strong> pulp yield, reduced pulp strength because of holes in the fibres, <strong>and</strong><br />

increased consumption of bleaching chemicals because of the high content of residual lignin in the<br />

pulp; cost of pulp production was there<strong>for</strong>e higher than from healthy bamboo. <strong>Bamboo</strong> attacked by<br />

brown rot was unsuitable <strong>for</strong> pulping, but the incidence of brown rot was insignificant.<br />

541. Beeson, C.F.C. 1941. Ecology <strong>and</strong> control of <strong>for</strong>est insects of India <strong>and</strong> neighbouring<br />

countries. Vasant Press, Dehra Dun: 773p.<br />

Opening with a short survey of the history of <strong>for</strong>est entomology in India <strong>and</strong> the adjoining<br />

countries, <strong>and</strong> with some general notes on the methods of feeding of insects, life cycles <strong>and</strong> connected<br />

matters, the bulk of the book is devoted to a systematic record of available in<strong>for</strong>mation on the ecology<br />

of insects related to Indian <strong>for</strong>ests. In all 4,300 species are mentioned, `including at least one<br />

representative of every type of locality-plant-insect combination found in Indian <strong>for</strong>ests <strong>and</strong> every<br />

species which has been the subject of an expression of interest by a Forest Officer of the Indian<br />

Empire'. The in<strong>for</strong>mation is arranged alphabetically by orders <strong>and</strong> then families of insects, each<br />

species being dealt with separately, again in alphabetical sequence.<br />

542. Ch<strong>and</strong>ra, A; Guha, S.R.D. 1979. Studies on the decay of bamboo (Dendrocalamus<br />

strictus) during outside storage-degradation of cellulose. Indian Forester 105(6):<br />

444-450.<br />

Holocellulose <strong>and</strong> hemicellulose were analysed in untreated <strong>and</strong> preservative-treated bamboo<br />

after 4, 8 <strong>and</strong> 12 months storage. The contents of both declined with duration of storage; the effect of<br />

the preservatives was slight. After 12 months, the holocellulose content (originally 68 percent) was 59-<br />

63 percent <strong>and</strong> the hemicellulose content (originally 51 percent) was 36-39 percent. The degree of<br />

polymerization of the cellulose in untreated samples decreased over 12 months from 1074 to 948; that<br />

of the hemicellulose decreased from 1309 to 1105 (1300 to 1259 <strong>for</strong> PCP - treated samples.<br />

543. Ch<strong>and</strong>ra, A; Guha, S.R.D. 1979. Studies on the decay of bamboo (Dendrocalamus<br />

strictus) during outside storage-effect on Hemicellulose. Journal of Timber<br />

Development Association 25(3): 10-13.<br />

In this paper investigations on how the decaying organisms attacked the hemicelluloses of<br />

bamboo during outside storage <strong>and</strong> preferentially utilized the constituting monosaccharide <strong>for</strong> their<br />

metabolism <strong>and</strong> growth are reported.<br />

69


544. Ch<strong>and</strong>ra, A; Guha, S.R.D. 1981. Studies on the decay of bamboo (Dendrocalamus<br />

strictus) during outside storage-degradation of lignin. Indian Forester 107(1): 54-59.<br />

During outside storage the bamboo (Dendrocalamus strictus) was attacked by various wood<br />

destroying microorganisms. Lignin also was degraded gradually due to decay. The degradation was<br />

caused by white rot type of fungal decay. Fungal decay also chemically changed the lignin<br />

macromolecule. Chemical analysis of lignin from freshly felled bamboo <strong>and</strong> stored bamboo showed<br />

this difference. The decayed lignin was higher in oxygen, lower in hydrogen, methoxyl value <strong>and</strong><br />

carbon contents compared to fresh lignin.<br />

545. Chen, R.Y; Liu, M.S; Chang, T.C; Tsai, M.J. 1989. Postharvest h<strong>and</strong>ling <strong>and</strong> storage of<br />

bamboo shoots (Bambusa oldhami Munro). Acta Horticulturae: <strong>International</strong> symposium<br />

on postharvest h<strong>and</strong>ling of fruits <strong>and</strong> vegetables, Leuven, Belgium, 29th August <strong>and</strong> 2nd<br />

September 1988: No. 258: 309-316.<br />

Following harvesting, bamboo shoot fibre content increased quickly from the cut end toward the<br />

tip. Crude fibre content could be reduced by keeping shoots at high humidity, low temperature or both<br />

during h<strong>and</strong>ling. Phenylalanine ammonia lyase (PAL) <strong>and</strong>peroxidase activities rapidly increased in<br />

harvested shoots but no trends were observed <strong>for</strong> polyphenol oxidase activity. PAL activity was closely<br />

correlated with increasing crude fibre <strong>and</strong> lignin content <strong>and</strong> was partly due to de novo enzyme<br />

synthesis.<br />

546. Gardener, J.C.M. 1945. A note on the insect borers of bamboo <strong>and</strong> their control. Indian<br />

Forest Bulletin (New Series), Entomology No. 125. FRI, Dehra Dun.<br />

Certain qualities of the bamboo itself so far as they appear to affect control of borers are<br />

mentioned. Notes on the insect borers are given with special reference to the Bostrichidae, the most<br />

important family. The amount of starch in the bamboo, which is intimately connected with liability to<br />

attack, varies with the season; also starch may under certain conditions decrease to nil in a culm in<br />

about 3 weeks after felling; in culms felled in hot dry weather starch is high to start with <strong>and</strong> shows little<br />

depletion after felling; such culms are liable to heavy attack if not treated against insect attack. Water<br />

immersion <strong>for</strong> 3 months prevents Bostrichid attack; the starch content in the immersed culms is not<br />

apparently altered, only the soluble sugars being removed. A method devised <strong>for</strong> protection of hollow<br />

culms (internodal injection) is described. This appears entirely satisfactory <strong>for</strong> large-scale work.<br />

Impregnation of hollow culms with aqueous solutions of inorganic salts or creosote by the `Basal<br />

incision method' is dealt with. Solid culms may be so impregnated if rubber tubes are used to convey<br />

the preservative (Boucherie). The leaf-suction method worked satisfactorily to draw the solutions of<br />

inorganic salts to considerable heights but is considered impracticable <strong>for</strong> large-scale work. Baking<br />

culms has no deterrent effect against Bostrichidae unless the moisture content is reduced to near 5 per<br />

cent. <strong>and</strong> sufficient moisture to support Bostrichid life is not absorbed from the air subsequently.<br />

Superficial swabbing with creosote <strong>and</strong> fuel oil (or rape oil) gives temporary protection <strong>for</strong> about one<br />

year. Methods of impregnation with preservatives by soaking, open tank <strong>and</strong> pressure processes are<br />

briefly discussed.<br />

547. Guha, S.R.D; Bakshi, B.K; Thapar, H.S. 1958. The effect of the fungus attack on bamboo<br />

on the preparation <strong>and</strong> properties of pulp. Journal of the Scientific <strong>and</strong> Industrial<br />

Research 17(4): 72-74.<br />

The decay caused by the white-rot fungi Daedales flavida, Polystictus sanguineus <strong>and</strong> Lentinus<br />

praerifdus on Dendrocalamus strictus was studied. All caused some damage, that by D. flavida being<br />

extensive. Lignin content in the cell-wall was depleted, but since the lignin percentage remained the<br />

same in damaged <strong>and</strong> undamaged bamboo it is concluded that the fungi attack other cell-wall<br />

constituents. Strength properties of pulps from decayed chips were appreciably reduced <strong>and</strong> this is<br />

explained by the par<strong>for</strong>ations <strong>and</strong> corrosion marks in the cell-walls (illustrated by photomicrographs)<br />

caused by the fungi.<br />

548. Guha, S.R.D; Ch<strong>and</strong>ra, A. 1979. Studies on the decay of bamboo (Dendrocalamus<br />

strictus) during outside storage-I. Effect of preservatives II. Effect on pulping<br />

qualities. Indian Forester 105(4): 293-300.<br />

70


Experiments were conducted at Dehra Dun to study (i) the loss of wood substance in bamboo<br />

during outside storage (ii) the effect of various wood destroying microorganisms on the chemical<br />

constituents of bamboo (iii) the efficacy of three preservatives compositions in resting the fungal decay<br />

<strong>and</strong> to evaluate the effect of decay on the pulp qualities of bamboo after different storage period with<br />

<strong>and</strong> without chemical treatments <strong>and</strong> its results are presented. It is reported that the preservative<br />

treatments reduced wood substance loss by 28-30 percent <strong>and</strong> pulp yield loss by about 30 percent.<br />

549. Kirkpatrick, T.W; Simmonds, N.W. 1958. <strong>Bamboo</strong> borers <strong>and</strong> the moon. Tropical<br />

Agriculture, Trinidad 35(4): 299-301.<br />

Internodes, taken from the top, middle <strong>and</strong> bottom of mature (5- to 10-year) <strong>and</strong> immature culms<br />

of Bambusa vulgaris, felled, some during the waxing, others during the waning of the moon, were<br />

placed in a greenhouse with pieces heavily infested with Dinoderus minutus. Tables show infestation<br />

in number of holes per 100 sq.in. of surface after 63 <strong>and</strong> 97 days. Popular local rhyming statements<br />

that (a) `<strong>Bamboo</strong> cut with moon on wane will ensure financial gain', (b) `But beetles bore it very soon, if<br />

cut upon the waxing moon', <strong>and</strong> (c) `Moreover it's a well-known fact that ripe bamboo is less attacked'<br />

are disproved by the data, which show a non-significant advantage <strong>for</strong> (b) <strong>and</strong> a highly significant (P<br />


555. Kumar, S; Singh, M.M; Guha, S.R.D. 1980. Protection of pulpwood in outside storage - A<br />

case <strong>for</strong> using chemicals <strong>for</strong> prophylactic treatments. Journal of the Timber<br />

Development Association of India 26(2): 30-42.<br />

A review of the laboratory work done on storage losses with different wood species including<br />

bamboo <strong>and</strong> the adverse effect of inadequate protection on strength of paper sheets, bleach<br />

consumption <strong>and</strong> brightness <strong>and</strong> loss in digester capacity utilisation. Possible saving by using effective<br />

chemicals on some of these counts have also been qualitatively <strong>and</strong> quantitatively enumerated.<br />

556. Maheshwari, S; Maheswari, O.N; Bajaj, V.D. 1988. Efficient management of bamboo<br />

storage to reduce cost of paper production. IPPTA 25(2): 1-7.<br />

The paper deals with a few aspects of efficient management of storage of bamboo. The emphasis<br />

has been made to have optimum inventory of bamboo at different places of storage. Proper selection<br />

of site <strong>for</strong> storage, layout of stacks in the yard in compliance to the insurance rules <strong>and</strong> easy approach<br />

<strong>for</strong> transport system, stacks design, etc are to be given due consideration to reduce cost of loading <strong>and</strong><br />

unloading, prevention from fire hazards, preservation of raw material <strong>and</strong> overall reduction in cost of<br />

raw material. The paper also discusses in detail the biological infestations due to prolonged storage.<br />

Details regarding types of infestations <strong>and</strong> remedial measures to check the same are also described. A<br />

brief account of the experiments conducted to evaluate the efficacy of prophylactic treatment to check<br />

degradation of bamboo <strong>and</strong> its effect on papermaking characterestic given along with the mill<br />

experience. It is concluded that adoption of scientific <strong>for</strong>est management practices, systematic storage,<br />

optimum inventory <strong>and</strong> preservative treatment would be helpful in checking loss of woody substance at<br />

various stages of operation, which would ultimately give better pulp <strong>and</strong> paper quality with improved<br />

productivity.<br />

557. Mai-Aung, U; Htway, D.K; Kyaw, Z.U. 1969. Pulps from stored bamboo. Union of Burma<br />

Journal of Science <strong>and</strong> Technology 2(2): 345-354.<br />

When Bambusa polymorpha <strong>and</strong> Cephalostachyum pergracile were stored in Burma <strong>for</strong> 12<br />

months in piles in the open or submerged in a natural pond, deterioration through stain <strong>and</strong> rot fungi<br />

<strong>and</strong> beetle attack were severe in the open but negligible in water. Losses of specific gravity were<br />

respectively 16.7 <strong>and</strong> 6.13% B. polymorpha <strong>and</strong> 6.52 <strong>and</strong> 1.61% in C. pergracile. Neither duration nor<br />

method of storage had a great effect on chemical composition <strong>and</strong> sulphate pulp yields, but some<br />

strength properties of the pulp decreased about equally in both methods during storage. Brightness<br />

<strong>and</strong> response to bleaching was better in pulp from water-stored <strong>Bamboo</strong>; this was also confirmed in a<br />

limited bleaching trial on mechanical pulp from B. polymorpha.<br />

558. Mathew, G; Nair, K.S.S. 1990. Storage pests of bamboo in Kerala. In: Rao, I.V.R,<br />

Gnanaharan, R <strong>and</strong> Sastry, C.B (Eds.). <strong>Bamboo</strong>s Current Research: Proceedings of the<br />

<strong>International</strong> Workshop, Cochin 1989. KFRI, Peechi <strong>and</strong> IDRC, Canada: 212-214.<br />

About 12 spp. of insects, mostly beetles, were recorded causing damage to stored reeds <strong>and</strong><br />

bamboos in Kerala, including an unidentified subterranean termite <strong>and</strong> 2 spp. of beetles, Dinoderus<br />

minutus <strong>and</strong> D. ocellaris (Bostrichidae), which were the most serious borers. Observations on the<br />

seasonal incidence, general characteristics as well as the nature of attack caused by these beetles are<br />

given.<br />

559. Murphy, R.J; Alvin, K.L; Tan, Y.F. 1991. Development of soft rot decay in the bamboo<br />

Sinobambusa tootsik. IAWA Bulletin 12(1): 85-94.<br />

The development of decay cavities caused by growth of the soft rot fungus Chaetomium globosum<br />

in the fibre cell walls of Sinobambusa tootsik was studied in 1- <strong>and</strong> 3-year-old culms. Soft rot attack<br />

was found only in the cell walls of fibres; parenchya <strong>and</strong> vessel elements remained unattacked. The<br />

extent of soft rot <strong>and</strong> cavity morphology were influenced by the position of the fibre bundles in the culm<br />

wall, culm age <strong>and</strong> the degree of lignification of individual fibres. Decay was greatest in the walls of<br />

those fibres which matured late in the course of culm development <strong>and</strong> in which the wall contained<br />

zones of low lignin content. It was least in the early maturing, uni<strong>for</strong>mly lignified fibres <strong>and</strong> in very<br />

immature, thin-walled fibres. The results are discussed in relation to developmental anatomy <strong>and</strong> the<br />

reported ultrastructure of bamboo fibre walls.<br />

72


560. Nair, K.S.S; Mathew, G; Varma, R.V; Gnanaharan, R. 1983. Preliminary investigations on<br />

the biology <strong>and</strong> control of beetles damaging stored reed. KFRI Research Report No. 19.<br />

Kerala Forest Research Institute, Kerala, India: 35p.<br />

The damage potential of Dinoderus beetles stored bamboo, reed Ochl<strong>and</strong>ra travancorica, one of<br />

the fibrous raw materials <strong>for</strong> paper pulps <strong>and</strong> possible methods of their control were investigated. The<br />

study included a general survey of insect damage of stored reed in Kerala, development of methods <strong>for</strong><br />

rearing dinoderus in the laboratory, experimental investigations on factors influencing succeptibility of<br />

reed to Dinoderus <strong>and</strong> evaluation of several chemicals under laboratory as well as field conditions <strong>for</strong><br />

control of the borers.<br />

561. Purushotham, A. 1970. Protection of pulpwood (timber, bamboo) from deterioration<br />

due to biological agencies (fungi <strong>and</strong> insects, etc.) during transit <strong>and</strong> storage. Journal<br />

of the Timber Development Association 16(2): 50-53.<br />

Author suggests measures <strong>for</strong> protection of bamboo against insects <strong>and</strong> fungus attack at felling<br />

<strong>and</strong> stacking site. Methods of prophylactic treatments are described.<br />

562. Sadawarte, N.S; Prasad, A.K. 1978. Indian experience in collecting, h<strong>and</strong>ling, storing,<br />

preservation, <strong>and</strong> preparing bamboo <strong>for</strong> pulping. USA, Technical Association of the Pulp<br />

<strong>and</strong> Paper Industry, Nonwood Plant Fiber Committee. Nonwood plant fiber pulping. Progress<br />

report No. 9: 3-9 TAPPI, Atlanta, Georgia, USA.<br />

<strong>Bamboo</strong> accounts <strong>for</strong> over 60 of the raw material used in the Indian pulp <strong>and</strong> paper industry.<br />

Research done at Central Pulp Mills in India is briefly described on removing silica from bamboo prior<br />

to pulping <strong>and</strong> on utilizing bamboo dust as fuel <strong>and</strong> in pulping.<br />

563. Sai Ram, M; Seenayya, G. 1991. Production of ethanol from straw <strong>and</strong> bamboo pulp by<br />

primary isolates of Clostridium thermocellum. World Journal of Microbiology <strong>and</strong><br />

Biotechnology 7(3): 372-378.<br />

Two strains of Clostridium thermocellum have been isolated <strong>and</strong> these strains are found displaying<br />

higher ethanol tolerance <strong>and</strong> can grow <strong>and</strong> degrade cellulose in the presence of 1.5 percent ethanol.<br />

The abilities of these isolates to degrade native <strong>and</strong> pretreated agricultural material such as rice straw,<br />

bamboo pulp (Bambusa sp.) <strong>and</strong> stems of Lantana <strong>and</strong> Parthenium weeds are reported. The effect of<br />

reducing sugars <strong>and</strong> ethanol on the cellulose fermentations is also reported.<br />

564. Satish Kumar; Kalra, K.K; Dobriyal, P.B. 1985. Protection of pulp-bamboo in outside<br />

storage. Journal of the Timber Development Association 31(4): 5-12.<br />

Field trials on protection of flowered, semi dry, dried <strong>and</strong> green bamboos were carried out at Sirpur<br />

Paper Mills, Kagazagar, Andhra Pradesh Paper Mills, Rajahmundhary <strong>and</strong> Bengal Paper Mills,<br />

Raniganj. At the three mill sites, variable losses in raw material were noticed. Real losses were,<br />

however, more than the apparent losses as the <strong>for</strong>mer were camouflaged due to loss in wood content.<br />

Prophylactic treatment with mixture of sodium-pentachlorophenate-boric acid-borax affected a saving<br />

of nearly 60 percent, in terms of pulp yield, in green material over a storage period of one year. Single<br />

treatment at the time of making a stack has a limited scope as the chemicals are leachable. However,<br />

the savings affected make the treatment economically viable.<br />

565. Satish Kumar; Dobriyal, P.B. 1990. Management of biodegradation of timber logs <strong>and</strong><br />

bamboos during storage: A review <strong>for</strong> Indian conditions. Journal of the Timber<br />

Development Association of India 36(3): 5-14.<br />

Studies on the effect of storage of pulp wood revealed that untreated material attacked by borer<br />

<strong>and</strong> fungi while the treated material degraded less. The degree <strong>and</strong> type of attack depend on the<br />

climatic conditions <strong>and</strong> the moisture content of the wood. Borer <strong>and</strong> fungus attack influence the pulp<br />

yield <strong>and</strong> cause appreciable decrease in strength properties of paper. It is reported that prophylactic<br />

treatment of bamboos with effective chemicals can affect considerable savings in wood raw materials.<br />

The best treatment was found to be with 2.5 per cent solution of Boric acid, Borax <strong>and</strong> Sodium<br />

pentachlorophenate (1:1:05). Laboratory screening tests on fungicides/insecticides revealed several<br />

<strong>for</strong>mulations to be tried <strong>for</strong> field application.<br />

73


566. Singh, M.M. 1977. Summary of FRI investigation on affects of storage on paper making<br />

raw materials. IPPTA Zonal Seminar on Af<strong>for</strong>estation, Exploitation <strong>and</strong> Preservation of<br />

Forest Raw Materials, 1977, Dehra Dun.<br />

567. Sulaiman, O; Murphy, R.J. 1992. The development of soft rot decay in bamboo fibres.<br />

Twentythird Annual Meeting - <strong>International</strong> Research Group on Wood Preservation,<br />

Harrogate, United Kingdom, 10-15 May 1992: 17p.<br />

568. Sulaiman, O; Murphy, R.J. 1995. Ultrastructure of soft rot decay in bamboo cell walls.<br />

Material und Organismen 29(4): 241-253.<br />

The penetration of soft rot (Chaetomium globosum) hyphae <strong>and</strong> cavity <strong>for</strong>mation was greatly<br />

influenced by the microfibrillar orientation of bamboo (Phyllostachys viridi-glaucescens) cell walls.<br />

Penetration hyphae normally changed direction when they encountered a different microfibrillar<br />

orientation of the cell wall, particularly associated with a narrow lamella. The microfibrillar structure of<br />

the bamboo cell walls led to the development of 3 types of soft rot branching:typical 'T' branching,<br />

'tangentially' orientated branching <strong>and</strong> 'radially' orientated branching. Penetrating hyphae that grew<br />

tangentially followed the microfibrillar angle of the narrow lamellae <strong>and</strong> the cavity was confined to just<br />

outside the transitional region between the broad <strong>and</strong> narrow lamellae. Radially orientated hyphae<br />

normally traversed across the cell wall either via pits or by direct penetration. Soft rot hyphae were able<br />

to exert a strong mechanical <strong>for</strong>ce to penetrate through the cell wall. Considerable distortion of the<br />

microfibrillar structure of fibre <strong>and</strong> parenchyma cell walls was commonly observed resulting from<br />

penetration hypha <strong>and</strong> during hyphal enlargement accompanying penetration. Lignin played an<br />

important part in decay produced by soft rot fungi. High lignin content was demonstrated to act as a<br />

barrier <strong>for</strong> the development of soft rot as shown in the decay resistance of the compound middle<br />

lamella.<br />

74


Abdul Latif Mohamod 161,294,324,331,458<br />

Abdullah, N 322<br />

Adkoli, N.S 131,132<br />

Aggarwal, R.K 22<br />

Agnihotri, V.G 516<br />

Agshikar, B.M 364<br />

Ahmad, N 265<br />

Aibara, S 245<br />

Akhtaruzzaman, A.F.M 274,376,380,447,448,449,<br />

450,451,472<br />

Alam, M.R 365,443<br />

Alvin, K.L 325,339,340,341,559<br />

American Paper <strong>and</strong> Pulp<br />

Association 23<br />

Anchalee Kamolratanakul 10<br />

Annam Raju, P.V 469,529,536<br />

Aranyaputi, S 63<br />

Arruda, M.C.Q. de 266,267<br />

Ashong, F.W.A 46<br />

Association 23<br />

Atchison, J.E 24<br />

Azuma, J 245<br />

Azzini, A 133,142,260,266,267,366,367,368<br />

Bahadur, O 144<br />

Bajaj, V.D 556<br />

Bajpai, P 444<br />

Bakshi, B.K 539,540,547<br />

Balasubramanian, A 258<br />

Bang, D.S 467<br />

Banthia, K.M 369,370,371,372<br />

Banthia, U.S 415<br />

Bapna, S 500,519<br />

Barrichello, L.E.G 327,373,374<br />

Barua, I.B 365,443<br />

Bawagan, P.V 59,268<br />

Beeson, C.F.C 541<br />

Beinhoff, O 282<br />

Belvin, W.L 25<br />

Beri, R.M 135<br />

Bh<strong>and</strong>ari, K.S 445<br />

Bh<strong>and</strong>ari, S.S 193,318<br />

Bharathi, S 236<br />

Bharatia, D.K 375<br />

Bhargava, G.G 217,470,494<br />

Bhargava, K.S 256,486,487,531,532<br />

Bhargava, M.P 26,136,137,446<br />

Bhargava, R.L 227,501<br />

Bhat, A.S 86<br />

Bhat, R.K 501<br />

Bhat, R.V 1,27,269,270,271,272,273,435,436,<br />

475,488<br />

Bhola, P.P 41,218,316,353,354,384,420,483,493,<br />

508,533,534<br />

Author Index<br />

75<br />

Bhowmick, K 274,376,447,448,449,450<br />

Bist, D.P.S 275,276<br />

Bist, V 511,530<br />

Biswas, B 28,410<br />

Biyani, B.P 377,378<br />

Bolker, H.I 379<br />

Bose, J.L 293<br />

Bose, S.K 380,451<br />

Bourdillon, T.F 138<br />

Bridgwater, A.V 67<br />

Browning B.L 381<br />

Bunchu Pakotiprapha 29<br />

Cai Mingde 2<br />

Cao, D.Y 213<br />

Carrasco, F 67<br />

Carrasco, N 30<br />

Casin, R.F 238<br />

CCF, Madhya Pradesh 3<br />

Chacko, V.J 117<br />

Chaliha, P.B 411,412<br />

Ch<strong>and</strong>, S 511<br />

Ch<strong>and</strong>ra, A 542,543,544<br />

Ch<strong>and</strong>ra, R 31,548<br />

Ch<strong>and</strong>rasekharan, C 476<br />

Chang, F.J 139,382<br />

Chang, T.C 545<br />

Chao, S.C 360,452<br />

Chapman, G.P 250,341<br />

Chary, K.N 348<br />

Chattar Singh 26,137,446<br />

Chatterji, R.N 223<br />

Chaudhari, R.R 87<br />

Chen, H.L 130<br />

Chen, J.X 453<br />

Chen, J.Y 242<br />

Chen, R.Y 545<br />

Chen, S.C 361,383<br />

Chen, W.L 140<br />

Chen, Y.D 243<br />

Chiang, P.Y 249<br />

Chiou, C.H 334,489<br />

Chiu, C.H 334<br />

Chowdhary, A.R 233,352,380,451<br />

Chowdhury, K.A 435,436<br />

Chu, W.F 326<br />

Ciaramello, D 141,142,181,266,267,368<br />

Clark, T.F 32,418<br />

Colodette, J.L 454<br />

Conde, A.R 253<br />

Correa de A 143<br />

CSIR, India 88,89<br />

Cunningham, R.L 32<br />

Das, P 233


Das, S.C 233<br />

Deb, D.B 90<br />

Deb, U.K 236<br />

Desai, B.P 91,92<br />

Deshmukh, D.K 93<br />

Desp<strong>and</strong>e, P.R 143a<br />

Dev, I 554<br />

Devgan, R.C 425<br />

Devi, N 384<br />

Dhawan, R 78,278,385<br />

Dhondiyal, S.N 144,392<br />

Doat, J 279,502<br />

Dobriyal, P.B 145,551,552,553,554,<br />

564,565<br />

Dong, J.W 251<br />

Donofrio, C.P 162<br />

Du, H.T 386<br />

Dubey, R.K 490<br />

Duh, M.H 139<br />

Dwivedi, R.P 217,490<br />

Eberhardt, L 362<br />

Ekwebelam, S.A 33<br />

El Bassam, N 146<br />

Eriksson, K.E 503<br />

Escolano, J.O 59,147,387,390,471<br />

Espiloy, Z.B 238,280<br />

Exconde, T.A.R 499<br />

Faix, O 281,282,283<br />

Fan, X.F 251<br />

FAO 34<br />

Farkas, J 389,403<br />

Faul, K.K 504<br />

Fazanaro, R 327<br />

Felix, G.T 387<br />

Fellegi, J 4,528<br />

Fengel, D 35,244,284<br />

Fleury, J.E 177<br />

Foelkel, C.E.B 327,373,374<br />

FPRDI 148<br />

Fraipont, L 200,431<br />

Francis, K 119,350,351<br />

Frazao, F.J.L 143<br />

Frison, E 149<br />

Fu, M.Y 242<br />

Fujii, Y 245<br />

Fujita, M 320<br />

Fukuyama, G 150,388<br />

Gabir, S 105<br />

Gajdos, J 389,403<br />

Gamble, J.S 94<br />

Gantayet, R.G 256<br />

Garceau, J.J 67<br />

Gardener, J.C.M 546<br />

Garg, R.K 151<br />

George, M 119<br />

Ghosh, D 236<br />

76<br />

Ghosh, P.C 404<br />

Ghosh, P.K 5<br />

Ghosh, S.R 491<br />

Ghosh, S.S 246<br />

Giri, S.S 247<br />

Gnanaharan, R 560<br />

Goel, S 5<br />

Gohain, P.D 412<br />

Gomide, J.L 248,253,454,474<br />

Gondim, T.R.M.A 367<br />

Gong, J.P 243<br />

Gonzalez, T 390<br />

Gonzalez Vila, F.J 305<br />

Gopal, A.V 505<br />

Gopich<strong>and</strong>, K 413<br />

Gorbatsovisch, S.N 378<br />

Goring, D.A.I 461<br />

Goswami, N.C 472<br />

Goswami, T 36<br />

Goyal, P 5,455,492<br />

Goyel, R 5<br />

Grant, J 37,506<br />

Gremler, E.R 391<br />

Grosser, D 336<br />

Gu, X.P 95<br />

Guang-zhi, Z 215<br />

Guha, S.R.D 6,27,38,39,40,41,42,96,<br />

152,153,154,155,156,194,269,270,271,275,<br />

276,285,295,307,311,313,384,392,393,394,<br />

395,396,397,398,416,420,429,430,457,457a,<br />

493,507,508,509,510,512,515,539,540,542,<br />

543,544,547,548<br />

Gulati, A.S 457a<br />

Gupta, N.K 477<br />

Gupta, R.K 531<br />

Gupta, S 539<br />

Gupta, T 7<br />

Gupte, V.M 13<br />

Han, H 286<br />

H<strong>and</strong>igol, M.P.H 465,466<br />

Hanzawa, M 440<br />

Harikishore 527<br />

Harris, J.F 43<br />

Hasan, S.M 97<br />

Hasegava, T 287<br />

Hayes, M.H.B 209<br />

Hegde, N.G 98<br />

Heremans, R 159<br />

Higaki, M 319<br />

Higuchi, T 72,288,289,290,291,299,308<br />

Hirknnawar, S 5<br />

Hodge, W.H 99<br />

Hontoy, J 219<br />

Horio, M 477a<br />

Htway, D.K 496,557<br />

Hu, A.Q 329


Hu, C.Z 328<br />

Huang Jingsheng 568<br />

Huang, L.Y 329<br />

Huang, S.K 222<br />

Huang, Y.C 129<br />

Hukuhara, S 201<br />

Hunter, I.R 157<br />

Hwang, J.S 249<br />

Hwang, S.G 222<br />

ICFRE 100<br />

Idei, T 292,321<br />

Iijima, T 319<br />

Imagawa, H 239,298<br />

Imai, M 202<br />

INBAR 158<br />

Ingle, T.R 293<br />

Interox, S.A 516<br />

Islam, M.A 407<br />

Islam, N 443<br />

Islam, S 511<br />

Isono, Z 399,400,401,402,432<br />

Istas, J.R 44,159,160,219,220<br />

Ito, M 287<br />

Jadhav, A.G 393,397<br />

Jain, D.K 512<br />

Jain, K.D 313,317<br />

Jain, R.C 397<br />

Jain, S.C 477<br />

Jakab, E 281<br />

Jakob, K 146<br />

Jalil, A.A 161,324,330,331,458<br />

Jamaludin, K 161,294,324,330,331,458<br />

Janci, J 389,403<br />

Janmejay, L.S 247<br />

Jaspal, N.S 171,227,272,465,466,498<br />

Jauhari, M.B 404<br />

Jena, S.C 406<br />

Jha, Y.P 101<br />

Jivendra 500,519<br />

Joedodibroto, R 45<br />

Joglekar, M.H 162<br />

Johansson, G 314<br />

Joshi, H.C 428<br />

Joshi, R.C 415,494<br />

Jung, T.M 259<br />

Jurasck, L 493a<br />

Kadambi, K 46<br />

Kadarisman, D 405<br />

Kaitpraneet, W 102<br />

Kala, R.P 221<br />

Kalra, K.K 553,564<br />

K<strong>and</strong>elaki, T.E 103<br />

Kang, T.Y 222<br />

Kang, Z.Y 222<br />

Kapoor, S.K 236,295<br />

Kar, S.K 406<br />

77<br />

Karim, M.S 407<br />

Karira, B.G 42,78<br />

Karira, K.K 78<br />

Karnik, M.G 104,135,265,296,297,477b,478,<br />

479,480,480a,488<br />

Kashihara, M 82<br />

Kato, F 408,409<br />

Kato, H 47<br />

Kato, N 319<br />

Kato, Y 201<br />

Kaul, S.S 490<br />

Kawai, S 81,82<br />

Kawamura, I 289<br />

Kawase, K 150,239,298,388<br />

Kedharnath, S 223<br />

Khalid ul Islam, M 407<br />

Khan, A.B 365<br />

Khan, M.A.W 117<br />

Kh<strong>and</strong>uri, S.C 410<br />

Khanna, P.P 513<br />

Khare, A 494<br />

Khoo, K.C 324,331<br />

Khristov, T 105<br />

Khristova, P 105<br />

Kiang, T 163,363<br />

Kirk, T.K 503<br />

Kirkpatrick, T.W 549<br />

Kitamura, H 164,332<br />

Kitamura, T 72<br />

Kitpraneet, W 102<br />

Kocholia, R.S 5<br />

Kokta, B.V 67<br />

Kolambe, S.L 462<br />

Koorse, G.M 459,460<br />

Koshijima, T 301,302<br />

Kothari, M.B 56<br />

Kothari, R.M 151<br />

Kozukue, E 550<br />

Kozukue, N 550<br />

Kraebel, C.J 363<br />

Krishnagopalan, A 333,514<br />

Krishnamachari, K.S 48<br />

Ku, Y.C 165,166,167,224,334<br />

Kuang, S.J 461<br />

Kulkarni, A.G 236,462<br />

Kulkarni, A.Y 49,500,519<br />

Kumar, A 515<br />

Kumar, K 39<br />

Kumar, M 118<br />

Kumar, P.P 229<br />

Kumar, S 551,552,553,554,555<br />

Kuo, L.S 382<br />

Kuroda, H 299<br />

Kutscha, N.P 514<br />

Kyaw, Z.U 496,557<br />

Labarre, E.J 50


Lakshmana, A.C 106<br />

Lakshmi Sharma 354<br />

Lal, K 353<br />

Lan, X.G 328<br />

Lange, W 282<br />

Ledoux, P 516<br />

Lee, S.L 230<br />

Lele, P.S 480b<br />

Li Yuanzhong 168<br />

Li, Q 335<br />

Li, R.G 242<br />

Li, X.L 243<br />

Liang, W.Y 95,129<br />

Libby, C.E 7a<br />

Liese, W 250,254,255,336,344<br />

Likit Harnjangsit 10<br />

Lin, J.G 251<br />

Lin, J.H 212<br />

Lin, S.C 361,383<br />

Lin, S.D 251<br />

Lin, S.J 361,383<br />

Lin, W.C 163<br />

Lin, Y.F 95,129<br />

Liou, J.L 264<br />

Lirn, T.R 438,537<br />

Liu, M.S 545<br />

Lopez, F.R 238<br />

Lorey, F.W 378<br />

Lu, Z.J 538<br />

Lunde, H 362a<br />

Luo, C.C 463<br />

Luo, L.F 212<br />

Luz, C.N.R 143<br />

Ma Naxiun 169,286<br />

Ma, L.F 286,337<br />

Ma, N.X 213<br />

Madan, R.N 78,252,263<br />

Madhav Gadgil 107<br />

Maekawa, E 300,301,302<br />

Mahanta, D 303,411,412<br />

Maheshwari, D.K 487<br />

Maheshwari, H.K 526<br />

Maheshwari, S 51,170,171,172,173,174,175,176,<br />

225,226,227,228,304,406,413,464,495,500,<br />

517,518,519,556<br />

Maheswari, O.N 556<br />

Mai-Aung, U 177,496,520,557<br />

Mall, I.D 52<br />

Manfredi, V 327<br />

Mantri, T.C 236<br />

Marchessault, R.H 245<br />

Martin, F 305<br />

Martin, M 107a<br />

78<br />

Mathew, G 558,560<br />

Mathur, C.M 40<br />

Mathur, G.M 144,317,392,457<br />

Mathur, R.M 462,528<br />

Matsui, Z 178<br />

Matsumoto, A 473<br />

Mazzei, F.M 179<br />

McCormac, C.W 108<br />

McGorovern, J.N 180,391,414<br />

Medina, J.C 181<br />

Meier, D 283<br />

Merck, A.G.E 53<br />

Meshramkar, P.M 171<br />

Mian, A.J 274,376, 447,448,449,450<br />

Mishra, B.P 415<br />

Mishra, N.D 54,55,56,57,229,369,369a,370,371,<br />

372,456,492<br />

Misra, D.K 521<br />

Mithal, K.C 398,509<br />

Mizuno, T 421,422,423<br />

Mohan, S.M 470<br />

Mohanty, A.P 109<br />

Monsalud, M.R 8,58,59,338,471<br />

Montalvao Filho, A 253<br />

Monteiro, R.F.R 306<br />

Mooney, H.F 110<br />

Morak, A.J 297<br />

Moredo, C.C. 499<br />

Morin, F.G 245<br />

Mottet, A 200,431<br />

Moulik, S 111<br />

Mukherjea, V.N 79,182,307,416<br />

Murakami, K 208,356,357<br />

Murphy, R.J 325,339,340,341,559,567,568<br />

Murthy, K.S 236<br />

Murthy, N.V.S.R 469,529,536<br />

Nafziger, T.R 417<br />

Nagai, V 368<br />

Nagaiah, K 229<br />

Nagamori, N 441<br />

Nagashima, T 164<br />

Nair, K.S 112<br />

Nair, K.S.S 558,560<br />

Nair, P.N 9<br />

Nair, V.K.S 42,60<br />

Naiyana Niyomwan 10<br />

Nakatsubo, F 291,308<br />

Nanko, H 357<br />

Narendra Prasad, S 107<br />

Navarro, J.R 419<br />

Nazak, R.G 465,466<br />

Negi, J.S 309,310,394<br />

Negi, S.S 246<br />

Nelson, G.H 61<br />

Nepenin, N 467<br />

Nerurkar, D.L 5


Ni, M.A 243<br />

Nicholas, P.M 419<br />

Nicholas, P.O 387<br />

Nicholson, J.W 113<br />

Nirankari Devi 420<br />

Nomura, T 183,342<br />

Oberoi, M.S 532<br />

Ohrnberger, D 114<br />

Okamura, K 245<br />

Oliveira R.C. de 454<br />

Om Bahadur 457<br />

Ono, K 12,184,399,400,401,402,432,433<br />

Ota, M 343<br />

Oye, R 421,422,423,522<br />

Pakotiprapha, B 230<br />

Pama, R.P 230<br />

Pan, T.T 224,360,452<br />

P<strong>and</strong>e, G.C 62,523,524,525<br />

P<strong>and</strong>e, S.P 271<br />

P<strong>and</strong>it, S.V 13<br />

Pant, P.C 285,395,396<br />

Pant, R 6,311,427,462,511,527,528,530<br />

Pant, R.K 540<br />

Paquot, M 200,431<br />

Parameswaran, N 254,344<br />

Parekh, M.C 229<br />

Parkhe, P.M 49<br />

Pasaribu, R.A 497<br />

Patel, M 345,349<br />

Patnaik, J.K 256<br />

Pattanath, P.G 346<br />

Pearson, R.S 186,187,188<br />

Perdue, R.E 363<br />

Pesantes Rebaza, M.A 115<br />

Pharasi, S.C 135<br />

Podder, V 14,15<br />

Prasad, A.K 562<br />

Prasad, J 116<br />

Pravin, G 468<br />

Premrasmi, T 63<br />

Preston, R.D 347<br />

Pulp <strong>and</strong> Paper Canada 16<br />

Puntambekar, P.P 13<br />

Purkayastha, S.K 353,354,533,534<br />

Purushotham, A 561<br />

Qiu, F.G 64<br />

Quin, W.L 243<br />

Raekaelboom, E.L 159,160,220<br />

Raghuveer, S 73<br />

Rai, A.K 237<br />

Rai, P.A 498<br />

Raitt, W 65,231,232,424<br />

Rajan, T.N.S 5<br />

Rajulu, A.V 348<br />

Ramanathan, T 66<br />

Ramaswami, V 66<br />

79<br />

Ramsarma, B.V 481<br />

Rangan, S.G 48<br />

Rao, A.R.K 4,526,528<br />

Rao, A.V 57,369a,370,371,372<br />

Rao, B.Y 364<br />

Rao, G.M 369a,370,371,372<br />

Rao, M.N.R 527,528<br />

Rao, M.S 364<br />

Rao, P.J.M 17,256<br />

Rao, V.G 469,529<br />

Ravindranathan, N 48<br />

Rawat Rajesh 470<br />

Ray, A.K 67<br />

Razzaque, M.A 68,233<br />

Reddy, D.V 48<br />

Reddy, G.R 148<br />

Reddy, V.G 501<br />

Rediko, B.V.P 179<br />

Rehman, A 412<br />

Revol, J.F 461<br />

Rita Dhawan 312<br />

Rodriguez, S.K 69<br />

Romana, M.S.S 499<br />

Roy, T.K 236,530<br />

Rydholm, S.A 70,71<br />

Sabharwal, H.S 313<br />

Saboo, R.N 482<br />

Sadawarte, N.S 562<br />

Sagreiya, K.P 117<br />

Sahu, A.K 349<br />

Sahunalu, P 102<br />

Sai Ram, M 563<br />

Saiki, H 320<br />

Saikia, C.N 36,491<br />

Saini, B.K 318<br />

Saiz Jimenez, C 305<br />

Sakamoto, I 164<br />

Sakata, I 441<br />

Saksena, U.L 5<br />

Salgado A.L. de B 266,267<br />

Salvador 30<br />

Samapuddhi, K 257<br />

Sanyal, A.K 425<br />

Sasaki, H 81,82<br />

Satish Kumar 145,564,565<br />

Sato, A 72,290<br />

Sato, K 298<br />

Satonaka, S 388,440<br />

Satpathy, K.C 172,173,174,175,176,228<br />

Satyanarayana, G 73<br />

Sayeed, M 233<br />

Schallinger, K.M 209<br />

Schowing, A.G 314<br />

Schwenzon, K 74,75<br />

Seabra, L-de 189<br />

Seenayya, G 563


Seethalakshmi, K.K 118<br />

Sekhar, T 258<br />

Sekyere, D 234<br />

Semana, J.A 147,238,426,471<br />

Sen, D.L 480<br />

Seth, V.K 18,19<br />

Shah, M.A 472<br />

Shah, N 7<br />

Shanmughavel, P 119,190,235,350,351<br />

Shao, X 244,284<br />

Shao-nan, C 215<br />

Sharma, G.D 470<br />

Sharma, G.S.R.P 469,529,536<br />

Sharma, L 533<br />

Sharma, M.C 487,532<br />

Sharma, R.K 151<br />

Sharma, Y.K 38,39,40,393,397,427,457a,507,534<br />

Sharma, Y.M.L 120,121<br />

Sheikh, M.A 191<br />

Sheng, H.J 264<br />

Shi, Q.T 129<br />

Shimada, M 299,315<br />

Shin, D.S 259<br />

Shukla, K.S 554<br />

Siddique, A.B 68,352<br />

Sieber, R 19a<br />

Silitonga, T 405,497<br />

Simar, G.L 514<br />

Simionescu, C 482a,482b,482c<br />

Simmonds, N.W 549<br />

Sindall, R.W 192<br />

Singh, A.R 52<br />

Singh, K 347<br />

Singh, M.M 41,42,76,77,78,79,275,276,311,313,<br />

316,317,353,354,379,384,398,415,420,427,<br />

457a,483,490,493,494,508,509,510,515,531,<br />

532,533,534,555,566<br />

Singh, S 122,353,540<br />

Singh, S.P 193,237,318,428,507,510<br />

Singh, S.V 193,194,236,237,275,276,278,312,<br />

318,429,430,512,515<br />

Skoupy, J 97<br />

Soundararajan, T.N 501<br />

Sproull, R.C 472a<br />

Srinivasan, G 526<br />

Stevens, R.H 80<br />

Stracey, P.D 195<br />

Subhash, M 535<br />

Subramanian, K 92<br />

Sude, Y 236<br />

Sugiharto, A 45<br />

Sulaiman, O 567,568<br />

Suleiman, K.M 196<br />

Suman, S 535<br />

Sumg, Y.H 20<br />

Surendran, P.N 123<br />

80<br />

Susuki, S 197<br />

Suzuki, H 484<br />

Swaleh, M 513<br />

Szekely, T 281<br />

Takei, T 319<br />

Takhama, M 477a<br />

Tamolang, F.N 8,238,355<br />

Tan, Y.F 559<br />

Tanahashi, M 290,291,308<br />

T<strong>and</strong>on, R.C 551<br />

Taneja, K 540<br />

Tang, Y.Y 21<br />

Tewari, D.N 124<br />

Thaiutsa, B 102<br />

Thapar, H.S 547<br />

Thonart, P 200,431<br />

Tian, X.P 212<br />

Tian-jian, H 215<br />

Till, F 281<br />

Tipre, D.S 551<br />

Tissot, M 198<br />

Tomazello Filho, M 260,266,267<br />

Tono, T 261<br />

Torres, M 69<br />

Trivedi, R 345<br />

Tsai, L.H 489<br />

Tsai, M.J 545<br />

Tshiamala, T 199,200,431<br />

Tsuchida, H 550<br />

Tsuji, H 432,433<br />

Tutiya, M 201,202<br />

Ujiie, M 239,298,473<br />

Ukil, T 203<br />

Upadhya, Y.D 52<br />

Upadyay, S.N 52<br />

Uppin, S.F 125<br />

Uriate, M.T 206<br />

Uriate, N.S 206<br />

Vaclav, E 97<br />

Vaikuntam, K 73<br />

Varma, R.V 560<br />

Varshney, M.C 262<br />

Veeramani, H 375,459,460<br />

Venkatappa Setty, K.R 126<br />

Venkobarao, G 536<br />

Vidyasagar, C.H.V 529,536<br />

Vijan, A.R 252,263<br />

Vilar, R 248<br />

Villavicencio, E.J 204<br />

Vincent, H 205<br />

Viramani, K.C 27,273,475<br />

Virtucio, F.D 206<br />

Vivone, R.R 248,474<br />

Vroom, K 434<br />

Vyas, G.M 435,436<br />

Waheed khan, M.A 127,128,207


Wai, N.N 208,356,357<br />

Wang Guorong 2<br />

Wang Songxue 2<br />

Wang, H 437,438,537<br />

Wang, K.T 439<br />

Wang, Y.F 463<br />

Wang, Y.J 167<br />

Wang, Z.W 485<br />

Ward, K 297<br />

Wegner, G 35<br />

Weiner, G 250<br />

Wilson, J 209<br />

Witkoski, C.J 210<br />

Wolff, I.A 418<br />

Wu, H.Y 212<br />

Wu, S.C 264<br />

Wu, Z.H 240<br />

Xia, N.H 241<br />

Xia, Y.F 358<br />

Xiang, Y.M 323<br />

Xiao, J.H 95,130<br />

Xie, J.H 242<br />

Xie, T.M 538<br />

Xu, Q.F 240<br />

Yamada, T 342<br />

Yamagishi, K 440<br />

Yamaguchi, H 441<br />

Yamawaki, T 82<br />

Yang, L.P 328<br />

Yang, X.S 129<br />

Yao, G.Y 442<br />

81<br />

Yao, H.S 326<br />

Ye, K.L 211<br />

Yi, C.Q 213<br />

Yoshida, Y 82<br />

Yoshinaga, A 320<br />

Yoshizawa, N 321<br />

Yu, J.L 453<br />

Yuan, Y.P 130<br />

Zafar, S.I 322<br />

Zamuco, G.I.T 359<br />

Zeng, J 358<br />

Zeng, M.C 323<br />

Zhan, H.Y 453<br />

Zhang, A.L 242<br />

Zhang, C 95<br />

Zhang, H.M 213<br />

Zhang, J.W 286<br />

Zhang, M 81,82<br />

Zhang, Q.S 212<br />

Zhang, W.Y 213<br />

Zhang, X 214<br />

Zheng Qingyan 168<br />

Zhen-xing, S 215<br />

Zhou, D.S 213<br />

Zhou, J.Y 328<br />

Zhu, L.F 329<br />

Zhu, L.Q 337<br />

Zhu, W.S 130<br />

Zou, Z.X 442<br />

Zu, Z.W 286

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